新型功能超分子化合物的设计合成与性能
仿生金属簇合物的结构调控与性能研究

   

070301-无机化学
070304-物理化学（含：化学物理）

新型功能超分子化合物的设计合成与性能
仿生金属簇合物的结构调控与性能研究

2001-03--2006-01 英国纽卡斯尔大学(University of Newcastle Upon Tyne) 理学博士
1987-09--1991-07 厦门大学化学系 学士

-- 研究生

-- 博士

   

2006-07--今 福建物质结构研究所 副研究员
1991-08--2001-02 福建物质结构研究所工作 助理研究员

   

（1） 金属簇合物红外非线性光学材料的研究，三等奖，省级，2003

   

[1] Zhang, Kai, Lin, Ping, Du, ShaoWu. Facile and scalable synthesis of Ti6Mn2 oxo-cluster nanocrystals with flower-like morphology and excellent photocatalytic properties. DALTON TRANSACTIONS[J]. 2020, 49(8): 2444-2451, https://www.webofscience.com/wos/woscc/full-record/WOS:000517990300009.
[2] Zhang, Huabin, Zhang, Mingjian, Lin, Ping, Malgras, Victor, Tang, Jing, Alshehri, Saad M, Yamauchi, Yusuke, Du, Shaowu, Zhang, Jian. A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2016, 22(3): 1141-1145, https://www.webofscience.com/wos/woscc/full-record/WOS:000368906200037.
[3] Han, YunHu, Tian, ChongBin, Lin, Ping, Du, ShaoWu. An unprecedented anionic Ln-MOF with a cage-within-cage motif: spontaneous reduction and immobilization of ion-exchanged Pd(II) to Pd-NPs in the framework. JOURNAL OF MATERIALS CHEMISTRY A[J]. 2015, 3(48): 24525-24531, http://dx.doi.org/10.1039/c5ta04937g.
[4] Han, YunHu, Tian, ChongBin, Lin, Ping, Du, ShaoWu. An unprecedented anionic Ln-MOF with a cage-within-cage motif: spontaneous reduction and immobilization of ion-exchanged Pd(II) to Pd-NPs in the framework. JOURNAL OF MATERIALS CHEMISTRY A[J]. 2015, 3(48): 24525-24531, http://dx.doi.org/10.1039/c5ta04937g.
[5] Feng, Yanan, Chen, Chi, Liu, Zhuguang, Fei, Binjie, Lin, Ping, Li, Qipeng, Sun, Shigang, Du, Shaowu. Application of a Ni mercaptopyrimidine MOF as highly efficient catalyst for sunlight-driven hydrogen generation. JOURNAL OF MATERIALS CHEMISTRY A[J]. 2015, 3(13): 7163-7169, http://dx.doi.org/10.1039/c5ta00136f.
[6] Zhang, Huabin, Lin, Ping, Chen, Erxia, Tan, Yanxi, Wen, Tian, Aldalbahi, Ali, Alshehri, Saad M, Yamauchi, Yusuke, Du, Shaowu, Zhang, Jian. Encapsulation of an Interpenetrated Diamondoid Inorganic Building Block in a Metal-Organic Framework. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2015, 21(13): 4931-4934, https://www.webofscience.com/wos/woscc/full-record/WOS:000352140000008.
[7] Han, YunHu, Liu, YueCheng, Xing, XiuShuang, Tian, ChongBin, Lin, Ping, Du, ShaoWu. Chiral template induced homochiral MOFs built from achiral components: SHG enhancement and enantioselective sensing of chiral alkamines by ion-exchange. CHEMICAL COMMUNICATIONS[J]. 2015, 51(77): 14481-14484, https://www.webofscience.com/wos/woscc/full-record/WOS:000361206000014.
[8] Xue LiPing, Liu YueCheng, Han YunHu, Tian ChongBin, Li QiPeng, Lin Ping, Du ShaoWu. New Zn(II)/M(I) (M = Na, K and Rb) Metal-organic Frameworks Based on 5-Methylisophthalic Acid Ligand: Syntheses, Structures and Fluorescent Property. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY[J]. 2014, 33(8): 1191-1198, https://www.webofscience.com/wos/woscc/full-record/WOS:000341071000013.
[9] XUE Li-Ping, LIU Yue-Cheng, HAN Yun-Hu, LI Qi-Peng, TIAN Chong-Bin, LIN Ping, DU Shao-Wu. A New Acentric Heterometallic Inorganic-organic Hybrid Framework ZnK2(m-BDC)2(H20)2n: Fluorescent, NLO and Ferroelectric Properties. 结构化学[J]. 2014, 33(9): 1360-1366, http://lib.cqvip.com/Qikan/Article/Detail?id=664291399.
[10] Li, Qipeng, Qian, Jinjie, Tian, Chongbin, Lin, Ping, He, Zhangzhen, Wang, Ning, Shen, Jinni, Zhang, Huabin, Chu, Tao, Yuan, Daqiang, Yang, Yi, Xue, Liping, Du, Shaowu. Butterfly-like enantiomerically homochiral {(Co6Co4III)-Co-II} clusters exhibiting both slow magnetic relaxation and ferroelectric property. DALTON TRANSACTIONS[J]. 2014, 43(8): 3238-3243, https://www.webofscience.com/wos/woscc/full-record/WOS:000330785100027.
[11] Zhang, Huabin, Shan, Xiaochen, Ma, Zuju, Zhou, Liujiang, Zhang, Mingjian, Lin, Ping, Hu, Shengmin, Ma, En, Li, Renfu, Du, Shaowu. A highly luminescent chameleon: fine-tuned emission trajectory and controllable energy transfer. JOURNAL OF MATERIALS CHEMISTRY C[J]. 2014, 2(8): 1367-1371, https://www.webofscience.com/wos/woscc/full-record/WOS:000331508400002.
[12] Zhang, Huabin, Lin, Ping, Shan, Xiaochen, Han, Liwei, Du, Shaowu. Absolute helicity induction: chiral information transfer from metal centre to the framework. CRYSTENGCOMM[J]. 2014, 16(7): 1245-1248, https://www.webofscience.com/wos/woscc/full-record/WOS:000330780900005.
[13] Tian, ChongBin, Yuan, DaQiang, Han, YunHu, Li, ZhiHua, Lin, Ping, Du, ShaoWu. Synthesis, structures, and magnetic properties of a series of new heterometallic hexanuclear Co(2)Ln(4) (Ln = Eu, Gd, Tb and Dy) clusters. INORGANIC CHEMISTRY FRONTIERS[J]. 2014, 1(9): 695-704, https://www.webofscience.com/wos/woscc/full-record/WOS:000364543000006.
[14] Liu, Yuecheng, Zhang, Huabin, Tian, Chongbin, Lin, Ping, Du, Shaowu. Interweaving of two enantiomorphic 3D Cd(II)/K(I) coordination polymers with homochiral unequal triple concentric helical chains. CRYSTENGCOMM[J]. 2013, 15(26): 5201-5204, https://www.webofscience.com/wos/woscc/full-record/WOS:000320223900001.
[15] Zhang, Huabin, Shan, Xiaochen, Zhou, Liujiang, Lin, Ping, Li, Renfu, Ma, En, Guo, Xiangguang, Du, Shaowu. Full-colour fluorescent materials based on mixed-lanthanide(III) metal-organic complexes with high-efficiency white light emission. JOURNAL OF MATERIALS CHEMISTRY C[J]. 2013, 1(5): 888-891, https://www.webofscience.com/wos/woscc/full-record/WOS:000314803600002.
[16] Zhang, Huabin, Lin, Ping, Zou, Guodong, Shan, Xiaochen, Du, Fenglei, Du, Shaowu. An unusual highly connected 3D net with hydrophilic pore surface. CRYSTENGCOMM[J]. 2013, 15(15): 3016-3021, https://www.webofscience.com/wos/woscc/full-record/WOS:000316224000031.
[17] Zhang, Huabin, Lin, Ping, Shan, Xiaochen, Du, Fenglei, Li, Qipeng, Du, Shaowu. An inorganic-organic composite framework with an unprecedented 3D heterometallic inorganic connectivity and white-light emission. CHEMICAL COMMUNICATIONS[J]. 2013, 49(22): 2231-2233, https://www.webofscience.com/wos/woscc/full-record/WOS:000315168800018.
[18] Zhang, Huabin, Zhou, Liujiang, Wei, Jing, Li, Zhihua, Lin, Ping, Du, Shaowu. Highly luminescent and thermostable lanthanide-carboxylate framework materials with helical configurations. JOURNAL OF MATERIALS CHEMISTRY[J]. 2012, 22(39): 21210-21217, http://dx.doi.org/10.1039/c2jm34088g.
[19] Tian, ChongBin, Zhang, HuaBin, Peng, Yan, Xie, YunEn, Lin, Ping, Li, ZhiHua, Du, ShaoWu. Synthesis, Structures, and Magnetic Properties of Three 3D Coordination Polymers Based on M4O4 Cubanes (M = MnII, FeII, CoII). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY[J]. 2012, 2012(25): 4029-4035, https://www.webofscience.com/wos/woscc/full-record/WOS:000307950500011.
[20] Xie, YunEn, Tian, ChongBing, Zhang, HuaBin, Peng, Yan, Li, XianQiang, Li, ZhiHua, Lin, Ping, Du, ShaoWu. A new 2D honeycomb-like cluster polymer built by a {Mn6Na3} cluster: Synthesis and magnetic property. INORGANIC CHEMISTRY COMMUNICATIONS[J]. 2012, 15: 198-201, http://dx.doi.org/10.1016/j.inoche.2011.10.023.
[21] Zhang, Huabin, Li, Ning, Tian, Chongbin, Liu, Tianfu, Du, Fenglei, Lin, Ping, Li, Zhihua, Du, Shaowu. Unusual High Thermal Stability within a Series of Novel Lanthanide TATB Frameworks: Synthesis, Structure, and Properties (TATB=4,4 ',4 ''-s-Triazine-2,4,6-triyl-tribenzoate). CRYSTAL GROWTH & DESIGN[J]. 2012, 12(2): 670-678, https://www.webofscience.com/wos/woscc/full-record/WOS:000300470600018.
[22] Zhang, Huabin, Zhang, Mingjian, Tian, Chongbin, Li, Ning, Lin, Ping, Li, Zhihua, Du, Shaowu. An effective method for the synthesis of 3D inorganic Ln(III)-K(I) sulfate open frameworks with unusually high thermal stability: in situ generation of sulfate anions. JOURNAL OF MATERIALS CHEMISTRY[J]. 2012, 22(14): 6831-6837, https://www.webofscience.com/wos/woscc/full-record/WOS:000301459500045.
[23] Li, XianQiang, Zhang, HuaBin, Wu, ShuTing, Lin, JianDi, Lin, Ping, Li, ZhiHua, Du, ShaoWu. Synthesis, structures and luminescent properties of new Pb(II)/M(I) (M = K, Rb and Cs) frameworks based on dicarboxylic acids: a novel icosahedral Pb6-M6 SBU. CRYSTENGCOMM[J]. 2012, 14(3): 936-944, http://dx.doi.org/10.1039/c1ce06111a.
[24] Peng, Yan, Tian, ChongBin, Zhang, HuaBin, Li, ZhiHua, Lin, Ping, Du, ShaoWu. Synthesis, structure and magnetic study of a novel mixed-valent (Co10Co4III)-Co-II shield constructed by mixed pyridine-alcoholate ligands. DALTON TRANSACTIONS[J]. 2012, 41(16): 4740-4743, https://www.webofscience.com/wos/woscc/full-record/WOS:000302023800004.
[25] Zhang, Huabin, Wu, Shuting, Tian, Chongbin, Lin, Zujin, Li, Zhihua, Lin, Ping, Du, Shaowu. Two enantiomorphic 3D Zn(II)-carboxylate MOFs with double helical structures serving as a chiral source induced by hydrogen bonding. CRYSTENGCOMM[J]. 2012, 14(12): 4165-4167, https://www.webofscience.com/wos/woscc/full-record/WOS:000304660000015.
[26] Tian, ChongBin, He, ZhangZhen, Li, ZhiHua, Lin, Ping, Du, ShaoWu. Two new ferrimagnetic Mn-II-carboxylate coordination polymers constructed from 5-tert-butyl isophthalic acid with (5/2,15/2) and (5/2,10/2) spin topologies. CRYSTENGCOMM[J]. 2011, 13(8): 3080-3086, http://ir.fjirsm.ac.cn/handle/335002/1511.
[27] Lin, JianDi, Long, XiFa, Lin, Ping, Du, ShaoWu. A Series of Cation-Templated, Polycarboxylate-Based Cd(II) or Cd(II)/Li(I) Frameworks with Second-Order Nonlinear Optical and Ferroelectric Properties. CRYSTAL GROWTH & DESIGN[J]. 2010, 10(1): 146-157, http://ir.fjirsm.ac.cn/handle/335002/2198.
[28] Li ZhiHua, Lin JianDi, Tian ChongBin, Lin Ping, Du ShaoWu. A New Layer W/Cu/S Polymer with Heterobimetallic Nodes and Tridentate Trithiocyanuric Acid. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY[J]. 2010, 29(12): 1874-1878, http://lib.cqvip.com/Qikan/Article/Detail?id=36294904.
[29] Tian, ChongBin, Li, ZhiHua, Lin, JianDi, Wu, ShuTing, Du, ShaoWu, Lin, Ping. Cluster-Based Cu-II-Azide Polymers: Synthesis, Structure, Magnetic Properties, and Effect of Polyamines on Crystal Structures. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY[J]. 2010, 427-437, http://ir.fjirsm.ac.cn/handle/335002/2396.
[30] Weng HuaSen, Lin Ping, Du ShaoWu. Three New d(10) Coordination Polymers with Arenedisulfonates: Syntheses, Crystal Structures and Luminescent Properties. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY[J]. 2009, 28(6): 752-760, http://lib.cqvip.com/Qikan/Article/Detail?id=30657087.
[31] Weng, HuaSen, Lin, JianDi, Long, XiFa, Li, ZhiHua, Lin, Ping, Du, ShaoWu. Syntheses, topological analyses and photoelectric properties of Ag(I)/Cu(I) metal-organic frameworks based on a tetradentate imidazolate ligand. JOURNAL OF SOLID STATE CHEMISTRY[J]. 2009, 182(6): 1408-1416, http://dx.doi.org/10.1016/j.jssc.2009.03.012.
[32] Lin, JianDi, Lin, MeiZhen, Tian, ChongBin, Lin, Ping, Du, ShaoWu. Syntheses, topological structures and physical properties of two 2D lanthanide-organic frameworks constructed from 5-nitroisophthalic acid. JOURNAL OF MOLECULAR STRUCTURE[J]. 2009, 938(1-3): 111-116, http://dx.doi.org/10.1016/j.molstruc.2009.09.010.
[33] Li JianRong, Lin Ping, Li ZhiHua, Du ShaoWu. Syntheses and Characterization of Two Novel Mo(W)/Cu/S Dodecanuclear Clusters with Triple Incomplete Cubane-like Structure. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY[J]. 2009, 28(11): 1475-1479, http://lib.cqvip.com/Qikan/Article/Detail?id=32209132.
[34] Li, Zhihua, Lin, Ping, Du, Shaowu. Four W(Mo)/Cu/S complexes containing N-heterocyclic thiones as linkers: Synthesis, structures and optical properties. JOURNAL OF MOLECULAR STRUCTURE[J]. 2008, 892(1-3): 182-187, http://dx.doi.org/10.1016/j.molstruc.2008.05.020.
[35] Li, Zhihua, Li, Xiuling, Lin, Ping, Du, Shaowu. Self-assembly of 1D coordination polymers containing copper(I) tert-butylthiolato clusters: Structural characterization and properties. JOURNAL OF CLUSTER SCIENCE[J]. 2008, 19(2): 357-366, http://ir.fjirsm.ac.cn/handle/350002/5602.
[36] Li, ZhiHua, Lin, Ping, Du, ShaoWu. Syntheses and characterization of three novel W(Mo)/Cu/S cluster-based layered polymers with 1,3,4-thiadiazole-2,5-dithiolate (SSS): Intriguing coordination modes of SSS. POLYHEDRON[J]. 2008, 27(1): 232-240, http://dx.doi.org/10.1016/j.poly.2007.09.003.
[37] Zhou, Hui, Lin, Ping, Li, ZhiHua, Du, ShaoWu. Four new coordination polymers based on multinuclear Cu(I) halide clusters and 1,3-bis(imidazol-1-yl-methyl)-benzene. JOURNAL OF MOLECULAR STRUCTURE[J]. 2008, 881(1-3): 21-27, http://dx.doi.org/10.1016/j.molstruc.2007.08.028.
[38] Song, Li, Lin, Ping, Li, ZhiHua, Li, JianRong, Du, ShaoWu, Wu, XinTao. W/Cu(Ag)/S complexes containing bridging diphosphine ligands: Synthesis, structures and optical properties. POLYHEDRON[J]. 2007, 26(6): 1199-1204, http://dx.doi.org/10.1016/j.poly.2006.10.013.
[39] Song, Li, Li, Jianrong, Lin, Ping, Li, Zhihua, Li, Tao, Du, Shaowu, Wu, Xintao. Synthesis and crystal structures of multidimensional coordination polymers based on W/Cu/S clusters with flexible imidazole ligands. INORGANIC CHEMISTRY[J]. 2006, 45(25): 10155-10161, http://www.corc.org.cn/handle/1471x/2379522.
[40] Lin, Ping, Clegg, William, Harrington, Ross W, Henderson, Richard A, Fletcher, Ashleigh J, Bell, Jon, Thomas, K Mark. Assembly of heterometallic clusters and coordination polymers by combining Mo-S-based clusters with Mn2+. INORGANIC CHEMISTRY[J]. 2006, 45(10): 4284-4302, https://www.webofscience.com/wos/woscc/full-record/WOS:000237593100060.
[41] Lin, P, Clegg, W, Harrington, RW, Henderson, RA. Synthesis and structures of 5-(pyridyl) tetrazole complexes of Mn(II). DALTON TRANSACTIONS[J]. 2005, 2388-2394, https://www.webofscience.com/wos/woscc/full-record/WOS:000230286600010.
[42] Lin, P, Smyth, L, Waldram, A, Henderson, RA. Kinetics of the reactions between S2MoS2Cu(SC6H4R-4)(2-)(R = MeO, H, Cl or NO2) and CN-: substitution mechanism at a 3-coordinate Cu-I site. DALTON TRANSACTIONS[J]. 2005, 3173-3178, https://www.webofscience.com/wos/woscc/full-record/WOS:000231979300010.
[43] Lin, P, Clegg, W, Harrington, RW, Henderson, RA. Synthesis and characterization of a Mo/Ag/Rb heterotrimetallic cluster with double-cage architecture. DALTON TRANSACTIONS[J]. 2005, 2349-2351, https://www.webofscience.com/wos/woscc/full-record/WOS:000230286600004.
[44] Lin, P, Henderson, RA, Harrington, RW, Clegg, W, Wu, CD, Wu, XT. New 1-and 2-dimensional polymeric structures of cyanopyridine complexes of Ag-I and Cu-I. INORGANIC CHEMISTRY[J]. 2004, 43(1): 181-188, https://www.webofscience.com/wos/woscc/full-record/WOS:000187971500022.
[45] 吴新涛, 王泉明, 余珩, 盛天录, 林平, 吴彪, 陈玲. The Synthesis and Crystallographic Characterization of Heterotrimetall. 结构化学[J]. 1998, 17(5): 361, http://lib.cqvip.com/Qikan/Article/Detail?id=5081370.
[46] 林平. "Synthesis and characterization of the Novel Dodecanuclear Heterobimetallic Cage Clusters: [NEt4]2[(M2Cu2S2O2edt2)3(u6-S2)]-CH2Cl2 (M = Mo, W; edt = -SC2H4S-). Inorg. Chem. 1998, 37, 5672-5675. 1998, 
[47] 林平. "Synthesis and characterization of the first dodecanuclear M-Ag-S cage cluster: [NEt4]2[{M2Ag2S2O2(S2C2H4)2}3(u6-S)]-CH2Cl2-MeCN (M = Mo, W).". Chem. Commun. 1997,1349-1350. 1997,