二次电池电极材料

固态电解质

无负极电池

(60) Yanfeng Zhang, Qiankun Meng, Ao Zeng, Shuaiqin Qiu, Hong Zhang, Enyue Zhao,*and Xiaoling Xiao*, Minutes-Scale Ultrafast Synthesis of New Oxyhalides Solid Electrolytes with Interfacial Ionic Conduction for All-Solid-State Batteries, Angew. Chem. Int. Ed. 2025, e16259.

(59) Ao Zeng, Na Li, Hong Zhang, Shuaiqin Qiu, Zihan Xu, Yanfeng Zhang, Wen Yin, Enyue Zhao,* and Xiaoling Xiao*, Anchoring Ligand Electron Enables Robust Metal-Oxygen Coordination Toward 4.5 V O3-Type Sodium-Ion Battery Cathodes, Angew. Chem. Int. Ed. 2025, e202514220.

(58) Jianyue Jiao, Hong Zhang, Ao Zeng, Enyue Zhao,* and Xiaoling Xiao*, Oxygen Stacking Controlled Cyclic Capacity and Stability of Layered Oxide Cathodes, Adv. Funct. Mater. 2025, e21704.

(57) Hong Zhang , Ao Zeng , Zhigang Zhang , Hua He , Yanwu Zhai , Tao He , Zhenbang Xu , Yoshihiro Kuroiwa , Sangwook Kim , Enyue Zhao, Xiaoling Xiao *, A dispersed buffer phase enables mitigated stress toward stable 4.6 V Graphite||NCM811 batteries, Materials Today 88 (2025) 382–392.

(56) Zihan Xu, Ao Zeng, Hong Zhang, Rongbin Dang,* Hua He, Yanwu Zhai, Enyue Zhao,*and Xiaoling Xiao*, One-Step Carbonization Tailored Functional Groups and Micropores toward Fast and Durable Na-Ion Storage inHard Carbon, Small 2025, 2503945.

(55) Na Li, Enyue Zhao,* Zhigang Zhang, Wen Yin, Lunhua He, Baotian Wang,Fangwei Wang, Xiaoling Xiao,* and Jinkui Zhao*, Gradient and De-Clustered Anionic Redox Enabled Undetectable O2 Formation in 4.5 V Sodium Manganese Oxide Cathodes, Adv. Mater. 2024, 2408984.

(54) Jianyue Jiao, Enyue Zhao,* Wen Yin, Jing Che, Yong Cheng, Zhengchang Xia, Xiaoling Xiao,* and Xingwang Zhang*, Revealing Roles of High-Electronegativity Fluorine Atoms in Boosting Redox Potential of Layered Sodium Cathodes, Small 2024, 2400483.

(53) Ao Zeng, Jianyue Jiao, Hong Zhang, Enyue Zhao,* Tao He, Zhenbang Xu, and Xiaoling Xiao*. Slow-Released Cationic Redox Activity Promoted Stable Anionic Redox and Suppressed Jahn−Teller Distortion in Layered Sodium Manganese Oxides, ACS Appl. Mater. Interfaces 2024, 16, 7119−7129.

(52)Na Li, Enyue Zhao*, Zhigang Zhang, Wen Yin , Bao-Tian Wang, Xiaoling Xiao*．De-clustered nonbonding oxygen state inhibits oxygen dimerization for highly activated and stable anionic redox in sodium-based layered cathodes, Chemical Engineering Journal, Volume 466, 15 June 2023, 143145.

(51) A. Zeng, J. Jiao, H. Zhang, E. Zhao*, W. Yin, B.-T. Wang,Xiaoling Xiao*．Clarifying effects of in-plane cationic-ordering degree on anionic redox chemistry in Na-ion battery layered oxide cathodes,　Materials Today Chemistry, Volume 30, June 2023, 101532.

(50) Jianyue Jiao，Hongquan Song，Enyue Zhao*，Wen Yin，Xiaoling Xiao*．Quantifying Effects of Ligand–Metal Bond Covalency on Oxygen-Redox Electrochemistry in Layered Oxide Cathodes，Inorg. Chem. 2023, 62, 18, 7045–7052.

(49) Jianyue Jiao, Zhigang Zhang, Yoshihiro Kuroiwa, Enyue Zhao*, Wen Yin, Baotian Wang, Fangwei Wang, Jinkui Zhao, Xingwang Zhang, Xiaoling Xiao*．Enabling robust anionic redox structure via tuning the symmetry of locally ordered lattice in Li-rich Li-Mn-O cathodes, Chemical Engineering Journal, Volume 454, Part 3, 15 February 2023, 140327.

(48) Kang Wu, Enyue Zhao*, Peilin Ran, Wen Yin, Zhigang Zhang, Bao-Tian Wang, Kazutaka Ikeda, Toshiya Otomo,  Xiaoling Xiao*, Fangwei Wang, Jinkui Zhao*. Localizing Oxygen Lattice Evolutions Eliminates Oxygen Release and Voltage Decay in All-Mn-Based Li-Rich Cathodes, Small, Volume19, Issue18, May 3, 2023, 2300419.

(47) Jianyue Jiao, Kang Wu, Na Li, Enyue Zhao*, Wen Yin, Zhongbo Hu, Fangwei Wang, Jinkui Zhao, Xiaoling Xiao*. Tuning anionic redox activity to boost high-performance sodium-storage in low-cost Na0.67Fe0.5Mn0.5O2 cathode, Journal of Energy Chemistry, Volume 73, October 2022, Pages 214-222.

(46) Rongbin Dang, Qing-Bo Yan, Enyue Zhao*, Na Li, Kang Wu, Zhongjun Chen, Zhonghua Wu, Xiangfeng Liu, Zhongbo Hu and Xiaoling Xiao*.Designing a durable high-rate K0.45Ni0.1Fe0.1Mn0.8O2 cathode for K-ion batteries: A joint study of theory and experiment. Science China Materials, 2022, 65, 1741-1750.

(45) Hong Zhang,　Kang Wu, Na Li, Xin Deng, Jianyue Jiao, Enyue Zhao*, Wen Yin, Baotian Wang, Jinkui Zhao, and Xiaoling Xiao*．Enhancing Thermal and High-Voltage Cycling Stability of Ni-Rich Layered Cathodes through a　Ti-Doping-Induced Surface-Disordered Structure,　ACS Appl. Energy Mater.　2022, 5, 10, 12673–12681.

(44) Na Li, Shaofei Wang, Enyue Zhao*, Wen Yin, Zhigang Zhang, Kang Wu, Juping Xu,Yoshihiro Kuroiwa, Zhongbo Hu, Fangwei Wang, Jinkui Zhao, Xiaoling Xiao*.Tailoring interphase structure to enable high-rate, durable sodium-ion battery cathode, Journal of Energy Chemistry, 2022,68, 564-571. 

(43) Kang Wu, Na Li, Kuanrong Hao, Wen Yin, Min Wang, Guofeng Jia, Yu Lin Lee, Rongbin Dang, Xin Deng, Xiaoling Xiao*, Enyue Zhao*, and Zhijian Wu*. Multiple Influences of Nickel Concentration Gradient Structure and Yttrium Element Substitution on the Structural and Electrochemical Performances of the NaNi0.25Mn0.25Fe0.5O2 Cathode Material, The Journal of Physical Chemistry C  2021, 125, 37, 20171-20183.

(42) Kang Wu, Jianyue Jiao, Na Li, Min Wang, Guofeng Jia, Yu Lin Lee, Rongbin Dang, Xin Deng, Xiaoling Xiao*, and Zhijian Wu*. Revealing the Multiple Influences of Zr Substitution on the Structural and Electrochemical Behavior of High Nickel LiNi0.8Co0.1Mn0.1O2 Cathode Material, The Journal of Physical Chemistry C.2021, 125, 19, 10260-10273.

(41) Xin Deng, Kang Wu, Rongbin Dang, Na Li, Hong Zhang, Jianyue Jiao, Yulin Lee, Zhongbo Hu and Xiaoling Xiao* . A Comprehensive Solution for Ni-Rich Cathodes by Lithium Silicate Coating. Journal of The Electrochemical Society, 2021, 168(5):050539. 

(40) Jianyue Jiao, Kang Wu, Rongbin Dang, Na Li, Xin Deng, Xiangfeng Liu, Zhongbo Hu, Xiaoling Xiao*, A collaborative strategy with ionic conductive Na2SiO3 coating and Si doping of P2-Na0.67Fe0.5Mn0.5O2 cathode: An effective solution to capacity attenuation, Electrochimica Acta,  2021, 384, 138362.

(39) Na Li, Kang Wu, Yulin Lee, Dang Rongbin, Xin Deng, Zhongbo Hu, Xiaoling Xiao*, A comprehensive study of the multiple effects of Y/Al substitution on O3-type NaNi0.33Mn0.33Fe0.33O2with improved cycling stability and rate capability for Na-ion battery applications, Nanoscale, 2020, 12, 16831-16839.

(38) Kang Wu, Junyang Wang, Qi Li, Yuqiang Yang, Xin Deng, Rongbin Dang, Meimei Wu, Zhijian Wu, Xiaoling Xiao* and  Xiqian Yu*,In situ synthesis of a nickel concentration gradient structure of Ni-rich LiNi_0.8Co_0.15Al_0.05O₂ with promising superior electrochemical properties at high cut-off voltage, Nanoscale, 2020, 12, 11182-11191.

(37) Rongbin Dang, Na Li, Yuqiang Yang, Kang Wu, Qingyuan Li , YuLin Lee, Xiangfeng Liu, Zhongbo Hu, Xiaoling Xiao*, Designing advanced P3-type K_0.45Ni_0.1Co_0.1Mn_0.8O₂ and improving electrochemical performance via Al/Mg doping as a new cathode Material for potassium-ion batteries, Journal of Power Sources,  2020, 464, 228190.

(36) Jing Ren, Rongbin Dang , Yuqiang Yang, Kang Wu, Yulin Lee, Zhongbo Hu, Xiaoling Xiao*, Min Wang*, Core–Shell Structure and X‐Doped (X = Li, Zr) Comodified O3‐NaNi_0.5Mn_0.5O₂: Excellent Electrochemical Performance as Cathode Materials of Sodium‐Ion Batteries, Energy Technology,  2020, 8, 1901504.

(35) Yuqiang Yang, Rongbin Dang, Kang Wu, Qi Li, Na Li, Zhongbo Hu, Xiaoling Xiao*, Semiconductor Material ZnO-Coated P2-type Na_2/3Ni_1/3Mn_2/3O₂ Cathode Materials for Sodium-Ion Batteries with Superior Electrochemical Performance, The Journal of Physical Chemistry C, 2020, 124, 3, 1780-1787.

 (34) Kang Wu, Qi Li, Rongbin Dang, Xin Deng, Minmin Chen , Yu Lin Lee, Xiaoling Xiao*, and Zhongbo Hu*, A novel synthesis strategy to improve cycle stability of LiNi_0.8Mn_0.1Co_0.1O₂ at high cut-off voltages through core–shell structuring, Nano Research, 2019, 12(10): 2460–2467.

 (33) Na Li, Jing Ren, Rongbin Dang, Kang Wu, Yu Lin Lee, Zhongbo Hu, and Xiaoling Xiao*.Suppressing phase transition and improving electrochemical performances of O3-NaNi_1/3Mn_1/3Fe_1/3O₂ through ionic conductive Na₂SiO₃ coating, Journal of Power Sources, 2019, 429, 38-45.

(32) Rongbin Dang, Minmin Chen, Qi Li, Kang Wu, Yu Lin Lee, Zhongbo Hu, and Xiaoling Xiao*. Na+-Conductive Na₂Ti₃O₇-Modified P2-type Na_2/3Ni_1/3Mn_2/3O₂ via a Smart in Situ Coating Approach: Suppressing Na⁺/Vacancy Ordering and P2–O2 Phase Transition, ACS Appl. Mater. Interfaces, 2019, 11 (1), pp 856–864.

(31) Rongbin Dang, Qi Li, Minmin Chen, Zhongbo Hu, Xiaoling Xiao*. CuO Coating and Cu²⁺ Doping Co-modify P2-type Na_2/3[Ni_1/3Mn_2/3]O₂ for Sodium-ion Batteries, Physical Chemistry Chemical Physics,  2019, 21, 314 - 321. 

(30) Qi Li, Rongbin Dang, Minmin Chen, Yulin Lee, Zhongbo Hu, and Xiaoling Xiao*, Synthesis Method for Long Cycle Life Lithium-Ion Cathode Material:Nickel-Rich Core−Shell LiNi_0.8Co_0.1Mn_0.1O₂, ACS Appl. Mater. Interfaces, 2018, 10, 17850–17860.

(29) Qi Li, Kang Wu, Minmin Chen, Yu Lin Lee, Dongfeng Chen, Meimei Wu, Faqiang Li, Xiaoling Xiao*, Zhongbo Hu, Designing High-voltage and High-rate Li_1-xNa_xCoO₂ by Enlarging Li Layer  Spacing,  Electrochimica Acta,  2018, 273, 145-153. 

(28) Guowei Yang, Enyue Zhao, Minmin Chen, Yingzhi Cheng, Li Xue, Zhongbo Hu, Xiaoling Xiao*, Faqiang Li*, Mg doping improving the cycle stability of LiNi0.5Mn0.5O2 at high voltage, Journal of Solid State Electrochemistry, 2017, 21, 3195-3203

(27) Minmin Chen, Enyue Zhao, Dongfeng Chen, Meimei Wu, Songbai Han, Qingzhen Huang, Limei Yang, Xiaoling Xiao* and Zhongbo Hu*,  Decreasing Li/Ni Disorder and Improving the Electrochemical Performances of Ni-Rich LiNi_0.8Co_0.1Mn_0.1O₂ by Ca Doping, Inorganic Chemistry, 2017, 56,8355-8362.

(26) Rongbin Dang, Minmin Chen, Yulin Lee, Yingzhi Cheng, Li Xue, Zhongbo Hu, Xiaoling Xiao*, Xuejie Huang*,  Lithium ion Conductor and Electronic Conductor Co-coating Modified Layered Cathode Material LiNi_1/3Mn_1/3Co_1/3O₂, Electrochimica Acta, 

2017, 247, 443-450. 

(25) Enyue Zhao, Lincan Fang, Minmin Chen, Dongfeng Chen, Qingzhen Huang, Zhongbo Hu, Qing-bo Yan*, Meimei Wu*, Xiaoling Xiao*, New Insight into Li/Ni Disorder in Layered Cathode Materials for Lithium ion Battery: A Joint Study of Neutron Diffraction, Electrochemical Kinetics Analysis and First-principles Calculations, Journal of Materials Chemistry A, 2017, 5, 1679-1686.

(24) Enyue Zhao, Minmin Chen, Zhongbo Hu, Dongfeng Chen, Limei Yang and Xiaoling Xiao*, Improved Cycle Stability of High-capacity Ni-rich LiNi_0.8Mn_0.1Co_0.1O₂ at High Cut-off Voltage by Li₂SiO₃ Coating, Journal of Power Sources, 2017, 343, 345-353.

(23) Minmin Chen, Enyue Zhao, Qingbo Yan, Zhongbo Hu, Xiaoling Xiao*and Dongfeng Chen*, The Effect of Crystal Face of Fe₂O₃ on the Electrochemical Performance for Lithium-ion Batteries, Scientific Reports, 2016, 6, 29381.

(22) Enyue Zhao, Minmin Chen, Zhongbo Hu, Xiaoling Xiao*and Dongfeng Chen*, Layere / Layered Homostyructure Ion Conductor Coating Strategy for High Performance Lithium Ion Batteries, Electrochimica Acta, 2016, 208, 64–70.

(21) Chao Lian, Xiaoling Xiao,  Zheng Chen, Yuxi Liu, Enyue Zhao,  Dingsheng Wang, Chen Chen* and Yadong Li, Preparation of hexagonal ultrathin WO₃ nano-ribbons and their electrochemical performance as an anode material in the lithium ion battery, Nano Research, 2016, 9, 435-441. 

(20) Enyue Zhao, Minmin Chen, Dongfeng Chen, Xiaoling Xiao*, and Zhongbo Hu*,  A Versatile Coating Strategy to Highly Improve the Electrochemical Properties of Layered Oxide LiMO2 (M = Ni_0.5Mn_0.5 and Ni_1/3Mn_1/3Co_1/3), ACS Appl. Mater. Interfaces, 2015, 7(49), 27096–27105.

(19) Enyue Zhao, Xiangfeng Liu, Hu Zhao, Xiaoling Xiao* and Zhongbo Hu*,Ionic Conductivity Li2SiO3 Coating Lithium-rich Layered Oxides Exhibiting High Rate Capability and Low Polarization, Chem. Commun., 2015, 51, 9093-9096.(Cover Paper)

(18) Enyue Zhao, Xiangfeng Liu Zhongbo Hu, Limei Sun, Xiaoling Xiao*,  Facile synthesis and enhanced electrochemical performances of Li₂TiO₃-coated Li-rich layered Li_1.13Ni_0.30Mn_0.57O₂ cathode materials for lithium-ion batteries, Journal of Power Sources, 2015,294,141-149.

(17) Enyue Zhao, Zhongbo Hu, Lei Xie, Xiping Chen, Xiaoling Xiao*and Xiangfeng Liu*, The studying of the structure-activity relationship of electrochemical performance and Li/Ni mixing of lithium-rich materials by neutron diffraction, RSC Advances, 2015,5,31238-31244.

(16) Xiaoling Xiao*, Xiangfeng Liu, Hu Zhao, Dongfeng Chen, Fengzhen Liu, Junhui Xiang, Zhongbo Hu, and Yadong Li*, Facile Shape-control of Co3O4 and The Crystal Plane Effect on Electrochemical Performance, Advanced Materials, 2012, 24, 5762-5766.

(15) Shuai Hao, Xiaoling Xiao, Zhongbo Hu, Limei Sun, Songbai Han, Dongfeng Chen, and Xiangfeng Liu. Improving the Electrochemical Performance of Li₄Ti₅O₁₂ Anode through Confinement into Ordered Bimodal Porous Carbon Frameworks, J. Phys. Chem. C, 2013, 26889-26895.

(14) Meng Yan, Yan Qing Tan, Hu Zhao, Jie Peng, Xiao Ling Xiao*, Zhong-Bo Hu*, Crystal structure, Dielectric and Magnetic Properties of Ba₅NdNi_1.5Nb_8.5O₃₀ Tungsten Bronze Ceramic, Materials Chemistry and Physics, 2012, 136, 487-491.

(13) Xiaoling Xiao, Xiangfeng Liu, Li Wang, Hu Zhao, Zhongbo Hu, Xiangming He, Yadong Li*, LiCoO₂ Nanoplates with Exposed (001) Planes and High Rate Capability for Lithium-Ion Batteries, Nano Research, 2012, 5, 395-401.

(12) Hu Zhao, Dongfeng Chen, Meng Yan, Jie Peng, Meimei Wu, Xiaoling Xiao*, ZhongBo Hu*, A novel two-step preparation of spinel LiMn₂O₄ nanowires and its electrochemical performance characterization, Journal of Materials Research, 2012, 27, 1750-1754.

(11) Xiaoling Xiao, Limei Yang, Hu Zhao, Zhongbo Hu, Yadong Li*, Facile Synthesis of LiCoO₂ Nanowires with High Electrochemical Performance, Nano Research. 2012, 5, 27-32. 

(10) Xiaoling Xiao, Ying Zhi Cheng, Mei Mei Wu, Jie Peng, Zhong Bo Hu*, The study of thermal expansion properties in solid solutions Ln_2-xCr_xMo₃O₁₂ (Ho and Lu) by high temperature X-ray diffraction, J. Phys. Chem. Solids. 2012, 73, 275-279. 

(9) Ying Zhi Cheng, Xiao Ling Xiao*, Xiang Feng Liu, Mei Mei Wu, Jie Peng, Zhong Bo Hu*, Study of the Structures and Thermal Expansion Properties of Solid Solutions Yb_2−xDy_xW₃O₁₂ (0≤x≤1.5 and 1.8≤x≤2.0), Physica B: Condensed Matter. 2013, 411, 173-177.

(8) Xiaoling Xiao, Jun Lu, Yadong Li*, LiMn₂O₄ Micromicrospheres: Synthesis and Characterization as Cathode of Lithium Ion Battery, Nano Research. 2010, 3, 733-737. 

(7) Xiaoling Xiao, Li. Wang, Dingsheng Wang, Xiangming He, Qing Peng, Yadong Li*, Hydrothermal synthesis of orthorhombic LiMnO₂ nanoparticles and LiMnO₂ nanorods and comparison of their electrochemical performances, Nano Research. 2009, 2, 923-930. 

(6) Xiaoling Xiao, Qingfen. Luan, Xin Yao*, Kebin Zhou, Single-crystal CeO₂ nanocubes used for the direct electron transfer and electrocatalysis of horseradish peroxidase, Biosensers and Bioelectronics. 2009, 24, 2447-2451. 

(5) Xiaoling Xiao, Wu Lu, Xin Yao*, Direct Electron Transfer and Electrocatalysis of Hemoglobin on Chitosan-TiO₂ Nanorods-Glass Carbon Electrode, Electroanalysis. 2008, 20, 2247-2252. 

(4) X.L. Xiao, J. Peng, M.M. Wu, Y.Z. Cheng, D.F. Chen, Z.B. Hu*, The Crystal Structure and Thermal Expansion Properties of Solid Solutions Ln2−xDyxW3O12 (Ln = Er and Y), J.Alloy Compd. 2008, 465, 556-561.

(3) X.L. Xiao, Y.Z. Cheng, J. Peng, M.M. Wu, D.F. Chen, Z.B. Hu*, R. Kiyanagi, J. S. Fieramosca, S. Short, J. Jorgensen, Thermal Expansion Properties of A₂(MO₄)₃ (A= Ho and Tm; M= W and Mo), Solid State Sci. 2008, 10, 321-325.

(2) J. Peng*, X.L. Xiao, Z. Hu, J.Z. Tao, Crystallographic and thermal expansion properties of rare earth solid solution Er_2-xR_xMo₄O₁₅, Solid State Sci. 2008, 10, 1543-1548. 

(1) M.M. Wu, X.L. Xiao, Z.B. Hu, Y.T. Liu, D.F. Chen*, Controllable thermal expansion and phase transition in Yb_2-xCr_xMo₃O₁₂，Solid State Sci. 2009, 1, 325-329.

(1) 每年度招收硕士1-2名，博士研究生1-2名

专业代码及名称：080502 材料学   

研究方向 ：新能源材料的制备、表征及应用 

考试科目 ： ①101思想政治理论；②201英语一； ③825物理化学(乙)；④819无机化学或302数学二

(2) 招收博士后1-2名

（a）申请人应具有材料、化学、物理或其他相关领域博士学位，锂/钠离子电池或固态电解质材料合成/表征、全电池组装与电化学性能测试等相关研究经历，同时具有同步辐射、电子显微技术及中子衍射表征等研究经历。

（b）申请人应具有扎实的学科基础，独立的科研工作能力和良好的英文水平，对科研工作充满热情与好奇心。

（c）待遇优厚，中国科学院大学为博士后研究员提供“中国科学院大学特别研究助理”资助项目（覆盖率可达90%以上），入选者年薪可达40万（税前，包含五险一金、房补等福利待遇）。

已指导学生

赵恩岳  硕士研究生  085204-材料工程  

陈敏敏  硕士研究生  085204-材料工程  

李琪  硕士研究生  085204-材料工程  

邓欣  硕士研究生  085204-材料工程  

党荣彬  博士研究生  080502-材料学  

李娜  博士研究生  080502-材料学  

张红  博士研究生  080502-材料学  

现指导学生

张砚峰  硕士研究生  085600-材料与化工  

曾澳  博士研究生  080502-材料学  

孟乾坤  硕士研究生  080502-材料学  

程瑞  硕士研究生  085600-材料与化工  

刘金华  硕士研究生  080502-材料学  

钟骏  硕士研究生  085600-材料与化工  

谢奕琛  博士研究生  080502-材料学  

邱帅钦  博士研究生  085600-材料与化工