刘天赋 女 中国科学院福建物质结构研究所
电子邮件： tfliu@fjirsm.ac.cn
通信地址： 福州市杨桥西路155号
邮政编码： 350002
研究领域
课题组成立于2016年，研究工作聚焦于超分子及氢键有机框架化合物（HOFs、SOFs）的设计、合成与性能研究。从结构化学的角度出发，实验室的研究工作关注于开发新型稳定多孔框架材料，获得对SOFs/HOFs化学更多的理解，并拓展它们的潜在应用范围。研究工作涉及生物医用、异相光/热催化、液体/气体分离与存储等交叉领域。
招生信息
课题组长期招收国内以及国际研究生、博士后。
招生专业
招生方向
教育背景及工作经历
2016.08 – 至今 中国科学院福建物质结构研究所，课题组长，研究员
2015. 04 – 2016.04 美国西北大学，博士后助理研究员
2011. 10 – 2015. 04 美国德州农工大学，博士后助理研究员
2006.09 – 2011.07 中国科学院福建物质结构研究所，博士学位
专利与奖励
1.曹荣，刘天赋，尹琦；基于稠环配体构筑的氢键有机框架材料、其制备方法及应用；申请号：201810220893.9；公布号：108727605 A；公布日期：2018年11月2日。
2. 刘天赋，黄阁；基于杂芳基官能团配体的金属有机框架材料及其制备方法和应用；申请号：202010023346．9；公布日期：2021年1月9日。
3. Hong-Cai Zhou, Tian-Fu Liu, Dawei Feng, Chromium metal organic frameworks and syntheses of metal organic frameworks, 发明, 2015, 美国发明专利: PCT/GB2015/05182
发表论文
54.Qing-Ping Huang, Chao Yang, Qi Yin, An-An Zhang, Hai-Xiong Liu, Lan Li, Mei-Mei Liu, Zhi-Bin Fang*, Tian-Fu Liu*, Building Ultrathin MOL/MOL S-Scheme Heterostructures toward Boosted Photocatalytic Charge Kinetics for Efficient H2 Evolution, Angew. Chem. Int. Ed. 2025, e202502009
https://doi.org/10.1002/anie.202502009
53.Yu-Lin Li‡, Jiang-Feng Lu‡, Qi Yin, Lei Cai, Hui-Jie Jiang, Chen Liu, Gang Xu*, Tian-Fu Liu*, Constructing Biomimetic Channels in Hydrogen-Bonded Organic Framework via Post-Synthesis for Enhanced Proton Conductivity, Angew. Chem. Int. Ed. 2025, e202504396
https://doi.org/10.1002/anie.202504396
52.Yu-Lin Li, An-An Zhang, Qi Yin, Zhi-Bin Fang, Chen Liu, Tian-Fu Liu*, Light-Modulated Electronic States of Pd Nanoclusters Stabilized in Ionic Hydrogen-Bonded Frameworks for Enhanced CO2 Photoreduction, Adv. Funct. Mater. 2025, 2505195
https://doi.org/10.1002/adfm.202505195
51.Yuhang Li‡, Hui Yuan‡, Yi-Lun Cheng‡, Qiu-Xia Li, Rong Cao, Jin-Lin Li, Qi Yin, Can-Zhong Lu*, Tian-Fu Liu*, Hydrogen-bonded organic framework for regulating pathogenic autoantigen and oxidative stress in psoriasis treatment, Natl. Sci. Rev. 2025, 12(6), nwaf132
https://doi.org/10.1093/nsr/nwaf132
50.Bai-Tong Liu‡, Tao Li‡, Sheng-Hao Gong‡, Jia-Chuan Liu, Ze-Yu Ruan, Han Han, Timothy Y.-Z. Li, Yuanning Feng, Rui Wang, Li Gong, Xieming Xu, Rong Cao, Ming-Liang Tong*, J. Fraser Stoddart, Tian-Fu Liu*, Air-stable radical polycyclic aromatic hydrogen-bonded organic frameworks, Chem. 2025, 102445
https://doi.org/10.1016/j.chempr.2025.102445
2024
49.Lei Cai, Mojtaba Khanpour, Qi Yin, Zi-Yu Wang, Zhi-Bin Fang, Hai-Xiong Liu, Ying Hou, Chen Liu, Wenzhuo Deng, Tian-Fu Liu*, Well-Defined Microenvironment in Metal-Organic Frameworks Enable Green, Benign, and Isolation-Free Catalytic Oxidation Reaction, CCS. Chem. 2024
https://doi.org/10.31635/ccschem.024.202404630
48.Lingling Wu, Xue Yang*, Haonan Jia, Lvyao Xiao, Chang Gao, Zhiqi Hu, Jiao Wang, Yanan Guo, Xusheng Wang, Tianfu Liu*, Rong Cao*, Robert Chunhua Zhao*, Freestanding Hydrogen-Bonded Organic Framework Membrane for Efficient Wound Healing. Adv. Mater. 2024, 36(47), 2411229
https://doi.org/10.1002/adma.202411229
47.An-An Zhang, Zi-Xiang Wang, Zhi-Bin Fang, Jin-Lin Li, Tian-Fu Liu*，Long-Range π-π Stacking Brings High Electron Delocalization for Enhanced Photocatalytic Activity in Hydrogen-Bonded Organic Framework，Angew. Chem. Int. Ed. 2024，63(46) e202412777.
https://doi.org/10.1002/anie.202412777
46.Hai-Xiong Liu‡, Zi-Jian Zhou‡, Lei Xie‡, Chen Liu, Lei Cai, Xin-Ping Wu*, Tian-Fu Liu*，Delocalized Orbitals Over Metal Clusters and Organic Linkers Enable Boosted Charge Transfer in Metal-Organic Framework for Overall CO2 Photoreduction，Angew. Chem. Int. Ed. 2024, 63(47) e202411508.
https://doi.org/10.1002/anie.202411508
45.Ying Zou‡, Hai-Xiong Liu‡, Lei Cai, Yu-Hang Li. Jiang-Shan Hu, Chen Liu, Tian-Fu Liu*，Strategy to Efficient Photodynamic Therapy for Antibacterium：Donor-Acceptor Structure in Hydrogen-Bonded Organic Framework，Adv. Mater. 2024, 36(35).
https://doi.org/10.1002/adma.202406026
44.Ying Hou, Xin-Song Huang, Sheng-Hao Gong, Chen Liu, Yangyang Liu*, and Tian-Fu Liu*, Stable hydrogen-bonded organic frameworks and their photo- and electro-responses, Nano Res. 2024, 17,7675-7699.
https://doi.org/10.1007/s12274-024-6665-7
43.Zi-Yu Wang‡, Rui Wang‡, Hannah M. Johnson, Lei Cai, An-An Zhang, Qiang Zhang* and Tian-Fu Liu*, Cationic Radical Metal–Organic Framework Enabling Low Water Evaporation Enthalpy and High Photothermal Conversion Efficiency for Solar-Driven Water Purification, J. Mater. Chem. A, 2024, 12, 12015-12025.
https://doi.org/10.1039/D4TA01126K
42.Rui Wang, Zi-Yu Wang,Yuan Zhang, A. R. Mahammed Shaheer, Tian-Fu Liu*, Rong Cao*,Bridging Atom Engineering for Low-Temperature Oxygen Activation in a Robust Metal-Organic Framework, Angew. Chem. Int. Ed. 2024, 63，e202400160.
https://doi.org/10.1002/anie.202400160
41.Qi Yin, Kuan Pang, Ya-Nan Feng, Lili Han, Ali Morsali, Xi-Ya Li, and Tian-Fu Liu*,Hydrogen bonded Organic Frameworks in Solution: Toward Continuous and High-crystalline Membranes for Gas Separation, Nature Commun. 2024, 15, 634.
https://doi.org/10.1038/s41467-024-44921-z
40.Jian Xiao, A.R. Mahammed Shaheer, Chen Liu, Tian-Fu Liu*, Rong Cao*,Hydrogen-Bonded Organic Framework Core-Shell Composite for Synergistic Antimicrobial Therapy, Aggregate. 2024, 5, e481.
https://doi.org/10.1002/agt2.481
2023
39.Hai-Xiong Liu, Duan-Hui Si, Mallory F. Smith, Ren-Fu Li, Xi-Ya Li, Lan Li, Hai-Bo Huang,Zhi-Bin Fang, Hong-Cai Zhou, Tian-Fu Liu*. Effificient CO2 photoreduction enabled by the energy transfer pathway in metal-organic framework，Aggregate. 2023，4(6).
https://doi.org/10.1002/agt2.383
38.Bai-Tong Liu, Sheng-Hao Gong , Xiao-Tian Jiang, Yuan Zhang, Rui Wang, Zhi-Jie Chen, Shuo Zhang, Kent O. Kirlikovali, Tian-Fu Liu*, Omar K. Farha*, and Rong Cao*，A Solution Processible Single-Crystal Porous Organic Polymer, Nat Synth. 2023，2，873-879.
https://doi.org/10.1038/s44160-023-00316-4
2022
37.Zu-Jin Lin, Shaheer A. R. Mahammed, Tian-Fu Liu,* and Rong Cao*,Multifunctional Porous Hydrogen-Bonded Organic Frameworks: Current Status and Future Perspectives, ACS Cent. Sci. 2022, 8 (12), 1589-1608.
https://doi.org/10.1021/acscentsci.2c01196
36.Rui Wang, Bai-Tong Liu, Shuo Zhang, Xin-Song Huang, Lei Xie, Tian-Fu Liu*, Rong Cao*, Design of a Metal-Organic Framework with Preset Binding Sites for Crystallographic Visualized Metalation, Small Struct. 2022, 3 (10), 2200148.
https://doi.org/10.1002/sstr.202200148
35.Qian-Qian Huang‡, Zhi-Bin Fang‡, Kuan Pang, Wei-Kang Qin, Tian-Fu Liu*, Rong Cao*, The Impact of Secondary Building Units in Metal–Organic Frameworks on Plasmonic Gold-Sensitized Photocatalysis, Adv. Funct. Mater. 2022, 32 (39), 2205147.
https://doi.org/10.1002/adfm.202205147
34.Zhao Xuan‡, Yin Qi‡, Mao Xinnan‡, Cheng Chen, Zhang Liang, Wang Lu*, Liu Tian-Fu*, Li Youyong, Li Yanguang*. Theory-Guided Design of Hydrogen-Bonded Cobaltoporphyrin Frameworks for Highly Selective Electrochemical H2O2 Production in Acid. Nature Commun. 2022, 13, 2721.
https://doi.org/10.1038/s41467-022-30523-0
33. Wei-Kang Qin, Duan-Hui Si, Qi Yin, Xiang-Yu Gao, Qian-Qian Huang, Ya-Nan Feng, Lei Xie, Shuo Zhang, Xin-Song Huang, Tian-Fu Liu,* and Rong Cao,* Reticular Synthesis of Hydrogen-Bonded Organic Frameworks and Their Derivative via Mechanochemistry, Angew. Chem. Int. Ed. 2022, 61 (27) , e202202089.
https://doi.org/10.1002/anie.202202089
32. An-An Zhang‡, Duanhui Si, Haibo Huang, Lei Xie, Zhi-Bin Fang, Tian-Fu Liu*, Rong Cao*, Partial Metalation of Porphyrin Moieties in Hydrogen-Bonded Organic Frameworks Provides Enhanced CO2 Photoreduction Activity, Angew. Chem. Int. Ed. 2022, 61, e202203955.
https://doi.org/10.1002/anie.202203955
31. An-An Zhang, Yu-Lin Li, Zhi-Bin Fang, Lei Xie, Rong Cao, Yangyang Liu,* Tian-Fu Liu,* Facile Preparation of Hydrogen-Bonded Organic Framework/Cu2O Heterostructure Films via Electrophoretic Deposition for Efficient CO2 Photoreduction, ACS Appl. Mater. Interfaces. 2022, 14(18), 21050-21058.
https://doi.org/10.1021/acsami.2c02917
30. Hai–Bo Huang, Zhi–Bin Fang, Rui Wang, Lan Li, Mojtaba Khanpour, Tian-Fu Liu*, Rong Cao*, Engineering Hierarchical Architecture of Metal-Organic Frameworks for Highly Efficient Overall CO2 Photoreduction, Small, 2022, 18(16), 2200407.
https://doi.org/10.1002/smll.202200407
29. Qi Yin, Eugeny V. Alexandrov, Duan-Hui Si, Qian-Qian Huang, Zhi-Bin Fang, Yuan Zhang, An-An Zhang, Wei-Kang Qin, Yu-Lin Li, Tian-Fu Liu*, and Davide M. Proserpio, Metallization-Prompted Robust Porphyrin-Based Hydrogen-Bonded Organic Frameworks for Photocatalytic CO2 Reduction, Angew. Chem. Int. Ed. 2022, 134 (6) , e202115854.
https://doi.org/10.1002/anie.202115854
2021
28. An-An Zhang‡, Xiyue Cheng‡, Xu He, Wei Liu, Shuiquan Deng, Rong Cao* and Tian-Fu Liu*, Harnessing Electrostatic Interactions for Enhanced Conductivity in Metal-Organic Frameworks, Research, 2021, 9874273.
https://spj.science.org/doi/10.34133/2021/9874273
27. Bai-Tong Liu, Xiao-Hong Pan, Ding-Yang Zhang, Rui Wang, Jun-Yu Chen, Han-Ru Fang, Tian-Fu Liu*，Construction of Function-Orientated Core-Shell Nanostructure in Hydrogen-Bonded Organic Framework for Near-infrared Responsive Bacterial Inhibition, Angew. Chem. Int. Ed. 2021, 60 (49) , 25701-25707.
https://doi.org/10.1002/anie.202114168
26. Lan Li†, Zhi-Bin Fang† (equal contribution), Wenzhuo Deng, Jun-Dong Yi, Rui Wang, and Tian-Fu Liu,* Precise Construction of Stable Bimetallic Metal-Organic Frameworks with Single-Site Ti(IV) Incorporation in Nodes for Efficient Photocatalytic Oxygen Evolution, CCS. Chem. 2021, 3, 2839-2849.
https://doi.org/10.31635/ccschem.021.202101241
25. Mojtaba Khanpour, Wen-Zhou Deng, Zhi-Bin Fang, Yu-Lin Li, Qi Yin, An-An Zhang, Farzaneh Rouhani, Ali Morsali,* Tian-Fu Liu,* Radiochromic Hydrogen-Bonded Organic Frameworks for X-ray Detection, Chem. - Eur. J. 2021, 27 (42) , 10957-10965.
https://doi.org/10.1002/chem.202101061
24. Nan Zhang, Qi Yin, Song Guo,* Kai-Kai Chen, Tian-Fu Liu,* Ping Wang, Zhi-Ming Zhang,* Tong-Bu Lu, Hot-electron leading-out strategy for constructing photostable HOF catalysts with outstanding H2 evolution activity, Applied Catalysis B: Environmental, 2021, 296, 120337.
https://doi.org/10.1016/j.apcatb.2021.120337
23. Jing Sun, Xuan Zhang, Dong Zhang, Ying-Pin Chen, Fei Wang, Lan Li, Tian-Fu Liu, Huanghao Yang, Jibin Song,* and Rong Cao*, Building Block Symmetry Relegation Brings Mesopore and Abundant Open Metal Sites in Metal-Organic Frameworks for Cancer Therapy, CCS. Chem. 2021, 3, 1048-1058.
https://doi.org/10.31635/ccschem.021.202000634
22. Tao Li, Bai-Tong Liu, Zhi-Bin Fang, Qi Yin, Rui Wang, and Tian-Fu Liu*, Integrating Active C3N4 Moieties in Hydrogen-bonded Organic Frameworks for Efficient Photocatalysis, J. Mater. Chem. A, 2021, 9, 4687-4691.
https://doi.org/10.1039/D1TA00100K
2020
21. Lan Li, Xu‐Sheng Wang, Tian‐Fu Liu*, and Jinhua Ye*, Titanium‐Based MOF Materials: From Crystal Engineering to Photocatalysis, Small Methods, 2020, 4 (12), 2000486.
https://doi.org/10.1002/smtd.202000486
20. Bai-Tong Liu, Xiao-Hong Pan, Dan-Yue Nie, Xiao-Jing Hu, En-Ping Liu, and Tian-Fu Liu*, Ionic Hydrogen-Bonded Organic Frameworks for Ion-Responsive Antimicrobial Membrane, Adv. Mater. 2020, 32 (48) , 2005912.
https://doi.org/10.1002/adma.202202280
19. Ji-Fei Feng, Tian-Fu Liu* and Rong Cao*, An Electrochromic Hydrogen-Bonded Organic Framework Film, Angew. Chem. Int. Ed. 2020, 59 (50) , 22392.
https://doi.org/10.1002/anie.202006926
18. Zhi-Bin Fang, Ting-Ting Liu, Junxue Liu, Shengye Jin, Xin-Ping Wu, Xue-Qing Gong, Kecheng Wang, Qi Yin, Tian-Fu Liu, Rong Cao*, and Hong-Cai Zhou, Boosting Interfacial Charge-Transfer Kinetics for Efficient Overall CO2 Photoreduction via Rational Design of Coordination Spheres on Metal−Organic Frameworks. J. Am. Chem. Soc. 2020, 142 (28), 12515-12523.
https://doi.org/10.1021/jacs.0c05530
17. Hai-Xiong Liu‡, Ting-Ting Liu‡, Tao Huang, Zhi-Bin Fang, Lan Li, Qi Yin, Rong Cao, Xue-Qing Gong*, Tian-Fu Liu*, Drastic Change of Electronic Band Structure with Preserved Topology and Porosity, J. Mater. Chem. A, 2020, 8, 12370-12377.
https://doi.org/10.1039/D0TA03905E
16. Bai-tong Liu, En-ping Liu, Rong-Jian Sa,* Tian-fu Liu*, Crystalline Hydrogen-Bonded Organic Chains Achieving Ultralong Phosphorescence via Triplet–Triplet Energy Transfer, Adv. Optical Mater. 2020, 8 (12) , 2000281.
https://doi.org/10.1002/adom.202000281
15. Ge Huang, Li Yang, Qi Yin, Zhi-Bin Fang, Xiao-Jing Hu, An-An Zhang, Jun Jiang, Tian-Fu Liu*, and Rong Cao*. A Comparison of Two Isoreticular Metal-Organic Frameworks with Cationic and Neutral Skeletons: Stability, Mechanism, and Functionality. Angew. Chem. Int. Ed. 2020, 59 (11) , 4385.
https://doi.org/10.1002/anie.201916649
14. Li Yu-Lin, Eugeny V. Alexandrov, Yin Qi, Li Lan, Fang Zhi-Bin, Yuan Wenbing*, Davide M. Proserpio* and Liu Tian-Fu*, Record Complexity in the Polycatenation of Three Porous Hydrogen-bonded Organic Frameworks with Stepwise Adsorption Behaviors. J. Am. Chem. Soc. 2020, 142 (15) , 7218.
https://doi.org/10.1021/jacs.0c02406
2019
13. Xiao-Jing Hu, Zi-Xuan Li, Huan Xue, Xinsong Huang, Rong Cao, Tian-Fu Liu*, Designing a bifunctional Brønsted acid-base heterogeneous catalyst through precise installation of ligands on metal-organic frameworks, CCS Chem. 2019, 1 (2), 616–622.
https://doi.org/10.31635/ccschem.019.201900040
12. Qi Yin, Yu-Lin Li, Lan Li, Jian Lü, Tian-Fu Liu*, Rong Cao*, Novel Hierarchical Meso-Microporous Hydrogen-bonded Organic Framework for Selective Separation of Acetylene and Ethylene versus Methane, ACS Appl. Mater. Interfaces, 2019, 11 (19) , 17823–17827.
https://doi.org/10.1021/acsami.9b03696
11. Yue Xie, Zhibin Fang, Lan Li, Hongxun Yang*, and Tian-Fu Liu*, Creating Chemisorption Sites for Enhanced CO2 Photoreduction Activity through Alkylamine Modification of MIL-101-Cr, ACS Appl. Mater. Interfaces, 2019, 11 (30) , 27017−27023.
https://doi.org/10.1021/acsami.9b09436
10. Qi Yin, Jian Lü, Hong-Fang Li, Tian-Fu Liu*, Rong Cao*, A Robust Microporous Porphyrin-based Hydrogen-bonded Organic Framework for Highly Selective Separation of C2 Hydrocarbons versus Methane, Cryst. Growth Des. 2019, 19 (7) , 4157-4161.
https://doi.org/10.1021/acs.cgd.9b00628
9. Lan Li, Jun-Dong Yi, Zhi-Bin Fang, Xu-Sheng Wang, Nan Liu, Ya-Nan Chen, Tian-Fu Liu* and Rong Cao, Creating Giant Secondary Building Layers via Alkali-Etching Exfoliation for Precise Synthesis of Metal-Organic Frameworks Chemistry of Materials, Chem. Mater. 2019, 31 (18) , 7584−7589.
https://doi.org/10.1021/acs.chemmater.9b02375
2018
8. Qi Yin, Peng Zhao, Rong-Jian Sa, Guang-Cun Chen, Jian Lü, Tian-Fu Liu*, Rong Cao*, An Ultra-Robust and Crystalline Redeemable Hydrogen-Bonded Organic Framework for Synergistic Chemo-Photodynamic Therapy, Angew. Chem. Int. Ed. 2018, 57 (26) , 7691-7696.
https://doi.org/10.1002/anie.201800354
Before 2017
7. Tian-Fu Liu, Nicolaas A. Vermeulen, Ashlee J. Howarth, Peng Li, Amy A. Sarjeant, Joseph T. Hupp, Omar K. Farha*, Adding to the Arsenal of Zirconium-Based Metal-Organic Frameworks: the Topology as a Platform for Solvent-Assisted Metal Incorporation, Eur. J. Inorg. Chem. 2016, 27, 4349-4352.
6. Shuai Yuan†, Tian-Fu Liu† (equal contribution), Dawei Feng, Jian Tian, Kecheng Wang, Junsheng Qin, Qiang Zhang, Yingpin Chen, Mathieu Bosch, Lanfang Zou, Scott J. Dalgarno, Hong-Cai Zhou*, “A Single Crystalline Porphyrinic Titanium Metal−Organic Framework,” Chem. Sci. 2015, 6 (7), 3926-3930.
5. Dahuan Liu†, Tian-Fu Liu† (equal contribution), Ying-Pin Chen, Lanfang Zou, Dawei Feng, Kecheng Wang, Qiang Zhang, Shuai Yuan, Chongli Zhong, and Hong-Cai Zhou*, “A Reversible Crystallinity-Preserving Phase Transition in Metal-Organic Frameworks: Discovery, Mechanistic Studies, and Potential Applications,” J. Am. Chem. Soc. 2015, 137 (24), 7740-7746.
4. Tian-Fu Liu†, Dawei Feng† (equal contribution), Ying-Pin Chen, Lanfang Zou, Mathieu Bosch, Shuai Yuan, Zhangwen Wei, Stephen Fordham, Kecheng Wang, and Hong-Cai Zhou*, “Topology Guided Design and Syntheses of Highly Stable Mesoporous Porphyrinic Zirconium MOFs with High Surface Area,” J. Am. Chem. Soc. 2015, 137 (1), 413-419.
3. Tian-Fu Liu, Lanfang Zou, Dawei Feng, Ying-Pin Chen, Stephen Fordham, Xuan Wang, Yangyang Liu, Hong-Cai Zhou*, “Stepwise Synthesis of Robust Metal-Organic Frameworks via Post-Synthetic Metathesis and Oxidation of Metal Nodes in a Single-Crystal to Single-Crystal Transformation,” J Am. Chem. Soc. 2014, 136 (22), 7813–7816.
2. Dawei Feng†, Tian-Fu Liu† (equal contribution), Jie Su, Mathieu Bosch, Zhangwen Wei, Wei Wan, Ying-Pin Chen, Xuan Wang, Kecheng Wang, Xizhen Lian, Zhi-Yuan Gu, Jihye Park, Daqiang Yuan, Xiaodong Zou, Hong-Cai Zhou*, “Stable Metal-Organic Frameworks Containing Single-Molecule Traps for Enzyme Encapsulation,” Nature Comm. 2014. 6, 5979.
1. Tian-Fu Liu, Ying-Pin Chen, Andrey A Yakovenko, Hongcai Zhou*, “An Interconversion between Discrete and a Chain of Nanocages: Self-Assembly via a Solvent-Driven, Dimension-Augmentation Strategy,” J. Am. Chem. Soc. 2012, 134 (42), 17358- 17361.