Xiaoling Xiao   College of Materials Science and Opto-Electronic Technology
Telephone: 010-88256856
Address: Yuquan Road 19A, Beijing, China
College of Materials Science and Opto-Electronic Technology,
Graduate Univeristy of Chinese Academy of Sciences
Postcode: 100049

Research Areas

Lithium Ion Battery
Inorganic Materials


Sep. 2005 ---- Ju. 2008    
Ph. D in Inorganic Chemistry
College of Chemistry and Chemical Engineering,    Graduate University of Chinese Academy of Sciences


Work Experience

Jul. 2008 --Ju. 2010             PostDoc   Tsinghua University
Jul. 2010--May. 2012           Lecturer 
                             College of Materials Science and Opto-Electronic Technology
                             Gradutate University of Chinese Academy of Sciences 
May. 2012                            Associate Professor 
                            College of Materials Science and Opto-Electronic Technology
                            Gradutate University of Chinese Academy of Sciences
December. 2017                   Professor 
                            College of Materials Science and Opto-Electronic Technology 
                            Gradutate University of Chinese Academy of Sciences 

Teaching Experience
Advanced Energy Materials and Technology



(46) Jianyue Jiao, Kang Wu, Na Li, Enyue Zhao*, Wen Yin, Zhongbo Hu, Fangwei Wang, Jinkui Zhao, Xiaoling Xiao*. Tuning anionic redox activity to boost high-performance sodium-storage in low-cost Na0.67Fe0.5Mn0.5O2 cathode, Journal of Energy Chemistry, Volume 73, October 2022, Pages 214-222.

(45) Rongbin Dang, Qing-Bo Yan, Enyue Zhao*, Na Li, Kang Wu, Zhongjun Chen, Zhonghua Wu, Xiangfeng Liu, Zhongbo Hu and Xiaoling Xiao*.Designing a durable high-rate K0.45Ni0.1Fe0.1Mn0.8O2 cathode for K-ion batteries: A joint study of theory and experiment. Science China Materials,, 2022, 65, 1741-1750.

(44) Na Li, Shaofei Wang, Enyue Zhao*, Wen Yin, Zhigang Zhang, Kang Wu, Juping Xu,Yoshihiro Kuroiwa, Zhongbo Hu, Fangwei Wang, Jinkui Zhao, Xiaoling Xiao*.Tailoring interphase structure to enable high-rate, durable sodium-ion battery cathode, Journal of Energy Chemistry,Volume 68, May 2022, Pages 564-571. 

(43) Kang WuNa LiKuanrong HaoWen YinMin WangGuofeng JiaYu Lin LeeRongbin DangXin Deng, Xiaoling Xiao*Enyue Zhao*, and Zhijian Wu*. Multiple Influences of Nickel Concentration Gradient Structure and Yttrium Element Substitution on the Structural and Electrochemical Performances of the NaNi0.25Mn0.25Fe0.5O2 Cathode Material, The Journal of Physical Chemistry C  2021, 125, 37, 20171-20183.

(42) Kang Wu, Jianyue Jiao, Na Li, Min Wang, Guofeng Jia, Yu Lin Lee, Rongbin Dang, Xin Deng, Xiaoling Xiao*, and Zhijian Wu*. Revealing the Multiple Influences of Zr Substitution on the Structural and Electrochemical Behavior of High Nickel LiNi0.8Co0.1Mn0.1O2 Cathode Material, The Journal of Physical Chemistry C.2021, 125, 19, 10260-10273.

    (41) and A Comprehensive Solution for Ni-Rich Cathodes by Lithium Silicate Coating. Journal of The Electrochemical Society, 2021, 168(5):050539. 

    (40Jianyue JiaoKang WuRongbin DangNa LiXin DengXiangfeng LiuZhongbo Hu, Xiaoling Xiao*A collaborative strategy with ionic conductive Na2SiO3 coating and Si doping of P2-Na0.67Fe0.5Mn0.5O2 cathode: An effective solution to capacity attenuation, Electrochimica Acta, Volume 384, 10 July 2021, 138362.

    (39) Na Li, Kang Wu, Yulin Lee, Dang Rongbin, Xin Deng, Zhongbo Hu, Xiaoling Xiao*, A comprehensive study of the multiple effects of Y/Al substitution on O3-type NaNi0.33Mn0.33Fe0.33O2with improved cycling stability and rate capability for Na-ion battery applications, Nanoscale, 2020, 12, 16831-16839.

    (38) Kang Wu, Junyang Wang, Qi Li, Yuqiang Yang, Xin Deng, Rongbin Dang, Meimei Wu, Zhijian Wu, Xiaoling Xiao* and  Xiqian Yu*,In situ synthesis of a nickel concentration gradient structure of Ni-rich LiNi0.8Co0.15Al0.05O2 with promising superior electrochemical properties at high cut-off voltage,Nanoscale, 2020, 12, 11182-11191.

    (37) Rongbin Dang, Na Li, Yuqiang Yang, Kang Wu, Qingyuan Li , YuLin Lee, Xiangfeng Liu, Zhongbo Hu, Xiaoling Xiao*Designing advanced P3-type K0.45Ni0.1Co0.1Mn0.8O2 and improving electrochemical performance via Al/Mg doping as a new cathode Material for potassium-ion batteries, Journal of Power Sources, Volume 464, 15 July 2020, 228190.

    (36Jing Ren, Rongbin Dang , Yuqiang Yang, Kang Wu, Yulin LeeZhongbo Hu, Xiaoling Xiao*Min Wang*, Core–Shell Structure and X‐Doped (X = Li, Zr) Comodified O3‐NaNi0.5Mn0.5O2: Excellent Electrochemical Performance as Cathode Materials of Sodium‐Ion Batteries, Energy TechnologyVolume 8, June 2020, 1901504.

    (35) Yuqiang Yang, Rongbin Dang, Kang Wu, Qi Li, Na Li, Zhongbo Hu, Xiaoling Xiao*, Semiconductor Material ZnO-Coated P2-type Na2/3Ni1/3Mn2/3O2Cathode Materials for Sodium-Ion Batteries with Superior Electrochemical Performance, The Journal of Physical Chemistry C2020, 124, 3, 1780-1787.


    (34) Kang Wu, Qi Li, Rongbin Dang, Xin Deng, Minmin Chen , Yu Lin Lee, Xiaoling Xiao*, and Zhongbo Hu*A novel synthesis strategy to improve cycle stability of LiNi0.8Mn0.1Co0.1O2 at high cut-off voltages through core–shell structuring, Nano Research, 2019, 12(10): 2460–2467.


    (33Na Li, Jing Ren, Rongbin Dang, Kang Wu, Yu Lin Lee, Zhongbo Hu, and Xiaoling Xiao*.Suppressing phase transition and improving electrochemical performances of O3-NaNi1/3Mn1/3Fe1/3O2 through ionic conductive Na2SiO3 coating, Journal of Power Sources, 2019, 429, 38-45.

    (32) Rongbin DangMinmin ChenQi LiKang WuYu Lin LeeZhongbo Hu, and Xiaoling Xiao*. Na+-Conductive Na2Ti3O7-Modified P2-type Na2/3Ni1/3Mn2/3O2 via a Smart in Situ Coating Approach: Suppressing Na+/Vacancy Ordering and P2–O2 Phase Transition, ACS Appl. Mater. Interfaces, 201911 (1), pp 856–864.

    (31) Rongbin Dang, Qi Li, Minmin Chen, Zhongbo Hu, Xiaoling Xiao*CuO Coating and Cu2+ Doping Co-modify P2-type Na2/3[Ni1/3Mn2/3]O2 for Sodium-ion Batteries, Physical Chemistry Chemical Physics,  2019, 21, 314 - 321. 

    (30) Qi Li, Rongbin Dang, Minmin Chen, Yulin Lee, Zhongbo Hu, anXiaoling Xiao*, Synthesis Method for Long Cycle Life Lithium-Ion Cathode Material:Nickel-Rich Core−Shell LiNi0.8Co0.1Mn0.1O2, ACS Appl. Mater. Interfaces, 2018, 10, 17850–17860.

    (29) Qi Li, Kang Wu, Minmin Chen, Yu Lin Lee, Dongfeng Chen, Meimei Wu, Faqiang Li, Xiaoling Xiao*, Zhongbo Hu, Designing High-voltage and High-rate Li1-xNaxCoO2 by Enlarging Li Layer  Spacing Electrochimica Acta,  2018, 273, 145-153. 

    (28) Guowei Yang, Enyue Zhao, Minmin Chen, Yingzhi Cheng, Li Xue, Zhongbo Hu, Xiaoling Xiao*Faqiang Li*, Mg doping improving the cycle stability of LiNi0.5Mn0.5O2 at high voltage, Journal of Solid State Electrochemistry2017, 21, 3195-3203

    (27) Minmin Chen, Enyue Zhao, Dongfeng Chen, Meimei Wu, Songbai Han, Qingzhen Huang, Limei Yang, Xiaoling Xiao* and Zhongbo Hu*,  Decreasing Li/Ni Disorder and Improving the Electrochemical Performances of Ni-Rich LiNi0.8Co0.1Mn0.1O2 by Ca Doping, Inorganic Chemistry, 2017, 56,8355-8362.

    (26) Rongbin Dang, Minmin Chen, Yulin Lee, Yingzhi Cheng, Li Xue, Zhongbo Hu, Xiaoling Xiao*, Xuejie Huang*,  Lithium ion Conductor and Electronic Conductor Co-coating Modified Layered Cathode Material LiNi1/3Mn1/3Co1/3O2, Electrochimica Acta, 

    2017, 247, 443-450. 

    (25) Enyue Zhao, Lincan Fang, Minmin Chen, Dongfeng Chen, Qingzhen Huang, Zhongbo Hu, Qing-bo Yan*, Meimei Wu*, Xiaoling Xiao*, New Insight into Li/Ni Disorder in Layered Cathode Materials for Lithium ion Battery: A Joint Study of Neutron Diffraction, Electrochemical Kinetics Analysis and First-principles Calculations, Journal of Materials Chemistry A2017, 5, 1679-1686.2016 Journal of Materials Chemistry A HOT Papers 2017 Journal of Materials Chemistry A HOT Papers

    (24) Enyue Zhao, Minmin Chen, Zhongbo Hu, Dongfeng Chen, Limei Yang and Xiaoling Xiao*, Improved Cycle Stability of High-capacity Ni-rich LiNi0.8Mn0.1Co0.1O2 at High Cut-off Voltage by Li2SiO3 Coating, Journal of Power Sources, 2017, 343, 345-353.

    (23) Minmin Chen, Enyue Zhao, Qingbo Yan, Zhongbo Hu, Xiaoling Xiao*and Dongfeng  Chen*, The Effect of  Crystal Face of Fe2O3 on the Electrochemical Performance for Lithium-ion Batteries, Scientific Reports, 2016, 6, 29381.

    (22) Enyue Zhao, Minmin Chen, Zhongbo Hu, Xiaoling Xiao*and Dongfeng Chen*, Layere / Layered Homostyructure Ion Conductor Coating Strategy for High Performance Lithium Ion Batteries, Electrochimica Acta2016, 208, 64–70.

    (21) Chao Lian, Xiaoling Xiao,  Zheng Chen, Yuxi Liu, Enyue Zhao,  Dingsheng Wang, Chen Chen* and Yadong Li, Preparation of hexagonal ultrathin WO3 nano-ribbons and their electrochemical performance as an anode material in the lithium ion battery, Nano Research, 2016, 9, 435-441. 

    (20) Enyue Zhao, Minmin Chen, Dongfeng Chen, Xiaoling Xiao*and Zhongbo Hu*,  A Versatile Coating Strategy to Highly Improve the Electrochemical Properties of Layered Oxide LiMO2 (M = Ni0.5Mn0.5 and Ni1/3Mn1/3Co1/3), ACS Appl. Mater. Interfaces2015, 7(49), 27096–27105.

    (19) Enyue Zhao, Xiangfeng Liu, Hu Zhao, Xiaoling Xiao* and Zhongbo Hu*,Ionic Conductivity Li2SiO3 Coating Lithium-rich Layered Oxides Exhibiting High Rate Capability and Low Polarization, Chem. Commun., 2015, 51, 9093-9096.(Cover Paper)

    (18) Enyue Zhao, Xiangfeng Liu Zhongbo Hu, Limei Sun, Xiaoling Xiao*,  Facile synthesis and enhanced electrochemical performances of Li2TiO3-coated Li-rich layered Li1.13Ni0.30Mn0.57O2 cathode materials for lithium-ion batteries, Journal of Power Sources, 2015,294,141-149.

    (17) Enyue Zhao, Zhongbo Hu, Lei Xie, Xiping Chen, Xiaoling Xiao*and Xiangfeng Liu*, The studying of the structure-activity relationship of electrochemical performance and Li/Ni mixing of lithium-rich materials by neutron diffraction, RSC Advances, 2015,5,31238-31244.

    (16) Xiaoling Xiao*Xiangfeng Liu, Hu Zhao, Dongfeng Chen, Fengzhen Liu, Junhui Xiang, Zhongbo Hu, and Yadong Li*, Facile Shape-control of Co3O4 and The Crystal Plane Effect on Electrochemical Performance, Advanced Materials2012, 24, 5762-5766. (Advanced Materials Top 40 for November 6th 2012) 

    (15) Shuai Hao, Xiaoling Xiao, Zhongbo Hu, Limei Sun, Songbai Han, Dongfeng Chen, and Xiangfeng Liu. Improving the Electrochemical Performance of Li4Ti5O12 Anode through Confinement into Ordered Bimodal Porous Carbon Frameworks, J. Phys. Chem. C2013, 26889-26895.

    (14) Meng Yan, Yan Qing Tan, Hu Zhao, Jie Peng, Xiao Ling Xiao*Zhong-Bo Hu*, Crystal structure, Dielectric and Magnetic Properties of Ba5NdNi1.5Nb8.5O30Tungsten Bronze Ceramic, Materials Chemistry and Physics2012, 136, 487-491.

    (13) Xiaoling Xiao, Xiangfeng Liu, Li Wang, Hu Zhao, Zhongbo Hu, Xiangming He, Yadong Li*, LiCoO2 Nanoplates with Exposed (001) Planes and High Rate Capability for Lithium-Ion Batteries, Nano Research2012, 5, 395-401.

    (12) Hu Zhao, Dongfeng Chen, Meng Yan, Jie Peng, Meimei Wu, Xiaoling Xiao*ZhongBo Hu*, A novel two-step preparation of spinel LiMn2O4 nanowires and its electrochemical performance characterization, Journal of Materials Research2012, 27, 1750-1754.

    (11) Xiaoling Xiao, Limei Yang, Hu Zhao, Zhongbo Hu, Yadong Li*, Facile Synthesis of LiCoO2 Nanowires with High Electrochemical Performance, Nano Research. 2012, 5, 27-32. 

    (10) Xiaoling Xiao, Ying Zhi Cheng, Mei Mei Wu, Jie Peng, Zhong Bo Hu*, The study of thermal expansion properties in solid solutions Ln2-xCrxMo3O12 (Ho and Lu) by high temperature X-ray diffraction, J. Phys. Chem. Solids. 2012, 73, 275-279. 

    (9) Ying Zhi Cheng, Xiao Ling Xiao*Xiang Feng Liu, Mei Mei Wu, Jie Peng, Zhong Bo Hu*, Study of the Structures and Thermal Expansion Properties of Solid Solutions Yb2−xDyxW3O12 (0≤x≤1.5 and 1.8≤x≤2.0), Physica B: Condensed Matter. 2013, 411, 173-177.

    (8) Xiaoling Xiao, Jun Lu, Yadong Li*, LiMn2O4 Micromicrospheres: Synthesis and Characterization as Cathode of Lithium Ion Battery, Nano Research. 2010, 3, 733-737. 

    (7) Xiaoling Xiao, Li. Wang, Dingsheng Wang, Xiangming He, Qing Peng, Yadong Li*, Hydrothermal synthesis of orthorhombic LiMnOnanoparticles and LiMnO2 nanorods and comparison of their electrochemical performances, Nano Research2009, 2, 923-930. 

    (6) Xiaoling Xiao, Qingfen. Luan, Xin Yao*, Kebin Zhou, Single-crystal CeO2 nanocubes used for the direct electron transfer and electrocatalysis of horseradish peroxidase, Biosensers and Bioelectronics2009, 24, 2447-2451. 

    (5) Xiaoling Xiao, Wu Lu, Xin Yao*, Direct Electron Transfer and Electrocatalysis of Hemoglobin on Chitosan-TiO2 Nanorods-Glass Carbon Electrode,Electroanalysis. 2008, 20, 2247-2252. 

    (4) X.L. Xiao, J. Peng, M.M. Wu, Y.Z. Cheng, D.F. Chen, Z.B. Hu*, The Crystal Structure and Thermal Expansion Properties of Solid Solutions Ln2−xDyxW3O12 (Ln = Er and Y), J.Alloy Compd. 2008, 465, 556-561.

    (3) X.L. Xiao, Y.Z. Cheng, J. Peng, M.M. Wu, D.F. Chen, Z.B. Hu*, R. Kiyanagi, J. S. Fieramosca, S. Short, J. Jorgensen, Thermal Expansion Properties of A2(MO4)3 (A= Ho and Tm; M= W and Mo), Solid State Sci. 2008, 10, 321-325.

    (2) J. Peng*, X.L. Xiao, Z. Hu, J.Z. Tao, Crystallographic and thermal expansion properties of rare earth solid solution Er2-xRxMo4O15Solid State Sci. 2008, 10, 1543-1548. 

    (1) M.M. Wu, X.L. Xiao, Z.B. Hu, Y.T. Liu, D.F. Chen*, Controllable thermal expansion and phase transition in Yb2-xCrxMo3O12Solid State Sci. 2009, 1, 325-329.

    (1) Li Y D, Xiao X L, Wang D S, Method for Preparing Cathode Active Materials of Lithium Battery. (US 12/879171)
    (2) Li Y D, Xiao X L, Lu J, Method for Preparing Cathode Active Materials of Lithium Battery. (US 12/878381)