1. 不对称催化转化生物质

2. 手性多相催化剂的制备与表征

3. 生物质能源开发与利用

4. 生物质基材料合成

周旭凯研究员，硕士、博士生导师。2013年毕业于合肥工业大学，获理学学士学位；2018年毕业于中国科学院大连化学物理研究所，获得有机化学专业博士学位。毕业后前往芝加哥大学进行博士后研究；2022年回所工作至今，历任副研究员、研究员。期间在Nature Catalysis, JACS, Angew, ACS Catalysis等学术期刊上发表论文32余篇，获得中科院院长优秀奖、延长石油一等奖、张大煜青年学者、大连市高层次人才等。

欢迎对生物质转化感兴趣的硕士、博士和博士后加入，为实现人类碳循环利用而奋斗！

070303-有机化学

C-C bond activation; Radical chemistry; Photochemistry; Biomass transformation; Asymmetric catalysis

2013-09--2018-06   中国科学院大连化学物理研究所   博士研究生
2009-09--2013-06   合肥工业大学   理学学士学位

2022-10 ~ 至今,         中国科学院大连化学物理研究所,  研究员
2022-07 ~ 2022-10,  中国科学院大连化学物理研究所,  副研究员
2019-02 ~ 2022-06,  美国芝加哥大学, 博士后

   

[1] Zhou Xukai, Daniel Pyle, Zining Zhang, Guangbin Dong. Deacylative Thiolation by Redox-Neutral Aromatization-Driven C−C Fragmentation of Ketones. Angew. Chem. Int. Ed.[J]. 2023, e202213691-, https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202213691.
[2] Zhou, Xukai, Yu, Tingting, Dong, Guangbin. Site-Specific and Degree-Controlled Alkyl Deuteration via Cu-Catalyzed Redox-Neutral Deacylation. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2022, 144(22): 9570-9575, http://dx.doi.org/10.1021/jacs.2c04382.
[3] Zhou, Xukai, Xu, Yan, Dong, Guangbin. Olefination via Cu-Mediated Dehydroacylation of Unstrained Ketones. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2021, 143(48): 20042-20048, http://dx.doi.org/10.1021/jacs.1c09587.
[4] Zhou, Xukai, Xu, Yan, Dong, Guangbin. Deacylation-aided C-H alkylative annulation through C-C cleavage of unstrained ketones. NATURE CATALYSIS[J]. 2021, 4(8): 703-710, http://dx.doi.org/10.1038/s41929-021-00661-7.
[5] Chen, XiaoYang, Zhou, Xukai, Wang, Jianchun, Dong, Guangbin. FMPhos: Expanding the Catalytic Capacity of Small-Bite-Angle Bisphosphine Ligands in Regioselective Alkene Hydrofunctionalizations. ACS CATALYSIS[J]. 2020, 10(24): 14349-14358, https://www.webofscience.com/wos/woscc/full-record/WOS:000608850500002.
[6] Zhou, Xukai, Xia, Jintao, Zheng, Guangfan, Kong, Lingheng, Li, Xingwei. Divergent Coupling of Anilines and Enones by Integration of C-H Activation and Transfer Hydrogenation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2018, 57(22): 6681-6685, https://www.webofscience.com/wos/woscc/full-record/WOS:000434041700051.
[7] Liu, Bingxian, Li, Jie, Hu, Panjie, Zhou, Xukai, Bai, Dachang, Li, Xingwei. Divergent Annulative C-C Coupling of Indoles Initiated by Manganese-Catalyzed C-H Activation. ACSCATALYSIS[J]. 2018, 8(10): 9463-9470, http://cas-ir.dicp.ac.cn/handle/321008/166830.
[8] Zhou, Xukai, Sun, Jiaqiong, Li, Xingwei. Chemo-selective couplings of anilines and acroleins/enones under substrate control and condition control. CHINESE JOURNAL OF CATALYSIS[J]. 2018, 39(11): 1782-1791, http://cas-ir.dicp.ac.cn/handle/321008/166870.
[9] Zhou, Xukai, Luo, Yixin, Kong, Lingheng, Xu, Youwei, Zheng, Guangfan, Lan, Yu, Li, Xingwei. Cp*Co-III-Catalyzed Branch-Selective Hydroarylation of Alkynes via C-H Activation: Efficient Access to alpha-gem-Vinylindoles. ACS CATALYSIS[J]. 2017, 7(10): 7296-7304, http://cas-ir.dicp.ac.cn/handle/321008/150132.
[10] Liu, Bingxian, Hu, Panjie, Zhou, Xukai, Bai, Dachang, Chang, Junbiao, Li, Xingwei. Cp*Rh(III)-Catalyzed Mild Addition of C(sp(3))-H Bonds to alpha,beta-Unsaturated Aldehydes and Ketones. ORGANIC LETTERS[J]. 2017, 19(8): 2086-2089, http://cas-ir.dicp.ac.cn/handle/321008/151966.
[11] Zhou, Xukai, Pan, Yupeng, Li, Xingwei. Catalyst-Controlled Regiodivergent Alkyne Insertion in the Context of C-H Activation and Diels-Alder Reactions: Synthesis of Fused and Bridged Cycles. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2017, 56(28): 8163-8167, https://www.webofscience.com/wos/woscc/full-record/WOS:000404140900021.
[12] Zhou, Xukai, Qi, Zisong, Yu, Songjie, Kong, Lingheng, Li, Yang, Tian, WanFa, Li, Xingwei. Synthesis of 2-Substituted Quinolines via Rhodium(III)-Catalyzed C-H Activation of Imidamides and Coupling with Cyclopropanols. ADVANCED SYNTHESIS & CATALYSIS[J]. 2017, 359(10): 1620-1625, https://www.webofscience.com/wos/woscc/full-record/WOS:000401528100003.
[13] Zhou, Xukai, Yu, Songjie, Qi, Zisong, Kong, Lingheng, Li, Xingwei. Rhodium(III)-Catalyzed Mild Alkylation of (Hetero)Arenes with Cyclopropanols via C-H Activation and Ring Opening. JOURNAL OF ORGANIC CHEMISTRY[J]. 2016, 81(11): 4869-4875, http://cas-ir.dicp.ac.cn/handle/321008/170610.
[14] Yu, Songjie, Li, Yunyun, Zhou, Xukai, Wang, He, Kong, Lingheng, Li, Xingwei. Access to Structurally Diverse Quinoline-Fused Heterocycles via Rhodium(III)-Catalyzed C-C/C-N Coupling of Bifunctional Substrates. ORGANIC LETTERS[J]. 2016, 18(12): 2812-2815, http://cas-ir.dicp.ac.cn/handle/321008/170492.
[15] Zhou, Xukai, Yu, Songjie, Kong, Lingheng, Li, Xingwei. Rhodium(III)-Catalyzed Coupling of Arenes with Cyclopropanols via C-H Activation and Ring Opening. ACS CATALYSIS[J]. 2016, 6(2): 647-651, http://cas-ir.dicp.ac.cn/handle/321008/171158.
[16] Kong, Lingheng, Yu, Songjie, Zhou, Xukai, Li, Xingwei. Redox-Neutral Couplings between Amides and Alkynes via Cobalt(III)-Catalyzed C-H Activation. ORGANIC LETTERS[J]. 2016, 18(3): 588-591, http://cas-ir.dicp.ac.cn/handle/321008/171208.
[17] Kong, Lingheng, Yang, Xifa, Zhou, Xukai, Yu, Songjie, Li, Xingwei. Cobalt(III)-catalyzed efficient synthesis of indenones through carboannulation of benzoates and alkynes. ORGANIC CHEMISTRY FRONTIERS[J]. 2016, 3(7): 813-816, http://cas-ir.dicp.ac.cn/handle/321008/170024.
[18] Yu, Songjie, Tang, Guodong, Li, Yingzi, Zhou, Xukai, Lan, Yu, Li, Xingwei. Anthranil: An Aminating Reagent Leading to Bifunctionality for Both C(sp(3))-H and C(sp(2))-H under Rhodium(III) Catalysis. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2016, 55(30): 8696-8700, http://cas-ir.dicp.ac.cn/handle/321008/170218.
[19] Yang, Xifa, Wang, He, Zhou, Xukai, Li, Xingwei. Iridium- and rhodium-catalyzed C-H activation and formyl arylation of benzaldehydes under chelation-assistance. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2016, 14(23): 5233-5237, http://cas-ir.dicp.ac.cn/handle/321008/170494.
[20] Yu, Songjie, Li, Yingzi, Kong, Lingheng, Zhou, Xukai, Tang, Guodong, Lan, Yu, Li, Xingwei. Mild Acylation of C(sp(3))-H and C(sp(2))-H Bonds under Redox-Neutral Rh(III) Catalysis. ACS CATALYSIS[J]. 2016, 6(11): 7744-7748, http://dx.doi.org/10.1021/acscatal.6b02668.
[21] Zhou, Xukai, Yu, Songjie, Qi, Zisong, Li, Xingwei. Rhodium(III)-catalyzed 3+2 annulative coupling between oximes and electron-deficient alkynes. SCIENCE CHINA-CHEMISTRY[J]. 2015, 58(8): 1297-1301, https://www.sciengine.com/doi/10.1007/s11426-015-5408-8.

   

（ 1 ） 中国科学院****, 负责人, 中国科学院计划, 2023-01--2025-12
（ 2 ） 生物质平台分子的高效催化转化, 负责人, 国家任务, 2023-01--2025-12
（ 3 ） 大连化物所创新基金专项基金, 负责人, 研究所自选, 2023-01--2025-12