基本信息
徐广强  男  硕导  中国科学院青岛生物能源与过程研究所
电子邮件: xu_gq@qibebt.ac.cn
通信地址: 山东省青岛市崂山区松岭路189号
邮政编码: 266101

研究领域

手性聚合物的选择性聚合

招生信息

   
招生专业
070305-高分子化学与物理
招生方向
手性材料合成

教育背景

2012-09--2017-07   中科院上海有机化学研究所   博士学位
2008-09--2012-07   山东大学   学士学位

工作经历

   
工作简历
2020-01~现在, 中科院青岛生物能源与过程研究所, 副研究员
2019-09~2019-12,中科院青岛生物能源与过程研究所, 助理研究员
2017-08~2019-08,中科院青岛生物能源与过程研究所, 博士后

专利与奖励

   
专利成果
( 1 ) 一种富电子芳烃的直接硝化方法, 发明, 2018, 第 2 作者, 专利号: 201810602331.0
( 2 ) 一种新型手性硝基联萘酚及其衍生物的合成方法, 发明, 2017, 第 2 作者, 专利号: 201810601310.7
( 3 ) 一种有机协同催化三元杂环开环聚合的无金属催化体系, 发明, 2018, 第 3 作者, 专利号: 201811621815.6
( 4 ) 一种有机协同催化内酯开环聚合的无金属催化体系, 发明, 2018, 第 3 作者, 专利号: 201811623377.7
( 5 ) 一种由甲基酮出发直接合成氧化呋咱的方法, 发明, 2019, 第 2 作者, 专利号: 201911113695.3
( 6 ) 一种应用聚酯材料可控解聚的锌催化剂及其催化方法, 发明, 2020, 第 2 作者, 专利号: 202010877970.5
( 7 ) 一种锌催化剂催化环酯开环聚合的方法, 发明, 2020, 第 2 作者, 专利号: 202010879046.0
( 8 ) 一种渐变式聚酯的合成方法, 发明, 2021, 第 2 作者, 专利号: 202110104799.9

出版信息

   
发表论文
[1] Zhou, Li, Wang, Zhenyu, Xu, Guangqiang, Lv, Chengdong, Wang, Qinggang. Structure and activity relationship studies of N-heterocyclic olefin and thiourea/urea catalytic systems: application in ring-opening polymerization of lactones. POLYMER CHEMISTRY[J]. 2021, 12(12): 1806-1815, https://www.webofscience.com/wos/woscc/full-record/WOS:000634883000006.
[2] Wang, ZhenYu, Xu, GuangQiang, Zhou, Li, Lv, ChengDong, Yang, RuLin, Dong, BingZhe, Wang, QingGang. Isoselective Ring-opening Polymerization of Racemic Lactide Catalyzed by N-heterocyclic Olefin/(Thio)urea Organocatalysts. CHINESE JOURNAL OF POLYMER SCIENCE[J]. 2021, 39(6): 709-715, http://dx.doi.org/10.1007/s10118-021-2535-x.
[3] Guo, Xuanhua, Xu, Guangqiang, Zhou, Li, Yan, Huating, Hao, XinQi, Wang, Qinggang. Synthesis and application of alpha-carbonyl nitrile oxides. ORGANIC CHEMISTRY FRONTIERS[J]. 2020, 7(17): 2467-2473, https://www.webofscience.com/wos/woscc/full-record/WOS:000562454200010.
[4] Mahmood, Qaiser, Xu, Guangqiang, Zhou, Li, Guo, Xuanhua, Wang, Qinggang. Chiral 1,5,7-triazabicyclo4.4.0dec-5-ene (TBD)-Catalyzed Stereoselective Ring-Opening Polymerization of rac-Lactide: High Reactivity for Isotactic Enriched Polylactides (PLAs). POLYMERS[J]. 2020, 12(10): https://www.webofscience.com/wos/woscc/full-record/WOS:000587424400001.
[5] Lv, Chengdong, Zhou, Li, Yuan, Ruiting, Mahmood, Qaiser, Xu, Guangqiang, Wang, Qinggang. Isoselective ring-opening polymerization and asymmetric kinetic resolution polymerization of rac-lactide catalyzed by bifunctional iminophosphorane-thiourea/urea catalysts. NEW JOURNAL OF CHEMISTRY[J]. 2020, 44(4): 1648-1655, [6] Yan, Huating, Xu, Guangqiang, Yang, Rulin, Lv, Chengdong, Zhou, Li, Hao, XinQi, Wang, Qinggang. Organocatalytic Ring-Opening Polymerization Strategies for Synthesis of Poly(phosphothioesters) with a Pendent Phenyl Group. SYNLETT[J]. 2020, 31(12): 1167-1171, [7] Xu Guangqiang. Chiral phosphoric acid catalyzed asymmetric kinetic resolution polymerization of 6-aryl-ε-caprolactones. Polym. Chem.. 2020, [8] Xu, Guangqiang, Mahmood, Qaiser, Lv, Chengdong, Yang, Rulin, Zhou, Li, Wang, Qinggang. Asymmetric kinetic resolution polymerization. COORDINATION CHEMISTRY REVIEWSnull. 2020, 414: http://dx.doi.org/10.1016/j.ccr.2020.213296.
[9] Xu Guangqiang. N-heterocyclic olefns catalyzed ring-opening polymerization of N-tosyl aziridines. Eur. Polym. J.. 2020, [10] Yuan, Ruiting, Xu, Guangqiang, Lv, Chengdong, Zhou, Li, Yang, Rulin, Wang, Qinggang. Bifunctional phosphazene-thiourea/urea catalyzed ring -opening polymerization of cyclic esters. MATERIALS TODAY COMMUNICATIONS[J]. 2020, 22: http://dx.doi.org/10.1016/j.mtcomm.2019.100747.
[11] Yang, Rulin, Xu, Guangqiang, Lv, Chengdong, Dong, Bingzhe, Zhou, Li, Wang, Qinggang. Zn(HMDS)(2) as a Versatile Transesterification Catalyst for Polyesters Synthesis and Degradation toward a Circular Materials Economy Approach. ACS SUSTAINABLE CHEMISTRY & ENGINEERING[J]. 2020, 8(50): 18347-18353, https://www.webofscience.com/wos/woscc/full-record/WOS:000602569600001.
[12] Xu Guangqiang. Phosphoric acids catalyzed asymmetric kinetic resolution polymerization of benzyl substituted ε-caprolactones: Effcient protocol for stereogradient polycaprolactones. Eur. Polym. J.. 2020, [13] 王庆刚. N-Heterocyclic olefins and thioureas as an efficient cooperative catalyst system for ringopening polymerization of δ-valerolactone. Synlett. 2019, [14] Guo, Xuanhua, Lv, Chengdong, Mahmood, Qaiser, Zhou, Li, Xu, Guangqiang, Wang, Qinggang. Solvent-controlled chemoselective N-dealkylation-N-nitrosation or C-nitration of N-alkyl anilines with tert-butyl nitrite. ORGANIC CHEMISTRY FRONTIERS[J]. 2019, 6(19): 3401-3407, https://www.webofscience.com/wos/woscc/full-record/WOS:000487508600013.

科研活动

   
科研项目
( 1 ) 氧羧基环内酸酐(OCAs)的不对称拆分聚合反应研究, 主持, 国家级, 2020-01--2022-12
( 2 ) 聚烯烃生物材料合成技术开发, 主持, 院级, 2019-04--2020-04