基本信息
胡向平 男 博导 中国科学院大连化学物理研究所
电子邮件: xiangping@dicp.ac.cn
通信地址: 大连市中山路457号催化楼109房间
邮政编码: 116023
电子邮件: xiangping@dicp.ac.cn
通信地址: 大连市中山路457号催化楼109房间
邮政编码: 116023
研究领域
主要从事新型手性配体的设计合成及其在不对称催化反应,特别是炔丙基转化反应中的应用研究。
招生信息
拟招收硕士研究生2 人,博士研究生2人
招生专业
070303-有机化学
招生方向
配体设计与催化不对称催化
教育背景
1999-09--2003-06 中国科学院大连化学物理研究所 研究生学历 博士学位1996-09--1999-06 中国农业大学 研究生学历 硕士学位1992-09--1996-06 中国农业大学 本科学历 学士学位
学历
中国科学院大连化学物理研究所 --20030630 研究生毕业
学位
-- 博士
出国学习工作
2005.2-2006.2 英国爱丁堡大学化学系博士后
工作经历
2003.7-2005.2 中国科学院大连化物所工作,助理研究员;
2006.6-2007.10 中国科学院大连化物所工作,助理研究员;
2007.10-2013.6 中国科学院大连化物所工作,副研究员;
2008.10-2011.2 中国科学院大连化物所206组副组长;
2011.5起任中国科学院大连化物所2T2组组长;
2013.7起任中国科学院大连化物所研究员。
2006.6-2007.10 中国科学院大连化物所工作,助理研究员;
2007.10-2013.6 中国科学院大连化物所工作,副研究员;
2008.10-2011.2 中国科学院大连化物所206组副组长;
2011.5起任中国科学院大连化物所2T2组组长;
2013.7起任中国科学院大连化物所研究员。
工作简历
2013-07~现在, 中国科学院大连化学物理研究所, 研究员2007-10~2013-06,中国科学院大连化学物理研究所, 副研究员2006-06~2007-09,中国科学院大连化学物理研究所, 助理研究员2005-03~2006-02,英国爱丁堡大学化学系, 博士后研究员2003-07~2005-02,中国科学院大连化学物理研究所, 助理研究员
教授课程
有机化学seminar考核有机化学博士专业课博士生seminar考核手性配体设计与不对称催化
专利与奖励
申请专利55项,授权7项
奖励信息
(1) Thieme Chemistry Journals Award 2015, , 其他, 2015(2) 科技创新奖, , 研究所(学校), 2014
专利成果
( 1 ) 一种手性4,6-二氧八氢吡咯并3,4-c吡咯-1-羧酸酯类化合物的合成方法, 发明专利, 2021, 第 1 作者, 专利号: CN113461690A( 2 ) 一种手性二茂铁-咪唑双膦配体及其合成方法和应用, 发明专利, 2021, 第 1 作者, 专利号: CN112824424A( 3 ) 铱催化亚胺不对称氢化制备手性胺的方法, 发明专利, 2021, 第 1 作者, 专利号: CN112824373A( 4 ) 一种手性膦-亚磷酰胺酯配体及其制备方法和应用, 发明专利, 2021, 第 1 作者, 专利号: CN112824421A( 5 ) 一种手性二茂铁-吲哚双膦配体及其制备方法和其应用, 发明专利, 2021, 第 1 作者, 专利号: CN112824422A( 6 ) 一种镍催化亚胺不对称氢化制备手性胺化合物的方法, 发明专利, 2021, 第 1 作者, 专利号: CN112824374A( 7 ) 一种手性二茂铁膦-吲哚氨基膦配体及其制备方法和应用, 发明专利, 2021, 第 1 作者, 专利号: CN112824423A( 8 ) 一种(E)-3-芳基-3-(2-甲基肼基)丙酸酯类化合物及其制备方法和应用, 发明专利, 2021, 第 1 作者, 专利号: CN112824379A( 9 ) 一种3,4-二甲基吡唑-5-甲酸酯类化合物的制备方法, 发明专利, 2021, 第 1 作者, 专利号: CN112824393A( 10 ) 一种钯催化亚胺不对称氢化制备手性胺化合物的方法, 发明专利, 2021, 第 1 作者, 专利号: CN112824375A( 11 ) 一种手性(E)-2-(1,3-二芳基烯丙基)丙二酸二甲酯类化合物及其制备方法, 发明专利, 2021, 第 1 作者, 专利号: CN112824371A( 12 ) 铜催化烯烃的不对称环丙烷化方法及其应用, 发明专利, 2021, 第 1 作者, 专利号: CN112824372A( 13 ) 一种炔丙基化含连续手性中心的3,3-二取代吲哚啉-2-酮类化合物及其合成方法, 发明专利, 2021, 第 1 作者, 专利号: CN112824384A( 14 ) 手性1′H-螺吲哚啉-3,4′-吡喃并2,3-c吡唑-2-酮类化合物, 发明专利, 2021, 第 1 作者, 专利号: CN112824412A( 15 ) 一种3-(1H-吡唑-1-基)丙烯酸乙酯类化合物的制备方法, 发明专利, 2021, 第 1 作者, 专利号: CN112661700A( 16 ) 一种手性2,3-二取代四氢喹啉衍生物的合成方法, 发明专利, 2021, 第 1 作者, 专利号: CN112521333A( 17 ) 一种手性α-氨基酸酯衍生物的合成方法, 发明专利, 2021, 第 1 作者, 专利号: CN112279743A( 18 ) 一种手性芳基肟醚化合物的制备方法, 发明专利, 2021, 第 1 作者, 专利号: CN112279779A( 19 ) 一种手性N-(2-(磷酰基)-1-苯乙基)酰胺的制备方法及应用, 发明专利, 2021, 第 1 作者, 专利号: CN112209965A( 20 ) 一种α,α-二取代的含手性季碳中心的α-苯甲酰氨基酸甲酯类化合物的合成方法, 发明专利, 2021, 第 1 作者, 专利号: CN112142616B( 21 ) 一种手性3,4,4-三取代吡咯烷酮类化合物的催化不对称合成方法, 发明专利, 2021, 第 1 作者, 专利号: CN111825509B( 22 ) 一种基于果糖衍生的手性单齿亚磷酸酯配体酮的不对称还原胺化的方法, 发明专利, 2020, 第 1 作者, 专利号: CN111285770A( 23 ) 一种通过催化体系合成聚天冬氨酸的方法, 发明专利, 2020, 第 1 作者, 专利号: CN111286026A( 24 ) 一种基于葡萄糖衍生的单齿亚磷酸酯配体不对称氢化制备手性胺方法, 发明专利, 2020, 第 1 作者, 专利号: CN111285773A( 25 ) 一种基于果糖衍生的吡啶醇类手性配体应用于酮的不对称还原胺化的方法, 发明专利, 2020, 第 1 作者, 专利号: CN111285775A( 26 ) 基于D-甘露醇衍生的手性单齿膦配体不对称氢化亚胺方法, 发明专利, 2020, 第 1 作者, 专利号: CN111285774A( 27 ) 一种采用催化体系合成聚天冬氨酸的方法, 发明专利, 2020, 第 1 作者, 专利号: CN111217998A( 28 ) 一种采用催化体系合成聚琥珀酰亚胺的方法, 发明专利, 2020, 第 1 作者, 专利号: CN111171316A( 29 ) 以联萘二胺为骨架的席夫碱Cu(Ⅱ)络合物及其制备方法, 发明专利, 2021, 第 1 作者, 专利号: CN111138312B( 30 ) 一种采用催化体系合成聚环氧琥珀酸盐的方法, 发明专利, 2020, 第 1 作者, 专利号: CN111100283A( 31 ) 一种聚环氧琥珀酸复配物的合成方法, 发明专利, 2020, 第 1 作者, 专利号: CN111100282A( 32 ) 一种无磷缓释阻垢剂及其合成方法, 发明专利, 2022, 第 1 作者, 专利号: CN111099752B( 33 ) 一种酮的不对称还原胺化制备手性胺的方法, 发明专利, 2019, 第 1 作者, 专利号: CN110551033A( 34 ) 一种铱催化酮的不对称还原胺化方法, 发明专利, 2019, 第 1 作者, 专利号: CN110551035A( 35 ) 一种铱/手性亚磷酸酯-吡啶催化亚胺不对称氢化方法, 发明专利, 2019, 第 1 作者, 专利号: CN110551036A( 36 ) 一种铱/手性双膦体系催化亚胺不对称氢化方法, 发明专利, 2019, 第 1 作者, 专利号: CN110551037A( 37 ) 一种酮的不对称还原胺化方法, 发明专利, 2019, 第 1 作者, 专利号: CN110551034A( 38 ) 一种铱/线型膦-亚磷酰胺体系催化亚胺不对称氢化方法, 发明专利, 2019, 第 1 作者, 专利号: CN110548546A( 39 ) 铱手性膦-胺基膦配体体系催化酮的不对称还原胺化方法, 发明专利, 2019, 第 1 作者, 专利号: CN110551032A( 40 ) 一种制备反式右旋菊酸的方法, 发明专利, 2019, 第 1 作者, 专利号: CN110467527A( 41 ) 一种制备手性反式第一菊酸的方法, 发明专利, 2019, 第 1 作者, 专利号: CN110343040A( 42 ) 一种用于手性反式第一菊酸制备的Salen/Ru催化剂, 发明专利, 2019, 第 1 作者, 专利号: CN109954516A( 43 ) 一种5,5,5-三氯-2-甲基-2-戊烯的合成方法, 发明专利, 2019, 第 1 作者, 专利号: CN109879718A( 44 ) 一种九元环化合物的合成方法, 发明专利, 2019, 第 1 作者, 专利号: CN109851607A( 45 ) 一种手性苯并环状β-酮酯类化合物的合成方法, 发明专利, 2019, 第 1 作者, 专利号: CN109851504A( 46 ) 一种高位阻手性P,N,N配体及其制备方法和应用, 发明专利, 2019, 第 1 作者, 专利号: CN109836457A( 47 ) 一种铱催化不对称氢化制备手性醇的方法, 发明专利, 2019, 第 1 作者, 专利号: CN109776245A( 48 ) 基于苯乙胺骨架的手性P,N,N配体类化合物及制备方法与应用, 发明专利, 2019, 第 1 作者, 专利号: CN109776610A( 49 ) 一种不对称氢化亚胺制备手性胺的方法, 发明专利, 2019, 第 1 作者, 专利号: CN109422602A( 50 ) 一种铱催化不对称氢化亚胺合成手性胺化合物的方法, 发明专利, 2019, 第 1 作者, 专利号: CN109422603A( 51 ) 一种基于碳-氢键活化的制备四取代呋喃类化合物的方法, 发明专利, 2021, 第 1 作者, 专利号: CN108976186B( 52 ) 一种手性1,4-二氢吡喃并2,3-c吡唑类化合物的合成方法, 发明专利, 2021, 第 1 作者, 专利号: CN108976241B( 53 ) 一种制备手性炔丙基化的脂肪族六元碳环类化合物的方法, 专利授权, 2018, 第 1 作者, 专利号: CN108101758A( 54 ) 一种铱催化不对称氢化制备手性β-羟基酯的方法, 发明专利, 2018, 第 1 作者, 专利号: CN108101785A( 55 ) 一种制备手性4-(2-炔丙基)苯酚类化合物的方法, 专利授权, 2018, 第 1 作者, 专利号: CN108101755A( 56 ) 一种手性α-氟-β-乙炔基酮化合物的催化不对称合成方法, 发明专利, 2018, 第 1 作者, 专利号: CN108059591A( 57 ) 一种高位阻手性二茂铁P,N,N配体及制备方法与应用, 专利授权, 2017, 第 1 作者, 专利号: CN107522751A( 58 ) 一种制备手性炔丙基芳基醚类化合物的方法, 专利授权, 2017, 第 1 作者, 专利号: CN106866389A( 59 ) 2-位含有手性季碳中心的3-亚甲基-2,3-二氢呋喃的合成方法, 专利授权, 2017, 第 1 作者, 专利号: CN106854191A( 60 ) 含PNN结构骨架配体的三元催化剂体系及其应用, 专利授权, 2017, 第 1 作者, 专利号: CN106853378A( 61 ) 一种三元催化剂体系及其在乙烯选择性齐聚的应用, 专利授权, 2017, 第 1 作者, 专利号: CN106853379A( 62 ) 一种制备含有两个手性中心α-氟-β-乙炔基酮化合物的方法, 专利授权, 2017, 第 1 作者, 专利号: CN106854125A( 63 ) 一种制备手性2-亚甲基-2,3-二氢萘并2,1-b呋喃类化合物的方法, 专利授权, 2017, 第 1 作者, 专利号: CN106478567A( 64 ) 一种制备手性二氢1,4-苯并噁嗪类化合物的方法, 专利授权, 2017, 第 1 作者, 专利号: CN106478539A( 65 ) 一种制备手性4,5-二氢吡唑类化合物的方法, 发明专利, 2016, 第 1 作者, 专利号: CN105732502A( 66 ) 一种制备手性3-亚甲基-2,3-二氢呋喃类化合物的方法, 发明专利, 2016, 第 1 作者, 专利号: CN105732550A( 67 ) 一种制备手性2-亚甲基-2,3-二氢呋喃的方法, 发明专利, 2016, 第 1 作者, 专利号: CN105294372A( 68 ) 一种手性炔丙基胺化合物的催化不对称合成方法, 发明专利, 2015, 第 1 作者, 专利号: CN104693143A( 69 ) 一种手性β-乙炔基酮化合物的催化不对称合成方法, 发明专利, 2015, 第 1 作者, 专利号: CN104692989A( 70 ) 一种由β-酮酸不对称合成手性β-乙炔基酮的方法, 发明专利, 2015, 第 1 作者, 专利号: CN104513146A( 71 ) 一种手性β-乙炔基酮化合物的催化不对称合成方法, 发明专利, 2015, 第 1 作者, 专利号: CN104513117A( 72 ) 一种手性铜催化剂催化合成手性炔丙基胺化合物的方法, 发明专利, 2012, 第 1 作者, 专利号: CN102826947A( 73 ) 一种手性双环n.3.1化合物的催化不对称合成方法, 发明专利, 2014, 第 1 作者, 专利号: CN103570513A( 74 ) 一种高位阻手性芳香胺化合物的不对称氢化合成方法, 发明专利, 2014, 第 1 作者, 专利号: CN103570484A( 75 ) 一种手性单齿亚磷酸酯配体及制备方法和应用, 发明专利, 2007, 第 1 作者, 专利号: CN1951946A( 76 ) 一种膦-亚磷酰胺酯配体和制备方法及应用, 发明专利, 2007, 第 1 作者, 专利号: CN1951945A( 77 ) 一种以膦-亚磷酰胺酯为配体的催化剂及制法和应用, 发明专利, 2006, 第 2 作者, 专利号: CN1768944A
出版信息
以第一和通讯作者发表手性配体设计和不对称催化相关论文100余篇,包括J. Am. Chem. Soc. 1篇,Angew. Chem. Int. Ed. 4篇,撰写英文专著章节2章。
发表论文
(1) Chiral P,N,N-Ligands for Asymmetric Hydrogenation, ADVANCED SYNTHESIS & CATALYSIS, 2024, 通讯作者(2) Cobalt‐catalyzed dehalogenative deuterations with D2O, CHINESE JOURNAL OF CATALYSIS, 2024, 通讯作者(3) Copper-Catalyzed Difunctionalization of Propargylic Carbonates through Tandem Nucleophilic Substitution/Boroprotonation, ORGANIC LETTERS, 2024, 通讯作者(4) Highly Enantioselective Iridium-Catalyzed Hydrogenation of o-Amidophenyl Ketones Enabled by 1,2-Diphenylethylenediamine- Derived P,N,N-Ligands with Tertiary Amine Terminus, ORGANIC LETTERS, 2022, 通讯作者(5) Highly Diastereo- and Enantioselective Copper-Catalyzed Dipropargylic Amination to Access Bispropargylic Diamines, ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2022, 第 4 作者(6) Intramolecular Copper-Catalyzed Asymmetric Propargylic 4+2-Cycloaddition toward Optically Active Tetrahydroisoindolo2,1-aquinoxalines, ORGANIC LETTERS, 2022, 通讯作者(7) Development of spirocyclic phosphoramidite-based hybrid diphosphorus ligands for enantioselective iridium-catalyzed hydrogenation of imines, ORGANIC & BIOMOLECULAR CHEMISTRY, 2022, 通讯作者(8) Rh-catalyzed asymmetric hydrogenation of alpha-aryl-beta-alkylvinyl esters with chiral ferrocenylphosphine-phosphoramidite ligand, TETRAHEDRON LETTERS, 2021, 通讯作者(9) Rh-catalyzed asymmetric hydrogenation of α-aryl-β-alkylvinyl esters with chiral ferrocenylphosphine-phosphoramidite ligand, TETRAHEDRON LETTERS, 2021, 通讯作者(10) Copper-Catalyzed Decarboxylative Propargylic Alkylation of Enol Carbonates: Stereoselective Synthesis of Quaternary alpha-Amino Acids, ACS CATALYSIS, 2021, 通讯作者(11) Iridium-catalyzed asymmetric hydrogenation of beta-ketophosphonates with chiral ferrocenyl P,N,N-ligands, APPLIED ORGANOMETALLIC CHEMISTRY, 2021, 通讯作者(12) Copper-Catalyzed One-Pot Cascade Cyclization for the Synthesis of Isoindolo2,1-aquinoxalines, ADVANCED SYNTHESIS & CATALYSIS, 2021, 通讯作者(13) Bicyclic Bridgehead Phosphoramidite-Based Hybrid Diphosphorus Ligands: Design, Synthesis, and Application in Catalytic Asymmetric Hydrogenation, ORGANIC LETTERS, 2021, 通讯作者(14) New chiral ferrocene/indole-based diphosphine ligands for Rh-catalyzed asymmetric hydrogenation of functionalized olefins, TETRAHEDRON LETTERS, 2020, 通讯作者(15) Copper-catalyzed formal propargylic 3+2 cycloaddition for stereoselective construction of (E)-beta-pyrazolylacrylates, TETRAHEDRON LETTERS, 2020, 通讯作者(16) Copper-Catalyzed Asymmetric Propargylic Alkylation with Oxindoles: Diastereo- and Enantioselective Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters, ORGANIC LETTERS, 2020, 通讯作者(17) The catalyst-free decarboxylative dearomatization of isoquinolines with beta-keto acids and sulfonyl chlorides in water: access to dihydroisoquinoline derivatives, ORGANIC & BIOMOLECULAR CHEMISTRY, 2020, 通讯作者(18) Enantioselective Copper-Catalyzed 3+3 Cycloaddition of Tertiary Propargylic Esters with 1H-Pyrazol-5(4H)-ones toward Optically Active Spirooxindoles, ORGANIC LETTERS, 2020, 通讯作者(19) Traceless-Activation Strategy for Rh-Catalyzed Csp(2)-H Arylation of Coumarins, ORGANIC LETTERS, 2019, 通讯作者(20) Copper-catalyzed asymmetric tandem double Michael reactions of diethylzinc to alpha,beta-unsaturated ketones followed by trapping with nitroolefins, TETRAHEDRON, 2019, 通讯作者(21) Copper-catalyzed asymmetric propargylic etherification of oximes promoted by chiral tridentate P,N,N-ligand, TETRAHEDRON LETTERS, 2019, 通讯作者(22) Diastereo- and Enantioselective Copper-Catalyzed Decarboxylative Ring-Opening 3+2 Annulation of Tertiary Propargylic Carbamates through Regioselective alpha-Attack of gamma-Butenolides, ORGANIC LETTERS, 2019, 通讯作者(23) Chiral P,N-ligands for the highly enantioselective addition of diethylzinc to aromatic aldehydes, APPLIED ORGANOMETALLIC CHEMISTRY, 2019, 通讯作者(24) Ir-catalyzed Asymmetric Hydrogenation of alpha-Imino Esters with Chiral Ferrocenylphosphine-Phosphoramidite Ligands, ADVANCED SYNTHESIS & CATALYSIS, 2019, 通讯作者(25) Ir-Catalyzed Asymmetric Hydrogenation of α-Imino Esters with Chiral Ferrocenylphosphine-pPhosphoramidite Ligands, Adv. Synth. Catal., 2019, 通讯作者(26) Palladium‐Catalyzed Propargylic n+2 Cycloaddition: An Efficient Strategy for Construction of Benzo‐Fused Medium‐Sized Heterocycles, ADVANCED SYNTHESIS & CATALYSIS, 2019, 通讯作者(27) Copper-catalyzed asymmetric tandem double Michael reactions of diethylzinc to α,β-unsaturated ketones followed by trapping with nitroolefins, TETRAHEDRON, 2019, 第 5 作者(28) Highly Diastereo- and Enantioselective Ir-Catalyzed Hydrogenation of 2,3-Disubstituted Quinolines with Structurally Fine-Tuned Phosphine-Phosphoramidite Ligands, ORGANIC LETTERS, 2019, 通讯作者(29) Iridium-catalyzed asymmetric hydrogenation of beta-keto esters with new phenethylamine-derived tridentate p,n,n-ligands, SYNTHETIC COMMUNICATIONS, 2019, 通讯作者(30) Rh-Catalyzed Asymmetric Hydrogenation of (Z)‑β-Phosphorylated Enamides: Highly Enantioselective Access to β‑Aminophosphines, Org. Lett., 2019, 通讯作者(31) Rh-Catalyzed Asymmetric Hydrogenation of (Z)-beta-Phosphorylated Enamides: Highly Enantioselective Access to beta-Arninophosphines, ORGANIC LETTERS, 2019, 通讯作者(32) Iridium-catalyzed asymmetric hydrogenation of -keto esters with f-amphox ligands, SYNTHETIC COMMUNICATIONS, 2018, 通讯作者(33) Copper-catalyzed propargylic 3+3 cycloaddition with 1h-pyrazol-5(4h)-ones: enantioselective access to optically active dihydropyrano2,3-cpyrazoles, CHEMICAL COMMUNICATIONS, 2018, 通讯作者(34) Decarboxylation-promoted pd-catalyzed asymmetric propargylic 3+2 annulation for the enantioselective construction of a quaternary stereocenter in 2,3-dihydrofurans, ORGANIC & BIOMOLECULAR CHEMISTRY, 2018, 通讯作者(35) Copper-catalyzed, silver-mediated formal 3+2 cycloaddition of simple alkynes with -ketoesters through propargylic c(sp(3))-h functionalization, CHEMICAL COMMUNICATIONS, 2018, 通讯作者(36) A multi-electron transfer ferrocene derivative positive redox moiety with improved solubility and potential, CHEMICAL COMMUNICATIONS, 2018, 第 4 作者(37) Ir-catalyzed asymmetric hydrogenation of simple ketones with chiral ferrocenyl P,N,N-ligands, TETRAHEDRON LETTERS, 2018, 通讯作者(38) Quaternary Ammonium Salt-Promoted Multi-Component Reaction in Water: Access to 3-Alkyl-2, 3-Dihydro-1H-Isoindolin-1-One Derivatives, ADVANCED SYNTHESIS & CATALYSIS, 2017, 通讯作者(39) Copper-catalyzed domino cyclization of propargylic alcohol with tosyl isocyanate to oxazolidinones, SYNTHETIC COMMUNICATIONS, 2017, 第 5 作者(40) Cu-Catalyzed asymmetric Friedel-Crafts propargylic alkylation of phenol derivatives, ORGANIC & BIOMOLECULAR CHEMISTRY, 2017, 通讯作者(41) Ir-catalyzed asymmetric hydrogenation of beta-keto esters with chiral ferrocenyl p, n, n-ligands, RSC ADVANCES, 2017, 通讯作者(42) Ultrasmall Platinum Stabilized on Triphenylphosphine-Modified Silica for Chemoselective Hydrogenation, CHEMISTRY-A EUROPEAN JOURNAL, 2017, 第 5 作者(43) Copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives, CHEMICAL COMMUNICATIONS, 2017, 通讯作者(44) Enantioselective synthesis of chiral phosphonylated 2,3-dihydrofurans by copper catalyzed asymmetric formal 3+2 cycloaddition of propargylic esters with β-keto phosphonates, CHINESE JOURNAL OF CATALYSIS, 2016, 第 6 作者(45) Enantioselective synthesis of chiral phosphonylated 2,3-dihydrofurans by copper catalyzed asymmetric formal 3+2 cycloaddition of propargylic esters with beta-keto phosphonates, CHINESE JOURNAL OF CATALYSIS, 2016, 通讯作者(46) Multifunctional Single-Site Catalysts for Alkoxycarbonylation of Terminal Alkynes, CHEMSUSCHEM, 2016, 第 7 作者(47) 铜催化炔丙醇酯与β-羰基膦酸酯的不对称3+2环加成反应合成手性膦酰化2,3-二氢呋喃, Enantioselective synthesis of chiral phosphonylated 2,3-dihydrofurans by copper catalyzed asymmetric formal 3+2 cycloaddition of propargylic esters withβ-keto phosphonates, 催化学报, 2016, 第 6 作者(48) Sophisticated design of covalent organic frameworks with controllable bimetallic docking for a cascade reaction, CHEMISTRY-A EUROPEAN JOURNAL, 2016, 第 9 作者(49) Sterically Hindered Chiral Ferrocenyl P,N,N-Ligands for Highly Diastereo-/Enantioselective Ir-Catalyzed Hydrogenation of a-Alkyl-b-ketoesters via Dynamic Kinetic Resolution, Org. Lett., 2016, 通讯作者(50) 铜催化炔丙醇酯与β-羰基膦酸酯的不对称3+2环加成反应合成手性膦酰化2,3-二氢呋喃, Enantioselective synthesis of chiral phosphonylated 2,3-dihydrofurans by copper catalyzed asymmetric formal 3+2 cycloaddition of propargylic esters withβ-keto phosphonates, 催化学报, 2016, 第 6 作者(51) Highly diastereo-/enantioselective Cu-catalyzed propargylic alkylations of propargyl acetates with cyclic enamines, RSC ADVANCES, 2016, 通讯作者(52) Chiral Ferrocenyl P,N-Ligands for Palladium-Catalyzed Asymmetric Formal [3 + 2] Cycloaddition of Propargylic Esters with b-Ketoesters: Access to Functionalized Chiral 2,3-Dihydrofurans, Org. Lett., 2016, 通讯作者(53) Sterically Hindered Chiral Ferrocenyl P,N,N-Ligands for Highly Diastereo-/Enantioselective Ir-Catalyzed Hydrogenation of alpha-Alkyl-beta-ketoesters via Dynamic Kinetic Resolution, ORGANIC LETTERS, 2016, 通讯作者(54) Desilylation-activated propargylic transformation: enantioselective copper-catalyzed 3+2 cycloaddition of propargylic esters with -naphthol or phenol derivatives, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 通讯作者(55) Chiral ferrocenyl P,S-ligands for highly efficient copper-catalyzed asymmetric 3+2 cycloaddition of azomethine ylides, TETRAHEDRON, 2016, 通讯作者(56) Enantioselective Copper-Catalyzed Propargylic Etherification of Propargylic Esters with Phenols Promoted by Inorganic Base Additives, ADVANCED SYNTHESIS & CATALYSIS, 2016, 通讯作者(57) Desilylation-Activated Propargylic Transformation: Enantioselective Cu-Catalyzed 3+2 Cycloaddition of Propargylic Esters with b -Naphthol or Phenol Derivatives, ANGEWANDTE CHEMIE INTERNATIONAL EDITION, 2016, 第 5 作者(58) Chiral ferrocenyl p,n-ligands for palladium-catalyzed asymmetric formal 3+2 cycloaddition of propargylic esters with beta-ketoesters: access to functionalized chiral 2,3-dihydrofurans, ORGANIC LETTERS, 2016, 通讯作者(59) Chiral phosphine-phosphoramidite ligands in asymmetric catalysis, SYNTHETIC COMMUNICATIONS, 2016, 通讯作者(60) Enantioselective Copper-Catalyzed Formal 4+2 Cycloaddition of o-Aminophenol Derivatives with Propargylic Esters for Synthesis of Optically Active 3,4-Dihydro-2H-1,4-benzoxazines, ORGANIC LETTERS, 2016, 通讯作者(61) Asymmetric hydrogenation of a-keto phosphonates with chiral phosphine-phosphoramidite ligands, TETRAHEDRON-ASYMMETRY, 2015, 第 5 作者(62) Cu催化吲哚啉的炔丙基烷基化/脱氢对映选择性合成手性N-炔丙基吲哚化合物(英文), Enantioselective N-propargylation of indoles via Cu-catalyzed propargylic alkylation/dehydrogenation of indolines, 催化学报, 2015, 第 2 作者(63) Recent advances in copper-catalyzed propargylic substitu-, TETRAHEDRON LETTERS, 2015, 第 2 作者(64) Copper-Catalyzed Asymmetric Formal 3 + 2 Cycloaddition of Propargylic Acetates with Hydrazines: Enantioselective Synthesis of Optically Active 2‑Pyrazolines, ACS CATALYSIS, 2015, 第 4 作者(65) Asymmetric hydrogenation of alpha-keto phosphonates with chiral phosphine-phosphoramidite ligands, TETRAHEDRON-ASYMMETRY, 2015, 第 5 作者(66) Copper-Catalyzed Asymmetric Formal 3+2 Cycloaddition of Propargylic Acetates with Hydrazines: Enantioselective Synthesis of Optically Active 2-Pyrazolines, ACS CATALYSIS, 2015, 通讯作者(67) Recent advances in copper-catalyzed propargylic substitution, TETRAHEDRON LETTERS, 2015, 通讯作者(68) Cu催化吲哚啉的炔丙基烷基化/脱氢对映选择性合成手性N-炔丙基吲哚化合物, Enantioselective N-propargylation of indoles via Cu-catalyzed propargylic alkylation/dehydrogenation of indolines, CHINESE JOURNAL OF CATALYSIS, 2015, 通讯作者(69) Tridentate P,N,N-ligand promoted copper-catalyzed 3+2 cycloaddition of propargylic esters with ß-enamino esters: synthesis of highly functionalized pyrroles, RSC ADVANCES, 2015, 第 6 作者(70) Chiral phosphine-phosphoramidite ligands for highly enantioselective hydrogenation of N-arylimines, RSC ADVANCES, 2015, 第 7 作者(71) Tridentate P,N,N-ligand promoted copper-catalyzed 3+2 cycloaddition of propargylic esters with beta-enamino esters: synthesis of highly functionalized pyrroles, RSC ADVANCES, 2015, 第 6 作者(72) Recent advances in catalytic stereo-controlled cycloaddition with terminal propargylic compounds, SYNTHESIS-STUTTGART, 2015, 通讯作者(73) Enantioselective N—propargylation of indoles via Cu—catalyzed propargylic alkylation/dehydrogenation of indolines, CHINESE JOURNAL OF CATALYSIS催化学报, 2015, 第 2 作者(74) Highly diastereo- and enantioselective copper-catalyzed propargylic alkylation of acyclic ketone enamines for the construction of two vicinal stereocenters, CHEMICAL COMMUNICATIONS, 2014, 通讯作者(75) Rh-ImiFerroPhos complexes catalyzed asymmetric hydrogenation of β-substituted α,β-unsaturated hosphonates, CHINESE JOURNAL OF CATALYSIS, 2014, 第 4 作者(76) Enantioselective Synthesis of Highly Functionalized Dihydrofurans through Copper-Catalyzed Asymmetric Formal 3+2 Cycloaddition of ß-Ketoesters with Propargylic Esters, ANGEWANDTE CHEMIE INTERNATIONAL EDITION, 2014, 第 5 作者(77) WalPhos配体/铑配合物对β,y-不饱和膦酸酯的不对称催化氢化, Rh-catalyzed Asymmetric Hydrogenation of β,y-Unsaturated Phosphonates with WalPhos Ligands, 应用化学, 2014, 第 2 作者(78) WalPhos配体 / 铑配合物对β,γ-不饱和膦酸酯的不对称催化氢化, Rh-catalyzed Asymmetric Hydrogenation of β,γ-Unsaturated Phosphonates with WalPhos Ligands, 应用化学, 2014, 第 5 作者(79) Rh-ImiFerroPhos complexes catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates, CHINESE JOURNAL OF CATALYSIS, 2014, 第 4 作者(80) Enantioselective Synthesis of Highly Functionalized Dihydrofurans via Copper-Catalyzed Asymmetric Formal [3+2] Cycloaddition of ?-Ketoesters with Propargylic Esters, Angew. Chem. Int. Ed., 2014, 通讯作者(81) Enantioselective Synthesis of Highly Functionalized Dihydrofurans through Copper-Catalyzed Asymmetric Formal 3+2 Cycloaddition of beta-Ketoesters with Propargylic Esters, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 通讯作者(82) Highly Enantioselective Copper-Catalyzed Propargylic Substitution of Propargylic Acetates with 1,3-Dicarbonyl Compounds, ORGANIC LETTERS, 2014, 通讯作者(83) 铑-ImiFerroPhos配合物对β-取代-α,β-不饱和磷酸酯的不对称氢化, Rh-lmiFerroPhos complexes catalyzed asymmetric hydrogenation of β-substituted α,β-unsaturated phosphonates, 催化学报, 2014, 第 4 作者(84) 铑-ImiFerroPhos配合物对β-取代-α,β-不饱和磷酸酯的不对称氢化, Rh-lmiFerroPhos complexes catalyzed asymmetric hydrogenation of β-substituted α,β-unsaturated phosphonates, 催化学报, 2014, 第 4 作者(85) Enantioselective Copper-Catalyzed Decarboxylative Propargylic Alkylation of Propargyl ß-Ketoesters with a Chiral Ketimine P,N,N-Ligand, ANGEWANDTE CHEMIE INTERNATIONAL EDITION, 2014, 第 8 作者(86) Enantioselective Copper-Catalyzed Decarboxylative Propargylic Alkylation of Propargylic Esters with beta-Keto Acids, ADVANCED SYNTHESIS & CATALYSIS, 2014, 通讯作者(87) Enantioselective Copper-Catalyzed Decarboxylative Propargylic Alkylation of Propargyl beta-Ketoesters with a Chiral Ketimine P,N,N-Ligand, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 第 8 作者(88) Enantioselective Copper-Catalyzed Decarboxylative Propargylic Alkylation of Propargylic Esters with ß-Keto Acids, ADVANCED SYNTHESIS & CATALYSIS, 2014, 第 8 作者(89) Enantioselective Cu-catalyzed decarboxylative propargylic amination of propargyl carbamates, TETRAHEDRON LETTERS, 2014, 通讯作者(90) 铑催化不对称氢化2-苯基-2-丙烯醇合成手性2-苯基丙醇, Enantioselective Synthesis of Chiral 2-Phenylpropanol via Rh-catalyzed Asymmetric Hydrogenation of 2-Phenylprop-2-en-l-ol, 应用化学, 2014, 第 5 作者(91) Rh-ImiFerroPhos complexes catalyzed asymmetric hydrogenation of β‐\\\substituted α;β‐\\\unsaturated phosphonates, CHINESE JOURNAL OF CATALYSIS催化学报, 2014, 第 4 作者(92) Enantioselective Synthesis of Chiral 2-Phenylpropanol via Rh-catalyzed Asymmetric Hydrogenation of 2-Phenylprop-2-en-1-ol, 应用化学, 2014, 第 5 作者(93) 铑催化不对称氢化2-苯基-2-丙烯醇合成手性2-苯基丙醇, Enantioselective Synthesis of Chiral 2-Phenylpropanol via Rh-catalyzed Asymmetric Hydrogenation of 2-Phenylprop-2-en-l-ol, 应用化学, 2014, 第 5 作者(94) Highly enantioselective copper-catalyzed propargylic substitution of propargylic acetates with 1,3-diczrbonyl compounds, ORGANIC LETTERS, 2014, 第 7 作者(95) 亚胺的不对称催化氢化研究进展, 有机化学, 2013, 第 6 作者(96) Enantioselective Copper-Catalyzed 3+3 Cycloaddition of Azomethine Ylides with Azomethine Imines, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 其他(合作组作者)(97) Synthesis of new chiral ferrocenyl P,N-ligands with a benzoxazole ring and their application in Ag-catalyzed asymmetric 3+2 cycloaddition, TETRAHEDRON LETTERS, 2013, 第 6 作者(98) New and Efficient Synthesis of 1,3-Dienylphosphonates by Palladium-Catalyzed Substitution of Propargylic Esters to Diethyl Phosphite, SYNTHETICCOMMUNICATIONS, 2013, 第 4 作者(99) Progress on the Catalytic Asymmetric Hydrogenation of Imines, CHINESEJOURNALOFORGANICCHEMISTRY, 2013, 第 6 作者(100) 衍生于手性双二茂铁乙胺的单齿亚磷酰胺配体在不对称催化氢化中的应用, Chiral Bis (1-ferrocenylethyl) amine-derived Monophosphoramidite Ligands for Rh-catalyzed Asymmetric Hydrogenation, 分子催化, 2012, 第 3 作者(101) 非对称杂化的手性膦-亚磷酰胺酯配体在不对称催化反应中的应用进展, 有机化学, 2012, 第 4 作者(102) Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines, ORGANIC LETTERS, 2012, 通讯作者(103) Highly Diastereo- and Enantioselective Cu-Catalyzed 3+3 Cycloaddition of Propargyl Esters with Cyclic Enamines toward Chiral Bicyclon.3.1 Frameworks, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 通讯作者(104) Progress on Unsymmetrical Hybrid Chiral Phosphine-phosphoramidite Ligands and Their Application in Asymmetric Catalytic Reactions, CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2012, 第 4 作者(105) Ir-Catalyzed Enantioselective Hydrogenation of 2H-1,4-Benzoxazines with a Chiral 1,2,3,4-Tetrahydro-1-naphthylamine Derived Phosphine-aminophosphine Ligand, CHINESE JOURNAL OF CHEMISTRY, 2012, 通讯作者(106) Highly Diastereo- and Enantioselective Cu-Catalyzed [3+3] Cycloaddition of Propargylic Esters with Cyclic Enamines toward Chiral Bicyclo[n.3.1] Frameworks, J. Am. Chem. Soc., 2012, 通讯作者(107) Chiral Tridentate P,N,N Ligands for Highly Enantioselective Copper-Catalyzed Propargylic Amination with both Primary and Secondary Amines as Nucleophiles, ADVANCED SYNTHESIS & CATALYSIS, 2012, 通讯作者(108) New chiral ferrocenyl P,S-ligands for highly diastereo- and enantioselective Ag(I)-catalyzed asymmetric 3+2 cycloaddition of azomethine ylides, TETRAHEDRON-ASYMMETRY, 2012, 通讯作者(109) 苯乙胺衍生的手性膦-亚磷酰胺酯配体在Rh-催化α-烯醇酯膦酸酯的不对称氢化反应中的应用, 分子催化, 2012, 第 4 作者(110) Enantioselective synthesis of optically active alkylphosphonates via Rh-catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates, TETRAHEDRON-ASYMMETRY, 2012, 第 4 作者(111) Adventure in Asymmetric Hydrogenation:Synthesis of Chiral Phosphorus Ligands and Asymmetric Hydrogenation of Heteroaromatics, TOPICS IN ORGANOMETALLIC CHEMISTRY, 2011, 第 1 作者(112) BoPhoz类膦-氨基膦配体在Rh-催化β-脱氢氨基酸酯的不对称氢化反应中的应用, Rh-Catalyzed Asymmetric Hydrogenation of β- (Acylamino) acrylates with BoPhoz-type Ligands, 分子催化, 2011, 第 5 作者(113) Chiral ferrocenyl phosphine-phosphoramidite ligands for Cu-catalyzed asymmetric conjugate reduction of alpha,beta-unsaturated esters, TETRAHEDRON-ASYMMETRY, 2011, 通讯作者(114) An enantioselective synthesis of 3-aryl-4-phosphonobutyric acid esters via Cu-catalyzed asymmetric conjugate reduction, TETRAHEDRON-ASYMMETRY, 2011, 第 4 作者(115) Asymmetric synthesis of 2-alkyl-3-phosphonopropanoic acid derivatives via Rh-catalyzed asymmetric hydrogenation, TETRAHEDRON-ASYMMETRY, 2011, 第 5 作者(116) New chiral amino alcohol ligands derived from 1-phenylethylamine for efficient Ru-catalyzed asymmetric transfer hydrogenation, TETRAHEDRON-ASYMMETRY, 2011, 通讯作者(117) Adventure in Asymmetric Hydrogenation: Synthesis of Chiral Phosphorus Ligands and Asymmetric Hydrogenation of Heteroaromatics, ASYMMETRICCATALYSISFROMACHINESEPERSPECTIVE, 2011, 第 1 作者(118) Enantioselective Rh-Catalyzed Hydrogenation of 3-Aryl-4-phosphonobutenoates with a P-Stereogenic BoPhoz-Type Ligand, JOURNAL OF ORGANIC CHEMISTRY, 2010, 通讯作者(119) New Chiral Ferrocenyl P,S-Ligands for Highly Diastereo-/Enantioselective Catalytic 3+2 Cycloaddition of Azomethine Ylides with Cyclic and Acyclic Enones, ORGANIC LETTERS, 2010, 通讯作者(120) Chiral 1-phenylethylamine-derived phosphine-phosphoramidite ligands for highly enantioselective Rh-catalyzed hydrogenation of beta-(acylamino)acrylates: significant effect of substituents on 3,3 '-positions of binaphthyl moiety, ORGANIC & BIOMOLECULAR CHEMISTRY, 2010, 通讯作者(121) Readily available chiral phosphine-aminophosphine ligands derived from 1-phenylethylamine for Rh-catalyzed enantioselective hydrogenations, TETRAHEDRON-ASYMMETRY, 2010, 通讯作者(122) Enantioselective Ag(I)-catalyzed 3+2 cycloaddition of azomethine ylides using a chiral ferrocene-based phosphine-phosphoramidite ligand having a stereogenic P-center, TETRAHEDRON-ASYMMETRY, 2009, 通讯作者(123) Asymmetric synthesis of chiral glutaric acid derivatives via Rh-catalyzed enantioselective hydrogenation, TETRAHEDRON-ASYMMETRY, 2009, 通讯作者(124) Enantioselective Rh-Catalyzed Hydrogenation of 3-Aryl-2-phosphonomethylpropenoates by a New Class of Chiral Ferrocenyl Diphosphine Ligands, ORGANIC LETTERS, 2009, 通讯作者(125) Highly Enantioselective Rh-Catalyzed Hydrogenation of β;γ-Unsaturated Phosphonates with Chiral Ferrocene-Based Monophosphoramidite Ligands, JOURNAL OF ORGANIC CHEMISTRY, 2009, 第 2 作者(126) New bis(1-ferrocenylethyl)amine-derived monodentate phosphoramidite ligands for highly enantioselective copper-catalyzed 1,4-conjugate addition, TETRAHEDRON-ASYMMETRY, 2009, 通讯作者(127) Cu-catalyzed asymmetric conjugate reduction of beta-substituted alpha,beta-unsaturated phosphonates: an efficient synthesis of optically active beta-stereogenic alkylphosphonates, TETRAHEDRON LETTERS, 2009, 通讯作者(128) Highly Enantioselective Rh-Catalyzed Hydrogenation of beta,gamma-Unsaturated Phosphonates with Chiral Ferrocene-Based Monophosphoramidite Ligands, JOURNAL OF ORGANIC CHEMISTRY, 2009, 通讯作者(129) Cu-catalyzed asymmetric conjugate reduction of b-substituted a;b-unsaturated phosphonates: an efficient synthesis of optically active b-stereogenic alkylphosphonates, TETRAHEDRON LETTERS, 2009, 第 2 作者(130) Enantioselective Synthesis of Chiral alpha-Aryl or alpha-Alkyl Substituted Ethylphosphonates via Rh-Catalyzed Asymmetric Hydrogenation with a P-Stereogenic BoPhoz-Type Ligand, JOURNAL OF ORGANIC CHEMISTRY, 2009, 通讯作者(131) Enantioselective Synthesis of Chiral α-Aryl or α-Alkyl Substituted Ethylphosphonates via Rh-Catalyzed Asymmetric Hydrogenation with a P-Stereogenic BoPhoz-Type Ligand, JOURNAL OF ORGANIC CHEMISTRY, 2009, 第 2 作者(132) Asymmetric synthesis of chiral Roche ester and its derivatives via Rh-catalyzed enantioselective hydrogenation with chiral phosphine-phosphoramidite ligands, TETRAHEDRON-ASYMMETRY, 2009, 通讯作者(133) Enantioselective Synthesis of Optically Active Alkanephos- phonates via Rhodium-Catalyzed Asymmetric Hydrogenation of -Substituted ;-Unsaturated Phosphonates with Ferrocene-Based Monophosphoramidite Ligands, ADVANCED SYNTHESIS & CATALYSIS, 2008, 第 2 作者(134) Readily Available Chiral Phosphine-Aminophosphine Ligands for Highly Efficient Rh-Catalyzed Asymmetric Hydrogenation of -Enol Ester Phosphonates and -Enamido Phosphonates, JOURNAL OF ORGANIC CHEMISTRY, 2008, 第 3 作者(135) Novel chiral phosphine-phosphoramidite ligands derived from 1-naphthylamine for highly efficient Rh-catalyzed asymmetric hydrogenation, TETRAHEDRON-ASYMMETRY, 2008, 通讯作者(136) Synthesis of novel chiral phosphine-triazine ligand derived from α-phenylethylamine for Pd-catalyzed asymmetric allylic alkylation, CHINESE CHEMICAL LETTERS(中国期刊), 2008, 第 2 作者(137) Enantioselective synthesis of beta-aryl-gamma-amino acid derivatives via Cu-catalyzed asymmetric 1,4-reductions of gamma-phthalimido-substituted alpha,beta-unsaturated carboxylic acid esters, JOURNAL OF ORGANIC CHEMISTRY, 2008, 通讯作者(138) Readily available chiral phosphine-aminophosphine ligands for highly efficient Rh-catalyzed asymmetric hydrogenation of alpha-enol ester phosphonates and alpha-enamido phosphonates, JOURNAL OF ORGANIC CHEMISTRY, 2008, 通讯作者(139) Enantioselective synthesis of optically active alkanephosphonates via rhodium-catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates with ferrocene-based monophosphoramidite ligands, ADVANCED SYNTHESIS & CATALYSIS, 2008, 通讯作者(140) Enantioselective Synthesis of β-Aryl-γ-amino Acid Derivatives via Cu-Catalyzed Asymmetric 1;4-Reductions of γ-Phthalimido-Substituted α;β-Unsaturated Carboxylic Acid Esters, JOURNAL OF ORGANIC CHEMISTRY, 2008, 第 2 作者(141) Ferrocence-based phosphine-triazine ligands for highly efficient Suzuki-Miyaura cross-coupling reaction of aryl chlorides, TETRAHEDRON LETTERS, 2008, 通讯作者(142) Enantioselective synthesis of beta(2)-Amino acids via Rh-catalyzed asymmetric hydrogenation with BoPhoz-type ligands: Important influence of an N-H proton in the ligand on the enantioselectivity, JOURNAL OF ORGANIC CHEMISTRY, 2008, 通讯作者(143) Chiral 1,2,3,4-tetrahydro-1-naphthylamine-derived phosphine-phosphoramidite ligand (THNAPhos): Application in highly enantioselective hydrogenations of functionalized C=C bonds, ADVANCED SYNTHESIS & CATALYSIS, 2008, 通讯作者(144) Modular Phosphine-Aminophosphine Ligands Based on Chiral 1,2,3,4-Tetrahydro-1-naphthylamine Backbone: A New Class of Practical Ligands for Enantioselective Hydrogenations, ADVANCED SYNTHESIS & CATALYSIS, 2008, 通讯作者(145) Enantioselective Synthesis of β2-Amino Acids via Rh-Catalyzed Asymmetric Hydrogenation with BoPhoz-Type Ligands: Important Influence of an N-H Proton in the Ligand on the Enantioselectivity, JOURNAL OF ORGANIC CHEMISTRY, 2008, 第 2 作者(146) Rh-catalyzed asymmetric hydrogenation of gamma-phthalimido-substituted alpha,beta-unsaturated carboxylic acid esters: An efficient enantioselective synthesis of beta-aryl-gamma-amino acids, ORGANIC LETTERS, 2007, 通讯作者(147) Highly enantioselective synthesis of alpha-hydroxy phosphonic acid derivatives by Rh-catalyzed asymmetric hydrogenation with phosphine-phosphoramidite ligands, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 通讯作者(148) Readily available phosphine-imine ligands from alpha-phenylethylamine for highly efficient Pd-catalyzed asymmetric allylic alkylation, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 通讯作者(149) Readily available phosphine–imine ligands from -phenylethylamine for highly efficient Pd-catalyzed asymmetric allylic alkylation, JOURNAL OF MOLECULAR CATALYSIS A, 2007, 第 2 作者(150) Highly Enantioselective Synthesis of a-Hydroxy Phosphonic Acid Derivatives by Rh-Catalyzed Asymmetric Hydrogenation with Phosphine–Phosphoramidite Ligands, ANGEWANDTE CHEMIE INTERNATIONAL EDITION, 2007, 第 2 作者(151) Rh-Catalyzed Asymmetric Hydrogenation of ç-Phthalimido-Substituted r;â-Unsaturated Carboxylic Acid Esters: An Efficient Enantioselective Synthesis of â-Aryl-ç-amino Acids, ORGANIC LETTERS, 2007, 第 4 作者(152) Synthesis of Novel C2-Symmetrical Bidentate Phosphoramidite Ligands for Rh-catalyzed Asymmetric Hydrogenation of β-(Aclamino)acrylates, CHINESE CHEMICAL LETTERS(中国期刊), 2006, 第 2 作者(153) Unsymmetrical Ferrocenylethylamine-Derived Monophosphoramidetes:Highly Efficient Chiral Ligands for Rh-Catalyzed Enantioselective Hydrogenation of Enamides and α-Dehydroamino Acid Derivatives, JOURNAL OF ORGANIC CHEMISTRY, 2006, 第 2 作者(154) Synthesis of novel C-2-symmetrical bidentate phosphoramidite ligands for Rh-catalyzed asymmetric hydrogenation of beta-(acylamino)acrylates, CHINESE CHEMICAL LETTERS, 2006, 第 2 作者(155) Readily available phosphine-phosphoramidite ligands for highly efficient Rh-catalyzed enantioselective hydrogenations, ORGANIC LETTERS, 2006, 第 2 作者(156) Synthesis of Novel Monophosphoramidite Ligands Derived from L-Proline for Rh-catalyzed Asymmetric Hydrogenation of α-Dehydroamino Acid Esters, CHINESE CHEMICAL LETTERS(中国期刊), 2005, 第 2 作者(157) 聚合手性二茂铁N;O-配体催化苯乙炔对醛的不对称加成反应, 催化学报, 2005, 第 2 作者(158) 平面手性二茂铁N,O-配体催化苯乙炔对醛的不对称加成反应, Enantioselective Addition of Phenylacetylene to Aldehydes Using a Planar Chiral N,O-Ferrocene Ligand, 催化学报, 2005, 第 2 作者(159) Ferrocene-Based Chiral Phosphine-Triazines: A New Family of Highly Efficent P;N Ligands for Asymmetric Catalysis, ADVANCED SYNTHESIS & CATALYSIS, 2005, 第 1 作者(160) practical Rh(I)-Catalyzed Asymmetric Hydrogenation of β-(Acylamino)acrylates Using a New Unsymmetrical Hybrid Ferrocenylphosphine-phosphoramidite Ligand: Crucial Influence of an N-H Proton in the Ligand, ORGANIC LETTERS, 2005, 第 1 作者(161) 新型手性双二茂铁希呋碱亚胺配体的合成及其在不对称环丙烷化反应中的应用, 分子催化, 2004, 第 2 作者(162) Efficient P;N;N-type ligands for Ru(II)-catalyzed asymmetric cyclopropanations, JOURNAL OF MOLECULAR CATAYLSIS A:CHEMICAL, 2004, 第 2 作者(163) Synthesis and Potential Application of Novel C2-Symmetrical Bis(ferrocenyl)P2N Ligand, 中国化学快报, 2003, 第 1 作者(164) 平面手性二茂铁配体的设计、合成及其Pd-配合物在催化不对称烯丙基取代反应中的应用研究, Design and Synthesis of Chiral Ferrocene Based Ligands with Central and Planar Chirality and Their Applications in Pd-catalyzed Asymmetric Allylic Substitution, 2003, 第 1 作者(165) Knochel双膦配体合成新方法及其在Pd-催化不对称烯丙基取代反应中的应用, 分子催化, 2003, 第 1 作者(166) 含二藏铁和吡啶单元的手性席夫碱配体在钌催化的不对称氢转移反应中的应用, Chiral Schiff Base Ligands Containing Ferrocene and Pyridine Units for Ruthenium-Catalyzed Assmmetric Transfer Hydrogenation, CHINESE JOURNAL OF CATALYSIS, 2003, 第 2 作者(167) Syntheses of novel ferrocenylphosphine-amidine ligands and their application in Pd-catalyzed asymmetric allylic alkylation, TETRAHEDRON LETTERS, 2002, 第 1 作者(168) 高效手性膦-亚胺配体用于Pd-催化不对称烯丙基取代反应, Highly effective phosphine-imine ligands for Pd-catalyzed asymmetric allylic alkylation, 14th international conference on organic synthesis, 2000, 第 1 作者(169) 高效手性膦-亚胺配体用于Pd-催化不对称烯丙基取代反应, Highly effective phosphine-imine ligands for Pd-catalyzed asymmetric allylic alkylation, 14th international conference on organic synthesis, 2000, 第 1 作者(170) Copper-catalyzed formal propargylic 3 + 2 cycloaddition for stereoselective construction of (E)-β-pyrazolylacrylates, TETRAHEDRON LETTERS, 通讯作者
发表著作
(1) Chiral Amine Synthesis, Chiral Amine Synthesis, Wiley-VCH, 2010-10, 第 1 作者(2) Asymmetric Catalysis from a Chinese Perspective, Asymmetric Catalysis from a Chinese Perspective, Springer, 2011-08, 第 1 作者
科研活动
科研项目
( 1 ) 新型配体设计、合成及在功能有机分子合成中的应用研究, 负责人, 研究所自主部署, 2011-04--2016-04( 2 ) 精细化学品及关键中间体的技术开发, 负责人, 其他国际合作项目, 2013-07--2016-07( 3 ) 3,3-亚氨基二丙腈制备氨基丙腈技术, 负责人, 其他国际合作项目, 2013-05--2016-05( 4 ) 氢化催化剂和配体的技术开发, 负责人, 其他国际合作项目, 2014-06--2019-06( 5 ) Cu-催化炔丙醇酯与双亲核试剂间的不对称环加成反应研究, 负责人, 国家任务, 2016-01--2019-12( 6 ) 新型手性P,N,N-配体的构建及其在Cu-催化不对称炔丙基取代反应中的应用研究, 负责人, 国家任务, 2018-01--2021-12( 7 ) 精异丙甲草胺原药工艺开发, 负责人, 境内委托项目, 2017-03--2026-12( 8 ) 手性N-(2-乙基-6-甲基苯基)-1-甲氧基-2-丙胺(MEA)的合成新技术开发, 负责人, 境内委托项目, 2017-04--2022-04( 9 ) 反式右旋第一菊酸的不对称合成中试研究, 负责人, 境内委托项目, 2019-04--2021-04( 10 ) 用于精异丙甲草胺类除草剂合成中的高效手性催化剂制备技术, 负责人, 地方任务, 2018-01--2020-12( 11 ) 新型手性膦-亚磷酰胺酯配体的构建及其在不对称催化反应中的应用研究, 负责人, 国家任务, 2021-01--2024-12( 12 ) 农药制备新技术开发, 负责人, 境内委托项目, 2024-01--2028-12( 13 ) 原料采购合同(手性加氢催化剂), 负责人, 境内委托项目, 2024-04--2026-12( 14 ) 手性N-(2-乙基-6-甲基苯基)-1-甲氧基-2-丙胺的催化不对称合成研究, 负责人, 境内委托项目, 2023-04--2025-04( 15 ) 原料采购合同(手性加氢催化剂), 负责人, 境内委托项目, 2024-01--2026-12( 16 ) 购销合同(环丙烷化催化剂), 负责人, 境内委托项目, 2022-03--2024-12( 17 ) 购销合同(开平牵牛生化制药有限公司), 负责人, 境内委托项目, 2022-03--2025-03