基本信息

高中华 男 中国科学院化学研究所
电子邮件: gaozh@iccas.ac.cn
通信地址: 北京市海淀区中关村北一街2号
邮政编码: 100190
电子邮件: gaozh@iccas.ac.cn
通信地址: 北京市海淀区中关村北一街2号
邮政编码: 100190
招生信息
招生专业
070303-有机化学
招生方向
有机小分子催化,不对称催化,可见光催化
教育背景
2013-09--2016-07 中国科学院化学研究所 博士学位2010-09--2013-07 中国科学院昆明植物研究所 硕士学位2006-09--2010-07 云南农业大学 学士学位
工作经历
工作简历
2016-07~现在, 中国科学院化学研究所, 助理研究员/副研究员2013-09~2016-07,中国科学院化学研究所, 博士学位2010-09~2013-07,中国科学院昆明植物研究所, 硕士学位2006-09~2010-07,云南农业大学, 学士学位
教授课程
有机化学有机化学习题课前沿化学实验有机化学习题课-2
专利与奖励
奖励信息
(1) 化学所优秀职工, 研究所(学校), 2019(2) 青年科学奖特别优秀奖, , 研究所(学校), 2019
专利成果
( 1 ) 一种氮杂䓬酮化合物及其制备方法, 2018, 第 2 作者, 专利号: 201810565619.5
出版信息
发表论文
(1) N-heterocyclic carbene-catalyzed intramolecular aza-Michael addition of alkyl amines to a,b-unsaturated carboxylic acid: Synthesis of pyrrolidines and piperidines, Tetrahydron, 2021, 第 2 作者(2) NHC/Copper-Cocatalyzed [4 + 3] Annulations of Salicylaldehydes with Aziridines for the Synthesis of 1,4-Benzoxazepinones, Org. Lett., 2020, 第 2 作者(3) N-Heterocyclic carbene/photo-cocatalyzed oxidative Smiles rearrangement: synthesis of aryl salicylates from O-aryl salicylaldehydes, Chem. Commun., 2020, 第 3 作者(4) N-Heterocyclic Carbene Catalyzed Photooxidation: Intramolecular Cross Dehydrogenative Coupling of Tetrahydroisoquinoline-Tethered Aldehydes, Adv. Synth. Catal., 2020, 第 1 作者(5) Bifunctional N-Heterocyclic Carbenes Derived from L-Pyroglutamic Acid and Their Applications in Enantioselective Organocatalysis, Acc. Chem. Res., 2020, 第 2 作者(6) (Dynamic) Kinetic Resolution of Enamines/Imines: Enantioselective N‐Heterocyclic Carbene‐Catalyzed [3+3] Annulation of Bromoenals and Enamines/Imines, Angew. Chem. Int. Ed., 2019, 第 2 作者(7) Bifunctional N-heterocyclic carbene catalyzed [3 + 4] annulation of enals with azadienes: enantioselective synthesis of benzofuroazepinones, Org. Chem. Front., 2019, 第 2 作者(8) N‐Heterocyclic Carbene Catalyzed Synthesis of Dihydroxybenzophenones from β‐Methylenals and Aurones, Chem. Eur. J., 2019, 第 3 作者(9) Visible light mediated oxidative lactonization of 2-methyl-1,1'-biaryls for the synthesis of benzocoumarins, Org. Biomol. Chem., 2019, 第 2 作者(10) Oxidative N‐Heterocyclic Carbene‐Catalyzed [8+2] Annulation of Tropone and Aldehydes: Synthesis of Cycloheptatriene‐Fused Furanones, Adv. Synth. Catal., 2019, 第 2 作者(11) Visible-Light-Promoted Oxo-difluoroalkylation of Alkenes with DMSO as the Oxidant, J. Org. Chem., 2019, 第 2 作者(12) Visible‐Light‐Driven N‐Heterocyclic Carbene‐catalyzed γ‐ and ε‐Alkylation with Alkyl Radicals, Angew. Chem. Int. Ed., 2019, 通讯作者(13) Intramolecular α-Oxygenation of Amines via N-Heterocyclic Carbene-Catalyzed Domino Reaction of Aryl Aldehyde: Experiment and DFT Calculation, CCS Chem., 2019, 第 4 作者(14) N‐Heterocyclic Carbene‐Catalyzed Annulation of α‐Chloroaldehydes with γ‐/δ‐Amino‐α,β‐Unsaturated Ketones: Enantioselective Synthesis of Pyrrolidones and Piperidones, Chem. Eur. J., 2018, 第 4 作者(15) Switchable Decarboxylative Heck-Type Reaction and Oxo-alkylation of Styrenes with N-Hydroxyphthalimide Esters under Photocatalysis, Org. Lett., 2018, 通讯作者(16) Enantioselective Synthesis of Cyclic α‐Aminophosphonates through N‐Heterocyclic Carbene‐Catalyzed [4+2] Annulation of Enals with α‐Iminophosphonates, Asian J. Org. Chem., 2018, 第 2 作者(17) Enantioselective N-Heterocyclic Carbene Catalyzed Synthesis of Spirocyclic Oxindole-benzofuroazepinones, J. Org. Chem., 2018, 第 1 作者(18) [4 + 2] and [3 + 2] Annulation of α-Chloroaldehydes and Dithioesters: Synthesis of 1,4-Oxathiin-2(3H)-ones and 1,3- Oxathioles, Adv. Synth. Catal., 2017, 第 2 作者(19) Formylation or methylation: what determine the chemoselectivity of the reaction of amine, CO2, and hydrosilane, catalyzed by 1,3,2-diazaphospholene?, Chem. Sci., 2017, 第 2 作者(20) N-Heterocyclic carbene-catalyzed [4 + 2] annulation of α,β-unsaturated carboxylic acids: enantioselective synthesis of dihydropyridinones and spirocyclic oxindolodihydropyridinones, Org. Chem. Front., 2016, 第 4 作者(21) Brønsted Acid-Catalyzed Synthesis of N-Arylindoles from 2- Vinylanilines and Quinones, Chem. Asian J., 2016, 第 2 作者(22) N-Heterocyclic Carbene-Catalyzed Synthesis of Multi-Substituted Benzenes from Enals and a-Cyano-b-methylenones, Adv. Synth. Catal., 2016, 第 2 作者
科研活动
科研项目
( 1 ) 光促进的氮杂环卡宾催化偶联及加成反应研究, 负责人, 国家任务, 2018-01--2020-12( 2 ) 基于自由基中间体的卡宾催化反应, 参与, 国家任务, 2017-01--2020-12( 3 ) 氮杂环卡宾催化远端不对称反应研究, 负责人, 国家任务, 2021-01--2024-12
参与会议
(1)Visible light mediated oxo-difluoroalkylation of simple alkenes with DMSO as oxidant 中国化学会第二届全国有机自由基化学会议 夏子豪,高中华,代磊,叶松 2020-04-12(2)N-Heterocyclic Carbene Catalyzed [3+4] Annulation of Enals and Azadienes: Enantioselective Synthesis of Bioactive Benzofuroazepinones 中国化学会第12届全国天然有机化学学术会议 高中华,陈坤泉,张岩,孔令梅,李艳,叶松 2018-07-28(3)氮杂环卡宾催化β,β-双取代烯醛与不饱和亚胺的[4 + 3]环加成反应 中国化学会第31届学术年会 高中华,陈坤泉,张岩,叶松 2018-05-05