• 团簇化学
• 理论模拟
• 质谱技术
• 能源催化

   

070304-物理化学

质谱技术
团簇催化
理论计算

2009-09--2015-07   中国科学院金属研究所   博士
2005-09--2009-07   河北工业大学   学士

2019-01~2021-02,马普化学能源转化研究所, 博士后
2015-08~2018-12,柏林工业大学, 博士后

   

[1] Journal of the American Chemical Society. 2025, 第 9 作者  通讯作者  
[2] Angewandte Chemie International Edition. 2025, 第 5 作者  通讯作者  
[3] Journal of the American Chemical Society. 2025, 第 6 作者  通讯作者  
[4] Journal of the American Chemical Society. 2025, 第 6 作者  通讯作者  
[5] Coordination Chemistry Reviews. 2024,   通讯作者  
[6] Physical Chemistry Chemical Physics. 2024,   通讯作者  
[7] 质谱学报. 2024,   通讯作者  
[8] Angewandte Chemie International Edition. 2024,   通讯作者  
[9] 张丽丽, 周健, 房聪, 孙晓岩. 基于软电离质谱技术的金属纳米团簇合成、结构解析与催化反应机理研究的进展. 质谱学报[J]. 2024, 第 4 作者45(1): 69-89, https://zpxb.xml-journal.net/article/doi/10.7538/zpxb.2023.0088.
[10] 马智明, 于博 （共同第一作者）, 刘世强, 刘义凡, Ken Motokura, 孙晓岩, 杨勇. Single-Atom palladium engineered cobalt nanocomposite for selective aerobic oxidation of sulfides to sulfoxides. Journal of Colloid and Interface Science[J]. 2024, 第 6 作者null(null): 
[11] Nat. Commun.. 2023,   通讯作者  
[12] Zhang, Lili, Guo, Mengdi, Zhou, Jian, Fang, Cong, Sun, Xiaoyan. Benchmark Models for Elucidating Ligand Effects: Thiols Ligated Isostructural Cu 6 Nanoclusters. SMALL[J]. 2023, 第 5 作者  通讯作者  19(41): https://www.webofscience.com/wos/woscc/full-record/WOS:001009887200001.
[13] 张丽丽, 郭梦迪, 房聪, 周健, 孙晓岩. Benchmark Models for Elucidating Ligand Effects: Thiols Ligated Isostructural Cu6 Nanoclusters. Small[J]. 2023, 第 5 作者  通讯作者  
[14] Guo, Mengdi, Zhou, Shaodong, Sun, Xiaoyan. Room-Temperature Conversion of Methane to Methanediol by FeO2+. JOURNAL OF PHYSICAL CHEMISTRY LETTERS. 2023, 第 3 作者  通讯作者  1633-1640, http://dx.doi.org/10.1021/acs.jpclett.2c03786.
[15] Qun Yu, Jian Zhou, Wenquan Wang, De-Chang Li, Xiaoyan Sun, Guang-Hui Wang. Space-confined Carbon-doped Pd Nanoparticles as Highly Efficient Catalyst for Selective Phenol Hydrogenation. ACS Catalysis[J]. 2023, 第 5 作者  通讯作者  13: 3925-3933, 
[16] 李庆林, 房聪, 孙晓岩, 杨勇. Modulating the Oxidation State of Titanium via Dual Anions Substitution for Efficient N2 Electroreduction. Small[J]. 2022, 第 3 作者  通讯作者  https://onlinelibrary.wiley.com/doi/10.1002/smll.202201343.
[17] Ding, Yuxiao, Zhang, Pengfei, Xiong, Hailong, Sun, Xiaoyan, Klyushin, Alexander, Zhang, Bingsen, Liu, Zigeng, Zhang, Jinshui, Zhu, Huiyuan, Qiao, ZhenAn, Heumann, Saskia, Dai, Sheng. Tuning regioselective oxidation toward phenol via atomically dispersed iron sites on carbon. GREEN CHEMISTRY[J]. 2020, 第 4 作者22(18): 6025-6032, https://www.webofscience.com/wos/woscc/full-record/WOS:000571356300033.
[18] Sun, Xiaoyan, Zhou, Shaodong, Yue, Lei, Guo, Cheng, Schlangen, Maria, Schwarz, Helmut. On the Remarkable Role of the Nitrogen Ligand in the Gas-Phase Redox Reaction of the N2O/CO Couple Catalyzed by NbN(+). ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2019, 第 1 作者58(11): 3635-3639, http://dx.doi.org/10.1002/anie.201814460.
[19] Zhou, Shaodong, Sun, Xiaoyan, Yue, Lei, Schlangen, Maria, Schwarz, Helmut. Tuning the Reactivities of the Heteronuclear AlnV3-nO7-n(+) (n=1,2) Cluster Oxides towards Methane by Varying the Composition of the Metal Centers. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2019, 第 2 作者25(12): 2967-2971, http://dx.doi.org/10.1002/chem.201805908.
[20] Sun, Xiaoyan, Zhou, Shaodong, Yu, Lei, Schlangen, Maria, Schwarz, Helmut. Thermal Activation of CH4 and H-2 as Mediated by the Ruthenium Oxide Cluster Ions RuOx(+) (x=1-3): On the Influence of Oxidation States. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2019, 第 1 作者25(14): 3550-3559, http://dx.doi.org/10.1002/chem.201806187.
[21] Zhou, Shaodong, Sun, Xiaoyan, Yue, Lei, Schlangen, Maria, Schwarz, Helmut. Selective C-O Coupling Hidden in the Thermal Reaction of Al2CuO5(+) with Methane. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2018, 第 2 作者24(55): 14649-14653, http://dx.doi.org/10.1002/chem.201804059.
[22] Lin, Yangming, Sun, Xiaoyan, Su, Dang Sheng, Centi, Gabriele, Perathoner, Siglinda. Catalysis by hybrid sp(2)/sp(3) nanodiamonds and their role in the design of advanced nanocarbon materials. CHEMICAL SOCIETY REVIEWS[J]. 2018, 第 2 作者47(22): 8438-8473, http://cas-ir.dicp.ac.cn/handle/321008/166644.
[23] Zhou, Shaodong, Sun, Xiaoyan, Yue, Lei, Schlangen, Maria. Mechanistic aspects of methane activation promoted by MO3(+) (M = Mn, Re). INTERNATIONAL JOURNAL OF MASS SPECTROMETRY[J]. 2018, 第 2 作者434: 240-245, http://dx.doi.org/10.1016/j.ijms.2018.10.009.
[24] Zhou, Shaodong, Sun, Xiaoyan, Yue, Lei, Guo, Cheng, Schlangen, Maria, Schwarz, Helmut. Selective Nitrogen-Atom Transfer Driven by a Highly Efficient Intersystem Crossing in the CeON(+)/CH4 System. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2018, 第 2 作者57(48): 15902-15906, http://dx.doi.org/10.1002/anie.201809583.
[25] Sun Xiaoyan. On the Origin of the Distinctly Different Reactivity Behavior of Ruthenium in [MO]+/CH4 Systems (M = Fe, Ru, Os). Angew. Chem. Int. Ed.. 2018, 第 1 作者
[26] Sun, Xiaoyan, Zhou, Shaodong, Yue, Lei, Schlangen, Maria, Schwarz, Helmut. Metal-Free, Room-Temperature Oxygen-Atom Transfer in the N2O/CO Redox Couple as Catalyzed by Si2Ox(center dot+) (x=2-5). ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2017, 第 1 作者56(33): 9990-9993, http://dx.doi.org/10.1002/anie.201703453.
[27] Sun, Xiaoyan, Zhou, Shaodong, Schlangen, Maria, Schwarz, Helmut. Thermal Methane Activation by the Metal-Free Cluster Cation Si2O4(center dot+). CHEMISTRY-A EUROPEAN JOURNAL[J]. 2017, 第 1 作者23(7): 1498-1501, http://dx.doi.org/10.1002/chem.201605496.
[28] Sun, Xiaoyan, Zhou, Shaodong, Schlangen, Maria, Schwarz, Helmut. Efficient Room-Temperature Methane Activation by the Closed-Shell, Metal-Free Cluster OSiOH(+): A Novel Mechanistic Variant. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2016, 第 1 作者22(40): 14257-14263, http://dx.doi.org/10.1002/chem.201601981.
[29] Sun, Xiaoyan, Zhou, Shaodong, Schlangen, Maria, Schwarz, Helmut. Thermal Methane Activation by Si2O5(center dot+) and Si2O5H2(center dot+): Reactivity Enhancement by Hydrogenation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2016, 第 1 作者55(42): 13345-13348, http://dx.doi.org/10.1002/anie.201607864.
[30] Sun, Xiaoyan, Ding, Yuxiao, Zhang, Bingsen, Huang, Rui, Su, Dang Sheng. New insights into the oxidative dehydrogenation of propane on borate-modified nanodiamond. CHEMICALCOMMUNICATIONS[J]. 2015, 第 1 作者51(44): 9145-9148, http://ir.imr.ac.cn/handle/321006/75019.
[31] Ding, Yuxiao, Sun, Xiaoyan, Zhang, Liyun, Mao, Shanjun, Xie, Zailai, Liu, ZhongWen, Su, Dang Sheng. Entrapping an Ionic Liquid with Nanocarbon: The Formation of a Tailorable and Functional Surface. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2015, 第 2 作者54(1): 231-235, http://ir.imr.ac.cn/handle/321006/73784.
[32] Sun, Xiaoyan, Xu, Junyuan, Ding, Yuxiao, Zhang, Bingsen, Feng, Zhenbao, Su, Dang Sheng. The Effect of Different Phosphorus Chemical States on an Onion-like Carbon Surface for the Oxygen Reduction Reaction. CHEMSUSCHEM[J]. 2015, 第 1 作者8(17): 2872-2876, http://dx.doi.org/10.1002/cssc.201500154.
[33] Sun, Xiaoyan, Ding, Yuxiao, Zhang, Bingsen, Huang, Rui, Chen, De, Su, Dang Sheng. Insight into the Enhanced Selectivity of Phosphate-Modified Annealed Nanodiamond for Oxidative Dehydrogenation Reactions. ACS CATALYSIS[J]. 2015, 第 1 作者5(4): 2436-2444, http://ir.imr.ac.cn/handle/321006/73927.
[34] Sun Xiaoyan. Evolution and Reactivity of Active Oxygen Species on sp2@sp3 Core-shell Carbon for Oxidative Dehydrogenation Reaction. ChemCatChem. 2014, 第 1 作者
[35] Sun Xiaoyan, Wang Rui, Su Dangsheng. Research progress in metal-free carbon-based catalysts. CHINESE JOURNAL OF CATALYSIS[J]. 2013, 第 1 作者34(3): 508-523, http://dx.doi.org/10.1016/S1872-2067(11)60515-9.

   

（ 1 ） 泰山学者青年项目, 负责人, 地方任务, 2020-01--2024-12
（ 2 ） 团簇化学与能源催化, 负责人, 研究所自主部署, 2020-06--2024-12
（ 3 ） “掺杂效应”调控能源小分子活化的气相反应研究, 负责人, 国家任务, 2022-01--2024-12
（ 4 ） 同主族纳米团簇的可控制备及电催化性能研究, 负责人, 地方任务, 2022-01--2024-12

（1）基于质谱技术的团簇催化剂设计及反应机理研究   第二十届全国青年催化学术会议   2024-05-10
（2）基于气相团簇的能源小分子催化转化机理研究   中国化学会第33届学术年会   2023-06-17
（3）基于质谱技术的团簇离子分子反应研究   2020-2023 年中国质谱学术大会   2023-06-09
（4）团簇催化能源小分子转化机理研究   第四届团簇科学与原子制造学术研讨会   2023-04-21