1.分子反应动力学

利用交叉分子束的方法，结合先进的激光技术研究重要基元化学反应相关的动力学机理。

2.自由电子激光关键技术

主要从事高量子效率光阴极制备、先进电子束制备技术以及大型自由电子激光装置物理调试与运行等。

   

070304-物理化学

物理化学II，原子分子物理
自由电子激光技术
光阴极注入器

2008-09--2015-01   中国科学院大连化学物理研究所   物理化学博士
2004-09--2008-07   大连理工大学   理学学士

博士研究生

理学博士学位

2015年3月-2018年6月 中国科学院大连化学物理研究所，助理研究员

2018年7月-2023年1月，中国科学院大连化学物理研究所，副研究员

2023年1月至今，中国科学院大连化学物理研究所，正高级工程师

   

（ 1 ） 速调管内部打火监测联锁方法, 发明专利, 2021, 第 1 作者, 专利号: CN109932989B

（ 2 ） 一种基于气体吸收的真空紫外光衰减装置及其衰减方法, 发明专利, 2021, 第 3 作者, 专利号: CN112666102A

（ 3 ） 光阴极电子枪射频同步慢漂抑制方法, 发明专利, 2020, 第 4 作者, 专利号: CN109936905B

（ 4 ） 脉冲调制器高压补偿装置, 实用新型, 2019, 第 3 作者, 专利号: CN109936347A

（ 5 ） 脉冲调制器高压补偿装置及方法, 发明专利, 2019, 第 1 作者, 专利号: CN109936345A

（ 6 ） 脉冲调制器高压稳定装置及方法, 专利授权, 2019, 第 3 作者, 专利号: CN109936348A

（ 7 ） 脉冲调制器高压稳定装置, 实用新型, 2019, 第 3 作者, 专利号: CN109936300A

（ 8 ） 光阴极电子枪射频同步慢飘抑制装置及方法, 发明专利, 2019, 第 4 作者, 专利号: CN109936905A

（ 9 ） 速调管内部打火监测联锁装置及方法, 发明专利, 2019, 第 1 作者, 专利号: CN109932989A

（ 10 ） 速调管内部打火监测联锁装置, 实用新型, 2019, 第 3 作者, 专利号: CN109932621A

（ 11 ） 光阴极电子枪射频同步慢飘抑制装置, 发明专利, 2019, 第 4 作者, 专利号: CN109936906A

（ 12 ） 基于飞行时间谱真空紫外光横向分布在线测量装置及方法, 发明专利, 2019, 第 3 作者, 专利号: CN109916510A

（ 13 ） 电子能量阈值在线监控辐射安全联锁系统装置及方法, 发明专利, 2019, 第 5 作者, 专利号: CN109922592A

（ 14 ） 基于离子成像的真空紫外光横向分布在线测量装置, 发明专利, 2019, 第 3 作者, 专利号: CN109916508A

（ 15 ） 基于离子成像的真空紫外光横向分布在线测量装置及方法, 发明专利, 2019, 第 3 作者, 专利号: CN109916507A

（ 16 ） 基于飞行时间谱真空紫外光横向分布在线测量装置, 发明专利, 2019, 第 3 作者, 专利号: CN109916509A

（ 17 ） 电子能量阈值在线监控辐射安全联锁系统装置, 发明专利, 2019, 第 5 作者, 专利号: CN109922593A

（ 18 ） 脉冲调制器高压稳定装置, 发明专利, 2018, 第 3 作者, 专利号: CN207801778U

（ 19 ） 速调管内部打火监测联锁装置, 发明专利, 2018, 第 3 作者, 专利号: CN207764342U

（ 20 ） 光阴极电子枪射频同步慢飘抑制装置, 实用新型, 2018, 第 4 作者, 专利号: CN207766636U

（ 21 ） 基于飞行时间谱真空紫外光横向分布在线测量装置, 实用新型, 2018, 第 3 作者, 专利号: CN207763825U

（ 22 ） 电子能量阈值在线监控辐射安全联锁系统装置, 实用新型, 2018, 第 5 作者, 专利号: CN207766637U

（ 23 ） 基于离子成像的真空紫外光横向分布在线测量装置, 实用新型, 2018, 第 3 作者, 专利号: CN207763824U

（ 24 ） 脉冲调制器高压补偿装置, 发明专利, 2018, 第 3 作者, 专利号: CN207743948U

（ 25 ） 一种变功率脉冲真空紫外光强度测量仪, 实用新型, 2017, 第 2 作者, 专利号: CN206410784U

   

[1] Siquan Feng, Jiali Mu, Xiangsong Lin, Xiangen Song, Siyue Liu, Wen Shi, Weiqing Zhang, Guorong Wu, Yang Jiayue, Wenrui Dong, Xueming Yang, Jingwei Li, Zheng Jiang, Yunjie Ding. Sulfur-poisoning on Rh NP but sulfur-promotion on single-Rh1-site for methanol carbonylation. APPLIED CATALYSIS B: ENVIRONMENTAL[J]. 2023, 325: http://dx.doi.org/10.1016/j.apcatb.2022.122318.
[2] Zhao, Yarui, Chen, Junjie, Luo, Zijie, Chang, Yao, Yang, Jiayue, Zhang, Weiqing, Wu, Guorong, Crane, Stuart W, Hansen, Christopher S, Ding, Hongbin, An, Feng, Hu, Xixi, Xie, Daiqian, Ashfold, Michael N R, Yuan, Kaijun, Yang, Xueming. The vibronic state dependent predissociation of H2S: determination of all fragmentation processes. CHEMICAL SCIENCE[J]. 2023, 14(10): 2501-2517, http://dx.doi.org/10.1039/d2sc06988a.
[3] 杨家岳, 董文锐, 江凌, 袁开军, 王方军, 吴国荣, 乔德志, 张未卿, 杨学明. 大连相干光源运行现状及科学应用. 中国科学. 化学[J]. 2023, 53(11): 2103-2116, http://sciencechina.cn/gw.jsp?action=detail.jsp&internal_id=7623571&detailType=1.
[4] 臧翔宇, 张兆燕, 王冲, 王天通, 郑会俊, 谢华, 杨家岳, 戴东旭, 吴国荣, 张未卿, 李刚, 杨学明, 江凌. 阿尔法蒎烯臭氧分解反应的极紫外自山电子激光光电离质谱研究. 化学物理学报[J]. 2022, 35(2): 281-288, http://lib.cqvip.com/Qikan/Article/Detail?id=7107044671.
[5] Zhao, Yarui, Chen, Junjie, Luo, Zijie, Li, Zhenxing, Yang, Shuaikang, Chang, Yao, An, Feng, Chen, Zhichao, Yang, Jiayue, Wu, Guorong, Zhang, Weiqing, Hu, Xixi, Xie, Daiqian, Ding, Hongbin, Yuan, Kaijun, Yang, Xueming. Photodissociation of H2S: A New Pathway for the Production of Vibrationally Excited Molecular Hydrogen in the Interstellar Medium. JOURNAL OF PHYSICAL CHEMISTRY LETTERS[J]. 2022, 13(42): 9786-9792, http://dx.doi.org/10.1021/acs.jpclett.2c02757.
[6] Zhang, Sue, Wu, Yucheng, Zhang, Zhaoxue, Luo, Zijie, Zhao, Yarui, Li, Zhenxing, Chang, Yao, Yang, Jiayue, Wu, Guorong, Zhang, Weiqing, Yu, Shengrui, Yuan, Kaijun, Yang, Xueming. Photodissociation dynamics of CO2 + hv -> CO(X-1 sigma(+)) + O(D-1(2)) via the 3P(1)pi(u) state. JOURNAL OF CHEMICAL PHYSICS[J]. 2022, 156(5): 
[7] Yao Chang, Yong Yu, Feng An, Zijie Luo, Donghui Quan, Xia Zhang, Xixi Hu, Qinming Li, Jiayue Yang, Zhichao Chen, Li Che, Weiqing Zhang, Guorong Wu, Daiqian Xie, Michael N R Ashfold, Kaijun Yuan, Xueming Yang. Three body photodissociation of the water molecule and its implications for prebiotic oxygen production. NATURE COMMUNICATIONS[J]. 2021, 12(1): https://doaj.org/article/fbb56a95a82f453d997002d53abc1d47.
[8] Li, Zhenxing, Zhao, Min, Xie, Ting, Luo, Zijie, Chang, Yao, Cheng, Gongkui, Yang, Jiayue, Chen, Zhichao, Zhang, Weiqing, Wu, Guorong, Wang, Xingan, Yuan, Kaijun, Yang, Xueming. Direct Observation of the C + S-2 Channel in CS2 Photodissociation. JOURNAL OF PHYSICAL CHEMISTRY LETTERS[J]. 2021, 12(2): 844-849, http://dx.doi.org/10.1021/acs.jpclett.0c03386.
[9] Luo, Zijie, Chang, Yao, Zhao, Yarui, Yang, Jiayue, Chen, Zhichao, Cheng, Yi, Che, Li, Wu, Guorong, Yang, Xueming, Yuan, Kaijun. Photodissociation Dynamics of H2O via the (E)over-tilde ' (B-1(2)) Electronic State. JOURNAL OF PHYSICAL CHEMISTRY A[J]. 2021, 125(17): 3622-3630, http://dx.doi.org/10.1021/acs.jpca.1c01459.
[10] Wang, Chong, Li, Qinming, Kong, Xiangtao, Zheng, Huijun, Wang, Tiantong, Zhao, Ya, Li, Gang, Xie, Hua, Yang, Jiayue, Wu, Guorong, Zhang, Weiqing, Dai, Dongxu, Zhou, Mingfei, Yang, Xueming, Jiang, Ling. Observation of Carbon-Carbon Coupling Reaction in Neutral Transition-Metal Carbonyls. JOURNAL OF PHYSICAL CHEMISTRY LETTERS[J]. 2021, 12(3): 1012-1017, http://dx.doi.org/10.1021/acs.jpclett.0c03766.
[11] Jiang, Shukang, Su, Mingzhi, Yang, Shuo, Wang, Chong, Huang, QianRui, Li, Gang, Xie, Hua, Yang, Jiayue, Wu, Guorong, Zhang, Weiqing, Zhang, Zhaojun, Kuo, JerLai, Liu, ZhiFeng, Zhang, Dong H, Yang, Xueming, Jiang, Ling. Vibrational Signature of Dynamic Coupling of a Strong Hydrogen Bond. JOURNAL OF PHYSICAL CHEMISTRY LETTERS[J]. 2021, 12(9): 2259-2265, http://dx.doi.org/10.1021/acs.jpclett.1c00168.
[12] 常尧, 贺志刚, 罗子杰, 周家米, 张志国, 陈志超, 杨家岳, 余永, 李钦明, 车丽, 吴国荣, 王兴安, 杨学明, 袁开军. 分光技术在自由电子激光结合里德堡态氢原子飞行时间谱装置中的应用. 化学物理学报[J]. 2020, 33(2): 139-144, http://lib.cqvip.com/Qikan/Article/Detail?id=7101593562.
[13] Chang, Yao, Yang, Jiayue, Chen, Zhichao, Zhang, Zhiguo, Yu, Yong, Li, Qingming, He, Zhigang, Zhang, Weiqing, Wu, Guorong, Ingle, Rebecca A, Bain, Matthew, Ashfold, Michael N R, Yuan, Kaijun, Yang, Xueming, Hansen, Christopher S. Ultraviolet photochemistry of ethane: implications for the atmospheric chemistry of the gas giants. CHEMICAL SCIENCE[J]. 2020, 11(19): 5089-5097, https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159213/.
[14] 杨家岳. H2S分子的极紫外波段光解离以及其对星际中自由级HS形成的影响. Nature Communications. 2020, 
[15] 杨家岳. 乙烷的极紫外光化学对气态巨行星大气化学的影响. Chemical Science. 2020, 
[16] Li, Gang, Wang, Chong, Li, Qinming, Zheng, Huijun, Wang, Tiantong, Yu, Yong, Su, Mingzhi, Yang, Dong, Shi, Lei, Yang, Jiayue, He, Zhigang, Xie, Hua, Fan, Hongjun, Zhang, Weiqing, Dai, Dongxu, Wu, Guorong, Yang, Xueming, Jiang, Ling. Infrared plus vacuum ultraviolet two-color ionization spectroscopy of neutral metal complexes based on a tunable vacuum ultraviolet free-electron laser. REVIEW OF SCIENTIFIC INSTRUMENTS[J]. 2020, 91(3): https://www.webofscience.com/wos/woscc/full-record/WOS:000519936100001.
[17] Chang, Yao, He, Zhigang, Luo, Zijie, Zhou, Jiami, Zhang, Zhiguo, Chen, Zhichao, Yang, Jiayue, Yu, Yong, Li, Qinming, Che, Li, Wu, Guorong, Wang, Xingan, Yang, Xueming, Yuan, Kaijun. Application of laser dispersion method in apparatus combining H atom Rydberg tagging time-of-flight technique with vacuum ultraviolet free electron laser(dagger). CHINESE JOURNAL OF CHEMICAL PHYSICS[J]. 2020, 33(2): 139-144, https://www.webofscience.com/wos/woscc/full-record/WOS:000537143100004.
[18] Zhou, Jiami, Luo, Zijie, Yang, Jiayue, Chang, Yao, Zhang, Zhiguo, Yu, Yong, Li, Qinming, Cheng, Gongkui, Chen, Zhichao, He, Zhigang, Che, Li, Yu, Shengrui, Wu, Guorong, Yuan, Kaijun, Yang, Xueming. State-to-state photodissociation dynamics of CO2 around 108 nm: the O(S-1) atom channel. PHYSICAL CHEMISTRY CHEMICAL PHYSICS[J]. 2020, 22(11): 6260-6265, https://www.webofscience.com/wos/woscc/full-record/WOS:000523409400020.
[19] Chang, Yao, An, Feng, Li, Qinming, Luo, Zijie, Che, Li, Yang, Jiayue, Chen, Zhichao, Zhang, Weiqing, Wu, Guorong, Hu, Xixi, Xie, Daiqian, Yuan, Kaijun, Yang, Xueming. Electronically Excited OH Super-rotors from Water Photodissociation by Using Vacuum Ultraviolet Free-Electron Laser Pulses. JOURNAL OF PHYSICAL CHEMISTRY LETTERS[J]. 2020, 11(18): 7617-7623, https://www.webofscience.com/wos/woscc/full-record/WOS:000574906500022.
[20] Jiami Zhou, Yarui Zhao, Christopher S Hansen, Jiayue Yang, Yao Chang, Yong Yu, Gongkui Cheng, Zhichao Chen, Zhigang He, Shengrui Yu, Hongbin Ding, Weiqing Zhang, Guorong Wu, Dongxu Dai, Colin M Western, Michael N R Ashfold, Kaijun Yuan, Xueming Yang. Ultraviolet photolysis of H2S and its implications for SH radical production in the interstellar medium. NATURE COMMUNICATIONS[J]. 2020, 11(1): https://doaj.org/article/0c908f7bc5eb4bccbeb680865fe097a5.
[21] 杨家岳. CO2在108nm下O（1S）产物通道的态-态光解离动力学. Physical Chemistry Chemical Physics. 2020, 
[22] 杨家岳. 基于可调谐真空极紫外自由电子激光的中性金属团簇的红外-极紫双色外电离谱. Review of Scientific Instruments. 2020, 
[23] 杨家岳. 水分子在真空紫外光解下产生羟基超转子. Nature Communications. 2019, 
[24] Li Qinming, Yu Yong, Yang Jiayue, Ding Hongli, Shi Lei, Tao Kai, Wang Guanglei, Wu Guorong, Dai Dongxu, Zhang Weiqing, Du Xuewei, Wei Shen, Wang Qiuping, Yang Xueming, Tschentscher T, Patthey L, Tiedtke K, Zangrando M. Photon diagnosis and transmission for Dalian Coherent Light Source. X-RAY FREE-ELECTRON LASERS: ADVANCES IN SOURCE DEVELOPMENT AND INSTRUMENTATION V. 2019, 11038: 
[25] Yao Chang, Yong Yu, Heilong Wang, Xixi Hu, Qinming Li, Jiayue Yang, Shu Su, Zhigang He, Zhichao Chen, Li Che, Xingan Wang, Weiqing Zhang, Guorong Wu, Daiqian Xie, Michael N R Ashfold, Kaijun Yuan, Xueming Yang. Hydroxyl super rotors from vacuum ultraviolet photodissociation of water. NATURE COMMUNICATIONS[J]. 2019, 10(1): 1-7, https://doaj.org/article/13bc265604e945f9b43dbea5af39a0f5.
[26] 余永, 李钦明, 杨家岳, 王光磊, 史磊, 丁洪利, 陶凯, 汤振兴, 贺志刚, 陈志超, 田宇欢, 戴东旭, 吴国荣, 张未卿, 杨学明, 冯超, 陈思, 王震, 谷端, 陈杰, 刘晓庆, 兰太和, 冯冽, 张文艳, 钟少鹏, 张俊强, 李林, 肖诚成, 李昊, 赵欢, 陈广花, 朱海君, 丁建国, 黄毛毛, 张伟, 赖龙伟, 杨夫彬, 王光宏, 相升旺, 胡晓, 刘以勇, 孙森, 高飞, 蒋志强, 周孝轩, 刘永芳, 吴勇华, 陈志豪, 王锐萍, 黄大章, 张猛, 邓海啸, 李宾, 林国强, 俞路阳, 阎映炳, 阎山川, 夏晓彬, 周巧根, 刘波, 顾强, 谷鸣, 方国平, 冷用斌, 殷立新, 王东, 赵振堂. 大连极紫外相干光源. 中国激光[J]. 2019, 43-50, https://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFDLAST2019&filename=JJZZ201901006&v=MTMyMjFYMUx1eFlTN0RoMVQzcVRyV00xRnJDVVI3cWVaK1J2Rml6a1Y3N0pMeWZSZExHNEg5ak1ybzlGWW9SOGU=.
[27] 杨家岳. 利用真空极紫外自电子激光研究水分子在111.5nm下的光解动力学. The Journal of Chemical Physics. 2018, 
[28] Zhang, Dong, Yang, Jiayue, Chen, Zhen, Chen, Rongjun, Jiang, Bo, Dai, Dongxu, Wu, Guorong, Zhang, Donghui, Yang, Xueming. CH stretching excitation promotes its cleavage in the F + CHD3(nu(1)=1) -> HF + CD3 reaction at low collision energies. PHYSICAL CHEMISTRY CHEMICAL PHYSICS[J]. 2017, 19(20): 13070-13074, http://dx.doi.org/10.1039/c7cp01428g.
[29] 杨家岳. 低碰撞能下，F+CHD3（v1=1）->CD3+HF反应中反应物CH键伸缩振动激发态会促进该反应通道的发生. Physical Chemistry Chemical Physics. 2017, 
[30] Chen, Wentao, Yu, Shengrui, Yuan, Daofu, Xie, Ting, Yang, Jiayue, Wang, Siwen, Luo, Chang, Tan, Yuxin, Miao, Yue, Zhang, Weiqing, Wu, Guorong, Yang, Xueming, Wang, Xingan. Crossed Molecular Beam Study of H-ECH4 and H+CD4 Reactions: Vibrationally Excited CH3/CD3 Product Channelst. CHINESE JOURNAL OF CHEMICAL PHYSICS[J]. 2017, 30(6): 609-613, http://cas-ir.dicp.ac.cn/handle/321008/168634.
[31] Chen Wentao, Yu Shengrui, Yuan Daofu, Xie Ting, Yang Jiayue, Wang Siwen, Luo Chang, Tan Yuxin, Miao Yue, Zhang Weiqing, Wu Guorong, Yang Xueming, Wang Xingan. Crossed Molecular Beam Study of H+CH_4 and H+CD_4 Reactions: Vibrationally Excited CH_3/CD_3 Product Channels. CHINESE JOURNAL OF CHEMICAL PHYSICS[J]. 2017, 30(6): 609-613, http://sciencechina.cn/gw.jsp?action=detail.jsp&internal_id=6149960&detailType=1.
[32] Yang, Jiayue, Zhang, Dong, Chen, Zhen, Blauert, Florian, Jiang, Bo, Dai, Dongxu, Wu, Guorong, Zhang, Donghui, Yang, Xueming. Effect of CH stretching excitation on the reaction dynamics of F + CHD3 -> DF + WCHD2. JOURNAL OF CHEMICAL PHYSICS[J]. 2015, 143(4): http://dx.doi.org/10.1063/1.4927504.
[33] 杨家岳. F/O（1D）原子与振动激发态甲烷分CH4（v3=1）/CHD3（v1=1）反应动力学的实验研究. 2015, 
[34] 杨家岳. CH键的振动激发对反应F + CHD3 → DF + CHD2动力学过程的影响. The Journal of Physical Chemistry Letters. 2015, 
[35] 潘慧琳, 杨家岳, 张冬, 帅全, 戴东旭, 吴国荣, 姜波, 杨学明. Effect of antisymmetric C—H stretching excitation on the dynamics of O(1D) + CH4 → OH + CH3. JOURNAL OF CHEMICAL PHYSICS[J]. 2015, 140(15): 154305, http://cas-ir.dicp.ac.cn/handle/321008/144513.
[36] Yang Jiayue, Zhang Dong, Chen Zhen, Florian Blauert, Jiang Bo, Dai Dongxu, Wu Guorong, Zhang Donghui, Yang Xueming. Effect of CH stretching excitation on the reaction dynamics of F + CHD3 → DF + CHD2. JOURNAL OF CHEMICAL PHYSICS[J]. 2015, 143(4): 0443161, http://cas-ir.dicp.ac.cn/handle/321008/148197.
[37] Yang, Jiayue, Zhang, Dong, Jiang, Bo, Dai, Dongxu, Wu, Guorong, Zhang, Donghui, Yang, Xueming. How Is C-H Vibrational Energy Redistributed in F + CHD3(v(1)=1) -> HF + CD3?. JOURNAL OF PHYSICAL CHEMISTRY LETTERS[J]. 2014, 5(11): 1790-1794, http://dx.doi.org/10.1021/jz5007252.
[38] Pan, Huilin, Yang, Jiayue, Shuai, Quan, Zhang, Dong, Zhang, Weiqing, Wu, Guorong, Dai, Dongxu, Jiang, Bo, Zhang, Donghui, Yang, Xueming. Velocity Map Imaging Study of the Reaction Dynamics of the H + CH4 -> H-2 + CH3 Reaction: The Isotope Effects. JOURNAL OF PHYSICAL CHEMISTRY A[J]. 2014, 118(13): 2426-2430, http://dx.doi.org/10.1021/jp501681h.
[39] 杨家岳. 反应Cl+CH4（v3=1）立体动力学过程的成像实验研究. The Journal of Physical Chemistry Letters. 2014, 
[40] Yang Jiayue, Shao Kejie, Zhang Dong, Shuai Quan, Fu Bina, Zhang Donghui, Yang Xueming. Trapped Abstraction in the O(1D) + CHD3 → OH + CD3 Reaction. JOURNAL OF PHYSICAL CHEMISTRY LETTERS[J]. 2014, 5(18): 3106, http://cas-ir.dicp.ac.cn/handle/321008/144418.
[41] 杨家岳. 反应F + CHD3（v1=1） → HF + CD3中反应物中CH键伸缩振动激发能量在反应过程中的分配机理. The Journal of Physical Chemistry Letters. 2014, 
[42] 杨家岳, 张冬, 姜波, 戴东旭, 吴国荣, 张东辉, 杨学明. How Is C−H Vibrational Energy Redistributed in F + CHD3(ν1 = 1) → HF + CD3?. JOURNAL OF PHYSICAL CHEMISTRY LETTERS[J]. 2014, 5(11): 1790, http://cas-ir.dicp.ac.cn/handle/321008/144511.
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（ 1 ） 基于极紫外相干光源的解离动力学研究, 参与, 国家任务, 2018-01--2021-12
（ 2 ） CH键伸缩振动激发对F/Cl+CHD3总反应性影响的动力学研究, 参与, 国家任务, 2017-01--2020-12
（ 3 ） 甲烷分子振动激发对与其相关反应动力学影响的研究, 负责人, 国家任务, 2016-01--2018-12
（ 4 ） 多原子分子激发态非绝热动力学的研究, 参与, 国家任务, 2016-01--2019-12