基本信息
阚剑博士,副研究员,硕士生导师
中国科学院福建物质结构研究所
中科院特聘研究骨干
电子邮件: jkan@fjirsm.ac.cn
通信地址: 杨桥西路155号
邮政编码: 350002
教育背景
2013-09--2016-06 中科院福建物质结构研究所 博士研究生/博士2004-09--2007-06 中科院福建物质结构研究所 硕士研究生/硕士2000-09--2004-06 安徽师范大学 本科/学士
工作经历
2018-12~2020-12,McGill University, 博士后
2016-12~现在, 中科院福建物质结构研究所, 副研究员
2007-07~2016-12,中科院福建物质结构研究所, 研习员、助理研究员
2016-12~现在, 中科院福建物质结构研究所, 副研究员
2007-07~2016-12,中科院福建物质结构研究所, 研习员、助理研究员
专利与奖励
奖励信息
(1) 海西研究院“春苗”青年人才专项, 研究所(学校), 2016
专利成果
( 1 ) 无水溴化铈的制备方法, 发明专利, 2017, 第 2 作者, 专利号: CN107215887A( 2 ) 一种惰性气氛造粒系统, 发明专利, 2017, 第 2 作者, 专利号: CN107081112A( 3 ) 一种惰性气氛造粒系统, 实用新型, 2017, 第 2 作者, 专利号: CN206810212U( 4 ) 稀土卤化物的制备方法, 发明专利, 2012, 第 2 作者, 专利号: CN102701261A( 5 ) 一种合成胺和亚胺的方法, 发明专利, 2013, 第 4 作者, 专利号: CN103058805A
出版信息
发表论文
(1) Synthesis of 3-substituted 2-oxindoles from secondary α-bromo-propionanilides via palladium-catalyzed intramolecular cyclization, Org. Biomol. Chem., 2022, 通讯作者(2) Umpolung carbonyls enable direct allylation and olefination of carbohydrates, Science Advances, 2022, 第 1 作者(3) Synergistic Relay Reactions To Achieve Redox-Neutral alpha-Alkylations of Olefinic Alcohols with Ruthenium(II) Catalysis, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 第 2 作者(4) Synthesis of alpha-enaminones from cyclic ketones and anilines using oxoammonium salt as an oxygen transfer reagent, GREEN CHEMISTRY, 2020, 第 5 作者(5) Oxidation of Enones for Regioselective 3+2 Cycloaddition through gamma-Enone Radical Intermediates, CHEMISTRY-A EUROPEAN JOURNAL, 2019, 第 1 作者(6) Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid, NATURE COMMUNICATIONS, 2017, 第 3 作者(7) Silver-Catalyzed Arylation of (Hetero)arenes by Oxidative Decarboxylation of Aromatic Carboxylic Acids, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 第 1 作者(8) Photoinduced C–H direct arylation of unactivated arenes, SCIENCE CHINA-CHEMISTRY, 2015, 第 1 作者(9) Ambient-Temperature Ortho C-H Arylation of Benzoic Acids with Aryl Iodides with Ligand-Supported Palladium Catalyst, ORGANIC LETTERS, 2015, 第 3 作者(10) Hydrogen bonded-extended lanthanide coordination polymers decoratedwith 2,3-thiophenedicarboxylate and oxalate: synthesis, structures, and properties, CRYSTENGCOMM, 2014, 第 5 作者(11) Three-dimensional pillared layered supramolecular networks comprising polymeric layers and tetrameric {H2O}(4) pillars, CRYSTENGCOMM, 2013, 第 6 作者(12) Bis(pyridyl) ancillary ligands modulated uninodal 4-, 5-and 6-connected Cd(II) coordination polymers based on 3,4-thiophenedicarboxylate linker, CRYSTENGCOMM, 2013, 第 6 作者(13) 2D lanthanide-organic frameworks constructed from lanthanide acetate skeletons and benzotriazole-5-carboxylic acid connectors: synthesis, structure, luminescence and magnetic properties, CRYSTENGCOMM, 2012, 第 4 作者(14) Pd/PR(3)-Catalyzed Cross-Coupling of Aromatic Carboxylic Acids with Electron-Deficient Polyfluoroarenes via Combination of Decarboxylation with sp(2) C-H Cleavage, JOURNAL OF ORGANIC CHEMISTRY, 2011, 第 4 作者(15) Pd-catalyzed cross-coupling of carboxylic acids with nitroethane via combination of decarboxylation and dehydrogenation, CHEMICAL COMMUNICATIONS, 2010, 第 3 作者(16) Pd-catalyzed decarboxylative arylation of silyl enol ester sp(3) beta-C-H bond under aerobic conditions, DALTON TRANSACTIONS, 2010, 第 3 作者(17) Copper-Catalyzed Direct Alkynylation of Electron-Deficient Polyfluoroarenes with Terminal Alkynes Using O-2 as an Oxidant, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 第 3 作者(18) Pd(O2CCF3)(2)/Benzoquinone: A Versatile Catalyst System for the Decarboxylative Olefination of Arene Carboxylic Acids, ORGANIC LETTERS, 2009, 第 2 作者(19) Palladium-Catalyzed Direct Arylation of Electron-Deficient Polyfluoroarenes with Arylboronic Acids, ORGANIC LETTERS, 2009, 第 2 作者(20) Synthesis and Crystal Structure of a Ruthenium(II) Compound of Dinitrogen, CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 第 1 作者(21) Wirelike dinuclear ruthenium complexes connected by bis(ethynyl) oligothiophene, INORGANIC CHEMISTRY, 2007, 第 2 作者(22) 二炔基桥联双核钌配合物的电喷雾质谱研究, Electrospray Ionization Iontrap Tandem Mass Spectrometric Research on Conjugated Organic Ligands Bridged Binuclear Ruthenium Complexes, 分析测试学报, 2007, 第 2 作者(23) (Acetonitrile)(4 '-phenyl-2,2 ': 6 ',2 ''-terpyridine)bis(tri-n-butylphosphine) ruthenium(II) bis(hexafluorophosphate) dichloromethane solvate, ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 第 1 作者
科研活动
科研项目
( 1 ) 新型优质稀土闪烁晶体材料与探测模块的研制子课题, 负责人, 国家任务, 2016-07--2020-06( 2 ) 面向有机小分子选择性氧化的金属簇合物催化剂研究, 参与, 国家任务, 2015-01--2019-12( 3 ) 甲醛氢甲酰化反应制备乙醇醛反应子课题, 负责人, 国家任务, 2019-11--2024-10( 4 ) 面向合成气直接制乙二醇的金属簇合物催化剂研究, 负责人, 国家任务, 2023-01--2026-12