Heterogeneous catalysis

Synthesis and application of molecular sieve materials

New technology of methanol and/or aromatics conversion

   

1. [1] Zhang, Siyu, Zhang, Xiaomin, Dong, Lei, Zhu, Shengjie, Yuan, Yangyang, Xu, Lei. In situ synthesis of Pt nanoparticles encapsulated in silicalite-1 zeolite via a steam-assisted dry-gel conversion method. CRYSTENGCOMM[J]. 2022, 24(14): 2697-2704, http://dx.doi.org/10.1039/d1ce01718g.
   [2] Miao, Dengyun, Pan, Xiulian, Jiao, Feng, Ji, Yi, Hou, Guangjin, Xu, Lei, Bao, Xinhe. Selective synthesis of para-xylene and light olefins from CO2/H-2 in the presence of toluene. CATALYSIS SCIENCE & TECHNOLOGY[J]. 2021, 11(13): 4521-4528, http://dx.doi.org/10.1039/d1cy00602a.
   [3] Chen, Lei, Zhang, Xiaomin, Han, Qiao, Xu, Lanjian, Zhang, Siyu, Yuan, Yangyang, Xu, Lei. Postsynthesis of hierarchical TS-1 and its unique catalytic performance in the direct hydroxylation of toluene. APPLIED CATALYSIS A-GENERAL[J]. 2020, 598: http://dx.doi.org/10.1016/j.apcata.2020.117588.
   [4] Xu, Lanjian, Yuan, Yangyang, Han, Qiao, Dong, Lei, Chen, Lei, Zhang, Xiaomin, Xu, Lei. High yield synthesis of nanoscale high-silica ZSM-5 zeolites via interzeolite transformation with a new strategy. CATALYSIS SCIENCE & TECHNOLOGY[J]. 2020, 10(23): 7904-7913, http://apps.webofknowledge.com/CitedFullRecord.do?product=UA&colName=WOS&SID=5CCFccWmJJRAuMzNPjj&search_mode=CitedFullRecord&isickref=WOS:000596714600012.
   [5] Xu, Lanjian, Yuan, Yangyang, Zhang, Jie, Zhang, Yanfei, Zhang, Xiaomin, Chen, Lei, Xu, Lei. In situ fabrication of core-shell-structured Beta@Silicalite-1 catalysts by a novel steam-assisted crystallization strategy. CRYSTENGCOMM[J]. 2020, 22(5): 945-954, https://www.webofscience.com/wos/woscc/full-record/WOS:000513784200008.
   [6] Li, Peidong, Han, Qiao, Yuan, Yangyang, Zhang, Xiaomin, Guo, Hongchen, Xu, Lei. The role of boron sites in side-chain alkylation of toluene with methanol and a high performance composite catalyst. CATALYSIS SCIENCE & TECHNOLOGY[J]. 2020, 10(13): 4321-4331, https://www.webofscience.com/wos/woscc/full-record/WOS:000547719400014.
   [7] Han, Qiao, Li, Peidong, Yuan, Yangyang, Zhang, Xiaomin, Guo, Hongchen, Xu, Lei. Efficient synthesis of styrene from toluene with MeOH: Via a ternary composite catalyst. APPLIED CATALYSIS A-GENERAL[J]. 2020, 605: http://dx.doi.org/10.1016/j.apcata.2020.117807.
   [8] Zhang, Jie, Huang, Zhihua, Xu, Lanjian, Zhang, Xiaomin, Zhang, Xinzhi, Yuan, Yangyang, Xu, Lei. Verifying the olefin formation mechanism of the methanol-to-hydrocarbons reaction over H-ZSM-48. CATALYSIS SCIENCE & TECHNOLOGY[J]. 2019, 9(9): 2132-2143, http://cas-ir.dicp.ac.cn/handle/321008/171855.
   [9] Huang, Zhihua, Zhang, Jie, Han, Qiao, Zhang, Xiaomin, Lu, Peng, Xu, Lanjian, Yuan, Yangyang, Xu, Lei. Promoting effects of desilication and dealumination on the catalytic performance of Al-rich HMOR for catalysing naphthalene tert-butylation with tertiary butanol. APPLIED CATALYSIS A-GENERAL[J]. 2019, 572: 80-89, http://www.corc.org.cn/handle/1471x/2372786.
   [10] Li, Peidong, Han, Qiao, Zhang, Xiaomin, Yuan, Yangyang, Zhang, Yanfei, Xu, Li, Guo, Hongchen, Xu, Lei. Explaining the influence of the introduced base sites into alkali oxide modified CsX towards side-chain alkylation of toluene with methanol. RSC ADVANCES[J]. 2019, 9(23): 13234-13242, http://cas-ir.dicp.ac.cn/handle/321008/171895.
   [11] Han, Qiao, Li, Peidong, Zhang, Yanfei, Lu, Peng, Xu, Li, Guo, Hongchen, Xu, Lei. Conversion of MeOH and Toluene into Styrene and Ethylbenzene Using Composite Catalysts Containing MeOH Dehydrogenation Components. CHEMCATCHEM[J]. 2019, 11(6): 1610-1614, http://cas-ir.dicp.ac.cn/handle/321008/165638.
   [12] Li, Peidong, Han, Qiao, Zhang, Xiaomin, Yuan, Yangyang, Zhang, Yanfei, Guo, Hongchen, Xu, Li, Xu, Lei. A new insight into the reaction behaviors of side-chain alkylation of toluene with methanol over CsX. CATALYSIS SCIENCE & TECHNOLOGY[J]. 2018, 8(13): 3346-3356, https://www.webofscience.com/wos/woscc/full-record/WOS:000437183200013.
   [13] Zhang, Jie, Xu, Lanjian, Zhang, Yanfei, Huang, Zhihua, Zhang, Xiaomin, Zhang, Xinzhi, Yuan, Yangyang, Xu, Lei. Hydrogen transfer versus olefins methylation: On the formation trend of propene in the methanol-to-hydrocarbons reaction over Beta zeolites. JOURNAL OF CATALYSIS[J]. 2018, 368: 248-260, http://dx.doi.org/10.1016/j.jcat.2018.10.015.
   [14] Zhang, Yanfei, Xu, Lanjian, Zhang, Jie, Li, Peidong, Yuan, Yangyang, Guo, Hongchen, Zhang, Xiaomin, Xu, Lei. Insight into the dissolution-crystallization strategy towards macro/meso/microporous Silicalite-1 zeolites and their performance in the Beckmann rearrangement of cyclohexanone oxime. CATALYSIS SCIENCE & TECHNOLOGY[J]. 2018, 8(17): 4526-4536, https://www.webofscience.com/wos/woscc/full-record/WOS:000444242800025.
   [15] Zhang, Yanfei, Zhang, Xiaomin, Zhang, Jie, Li, Peidong, Han, Qiao, Xu, Lei, Guo, Hongchen. Understanding of the dissolution-crystallization fabrication strategy towards macro/microporous ZSM-5 single crystals. CRYSTENGCOMM[J]. 2018, 20(42): 6786-6794, http://www.corc.org.cn/handle/1471x/2373138.
   [16] Lu, Peng, GomezHortiguela, Luis, Xu, Lei, Camblor, Miguel A. Synthesis of STW zeolites using imidazolium-based dications of varying length. JOURNAL OF MATERIALS CHEMISTRY A[J]. 2018, 6(4): 1485-1495, http://cas-ir.dicp.ac.cn/handle/321008/168580.
   [17] Qi, Liang, Li, Jinzhe, Wang, Linying, Wang, Chan, Xu, Lei, Liu, Zhongmin. Comparative investigation of the deactivation behaviors over HZSM-5 and HSAPO-34 catalysts during low-temperature methanol conversion. CATALYSIS SCIENCE & TECHNOLOGY[J]. 2017, 7(10): 2022-2031, https://www.webofscience.com/wos/woscc/full-record/WOS:000401907700007.
   [18] Zhang, Yanfei, Lu, Peng, Yuan, Yangyang, Xu, Li, Guo, Hongchen, Zhang, Xiaomin, Xu, Lei. One pot synthesis of hierarchically macro/microporous ZSM-5 single crystals. CRYSTENGCOMM[J]. 2017, 19(32): 4713-4719, http://cas-ir.dicp.ac.cn/handle/321008/149801.
   [19] Zhang, Jie, Huang, Zhihua, Li, Peidong, Zhang, Xiaomin, Zhang, Xinzhi, Yuan, Yangyang, Xu, Lei. Elucidating the reaction pathway for ethene and propene formation in the methanol-to-hydrocarbons reaction over high silica H-Beta. CATALYSIS SCIENCE & TECHNOLOGY[J]. 2017, 7(11): 2194-2203, https://www.webofscience.com/wos/woscc/full-record/WOS:000403002700005.
   [20] Huang, Zhihua, Zhang, Jie, Li, Peidong, Xu, Lanjian, Zhang, Xiaomin, Yuan, Yangyang, Xu, Lei. tert-Butylation of naphthalene by tertiary butanol over HY zeolite and cerium-modified HY catalysts. CATALYSIS SCIENCE & TECHNOLOGY[J]. 2017, 7(20): 4700-4709, http://cas-ir.dicp.ac.cn/handle/321008/168412.
   [21] Qi, Liang, Li, Jinzhe, Wang, Linying,  Xu, Lei, Liu, Zhongmin.  Unusual deactivation of HZSM-5 zeolite in the methanol to hydrocarbon reaction. CATALYSIS SCIENCE & TECHNOLOGY[J]. 2017, 7(4): 894-901, http://cas-ir.dicp.ac.cn/handle/321008/169492.
   [22] Qi, Liang, Li, Jinzhe, Xu, Lei, Liu, Zhongmin. Evolution of the reaction mechanism during the MTH induction period over the 2-dimensional FER zeolite. RSC ADVANCES[J]. 2016, 6(61): 56698-56704, http://cas-ir.dicp.ac.cn/handle/321008/170520.
   [23] Lu, Peng, Chen, Lei, Zhang, Yanfei, Yuan, Yangyang, Xu, Li, Zhang, Xiaomin, Xu, Lei. Rapid synthesis of ZSM-22 zeolites using imidazolium-based ionic liquids as OSDAs in fluoride media. MICROPOROUS AND MESOPOROUS MATERIALS[J]. 2016, 236: 193-201, http://dx.doi.org/10.1016/j.micromeso.2016.09.002.
   [24] Qi, Liang, Li, Jinzhe, Wei, Yingxu, Xu, Lei, Liu, Zhongmin. Role of naphthalene during the induction period of methanol conversion on HZSM-5 zeolite. CATALYSIS SCIENCE & TECHNOLOGY[J]. 2016, 6(11): 3737-3744, http://cas-ir.dicp.ac.cn/handle/321008/170512.
   [25] Qi, Liang, Li, Jinzhe, Wei, Yingxu, He, Yanli, Xu, Lei, Liu, Zhongmin. Influence of acid site density on the three-staged MTH induction reaction over HZSM-5 zeolite. RSC ADVANCES[J]. 2016, 6(57): 52284-52291, http://www.corc.org.cn/handle/1471x/2375666.
   [26] Chen, Lei, Lu, Peng, Yuan, Yangyang, Xu, Li, Zhang, Xiaomin, Xu, Lei. Hydrothermal synthesis of nanosized ZSM-22 and their use in the catalytic conversion of methanol. CHINESE JOURNAL OF CATALYSIS[J]. 2016, 37(8): 1381-1388, http://dx.doi.org/10.1016/S1872-2067(15)61099-3.
   [27] Qi, Liang, Wei, Yingxu, Xu, Lei, Liu, Zhongmin. Reaction Behaviors and Kinetics during Induction Period of Methanol Conversion on HZSM-5 Zeolite. ACS CATALYSIS[J]. 2015, 5(7): 3973-3982, http://cas-ir.dicp.ac.cn/handle/321008/146397.
   [28] Bi, Yi, Wang, Yingli, Chen, Xin, Yu, Zhengxi, Xu, Lei. Methanol aromatization over HZSM-5 catalysts modified with different zinc salts. CHINESE JOURNAL OF CATALYSIS[J]. 2014, 35(10): 1740-1751, http://dx.doi.org/10.1016/S1872-2067(14)60145-5.
   [29] Bi, Yi, Wang, Yingli, Wei, Yingxu, He, Yanli, Yu, Zhengxi, Liu, Zhongmin, Xu, Lei. Improved Selectivity toward Light Olefins in the Reaction of Toluene with Methanol Over the Modified HZSM-5 Catalyst. CHEMCATCHEM[J]. 2014, 6(3): 713-718, http://cas-ir.dicp.ac.cn/handle/321008/145911.

已指导学生

毕怡  博士研究生  081705-工业催化  

陈磊  硕士研究生  085216-化学工程  

亓良  博士研究生  081705-工业催化  

卢鹏  博士研究生  081705-工业催化  

李沛东  博士研究生  081705-工业催化  

张艳飞  博士研究生  081705-工业催化  

黄治华  博士研究生  081705-工业催化  

张洁  博士研究生  081705-工业催化  

陈磊  博士研究生  081705-工业催化  

韩乔  博士研究生  081705-工业催化  

许澜舰  博士研究生  081705-工业催化  

张思雨  硕士研究生  085216-化学工程  

现指导学生

董磊  博士研究生  081705-工业催化  

朱圣洁  博士研究生  081705-工业催化