可见光催化

自由基化学

碳氢活化

   

070303-有机化学

自由基，光催化，碳氢活化

2011-09--2017-06   厦门大学   研究生学历，博士学位
2007-09--2011-06   福建师范大学   学士

博士研究生学历

博士学位

2017.06-2020.07 中国科学院附件物质结构研究所        精英博士后

2020.08-至今       中国科学院附件物质结构研究所        副研究员

2020-08~现在, 中国科学院附件物质结构研究所, 副研究员
2017-07~2020-07,中国科学院附件物质结构研究所, 精英博士后

   

（1） 福建省高层次人才C类, 省级, 2023
（2） 博士后创新人才计划, 国家级, 2017
（3） 国家奖学金, 国家级, 2016
（4） 国家奖学金, 国家级, 2013

   

[1] Xiangwen Xu, Fanyuanhang Yang, Xiaofeng Zhang, Yuzhen Gao, Weiping Su. Visible-Light-Induced Paternò-Büchi Reaction of Anthraquinones for the Synthesis of Spirocyclic Oxetanes. Asian J. Org. Chem.[J]. 2023, https://onlinelibrary.wiley.com/doi/abs/10.1002/ajoc.202300069.
[2] Liu, Ge, Gao, Yuzhen, Su, Weiping. Photocatalytic Decarboxylative Coupling of Arylacetic Acids with Aromatic Aldehydes. JOURNAL OF ORGANIC CHEMISTRY. 2022, http://dx.doi.org/10.1021/acs.joc.2c01751.
[3] Chi, Zhuomin, Gao, Yuzhen, Yang, Lei, Zhou, Chunlin, Zhang, Meng, Cheng, Peiming, Li, Gang. Dearomative spirocyclization via visible-light-induced reductive hydroarylation of non-activated arenes. CHINESE CHEMICAL LETTERS[J]. 2022, 33(1): 225-228, http://apps.webofknowledge.com/CitedFullRecord.do?product=UA&colName=WOS&SID=5CCFccWmJJRAuMzNPjj&search_mode=CitedFullRecord&isickref=WOS:000746501400025.
[4] Chen, Xiaoxi, Fan, Shuai, Zhang, Meng, Gao, Yuzhen, Li, Shangda, Li, Gang. Palladium-catalyzed remote para-C-H activation of arenes assisted by a recyclable pyridine-based template. CHEMICAL SCIENCE[J]. 2021, 12(11): 4126-4131, https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179498/.
[5] Shi, Shanshan, Zheng, Zhipeng, Zhang, Yumeng, Yang, Yufei, Ma, Denghui, Gao, Yuzhen, Liu, Yan, Tang, Guo, Zhao, Yufen. Photoinduced Phosphorylation/Cyclization of Cyanoaromatics for Divergent Access to Mono- and Diphosphorylated Polyheterocycles. ORGANIC LETTERS[J]. 2021, 23(24): 9348-9352, http://dx.doi.org/10.1021/acs.orglett.1c03360.
[6] Cai, Tao, Zhang, Zhebing, Li, Peiqin, Sun, Tao, Chen, Xinyu, Ni, Yuqi, Chen, Jianhui, Xu, Huiting, Xu, Yanfei, Wu, Chunlei, Shen, Runpu, Gao, Yuzhen. Radical Cascade Bicyclization/Aromatization of 1,7-Enynes with 1,3-Dicarbonyl Compounds towards 2,3-Dihydro-1H-cyclopentaanaphthalenes. ADVANCED SYNTHESIS & CATALYSIS[J]. 2021, 363(15): 3750-3755, http://dx.doi.org/10.1002/adsc.202100678.
[7] Cai, Tao, Feng, Chengjie, Shen, Fangqi, Bian, Kejun, Wu, Chunlei, Shen, Runpu, Gao, Yuzhen. Synthesis of 2-Substituted Benzothio(seleno)phenes and Indoles via Ag-Catalyzed Cyclization/Demethylation of 2-Alkynylthio(seleno)anisoles and 2-Alkynyldimethylanilines. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY[J]. 2021, 2021(4): 653-656, http://dx.doi.org/10.1002/ejoc.202001465.
[8] Gao Yuzhen, Hao Wang1, Zhuomin Chi, Lei Yang, Chunlin Zhou, Li Gang. Spirocyclizative Remote Arylcarboxylation of Nonactivated Arenes with CO2 via Visible-Light-Induced Reductive Dearomatization. CCS Chem.[J]. 2021, 3: 1848-1859, [9] Cai, Tao, Shen, Fangqi, Ni, Yuqi, Xu, Huiting, Shen, Runpu, Gao, Yuzhen. Cascade Radical Annulation of 2-Alkynylthio(seleno)anisoles with Acetone or Acetonitrile: Synthesis of 3-Acetomethyl- or Cyanomethyl-Substituted Benzothio(seleno)phenes. JOURNAL OF ORGANIC CHEMISTRY[J]. 2021, 86(1): 1002-1011, https://www.webofscience.com/wos/woscc/full-record/WOS:000606840200082.
[10] Cai, Lei, Fu, Lei, Zhou, Chunlin, Gao, Yuzhen, Li, Shangda, Li, Gang. Rh(i)-Catalyzed regioselective arylcarboxylation of acrylamides with arylboronic acids and CO2. GREEN CHEMISTRY[J]. 2020, 22(21): 7328-7332, https://www.webofscience.com/wos/woscc/full-record/WOS:000583614600006.
[11] Wang, Hao, Gao, Yuzhen, Zhou, Chunlin, Li, Gang. Visible-Light-Driven Reductive Carboarylation of Styrenes with CO2 and Aryl Halides. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2020, 142(18): 8122-8129, http://dx.doi.org/10.1021/jacs.0c03144.
[12] Cai, Tao, Liu, Jian, Zhang, Huimiao, Wang, Xiaolong, Feng, Jing, Shen, Runpu, Gao, Yuzhen. Ag-Mediated Radical Cyclization of 2-Alkynylthio(seleno)anisoles: Direct Synthesis of 3-Phosphinoylbenzothio(seleno)phenes. ORGANIC LETTERS[J]. 2019, 21(12): 4605-4608, https://www.webofscience.com/wos/woscc/full-record/WOS:000473116000044.
[13] Fan, Shuai, Ding, Yongzheng, Chen, Xiaoxi, Gao, Yuzhen, Fu, Lei, Li, Shangda, Li, Gang. Palladium-Catalyzed C(sp(2))-H Olefination of Free Primary and Secondary 2-Phenylethylamines: Access to Tetrahydroisoquinolines. JOURNAL OF ORGANIC CHEMISTRY[J]. 2019, 84(20): 13003-13012, https://www.webofscience.com/wos/woscc/full-record/WOS:000492118100028.
[14] Ding, Yongzheng, Fan, Shuai, Chen, Xiaoxi, Gao, Yuzhen, Li, Shangda, Li, Gang. Ligand Promoted, Palladium-Catalyzed C(sp(2))-H Arylation of Free Primary 2-Phenylethylamines. ORGANIC LETTERS[J]. 2019, 21(11): 4224-4228, [15] Gao, Yuzhen, Cai, Zhihua, Li, Shangda, Li, Gang. Rhodium(I)-Catalyzed Aryl C-H Carboxylation of 2-Arylanilines with CO2. ORGANIC LETTERS[J]. 2019, 21(10): 3663-3669, [16] Cai, Zhihua, Li, Shangda, Gao, Yuzhen, Li, Gang. Rhodium(II)-Catalyzed Aryl C-H Carboxylation of 2-Pyridylphenols with CO2. ADVANCED SYNTHESIS & CATALYSIS[J]. 2018, 360(20): 4005-4011, https://www.webofscience.com/wos/woscc/full-record/WOS:000447633800020.
[17] Zhang, Chunhui, Ding, Yongzheng, Gao, Yuzhen, Li, Shangda, Li, Gang. Palladium-Catalyzed Direct C-H Carbonylation of Free Primary Benzylamines: A Synthesis of Benzolactams. ORGANIC LETTERS[J]. 2018, 20(9): 2595-2598, https://www.webofscience.com/wos/woscc/full-record/WOS:000431726900022.
[18] Cai, Zhihua, Li, Shangda, Gao, Yuzhen, Fu, Lei, Li, Gang. Weak, bidentate chelating group assisted cross-coupling of C(sp(3))-H bonds in aliphatic acid derivatives with aryltrifluoroborates. CHEMICAL COMMUNICATIONS[J]. 2018, 54(90): 12766-12769, http://dx.doi.org/10.1039/c8cc07481j.
[19] Gao, Yuzhen, Zhang, Pengbo, Li, Gang, Zhao, Yufen. Cascade Annulation of 2-Alkynylthioanisoles with Unsaturated alpha-Bromocarbonyls Leading to Thio-Benzobicyclic Skeletons. JOURNAL OF ORGANIC CHEMISTRY[J]. 2018, 83(22): 13726-13733, https://www.webofscience.com/wos/woscc/full-record/WOS:000451101000010.
[20] Gao, Yuzhen, Tang, Guo, Zhao, Yufen. Recent Advances of Phosphorus-Centered Radical Promoted Difunctionalization of Unsaturated Carbon-Carbon Bonds. CHINESE JOURNAL OF ORGANIC CHEMISTRY[J]. 2018, 38(1): 62-74, http://dx.doi.org/10.6023/cjoc201708023.
[21] Gao, Yuzhen, Li, Gang. Palladium-Catalyzed meta- and para-C-H Bond Functionalizations Assisted by a Directing Group. ALDRICHIMICA ACTA[J]. 2017, 50(3): [22] Gao Yuzhen. Recent Progresses Towards Organophosphorus Compounds Based on Phosphorus-Centered Radical Difunctionalizations. Phosphorus, Sulfur Silicon Relat. Elem.. 2017, [23] Gao Yuzhen, Zhang Pengbo, Ji Zhe, Tang Guo, Zhao Yufen. Copper-Catalyzed Cascade Radical Addition–Cyclization Halogen Atom Transfer between Alkynes and Unsaturated α-Halogenocarbonyls. ACSCATALYSIS[J]. 2017, [24] Gao, Yuzhen, Lu, Guozhang, Zhang, Pengbo, Zhang, Liangliang, Tang, Guo, Zhao, Yufen. A Cascade Phosphinoylation/Cyclization/Desulfonylation Process for the Synthesis of 3-Phosphinoylindoles. ORGANIC LETTERS[J]. 2016, 18(6): 1242-1245, https://www.webofscience.com/wos/woscc/full-record/WOS:000372664600007.
[25] Gao Yuzhen. Mn(OAc)3-Mediated Phosphonation–Lactonization of Alkenoic Acids: Synthesis of Phosphono-γ-Butyrolactones. Chem. Commun.. 2015, [26] Gao Yuzhen. Copper-Catalyzed Phosphonation−Annulation Approaches to the Synthesis of β-Phosphonotetra- hydrofurans Involving C− P and C−O Bonds Formation. J. Org. Chem.. 2015, [27] Gao Yuzhen. Mn(OAc)3- Mediated Arylation–Lactonization of Alkenoic Acids: Synthesis of γ,γ-Disubstituted Butyrolactones. RSC Adv.. 2015, [28] Gao, Yuzhen, Wu, Ju, Xu, Jian, Wang, Xuerui, Tang, Guo, Zhao, Yufen. Synthesis of 6-Phenanthridinephosphonates via a Radical Phosphonation and Cyclization Process Mediated by Manganese(III) Acetate. ASIAN JOURNAL OF ORGANIC CHEMISTRY[J]. 2014, 3(6): 691-694, https://www.webofscience.com/wos/woscc/full-record/WOS:000337688700003.
[29] Gao, Yuzhen, Xu, Jian, He, Yaohui, Tang, Guo, Lin, Zhiwei, Liu, Hongxia, Gao, Xiang, Zhao, Yufen. Cleavage of phosphorus-carbon (P-C) bonds of alpha-amino phosphonates with intramolecular hydrogen migration in the gas phase using electrospray ionization tandem mass spectrometry. RAPID COMMUNICATIONS IN MASS SPECTROMETRY[J]. 2014, 28(18): 1964-1970, https://www.webofscience.com/wos/woscc/full-record/WOS:000340452600002.
[30] Gao Yuzhen. Mn(OAc)3- Mediated Synthesis of β-Hydroxyphosphonates from P(O)–H Compounds and Alkenes. RSC Adv.. 2014, [31] Gao, Yuzhen, Huang, Zhongbin, Zhuang, Rongqiang, Xu, Jian, Zhang, Pengbo, Tang, Guo, Zhao, Yufen. Direct Transformation of Amides into alpha-Amino Phosphonates via a Reductive Phosphination Process. ORGANIC LETTERS[J]. 2013, 15(16): 4214-4217, https://www.webofscience.com/wos/woscc/full-record/WOS:000323363100044.

（1） Transition Metal-Catalyzed Remote meta-C–H Functionalization of Arenes Assisted by meta-Directing Templates, 2021 WILEY‐VCH GmbH (Online ISBN:9783527824137, DOI:10.1002/9783527824137.ch2), 2021-01, 第 1 作者

   

（ 1 ） 自由胺基导向的有机脂肪胺C(sp3)-H键羰基化等反应, 负责人, 国家任务, 2019-01--2021-12
（ 2 ） 基于可见光诱导自由基本位环化的非活化芳烃的1,4-双官能团化研究, 负责人, 国家任务, 2023-01--2026-12