基本信息

尹熙 研究员 中国科学院山西煤炭化学研究所
电子邮件： xiyin@sxicc.ac.cn
通信地址： 山西省太原市桃园南路27号
邮政编码： 030001

研究领域

电化学能量存储与转化

燃料电池

电解制氢

过氧化氢电合成

过氧化氢电化学循环储氢-储能系统

有机分子电化学催化剂

电催化模拟计算

招生信息

   
招生专业
070304-物理化学
080501-材料物理与化学
085600-材料与化工
招生方向
光电化学转化与催化
纳米材料制备及功能化
催化剂制备工程

教育背景

2012-08--2015-08   伊利诺伊大学香槟分校   博士
2010-09--2012-08   罗彻斯特大学   硕士
2004-09--2007-12   清华大学   硕士
2000-09--2004-07   清华大学   学士

工作经历

   
工作简历
2020-09~现在, 中国科学院山西煤炭化学研究所, 研究员
2018-08~2020-08,美国洛斯阿拉莫斯国家实验室, 研究员
2015-09~2018-08,美国洛斯阿拉莫斯国家实验室, 博士后

专利与奖励

   
专利成果
[1] 尹熙, 丁瑞敏, 刘珊珊. 一种过氧化氢规模化高效电化学储释氢系统和方法. CN: CN116623202A, 2023-08-22.
[2] 尹熙, 师文文, 黄梦雪, 杨洁, 丁瑞敏, 刘珊珊. 一种电催化合成H2O2用催化剂及其制备方法和应用. CN: CN114892197A, 2022-08-12.
[3] 尹熙, 黄梦雪, 丁瑞敏, 杨洁, 刘珊珊, 师淑芳. 一种碳基单原子催化剂的制备方法. CN: CN114864967B, 2023-08-15.
[4] 尹熙, 黄梦雪, 丁瑞敏, 杨洁, 刘珊珊, 师淑芳. 一种碳基单原子催化剂的制备方法. CN: CN114864967A, 2022-08-05.
[5] 尹熙, 韩秉秀. 一种圆盘电极动态涂覆机. CN: CN217369060U, 2022-09-06.
[6] 尹熙, 韩秉秀. 一种圆盘电极动态涂覆机. CN: CN114522857A, 2022-05-24.
[7] 尹熙, 杨洁, 刘畅, 丁瑞敏, 刘珊珊. 一种基于过氧化氢电化学循环的可逆电池系统和方法. CN: CN113871668A, 2021-12-31.
[8] 尹熙, 丁瑞敏, 刘畅, 刘珊珊, 杨洁. 一种电解过氧化氢制氢气的装置及方法. CN: CN113416971A, 2021-09-21.
[9] 尹熙, 丁瑞敏, 李佳欣, 张瑞杰, 刘珊珊. 一种单分散铱基氧化物催化剂及其制备方法和应用. CN: CN118287067A, 2024-07-05.
[10] 尹熙, 丁瑞敏, 张瑞杰, 兰会英. 一种担载型贵金属纳米催化剂及其制备方法. CN: CN117895016A, 2024-04-16.
[11] 尹熙, 黄梦雪, 杨洁, 师文文, 陈利芳, 丁瑞敏, 刘珊珊, 陈静超. 一种高活性、高位点密度燃料电池阴极催化剂的制备方法. CN: CN117691130A, 2024-03-12.
[12] 尹熙, 杨洁, 丁瑞敏, 师文文, 陈静超, 韩超奇, 黄梦雪. 含有高保水性和高离子导通性添加剂的碱性燃料电池催化剂层制备方法和应用. CN: CN117936807A, 2024-04-26.
[13] 尹熙, 丁瑞敏, 兰会英, 刘畅, 靖雪, 韩超奇. 一种Pt基有序合金纳米催化剂的制备方法和制备装置. CN: CN117117223A, 2023-11-24.
[14] 尹熙, 丁瑞敏, 刘畅, 韩超奇, 兰会英, 靖雪. 一种碳载Pt基合金纳米催化剂及其制备方法和应用. CN: CN117117224A, 2023-11-24.
[15] 尹熙, 丁瑞敏, 刘珊珊, 靖雪, 刘畅, 兰会英, 韩超奇. 一种碳载贵金属纳米催化剂及其制备方法. CN: CN117317251A, 2023-12-29.
[16] 尹熙, 韩秉秀. 一种膜电极高精度喷涂装置. CN: CN220027482U, 2023-11-17.

出版信息

   
发表论文

  1. M. Huang, X. Zhu, W. Shi, Q. Qin, J. Yang, S. Liu, L. Chen, R. Ding, L. Gan, X. Yin, "Manipulating the Coordination Dice: Alkali Metals Directed Synthesis of Co-N-C Catalysts with CoN4 Sites", Science Advances, 2025, 11 (9), eads6658 [Open Access]

  2. C. Liu, R. Ding, X. Yin, "Comprehensive Study on the Electrochemical Evolution, Reaction Kinetics, and Mass Transport at the Anion Exchange Ionomer-Pt Interface for Oxygen Reduction Reaction", ACS Applied Materials and Interfaces, 2024, 16 (38), 51660-51668 [Link] 

  3. S. Shi, J. Yang, L. Chen, M. Huang, C. Liu, R. Ding, X. Yin, "Identifying Electrocatalytic Activity Sequence of Metal Phthalocyanines for the Hydrogen Peroxide Oxidation Reaction", Journal of the Electrochemical Society, 2024, 171, 046504 [Open Access]

  4. J. Yang, R. Ding, C. Liu, L. Chen, Q. Wang, S. Liu, Q. Xu, X. Yin, "Maximization of Hydrogen Peroxide Utilization in A Proton Exchange Membrane H2O2 Electrolyzer for Efficient Power-to-Hydrogen Conversion", Green Chemistry, 2024, 26 (13), 7769-7778 [Open Access]

  5. J. Yang, R. Ding, C. Liu, Q. Xu, S. Liu, X. Yin, "Optimal MEA Structure and Operating Conditions for Fuel Cell Reactors with Hydrogen Peroxide and Power Cogeneration", Journal of Physics: Energy, 2024, 6 (1), 015022 [Open Access]

  6. C. Han, W. Shi, M. Huang, Q. Wang, J. Yang, J. Chen, R. Ding, X. Yin, "Solvent Effects on the Catalyst Ink and Layer Microstructure for Anion Exchange Membrane Fuel Cells", ACS Applied Materials and Interfaces, 2024, 16 (4), 4550-4560  [link]

  7. L. Chen, J. Li, X. Yin, "Angle-Dependent Electrocatalytic Activity of Twisted Bilayer Graphene for Hydrogen Evolution Reaction", ChemRxiv, 2024, Preprint DOI: 10.26434/chemrxiv-2024-t9c21

  8. J. Yang, W. Shi, Q. Xu, X. Yin*, P. Zelenay*, "Kinetic Analysis of Carbon Corrosion-Induced Degradation of Platinum Group Metal-Free Catalysts in Acidic Media", ACS Catalysis, 2023, 13 (22), 14476-15218 [Link]

  9. J. Chen, J. Yang, R. Ding, S. Liu, L. Chen, W. Shi, X. Yin, "Highly efficient sensing of hydrogen peroxide based on atomically dispersed iron- and nitrogen-doped carbon", Journal of the Electrochemical Society, 2023, 170 (2), 027503 [Open Access]

  10. (cover) C. Liu†, R. Ding†, J. Yang, S. Liu, L. Chen, Q. Xu, J. Li, X. Yin, "Low-Voltage Hydrogen Peroxide Electrolyzer for Highly Efficient Power-to-Hydrogen Conversion", ACS Sustainable Chemistry & Engineering, 2023, 11 (6), 2599-2606 (†Equal contributors.) [Link]

  11. M. Huang, L. Chen, R. Ding, W. Shi, Q. Qin, J. Yang, S. Shi, S. Liu, X. Yin, "Solution-phase synthesis of Co-N-C catalysts using alkali metals-induced NC templates with metal vacancy-Nx sites", ChemRxiv, 2022, Preprint. https://doi.org/10.26434/chemrxiv-2022-xnh88

  12. H. Tang, K. Geng, D. Aili, Q. Ju, J. Pan, G. Chao, X. Yin, X. Guo, Q. Li, N. Li, "Low Pt loading for high-performance fuel cell electrodes enabled by hydrogen-bonding microporous polymer binders", Nature Communications, 2022, 13, 7577

  13. M. Huang, R. Ding, J. Yang, W. Shi, S. Shi, L. Chen, S. Liu, X. Yin, "Formation of nitrogen-coordinated metal sites (M = Fe, Co) via solution-phase coordination on nickel- and nitrogen-co-doped carbon templates with metal vacancy-Nx sites", Journal of the Electrochemical Society, 2022, 169 (10), 106507 [Open Access]

  14. J. Yang, R. Ding, C. Liu, S. Liu, Q. Xu, L. Chen, J. Chen, J. Li, X. Yin, "Highly efficient unitized regenerative hydrogen peroxide cycle cell with ultra-low overpotential for renewable energy storage", Journal of Power Sources, 2022, 545, 231945 [link]

  15. H. Song, Y.-T. Liu, W.-S. Zhang, X.-F Zhang, X. Yin, J. Li, G.-P. Wu, "Rational design of carbon network structure in microporous layer toward enhanced mass transport of proton exchange membrane fuel cell", Journal of Power Sources, 2022, 539, 231623

  16. J. Yang, J. Li, R. Ding, C. Liu, X. Yin, "Kinetic effects of temperature on Fe-N-C catalysts for 2e- and 4e-oxygen reduction reactions", Journal of the Electrochemical Society, 2021, 168 (9), 096502 [Open Access]

  17. X. Yin, E. F. Holby, P. Zelenay, Comment on "Non-PGM electrocatalysts for PEM fuel cells: effect of fluorination on the activity and stability of a highly active NC_Ar+ NH 3 catalyst”, Energy & Environmental Science, 2021, 14, 1029-1033

  18. M. C. Elvington, H. T. Chung, L. Lin, X. Yin, P. Ganesan, P. Zelenay, H. R. Colón-Mercado, "Communication—On the lack of correlation between the voltammetric redox couple and ORR activity of Fe-NC catalysts", Journal of the Electrochemical Society, 2020, 167 (13), 134510

  19. (cover) T. Al-Zoubi, Y. Zhou, X. Yin, B. Janicek, C. Sun, C. E. Schulz, X. Zhang, A. A. Gewirth, P. Huang, P. Zelenay, H. Yang, "Preparation of nonprecious metal electrocatalysts for the reduction of oxygen using a low-temperature sacrificial metal", Journal of the American Chemical Society, 2020, 142 (12), 5477-5481

  20. (cover) X. Yin, L. Lin, U. Martinez, P. Zelenay, "2,2’-Dipyridylamine as heterogeneous organic molecular electrocatalyst for two-electron oxygen reduction reaction in acid media", ACS Applied Energy Materials, 2019, 2 (10), 7272-7278.

  21. X. Yin, L. Lin, H. T. Chung, U. Martinez, A. M. Baker, S. Maurya, P. Zelenay, "2,2'-Dipyridylamine as organic molecular electrocatalyst for hydrogen evolution reaction in acidic electrolytes", 2019. (Preprint on ChemRxiv, doi: 10.26434/chemrxiv.8273627)

  22. X. Yin, H. T. Chung, U. Martinez, L. Lin, K. Artyushkova, P. Zelenay, “PGM-free ORR catalysts designed by templating PANI-type polymers containing functional groups with high affinity to iron", Journal of the Electrochemical Society, 2019, 166 (7), F3240-F3245

  23. L. Osmieri, R. K. Ahluwalia, X. Wang, H. T. Chung, X. Yin, A. J. Kropf, J. Park, D. A. Cullen, K. L. More, P. Zelenay, D. J. Myers, K. C. Neyerlin, "Elucidation of Fe-N-C electrocatalyst active site functionality via in-situ X-ray absorption and operando determination of oxygen reduction reaction kinetics in a PEFC", Applied Catalysis B: Environmental, 2019, 117929

  24. (back cover) U. Martinez, S. K. Babu, E. F. Holby, H. T. Chung, X. Yin, P. Zelenay, “Progress in the development of Fe-based PGM-free electrocatalysts for oxygen reduction reaction”, Advanced Materials, 2019, 31 (31), 1806545

  25. (cover) X. Yin, M. Shi, K. S. Kwok, H. Zhao, D. L. Gray, J. A. Bertke, H. Yang, “Dish-like higher-ordered palladium nanostructures through metal ion-ligand complexation”, Nano Research, 2018, 11 (6), 3442–3452

  26. X. Yin, P. Zelenay, “(Invited) Kinetic Models for the Degradation Mechanisms of PGM-Free ORR Catalysts”, ECS Transactions, 2018, 85 (13), 1239-1250

  27. X. Yin, M. Shi, J. Wu, Y.-T. Pan, D. L. Gray, J. A. Bertke, H. Yang, “Quantitative analysis of different formation modes of platinum nanocrystals controlled by ligand chemistry”, Nano Letters, 2017, 17 (10), 6146–6150

  28. X. Yin†, L. Lin†, H. T. Chung, S. K. Babu, U. Martinez, G. M. Purdy, P. Zelenay, “Effects of MEA fabrication and ionomer composition on fuel cell performance of PGM-free ORR catalyst”, ECS Transactions, 2017, 77 (11), 1273–1281 (†Equal contributors.)

  29. J. Kim, P.-C. Shih, K.-C. Tsao, Y.-T. Pan, X. Yin, C. J. Sun, H. Yang, “High-performance pyrochlore-type yttrium ruthenate electrocatalyst for oxygen evolution reaction in acidic media”, Journal of the American Chemical Society, 2017, 139 (34), 12076–12083

  30. Y.-T. Pan, J. Wu, X. Yin, H. Yang, “In situ ETEM study of composition redistribution in Pt-Ni octahedral catalysts for electrochemical reduction of oxygen”, AIChE Journal, 2016, 62 (2), 399–407

  31. (front cover) X. Yin, J. Wu, P. P. Li, J., H. Yang, “Self-heating approach to the fast production of uniform metal nanotructures”, ChemNanoMat, 2016, 2 (1), 37–41

  32. X. Yin, X. H. Liu, Y.-T. Pan, K. A. Walsh, H. Yang, “Hanoi tower-like multilayered ultrathin palladium nanosheets”, Nano Letters, 2014, 14 (12), 7188–7194

  33. X. Yin, S. A. Warren, Y.-T. Pan, K.-C. Tsao, D. L. Gray, J. Bertke, H. Yang, “A new motif for infinite metal atom wires”, Angewandte Chemie International Edition, 2014, 53 (51), 14087–14091

  34. Y.-T. Pan†, X. Yin†, K. S. Kwok, H. Yang, “Higher-ordered nanostructures of flexible palladium two-dimensional nanosheets for fast hydrogen sensing”, Nano Letters, 2014, 14 (10), 5953–5959 (†Equal contributors.)

  35. J. Kim, X. Yin, K.-C. Tsao, S. Fang, H. Yang, “Ca2Mn2O5 as oxygen-deficient perovskite electrocatalyst for oxygen evolution reaction”, Journal of the American Chemical Society, 2014, 136 (42), 14646–14649

  36. J. Wu†, M. Shi†, X. Yin, H. Yang, “Enhanced oxidation reduction stability of (111) surface dominant Pt3Ni@Pt3Pd core-shell nanoparticle catalysts”, ChemSusChem, 2013, 6 (10), 1888–1892 (†Equal contributors.)

  37. J. Wu, P. Li, Y.-T. Pan, S. Warren, X. Yin, H. Yang, “Surface lattice-engineered bimetallic nanoparticles and their catalytic properties”, Chemical Society Reviews, 2012, 41, 8066–8074

  38. X. Yin, K. X. Chen, H. P. Zhou, X. S. Ning, “Combustion synthesis of Ti3SiC2/TiC composites from elemental powders under high gravity conditions”, Journal of the American Ceramic Society, 2010, 93 (8), 2182–2187

  39. X. Yin, K. X. Chen, H. P. Zhou, X. S. Ning, “Combustion synthesis of Ti3SiC2 from Ti/Si/C powders under high gravity conditions”, Rare Metal Materials and Engineering, 2008, 37 (9), 1606–1609


科研活动

   
科研项目
（ 1 ） 氢能与燃料电池研究, 主持, 市地级, 2020-09--2025-09
（ 2 ） 高通量燃料电池测试夹具研发设计, 主持, 省级, 2021-01--2025-12
（ 3 ） 用于电化学合成过氧化氢的单原子碳基催化剂及膜电极装置研究, 主持, 市地级, 2021-01--2022-12
（ 4 ） 膜电极多相界面的精准调控方法, 主持, 国家级, 2021-12--2025-11

专利成果