表面工程及材料表界面行为研究

   

080502-材料学

生物材料
特种功能涂层

2004-05--2005-04   香港城市大学   博士
2003-03--2006-03   中科院上海硅酸盐研究所   博士学位

   

（1） 骨植入体生物活性涂层材料研究与应用, 二等奖, 省级, 2009

[1] 李恺, 邵丹丹, 刘诗伟, 谢有桃, 郑学斌. 具有多种生物酶模拟活性的氧化铈还原氧化石墨烯纳米复合材料及其制备方法与应用. CN: CN114105128A, 2022-03-01.
[2] 李恺, 邵丹丹, 刘诗伟, 谢有桃, 郑学斌. 一种具有氧化还原响应释药功能的生物抗氧化纳米涂层及其制备方法与应用. CN: CN113827772A, 2021-12-24.
[3] 李恺, 刘诗伟, 邵丹丹, 谢有桃, 郑学斌. 具有促成骨活性的二氧化锰-聚（3,4-乙烯二氧噻吩）生物涂层及其制备方法与应用. CN: CN113827770A, 2021-12-24.
[4] 李恺, 邵丹丹, 谢有桃, 刘诗伟, 郑学斌. 一种具备生物抗氧化功能的氧化铈/氧化钛异质结薄膜及其制备方法与应用. CN: CN113388874A, 2021-09-14.
[5] 李恺, 陆翔, 黄利平, 谢有桃, 郑学斌. 一种纳米结构含硼硅酸钙生物涂层的制备方法. CN: CN109793923B, 2021-08-31.
[6] 李恺, 刘诗伟, 谢有桃, 郑学斌. 具有促成骨分化功能的离子吸附型二氧化锰涂层及其制备方法与应用. CN: CN112807488A, 2021-05-18.
[7] 李恺, 刘诗伟, 谢有桃, 邵丹丹, 郑学斌. 一种具有良好生物抗氧化功能的金属离子掺杂二氧化锰涂层及其制备方法和应用. CN: CN112755246A, 2021-05-07.
[8] 谢有桃, 丁玎, 李恺, 黄利平, 赵君, 郑学斌. 一种兼具良好生物相容性和光热转换效果的氧化钽涂层及其制备方法和应用. CN: CN110129712A, 2019-08-16.
[9] 谢有桃, 丁玎, 李恺, 黄利平, 赵君, 郑学斌. 一种具有显著促细胞成骨分化性能的钽基涂层及其制备方法和应用. CN: CN110075354A, 2019-08-02.
[10] 谢有桃, 丁玎, 李恺, 黄利平, 郑学斌. 一种具有微纳结构的促体外成骨分化钽基涂层及其制备方法. CN: CN109989089A, 2019-07-09.
[11] 李恺, 陆翔, 黄利平, 谢有桃, 郑学斌. 一种具促成骨分化和抗炎功能的纳米结构含硼硅酸钙生物涂层及其制备方法. CN: CN109793923A, 2019-05-24.
[12] 谢有桃, 吕林, 李恺, 赵君, 曹韫真, 郑学斌. 一种具免疫调节功能的骨植入体及其制备方法和应用. CN: CN109745150A, 2019-05-14.
[13] 顾静萍, 谢有桃, 李恺, 黄利平, 赵君, 贺延昌, 郑学斌. 一种具有优良生物相容性的微米/纳米多级结构二氧化钛涂层及其制备方法. CN: CN108588626A, 2018-09-28.
[14] 吕林, 谢有桃, 李恺, 曹韫真, 郑学斌. 一种二氧化钛薄膜及其制备方法和应用. CN: CN107815665A, 2018-03-20.
[15] 李恺, 谢有桃, 赵君, 沈晴昳, 黄利平, 郑学斌. 一种生物抗氧化性能良好的二氧化铈掺杂羟基磷灰石涂层及其应用. CN: CN107638591A, 2018-01-30.
[16] 李恺, 谢有桃, 黄利平, 郑学斌. 一种抗氧化生物涂层及其制备方法. CN: CN106913906A, 2017-07-04.
[17] 李恺, 谢有桃, 黄利平, 郑学斌. 一种抗降解和抗菌性能良好的二氧化铈掺杂硅酸钙涂层及其制备方法和应用. CN: CN106913905A, 2017-07-04.
[18] 陆翔, 李恺, 黄利平, 谢有桃, 郑学斌. 一种掺硼硅酸钙生物活性涂层的制备方法. CN: CN106668942A, 2017-05-17.
[19] 王秀惠, 林开利, 常江, 谢有桃, 郑学斌, 金晓刚. 高结晶度、纳米结构羟基磷灰石涂层及其制备方法. CN: CN105641741A, 2016-06-08.
[20] 李虹庆, 谢有桃, 黄利平, 赵君, 李恺, 季珩, 郑学斌. 用于陶瓷涂层的复合粉体组合物与陶瓷涂层及其制备方法. CN: CN104725038A, 2015-06-24.
[21] 李恺, 谢有桃, 黄利平, 郑学斌. 一种银掺杂的氧化铝陶瓷涂层及其制备方法. CN: CN104388874A, 2015-03-04.
[22] 张欢, 谢有桃, 黄利平, 郑学斌, 陈光. 采用等离子体喷涂技术制备的非晶合金涂层及其制备方法. CN: CN103882421A, 2014-06-25.
[23] 敖海勇, 郑学斌, 汤亭亭, 谢有桃, 季衍, 黄利平. I型胶原改性的多孔钛涂层及其制备方法. CN: CN103785066A, 2014-05-14.
[24] 敖海勇, 郑学斌, 汤亭亭, 谢有桃, 季衍, 黄利平. I型胶原/透明质酸改性的钛涂层及其制备方法. CN: CN103785063A, 2014-05-14.
[25] 敖海勇, 郑学斌, 汤亭亭, 谢有桃, 季衍, 黄利平. 透明质酸改性的多孔钛涂层及其制备方法. CN: CN103785067A, 2014-05-14.
[26] 谢有桃, 郑学斌, 李虹庆, 黄利平. 一种用于硬组织替代材料的石墨烯掺杂硅酸钙涂层的制备方法. CN: CN103536966A, 2014-01-29.
[27] 谢有桃, 敖海勇, 辛世刚, 黄利平, 郑学斌. 一种具有分级结构的Ti涂层硬组织替换材料的制备方法. CN: CN103526196A, 2014-01-22.
[28] 厉艳君, 谢有桃, 黄利平, 郑学斌. 一种构件表面的热障涂层及其制备方法. CN: CN103317787A, 2013-09-25.
[29] 李恺, 谢有桃, 黄利平, 赵君, 郑学斌. 一种抗降解和抗菌性能良好的生物涂层及其制备方法. CN: CN103285425A, 2013-09-11.
[30] 牛亚然, 郑学斌, 谢有桃, 黄利平, 季珩. 高导热性的钨铜热沉和电子封装材料及其制备方法. CN: CN103194712A, 2013-07-10.
[31] 赵君, 郑学斌, 谢有桃, 黄利平, 季珩, 牛亚然. 一种YSZ基复合热障涂层材料及其制备方法. CN: CN102503419A, 2012-06-20.
[32] 梁莹, 谢有桃, 季珩, 黄利平, 郑学斌. Ca 3 ZrSi 2 O 9 涂层—钛合金的骨替换材料及制备方法. 中国: CN102049065A, 2011-05-11.
[33] 梁莹, 谢有桃, 季珩, 黄利平, 郑学斌. Ca 3 ZrSi 2 O 9 涂层—钛合金的骨替换材料及制备方法. CN: CN102049065A, 2011-05-11.
[34] 李恺, 谢有桃, 黄利平, 季珩, 郑学斌. 一种抗降解、抗菌型生物涂层及其制备方法和应用. CN: CN101972490A, 2011-02-16.
[35] 季珩, 郑学斌, 黄利平, 黄静琪, 谢有桃. 一种人工髋臼螺纹孔的等离子喷涂保护装置. CN: CN201558796U, 2010-08-25.
[36] 陈益凯, 郑学斌, 季珩, 谢有桃, 黄利平. 抗菌型骨固定螺钉. CN: CN201551386U, 2010-08-18.
[37] 谢有桃, 常 江, 翟万银, 郑学斌, 丁传贤. 一种硅酸镁涂层－钛或钛合金硬组织替代材料及制备方法. CN: CN101658693A, 2010-03-03.
[38] 陈益凯, 郑学斌, 谢有桃, 季 珩, 丁传贤. 一种抗菌型生物活性钛涂层的制备方法. CN: CN100551450C, 2009-10-21.
[39] 陈益凯, 郑学斌, 谢有桃, 季 珩, 丁传贤. 钛涂层表面快速生成磷灰石的活化方法. CN: CN101342387A, 2009-01-14.
[40] 谢有桃, 郑学斌, 丁传贤. CaO－ZrO 2 －SiO 2 涂层和钛合金的骨替换材料及制备方法. CN: CN101254315A, 2008-09-03.
[41] 谢有桃, 郑学斌, 丁传贤. CaO-ZrO 2 -SiO 2 涂层和钛合金的骨替换材料及制备方法. 中国: CN101254315, 2008-09-03.
[42] 谢有桃, 郑学斌, 季珩, 丁传贤. 一种改进型的电弧等离子体喷涂涂层及其制备方法. CN: CN101073676A, 2007-11-21.
[43] 陈益凯, 郑学斌, 谢有桃, 季珩, 丁传贤. 一种抗菌型生物活性钛涂层及制备方法. CN: CN101073675A, 2007-11-21.
[44] 谢有桃, 刘宣勇, 郑学斌, 丁传贤. 硅酸二钙/氧化锆复合承载骨替换材料及制备方法. CN: CN1329085C, 2007-08-01.

   

[1] 张昕玮, 胡丹丹, 李恺, 谢有桃, 黄利平, 郑学斌. 微/纳米结构含锌硅酸钙基涂层成骨性能研究. 热喷涂技术. 2022, 14(1): 8-18, http://lib.cqvip.com/Qikan/Article/Detail?id=7107708860.
[2] Liu, Shiwei, Li, Kai, Shen, Qingyi, Shao, Dandan, Huang, Shansong, Xie, Youtao, Zheng, Xuebin. Electroactive MnO2-poly(3,4-ethylenedioxythiophene) composite nanocoatings enhance osteoblastic electrical stimulation. APPLIED SURFACE SCIENCE[J]. 2021, 545: http://dx.doi.org/10.1016/j.apsusc.2020.148827.
[3] Li, Kai, Lu, Xiang, Liu, Shiwei, Wu, Xiaodong, Xie, Youtao, Zheng, Xuebin. Boron-incorporated micro/nano-topographical calcium silicate coating dictates osteo/angio-genesis and inflammatory response toward enhanced osseointegration. BIOLOGICAL TRACE ELEMENT RESEARCH[J]. 2021, 199(10): 3801-3816, http://dx.doi.org/10.1007/s12011-020-02517-w.
[4] Shao, Dandan, Li, Kai, Hu, Tao, Wang, Shanjin, Xu, Haowei, Zhang, Shubao, Liu, Shiwei, Xie, Youtao, Zheng, Xuebin. Titania nanotube array supported nanoceria with redox cycling stability ameliorates oxidative stress-inhibited osteogenesis. CHEMICAL ENGINEERING JOURNAL[J]. 2021, 415: http://dx.doi.org/10.1016/j.cej.2021.128913.
[5] Jiang, Yuyin, Xie, Youtao, Chen, Zhaoming, Li, Kai, Zheng, Xuebin. Preparation and characteristics of a novel oxygen-releasing coating for improved cell responses in hypoxic environment. JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A[J]. 2021, 109(2): 248-261, https://www.webofscience.com/wos/woscc/full-record/WOS:000549462400001.
[6] Liu, Shiwei, Li, Kai, Hu, Tao, Shao, Dandan, Huang, Shansong, Xie, Youtao, Zheng, Xuebin. Zn-doped MnO2 nanocoating with enhanced catalase-mimetic activity and cytocompatibility protects pre-osteoblasts against H2O2-induced oxidative stress. COLLOIDS AND SURFACES B-BIOINTERFACES[J]. 2021, 202: http://dx.doi.org/10.1016/j.colsurfb.2021.111666.
[7] Liu, Shiwei, Li, Kai, Shao, Dandan, Shen, Qingyi, Huang, Shansong, Ji, Heng, Xie, Youtao, Zheng, Xuebin. Dual enzyme-like activities of transition metal-doped MnO2 nanocoatings and their dependence on the electronic band structure and ionic dissolution. APPLIED SURFACE SCIENCE[J]. 2020, 534: http://dx.doi.org/10.1016/j.apsusc.2020.147649.
[8] Li, Kai, Liu, Shiwei, Hu, Tao, Razanau, Ihar, Wu, Xiaodong, Ao, Haiyong, Huang, Liping, Xie, Youtao, Zheng, Xuebin. Optimized Nanointerface Engineering of Micro/Nanostructured Titanium Implants to Enhance Cell-Nanotopography Interactions and Osseointegration. ACS BIOMATERIALS SCIENCE & ENGINEERING[J]. 2020, 6(2): 969-983, https://www.webofscience.com/wos/woscc/full-record/WOS:000513086900018.
[9] Shao, Dandan, Li, Kai, You, Mingyu, Liu, Shiwei, Hu, Tao, Huang, Liping, Xie, Youtao, Zheng, Xuebin. Macrophage polarization by plasma sprayed ceria coatings on titanium-based implants: Cerium valence state matters. APPLIED SURFACE SCIENCE[J]. 2020, 504: http://dx.doi.org/10.1016/j.apsusc.2019.144070.
[10] Liu, Shiwei, Li, Kai, Hu, Tao, Wu, Xiaodong, Ao, Haiyong, Xie, Youtao, Zheng, Xuebin. Controlling Preosteoblast Behavior through Manganese Vacancy-Rich Birnessite with Enhanced Divalent Cation Modulation of Fibronectin-Integrin Interactions. ADVANCED MATERIALS INTERFACES[J]. 2020, 7(12): https://www.webofscience.com/wos/woscc/full-record/WOS:000529254500001.
[11] Li, Kai, Lu, Xiang, Razanau, Ihar, Wu, Xiaodong, Hu, Tao, Liu, Shiwei, Xie, Youtao, Huang, Liping, Zheng, Xuebin. The enhanced angiogenic responses to ionic dissolution products from a boron-incorporated calcium silicate coating. MATERIALS SCIENCE AND ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS[J]. 2019, 101: 513-520, http://dx.doi.org/10.1016/j.msec.2019.04.009.
[12] Chen, Zhaoming, Xie, Youtao, Li, Kai, Huang, Liping, Zheng, Xuebin. Synthesis of carbon coated-ceria with improved cytocompatibility. CERAMICS INTERNATIONAL[J]. 2019, 45(16): 19981-19990, http://dx.doi.org/10.1016/j.ceramint.2019.06.256.
[13] Lu, Xiang, Li, Kai, Xie, Youtao, Qi, Shengcai, Shen, Qingyi, Yu, Jiangming, Huang, Liping, Zheng, Xuebin. Improved osteogenesis of boron incorporated calcium silicate coatings via immunomodulatory effects. JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A[J]. 2019, 107(1): 12-24, https://www.webofscience.com/wos/woscc/full-record/WOS:000451882600002.
[14] Ding, Ding, Xie, Youtao, Li, Kai, Huang, Liping, Zheng, Xuebin. A COMPARATIVE STUDY ON VACUUM AND ATMOSPHERIC PLASMA SPRAYED TANTALUM COATINGS FOR THE MODIFICATION OF TITANIUM IMPLANTS. SURFACE REVIEW AND LETTERS[J]. 2019, 26(8): https://www.webofscience.com/wos/woscc/full-record/WOS:000484769800015.
[15] Li, Kai, Lu, Xiang, Razanau, Ihar, Wu, Xiaodong, Hu, Tao, Liu, Shiwei, Xie, Youtao, Huang, Liping, Zheng, Xuebin. The enhanced angiogenic responses to ionic dissolution products from a boron-incorporated calcium silicate coating. MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS[J]. 2019, 101: 513-520, http://dx.doi.org/10.1016/j.msec.2019.04.009.
[16] Zhang, Wenxin, Gu, Jingping, Zhang, Cheng, Xie, Youtao, Zheng, Xuebin. Preparation of titania coating by induction suspension plasma spraying for biomedical application. SURFACE & COATINGS TECHNOLOGY[J]. 2019, 358: 511-520, http://dx.doi.org/10.1016/j.surfcoat.2018.11.047.
[17] Zhang, Wenxin, Gu, Jingping, Li, Kai, Zhao, Jun, Ma, Hongshi, Wu, Chengtie, Zhang, Cheng, Xie, Youtao, Yang, Fei, Zheng, Xuebin. A hydrogenated black TiO2 coating with excellent effects for photothermal therapy of bone tumor and bone regeneration. MATERIALS SCIENCE AND ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS[J]. 2019, 102: 458-470, http://dx.doi.org/10.1016/j.msec.2019.04.025.
[18] Zhang, Hao, Wang, Guangchao, Liu, Peizhao, Tong, Dake, Ding, Chen, Zhang, Zequan, Xie, Youtao, Tang, Hao, Ji, Fang. Vancomycin-loaded titanium coatings with an interconnected micro-patterned structure for prophylaxis of infections: an in vivo study. RSC ADVANCES[J]. 2018, 8(17): 9223-9231, http://ir.sic.ac.cn/handle/331005/24574.
[19] Zhang, Zequan, Xie, Youtao, Pan, Houhua, Huang, Liping, Zheng, Xuebin. Influence of patterned titanium coatings on polarization of macrophage and osteogenic differentiation of bone marrow stem cells. JOURNAL OF BIOMATERIALS APPLICATIONS[J]. 2018, 32(7): 977-986, http://ir.sic.ac.cn/handle/331005/24519.
[20] Lv, Lin, Xie, Youtao, Li, Kai, Hu, Tao, Lu, Xiang, Cao, Yunzhen, Zheng, Xuebin. Unveiling the Mechanism of Surface Hydrophilicity-Modulated Macrophage Polarization. ADVANCED HEALTHCARE MATERIALS[J]. 2018, 7(19): https://www.webofscience.com/wos/woscc/full-record/WOS:000446822600016.
[21] Xia, Lunguo, Xie, Youtao, Fang, Bing, Wang, Xiuhui, Lin, Kaili. In situ modulation of crystallinity and nano-structures to enhance the stability and osseointegration of hydroxyapatite coatings on Ti-6Al-4V implants. CHEMICAL ENGINEERING JOURNAL[J]. 2018, 347: 711-720, http://dx.doi.org/10.1016/j.cej.2018.04.045.
[22] Ding, Ding, Xie, Youtao, Li, Kai, Huang, Liping, Zheng, Xuebin. Black plasma-sprayed Ta2O5 coatings with photothermal effect for bone tumor therapy. CERAMICS INTERNATIONAL[J]. 2018, 44(11): 12002-12006, http://dx.doi.org/10.1016/j.ceramint.2018.03.155.
[23] Li, Kai, Hu, Dandan, Xie, Youtao, Huang, Liping, Zheng, Xuebin. Sr-doped nanowire modification of Ca-Si-based coatings for improved osteogenic activities and reduced inflammatory reactions. NANOTECHNOLOGY[J]. 2018, 29(8): http://ir.sic.ac.cn/handle/331005/24460.
[24] Li, Kai, Shen, Qingyi, Xie, Youtao, You, Mingyu, Huang, Liping, Zheng, Xuebin. Incorporation of Cerium Oxide into Hydroxyapatite Coating Protects Bone Marrow Stromal Cells Against H2O2-Induced Inhibition of Osteogenic Differentiation. BIOLOGICAL TRACE ELEMENT RESEARCH[J]. 2018, 182(1): 91-104, http://ir.sic.ac.cn/handle/331005/24451.
[25] 顾静萍, 谢有桃, 黄利平, 贺延昌, 赵君, 郑学斌, 李红, 孙晋良. 微/纳多级结构${\rm{Ti}}{{\rm{O}}_2}$涂层的制备及生物学性能. 上海大学学报. 自然科学版[J]. 2018, 24(1): 44-55, http://www.corc.org.cn/handle/1471x/2166547.
[26] Ding, Ding, Xie, Youtao, Li, Kai, Huang, Liping, Zheng, Xuebin. Micro/Nano Structural Tantalum Coating for Enhanced Osteogenic Differentiation of Human Bone Marrow Stem Cells. MATERIALS[J]. 2018, 11(4): http://ir.sic.ac.cn/handle/331005/25018.
[27] Ding, Ding, Xie, Youtao, Li, Kai, Huang, Liping, Zheng, Xuebin. Improved Mechanical Compatibility and Cytocompatibility of Ta/Ti Double-Layered Composite Coating. JOURNAL OF THERMAL SPRAY TECHNOLOGY[J]. 2017, 26(6): 1292-1300, http://ir.sic.ac.cn/handle/331005/25474.
[28] Pan, Houhua, Xie, Youtao, Zhang, Zequan, Li, Kai, Hu, Dandan, Zheng, Xuebin, Tang, Tingting. Immunomodulation effect of a hierarchical macropore/nanosurface on osteogenesis and angiogenesis. BIOMEDICAL MATERIALS (BRISTOL)[J]. 2017, 12(4): http://ir.sic.ac.cn/handle/331005/25987.
[29] Wang, Guangchao, Zhang, Hao, He, Qianyun, Tong, Dake, Ding, Chen, Liu, Peizhao, Zhang, Zequan, Xie, Youtao, Ji, Fang. Micro-patterned titanium coatings with a grid-like structure doped with vancomycin against bacteria and affecting osteogenic differentiation. RSC ADVANCES[J]. 2017, 7(32): 19565-19575, http://ir.sic.ac.cn/handle/331005/25383.
[30] Pan, Houhua, Xie, Youtao, Zhang, Zequan, Li, Kai, Hu, Dandan, Zheng, Xuebin, Tang, Tingting. Hierarchical macropore/nano surface regulates stem cell fate through a ROCK-related signaling pathway. RSC ADVANCES[J]. 2017, 7(14): 8521-8532, http://ir.sic.ac.cn/handle/331005/26115.
[31] Pan, Houhua, Xie, Youtao, Zhang, Zequan, Li, Kai, Hu, Dandan, Zheng, Xuebin, Fan, Qirning, Tang, Tingting. YAP-mediated mechanotransduction regulates osteogenic and adipogenic differentiation of BMSCs on hierarchical structure. COLLOIDS AND SURFACES B-BIOINTERFACES[J]. 2017, 152: 344-353, http://dx.doi.org/10.1016/j.colsurfb.2017.01.039.
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（1） 生物材料和表面修饰, Biomaterials and surface modification , Signpost Research, 2007-06, 第 2 作者

   

（ 1 ） 纳米石墨烯增强硅灰石生物相容涂层研究, 主持, 国家级, 2012-01--2014-12
（ 2 ） 生物型人工关节涂层材料研发与批量化制备技术研究, 参与, 部委级, 2010-05--2012-12
（ 3 ） 假体表面涂层改性, 主持, 省级, 2009-07--2012-06
（ 4 ） 乙烯裂解炉低温烟气余热利用技术, 主持, 院级, 2013-01--2015-12
（ 5 ） 人工关节涂层技术服务, 参与, 院级, 2014-01--2016-06
（ 6 ） 硬组织病损精准治疗的个性化医疗器械增材制造技术 集成和应用示范, 参与, 国家级, 2017-07--2021-06

已指导学生

施韵琦  硕士研究生  080502-材料学  

张泽权  硕士研究生  080502-材料学  

陈昭铭  硕士研究生  080502-材料学