多孔框架催化材料应用于CO₂的催化转化

博士，硕士

070301-无机化学
070304-物理化学
080501-材料物理与化学

多孔框架材料
二氧化碳催化转化
电催化

2006-09--2009-06   复旦大学    博士
2003-09--2006-06   福建师范大学   硕士

研究生学历

无机化学博士，复旦大学，导师金国新教授

   

2017-01~现在, 中国科学院福建物质结构研究所, 研究员
2015-07~2016-12,中国科学院福建物质结构研究所, 副研究员
2014-09~2015-07,日本产业技术综合研究所（AIST）, JSPS邀请访问学者
2011-12~2014-09,中科院福建物构所, 副研究员
2009-07~2011-12,中科院福建物构所, 助理研究员

   

（1） 福建省创新之星, 省级, 2023
（2） 卢嘉锡杰出人才, , 研究所（学校）, 2023
（3） 中科院青促会优秀会员, 院级, 2018
（4） 福建省自然科学奖, 一等奖, 省级, 2018
（5） 中国科学院青年创新促进会会员, , 院级, 2014
（6） 2014年度海西研究院"春苗人才"计划, , 研究所（学校）, 2014

（ 1 ） 铼修饰的共价三嗪环吡啶框架催化剂及制备方法和应用, 发明专利, 2018, 第 3 作者, 专利号: CN107694606A

（ 2 ） 一种碳量子点/金属有机骨架催化剂的制备方法和应用, 专利授权, 2018, 第 4 作者, 专利号: CN107754861A

（ 3 ） 碳量子点@卟啉基金属有机骨架催化剂及制备方法和应用, 专利授权, 2018, 第 4 作者, 专利号: CN107694605A

（ 4 ） 一种多元锆基多孔材料、制备方法、光催化脱铬中的应用, 专利授权, 2017, 第 4 作者, 专利号: CN107433206A

（ 5 ） 一种金属有机骨架化学传感器和制备方法及其应用, 专利授权, 2017, 第 3 作者, 专利号: CN106916175A

（ 6 ） 一种阳离子有机聚合物的制备及催化二氧化碳固定的方法, 发明专利, 2017, 第 3 作者, 专利号: CN106423280A

（ 7 ） 一种离子型催化剂的制备及催化转化二氧化碳的方法, 发明专利, 2017, 第 3 作者, 专利号: CN106423278A

（ 8 ） 自组装Pd-Cu双金属多枝状纳米晶催化剂及其制备和用途, 专利授权, 2016, 第 3 作者, 专利号: CN105597780A

（ 9 ） 一种金属有机骨架材料用于有效分离尺寸相近的染料, 发明专利, 2016, 第 3 作者, 专利号: CN105617994A

（ 10 ） Pd 5.12 Cu多枝状纳米晶催化剂及其制备和用途, 发明专利, 2016, 第 3 作者, 专利号: CN105396600A

（ 11 ） 一种原位负载型催化剂及其制备和应用, 发明专利, 2014, 第 3 作者, 专利号: CN103623871A

（ 12 ） 多孔铟-有机框架吸附分离材料及其制备和应用, 发明专利, 2014, 第 1 作者, 专利号: CN103613555A

（ 13 ） 一种合金纳米催化剂的制备及光催化降解乙烯的方法, 发明专利, 2014, 第 1 作者, 专利号: CN103611573A

（ 14 ） 一种自固载型催化剂的制备及催化烯烃环氧化方法, 发明专利, 2012, 第 2 作者, 专利号: CN102380417A

   

（1） Boosting CO2 Electroreduction over a Covalent Organic Framework in the Presence of Oxygen, Angew. Chem. Int. Ed., 2024, 
（2） Oxygen-tolerant CO2 electroreduction over covalent organic frameworks via photoswitching control oxygen passivation strategy, Nature Communications, 2024, 
（3） Tandem Photocatalysis of CO2 to C2H4 via a Synergistic Rhenium-(I) Bipyridine/Copper-Porphyrinic Triazine Framework, J. Am. Chem. Soc., 2023, 
（4） Atomically Precise Copper Nanoclusters for Highly Efficient Electroreduction of CO2 towards Hydrocarbons via Breaking the Coordination Symmetry of Cu Site, Angew. Chem. Int. Ed., 2023, 
（5） A porous metal-organic cage liquid for sustainable CO2 conversion reactions, Nature Communications, 2023, 
（6） Boosting Electroreduction of CO2 over Cationic Covalent Organic Frameworks: Hydrogen Bonding Effects of Halogen Ions, Angew. Chem. Int. Ed., 2023, 
（7） Morphology and composition dependence of multicomponent Cu-based nanoreactor for tandem electrocatalysis CO2 reduction, APPLIED CATALYSIS B-ENVIRONMENTAL, 2022, 第 4 作者
（8） 石墨烯量子点/铁基金属-有机骨架复合材料高效光催化二氧化碳还原, Graphene Quantum Dots Supported on Fe-based Metal-Organic Frameworks for Efficient Photocatalytic CO;Reduction, 化学学报, 2022, 第 5 作者
（9） Spatial Sites Separation Strategy to Fabricate Atomically Isolated Nickel Catalysts for Efficient CO2 Electroreduction, ACS MATERIALS LETTERS, 2021, 第 4 作者  通讯作者
（10） Soluble imidazolium-functionalized coordination cages for efficient homogeneous catalysis of CO2 cycloaddition reactions, CHEMICAL COMMUNICATIONS, 2021, 第 5 作者  通讯作者
（11） Conductive phthalocyanine-based metal-organic framework as a highly efficient electrocatalyst for carbon dioxide reduction reaction, Conductive phthalocyanine-based metal-organic framework as a highly efficient electrocatalyst for carbon dioxide reduction reaction, SCIENCE CHINA-CHEMISTRY, 2021, 第 5 作者  通讯作者
（12） Conductive Two-Dimensional Phthalocyanine-based Metal-Organic Framework Nanosheets for Efficient Electroreduction of CO2, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 第 8 作者  通讯作者
（13） Self-Assembly of Imidazolium-Functionalized Zr-Based Metal-Organic Polyhedra for Catalytic Conversion of CO2 into Cyclic Carbonates, INORGANIC CHEMISTRY, 2021, 第 4 作者  通讯作者
（14） Construction of Donor-Acceptor Heterojunctions in Covalent Organic Framework for Enhanced CO2 Electroreduction, SMALL, 2021, 第 5 作者  通讯作者
（15） Atomically dispersed Ni species on N-doped carbon nanotubes for electroreduction of CO2 with nearly 100% CO selectivity, APPLIED CATALYSIS B-ENVIRONMENTAL, 2020, 第 4 作者  通讯作者
（16） Conductive Phthalocyanine-Based Covalent Organic Framework for Highly Efcient Electroreduction of Carbon Dioxide, Small, 2020, 第 1 作者  通讯作者
（17） Integration of metalloporphyrin into cationic covalent triazine frameworks for the synergistically enhanced chemical fixation of CO2, CATALYSIS SCIENCE & TECHNOLOGY, 2020, 第 4 作者  通讯作者
（18） Highly Selective CO2 Electroreduction to CH4 by In Situ Generated Cu2O Single-Type Sites on a Conductive MOF: Stabilizing Key Intermediates with Hydrogen Bonding, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 第 7 作者  通讯作者
（19） Integration of Strong Electron Transporter Tetrathiafulvalene into Metalloporphyrin-Based Covalent Organic Framework for Highly Efficient Electroreduction of CO2, ACS ENERGY LETTERS, 2020, 第 7 作者  通讯作者
（20） Imidazolium-Functionalized Cationic Covalent Triazine Frameworks Stabilized Copper Nanoparticles for Enhanced CO2 Electroreduction, CHEMCATCHEM, 2020, 第 6 作者  通讯作者
（21） Unraveling the relationship of the pore structures between the metal-organic frameworks and their derived carbon materials, INORGANIC CHEMISTRY COMMUNICATIONS, 2020, 第 4 作者  通讯作者
（22） Conductive Phthalocyanine-Based Covalent Organic Framework for Highly Efficient Electroreduction of Carbon Dioxide, Small, 2020, 第 5 作者  通讯作者
（23） 咪唑鎓盐官能化阳离子型金属-有机框架衍生的多孔氮/卤素双掺杂纳米碳高效氧还原催化剂, Porous nitrogen/halogen dual-doped nanocarbons derived from imidazolium functionalized cationic metal-organic frameworks for highly efficient oxygen reduction reaction, SCIENCE CHINA-MATERIALS, 2019, 第 5 作者  通讯作者
（24） A mesoporous cationic metal-organic framework with a high density of positive charge for enhanced removal of dichromate from water, DALTON TRANSACTIONS, 2019, 第 4 作者  通讯作者
（25） Metal-organic frameworks and porous organic polymers for sustainable fixation of carbon dioxide into cyclic carbonates, COORDINATION CHEMISTRY REVIEWS, 2019, 第 2 作者  通讯作者
（26） Salen-Co(iii) insertion in multivariate cationic metal-organic frameworks for the enhanced cycloaddition reaction of carbon dioxide, CHEMICAL COMMUNICATIONS, 2019, 第 4 作者  通讯作者
（27） Unraveling the Reactivity and Selectivity of Atomically Isolated Metal���Nitrogen Sites Anchored on Porphyrinic Triazine Frameworks for Electroreduction of CO2, CCS Chemistry, 2019, 
（28） 咪唑鎓盐官能化阳离子型金属-有机框架衍生的多孔氮/卤素双掺杂纳米碳高效氧还原催化剂, Porous nitrogen/halogen dual-doped nanocarbons derived from imidazolium functionalized cationic metal-organic frameworks for highly efficient oxygen reduction reaction, 中国科学:材料科学(英文版), 2019, 第 5 作者
（29） N-Doped Carbon Aerogel Derived from a Metal-Organic Framework Foam as an Efficient Electrocatalyst for Oxygen Reduction, CHEMISTRY-AN ASIAN JOURNAL, 2019, 第 4 作者  通讯作者
（30） Cobalt single-atoms anchored on porphyrinic triazine-based frameworks as bifunctional electrocatalysts for oxygen reduction and hydrogen evolution reactions, JOURNAL OF MATERIALS CHEMISTRY A, 2019, 第 12 作者  通讯作者
（31） Integration of adsorption and photosensitivity capabilities into a cationic multivariate metal-organic framework for enhanced visible-light photoreduction reaction, APPLIED CATALYSIS B-ENVIRONMENTAL, 2019, 第 11 作者  通讯作者
（32） 钼基金属有机框架为模板合成二硫化钼纳米棒用于高效电解水产氢, Solid-state synthesis of MoS2 nanorod from molybdenum-organic framework for efficient hydrogen evolution reaction, 中国科学:材料科学(英文版), 2019, 第 3 作者
（33） 钼基金属有机框架为模板合成二硫化钼纳米棒用于高效电解水产氢, Solid-state synthesis of MoS_2 nanorod from molybdenum-organic framework for efficient hydrogen evolution reaction, SCIENCE CHINA-MATERIALS, 2019, 第 3 作者  通讯作者
（34） Unraveling the relationship between the morphologies of metal-organic frameworks and the properties of their derived carbon materials, DALTON TRANSACTIONS, 2019, 第 6 作者  通讯作者
（35） Encapsulation of Phosphotungstic Acid into Metal-Organic Frameworks with Tunable Window Sizes: Screening of PTA@MOF Catalysts for Efficient Oxidative Desulfurization, INORGANIC CHEMISTRY, 2018, 第 7 作者
（36） Defective Pt nanoparticles encapsulated in mesoporous metal-organic frameworks for enhanced catalysis, CHEMICAL COMMUNICATIONS, 2018, 第 5 作者  通讯作者
（37） Fast, highly selective and sensitive anionic metal-organic framework with nitrogen-rich sites fluorescent chemosensor for nitro explosives detection, JOURNALOFHAZARDOUSMATERIALS, 2018, 第 4 作者  通讯作者
（38） Imidazolium-Based Cationic Covalent Triazine Frameworks for Highly Efficient Cycloaddition of Carbon Dioxide, CHEMCATCHEM, 2018, 第 7 作者  通讯作者
（39） Rhenium-modified porous covalent triazine framework for highly efficient photocatalytic carbon dioxide reduction in a solid-gas system, CATALYSIS SCIENCE & TECHNOLOGY, 2018, 第 5 作者  通讯作者
（40） Highly selective sensing of Fe3+ by an anionic metal-organic framework containing uncoordinated nitrogen and carboxylate oxygen sites, DALTON TRANSACTIONS, 2018, 第 4 作者  通讯作者
（41） An imidazolium-functionalized mesoporous cationic metal-organic framework for cooperative CO2 fixation into cyclic carbonate, CHEMICAL COMMUNICATIONS, 2018, 第 6 作者  通讯作者
（42） Zinc Porphyrin/Imidazolium Integrated Multivariate Zirconium Metal-Organic Frameworks for Transformation of CO2 into Cyclic Carbonates, INORGANIC CHEMISTRY, 2018, 第 7 作者  通讯作者
（43） Atomically Dispersed Iron-Nitrogen Active Sites within Porphyrinic Triazine-Based Frameworks for Oxygen Reduction Reaction in Both Alkaline and Acidic Media, ACS ENERGY LETTERS, 2018, 第 8 作者  通讯作者
（44） Facile ultrafine copper seed-mediated approach for fabricating quasi-two-dimensional palladium-copper bimetallic trigonal hierarchical nanoframes, NANO RESEARCH, 2017, 第 2 作者
（45） Platinum Nanoparticle-Decorated Porous Porphyrin-Based Metal-Organic Framework for Photocatalytic Hydrogen Production, CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2017, 第 5 作者  通讯作者
（46） A flexible porous copper-based metal-organic cage for carbon dioxide adsorption, INORGANIC CHEMISTRY COMMUNICATIONS, 2017, 第 5 作者  通讯作者
（47） Boosting Oxidative Desulfurization of Model and Real Gasoline over Phosphotungstic Acid Encapsulated in Metal-Organic Frameworks: The Window Size Matters, CHEMCATCHEM, 2017, 第 4 作者  通讯作者
（48） Hierarchically porous nitrogen-doped carbon nanotubes derived from core-shell ZnO@zeolitic imidazolate framework nanorods for highly efficient oxygen reduction reactions, JOURNAL OF MATERIALS CHEMISTRY A, 2017, 第 8 作者  通讯作者
（49） Multifunctional metal-organic framework catalysts: synergistic catalysis and tandem reactions, CHEMICAL SOCIETY REVIEWS, 2017, 第 1 作者
（50） Porous hollow MoS2 microspheres derived from core-shell sulfonated polystyrene microspheres@MoS2 nanosheets for efficient electrocatalytic hydrogen evolution, INORGANIC CHEMISTRY FRONTIERS, 2017, 第 5 作者  通讯作者
（51） Postsynthetic ionization of an imidazole-containing metal-organic framework for the cycloaddition of carbon dioxide and epoxides, CHEMICAL SCIENCE, 2017, 第 6 作者  通讯作者
（52） Soluble Metal-Nanoparticle-Decorated Porous Coordination Polymers for the Homogenization of Heterogeneous Catalysis, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 第 1 作者
（53） Water-Stable Anionic Metal-Organic Framework for Highly Selective Separation of Methane from Natural Gas and Pyrolysis Gas, ACS APPLIED MATERIALS & INTERFACES, 2016, 第 4 作者
（54） Water-medium C���H activation over a hydrophobic perfluoroalkane-decorated metal-organic framework platform, JOURNAL OF CATALYSIS, 2016, 第 1 作者
（55） 双功能催化剂：多级微介孔金属-有机框架材料负载合金纳米协同催化, 2016, 第 1 作者
（56） An Anion Metal-Organic Framework with Lewis Basic Sites-Rich toward Charge-Exclusive Cationic Dyes Separation and Size-Selective Catalytic Reaction, INORGANIC CHEMISTRY, 2016, 第 7 作者  通讯作者
（57） Hierarchically micro- and mesoporous metal���organic framework-supported alloy nanocrystals as bifunctional catalysts: Toward cooperative catalysis, JOURNAL OF CATALYSIS, 2015, 第 1 作者
（58） Bimetallic alloy nanocrystals encapsulated in ZIF-8 for synergistic catalysis of ethylene oxidative degradation, CHEMICAL COMMUNICATIONS, 2014, 第 1 作者
（59） ZIF-8原位负载Pd纳米粒子及其在Suzuki-Miyaura反应中的应用, In Situ Preparation of Palladium Nanoparticles Supported on ZIF-8 for Suzuki-Miyaura Reaction, 无机化学学报, 2014, 第 4 作者
（60） In Situ Preparation of Palladium Nanoparticles Supported on ZIF-8 for Suzuki-Miyaura Reaction, CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2014, 第 4 作者  通讯作者
（61） ZIF-8原位负载Pd纳米粒子及其在Suzuki-Miyaura反应中的应用, In Situ Preparation of Palladium Nanoparticles Supported on ZIF-8 for Suzuki-Miyaura Reaction, 无机化学学报, 2014, 第 4 作者
（62） Phosphotungstic acid encapsulated in the mesocages of amine-functionalized metal-organic frameworks for catalytic oxidative desulfurization, DALTON TRANSACTIONS, 2014, 第 2 作者  通讯作者
（63） Porous anionic indium-organic framework with enhanced gas and vapor adsorption and separation ability., CHEMSUSCHEM, 2014, 第 1 作者
（64） Syntheses, structures and photoluminescent properties of lanthanide coordination polymers based on pyridyl functionalized imidazole dicarboxylic acid, RSC ADVANCES, 2013, 第 2 作者
（65） Direct CH Bond Arylation of Indoles with Aryl Boronic Acids Catalyzed by Palladium Nanoparticles Encapsulated in Mesoporous Metal-Organic Framework, CHEMCATCHEM, 2013, 第 1 作者
（66） Crystalline Hybrid Solid Materials of Palladium and Decamethylcucurbit5uril as Recoverable Precatalysts for Heck Cross-Coupling Reactions, CHEMISTRY-A EUROPEAN JOURNAL, 2013, 第 4 作者
（67） Structure Versatility of Coordination Polymers Constructed from a Semirigid Tetracarboxylate Ligand: Syntheses, Structures, and Photoluminescent Properties, CRYSTAL GROWTH & DESIGN, 2013, 第 4 作者
（68） Construction of a Polyhedral Metal-Organic Framework via a Flexible Octacarboxylate Ligand for Gas Adsorption and Separation, INORGANIC CHEMISTRY, 2013, 第 2 作者
（69） Facile synthesis of palladium nanoparticles encapsulated in amine-functionalized mesoporous metal-organic frameworks and catalytic for dehalogenation of aryl chlorides, JOURNAL OF CATALYSIS, 2012, 第 1 作者
（70） Three-dimensional Yb(III)���Ag(I) heterometallic coordination polymer showing dual photoluminescent emissions in the visible and near-infrared regions, INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 第 2 作者
（71） Three-Dimensional Pillared-Layer 3d-4f Heterometallic Coordination Polymers With or Without Halides, CRYSTAL GROWTH & DESIGN, 2012, 第 2 作者
（72） A family of three-dimensional 3d-4f and 4d-4f heterometallic coordination polymers based on mixed isonicotinate and 2-sulfobenzoate ligands: syntheses, structures and photoluminescent properties, DALTON TRANSACTIONS, 2012, 第 2 作者
（73） Microwave-Assisted Synthesis of a Series of Lanthanide Metal-Organic Frameworks and Gas Sorption Properties, INORGANIC CHEMISTRY, 2012, 第 4 作者
（74） Two-dimensional decanuclear erbium wheel supported by mixed hemimellitate and 4-chlorobenzoate ligands, CRYSTENGCOMM, 2012, 第 2 作者
（75） Palladium Nanoparticles Supported on Mixed-Linker Metal-Organic Frameworks as Highly Active Catalysts for Heck Reactions, CHEMPLUSCHEM, 2012, 第 1 作者
（76） A Guest-Dependent Approach to Retain Permanent Pores in Flexible Metal-Organic Frameworks by Cation Exchange, CHEMISTRY-A EUROPEAN JOURNAL, 2012, 第 3 作者
（77） The fabrication of palladium-pyridyl complex multilayers and their application as a catalyst for the Heck reaction, JOURNAL OF MATERIALS CHEMISTRY, 2011, 第 2 作者
（78） Pore-size tuning in double-pillared metal-organic frameworks containing cadmium clusters, CRYSTENGCOMM, 2011, 第 5 作者
（79） Palladium Nanoparticles Encapsulated in a Metal-Organic Framework as Efficient Heterogeneous Catalysts for Direct C2 Arylation of Indoles, CHEMISTRY-A EUROPEAN JOURNAL, 2011, 第 1 作者
（80） Homochiral Nickel Coordination Polymers Based on Salen(Ni) Metalloligands: Synthesis, Structure, and Catalytic Alkene Epoxidation, INORGANIC CHEMISTRY, 2011, 第 1 作者
（81） Palladium nanoparticles supported on amino functionalized metal-organic frameworks as highly active catalysts for the Suzuki-Miyaura cross-coupling reaction, CATALYSIS COMMUNICATIONS, 2011, 第 1 作者

   

（ 1 ） 福建省创新之星人才计划, 负责人, 地方任务, 2024-01--2028-12
（ 2 ） 高性能串联电催化CO2制C2+高值化学品研究, 负责人, 国家任务, 2023-01--2026-12
（ 3 ） 卟啉基阳离子型共价有机框架串联催化二氧化碳与烯烃反应制环状碳酸酯, 负责人, 国家任务, 2021-01--2024-12
（ 4 ） 卟啉基共价三嗪框架固载的单原子金属电还原二氧化碳研 究, 负责人, 国家任务, 2019-01--2022-12
（ 5 ） 基于机器学习势函数的纳米材料催化动态模拟与理性设计, 参与, 国家任务, 2018-07--2023-06
（ 6 ） 2014年度青年创新促进会奖励, 负责人, 中国科学院计划, 2014-01--2017-12
（ 7 ） 春苗人才计划, 负责人, 研究所自主部署, 2014-01--2017-12
（ 8 ） 半封闭空间机动车排放污染物常温治理的关键纳米技术, 负责人, 国家任务, 2013-01--2017-12

（1）金属-有机框架化合物（MOFs） 负载钯纳米颗粒及其催化   第17届分子筛会议   黄远标   2013-08-31
（2）金属-有机框架化合物（MOFs） 负载钯纳米颗粒及其催化   第七届全国配位化学会议   黄远标   2013-07-29

已指导学生

朱宏静  博士研究生  070304-物理化学  

郑嵩  硕士研究生  085600-材料与化工  

付晓雪  硕士研究生  070301-无机化学  

现指导学生

陈子奥  博士研究生  070304-物理化学  

张玉銮  博士研究生  070304-物理化学  

黄渝  硕士研究生  085600-材料与化工  

桑婷婷  硕士研究生  070301-无机化学