Ø乏燃料的电化学处理技术研究

Ø钍基熔盐堆燃料的电化学分离技术研究

Ø熔盐堆堆运行化学研究

   

070301-无机化学

放射化学，熔盐电化学

2006-09--2011-06   中国科学院上海应用物理研究所   研究生/博士
2002-09--2006-06   清华大学   本科/学士

博士研究生

理学博士

   

2019-01~现在, 中国科学院上海应用物理研究所, 研究员
2014-01~2018-12,中国科学院上海应用物理研究所, 副研究员
2011-07~2013-12,中国科学院上海应用物理研究所, 助理研究员

   

[1] 李玉禾, 黄卫, 窦强, 李晴暖. 一种无水氯化铀酰的水相制备方法. CN: CN113772733A, 2021-12-10.
[2] 季男, 黄卫, 龚昱, 蒋锋, 彭浩, 佘长锋, 朱铁建. 一种氯化物熔盐体系中将稀土氧化物还原为稀土金属单质的方法. CN: CN112391653A, 2021-02-23.
[3] 蒋锋, 黄卫, 龚昱. 用于熔盐电化学测试的电极集成系统. CN: CN210803355U, 2020-06-19.
[4] 王鹏, 黄鹤, 严超, 佘长锋, 黄卫, 曹长青, 林俊. 一种熔盐取样装置以及一种熔盐取样方法. CN: CN109141969A, 2019-01-04.
[5] 周金豪, 陈梓, 孙波, 窦强, 黄卫, 龚昱, 李晴暖. 一种固态盐加热熔融装置及方法. CN: CN108295776A, 2018-07-20.
[6] 王鹏, 郑海洋, 佘长峰, 黄卫, 曹长青, 林俊. 一种三氟化铀的电沉积方法. CN: CN108179432A, 2018-06-19.
[7] 曹长青, 孙理鑫, 窦强, 胡聪伟, 黄卫, 牛永生, 王鹏, 周金豪, 林俊, 李晴暖. 一种制备熔盐反应堆燃料盐的装置和方法. CN: CN108109710A, 2018-06-01.
[8] 朱铁建, 郑海洋, 黄卫, 龙德武, 李晴暖, 吴国忠. 一种银/氯化银参比电极及其制备方法. CN: CN106290503A, 2017-01-04.
[9] 黄卫, 蒋锋, 田丽芳, 佘长锋, 郑海洋, 龙德武, 李晴暖. 熔盐的电化学净化方法. CN: CN106283112A, 2017-01-04.
[10] 朱铁建, 郑海洋, 张国欣, 黄卫, 龙德武, 李晴暖. 一种银/氯化银参比电极及其制作方法. CN: CN104297311A, 2015-01-21.
[11] 郑海洋, 蒋锋, 黄卫, 田丽芳, 佘长锋, 龙德武, 李晴暖. 用于氟化物熔盐的Ni/NiF 2 参比电极及制作方法. CN: CN104090004A, 2014-10-08.
[12] 郑海洋, 蒋锋, 黄卫, 田丽芳, 佘长锋, 龙德武, 李晴暖. 用于氟化物熔盐的Ni/NiF 2 参比电极及制作方法. 中国: CN104090004A, 2014-10-08.
[13] 龙德武, 黄卫, 蒋锋, 李晴暖. 电解槽. CN: CN203683681U, 2014-07-02.

   

[1] Yong Zuo, XueJiao Li, Feng Jiang, ChangFeng She, Wei Huang, Yu Gong. Electrochemical behavior of Sm(III)/Sm(II) and extraction of Sm on reactive electrode from molten LiF-BeF2. SEPARATION AND PURIFICATION TECHNOLOGY. 2023, 315: http://dx.doi.org/10.1016/j.seppur.2023.123737.
[2] Zuo, Yong, Peng, Hao, Ji, Nan, Huang, Wei, Gong, Yu. Electrochemical Study of Eu(III)/Eu(II) in LiF-BeF2 Molten Salt. JOURNAL OF THE ELECTROCHEMICAL SOCIETY[J]. 2023, 170(1): [3] Hao,Peng, Nan,Ji, Wei,Huang, Yu,Gong. Chemical Interactions between Thorium(IV) and O2- in the FLiBe and FLiNaK Molten Salt Systems. International Journal of Energy Research[J]. 2023, 2023: https://dx.doi.org/10.1155/2023/4447405.
[4] Ji, Nan, Jiang, Feng, Peng, Hao, Chen, Hao, Huang, Wei, Gong, Yu. The Electrolytic Reduction of MoO3 in CaCl2-NaCl Molten Salt. JOURNAL OF THE ELECTROCHEMICAL SOCIETY[J]. 2022, 169(8): [5] Jiang, Feng, Ji, Nan, Huang, Wei, Fu, Haiying. The Electrochemical Behavior of Neodymium(III) in FLiNaK Molten Salt on Pt Cathode. JOURNAL OF THE ELECTROCHEMICAL SOCIETY[J]. 2022, 169(10): http://dx.doi.org/10.1149/1945-7111/ac972e.
[6] Li, Yuhe, Lei, Qi, Xiong, Zhixin, Huang, Wei, Li, Qingnuan. Studies on the aqueous synthesis process of anhydrous uranyl chloride by U3O8, hydrochloric acid and H2O2. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY[J]. 2022, 331(1): 619-627, http://dx.doi.org/10.1007/s10967-021-08124-w.
[7] Ji, Nan, Peng, Hao, Jiang, Feng, Chen, Hao, Huang, Wei, Gong, Yu. Electrolytic Reduction of U3O8 and U3O8-MoO3 in CaCl2-NaCl Molten Salt. JOURNAL OF THE ELECTROCHEMICAL SOCIETY[J]. 2022, 169(10): [8] Li, Yuhe, Huang, Wei, Li, Qingnuan. Studies on the Electrodeposition of UO2 Production in UO2Cl2-LiCl-KCl Melt. JOURNAL OF THE ELECTROCHEMICAL SOCIETY[J]. 2022, 169(4): http://dx.doi.org/10.1149/1945-7111/ac62c1.
[9] Zhu, Tiejian, Huang, Wei, Gong, Yu. Influence of Fluoride Ions on the Speciation and Electrochemical Behavior of Th(IV) in Molten LiCl-KCl with a Copper Electrode. JOURNAL OF THE ELECTROCHEMICAL SOCIETY[J]. 2021, 168(2): https://www.webofscience.com/wos/woscc/full-record/WOS:000620536300001.
[10] Ji, Nan, Zhu, Tiejian, Peng, Hao, Jiang, Feng, Huang, Wei, Gong, Yu. The Electrolytic Reduction of Gd2O3 in LiCl-KCl-Li2O Molten Salt. JOURNALOFTHEELECTROCHEMICALSOCIETY[J]. 2021, 168(8): [11] Ji, Nan, Huang, Wei, Han, Wei. Electrochemical Behavior of Tb (III) in LiCl-KCl Molten Salt on Liquid Zn Electrode. JOURNAL OF THE ELECTROCHEMICAL SOCIETY[J]. 2021, 168(9): [12] Peng, Hao, Song, Yulong, Ji, Nan, Xie, Leidong, Huang, Wei, Gong, Yu. Inhibition effect of ZrF4 on UO2 precipitation in the LiF-BeF2 molten salt. RSC ADVANCES[J]. 2021, 11(31): 18708-18716, http://dx.doi.org/10.1039/d1ra02332b.
[13] 王先彬, 蒋锋, 朱铁建, 郑海洋, 佘长锋, 黄卫, 李晴暖. ThF4浓度对CeF3-ThF4-LiCl-KCl熔盐中Th电解沉积的影响. 核化学与放射化学[J]. 2020, 43(1): 57-63, http://lib.cqvip.com/Qikan/Article/Detail?id=7103918259.
[14] Zhu, Tiejian, Huang, Wei, Gong, Yu. Electrochemical separation of uranium from lanthanide (La, Eu, Gd) fluorides in molten LiCl-KCl. SEPARATION AND PURIFICATION TECHNOLOGY[J]. 2020, 235: http://dx.doi.org/10.1016/j.seppur.2019.116227.
[15] Peng, Hao, Huang, Wei, Xie, Leidong, Li, Qingnuan. Solubility and precipitation investigations of UO2 in LiF-BeF2 molten salt. JOURNAL OF NUCLEAR MATERIALS[J]. 2020, 531: http://dx.doi.org/10.1016/j.jnucmat.2020.152004.
[16] Han, Dong, She, Changfeng, Niu, Yongsheng, Yang, Xu, Geng, Junxia, Cui, Rongrong, Sun, Lixin, Hu, Congwei, Liu, Yiyang, Su, Tao, Liu, Hongtao, Huang, Wei, Gong, Yu, Li, Qingnuan. The oxidation of UF4 in FLiNaK melt and its electrolysis. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY[J]. 2019, 319(3): 899-906, https://www.webofscience.com/wos/woscc/full-record/WOS:000460148500024.
[17] Wang, Xianbin, Zheng, Haiyang, Xu, Qianhui, Zhu, Tiejian, Jiang, Feng, She, Changfeng, Wang, Chenyang, Cong, Haixia, Gong, Yu, Huang, Wei, Li, Qingnuan. Electrochemical behaviors and electrolytic separation of Th(IV) and Ce(III) in ThF4-CeF3-LiCl-KCl quaternary melt. SEPARATION AND PURIFICATION TECHNOLOGY[J]. 2019, 210: 236-241, http://dx.doi.org/10.1016/j.seppur.2018.08.013.
[18] Zhu, Tiejian, Wang, Chenyang, Fu, Haiying, Huang, Wei, Gong, Yu. Electrochemical and Raman Spectroscopic Investigations on the Speciation and Behavior of Chromium Ions in Fluoride Doped Molten LiCl-KCl. JOURNAL OF THE ELECTROCHEMICAL SOCIETY[J]. 2019, 166(10): H463-H467, https://www.webofscience.com/wos/woscc/full-record/WOS:000472066500001.
[19] Han, Dong, Li, Yuhe, Liu, Renduo, She, Changfeng, Huang, Wei, Gong, Yu, Li, Qingnuan. Communication-Electrochemical Behavior of UO22+ and Its Electrodeposition from UO2F2-FLiBe Melt. JOURNAL OF THE ELECTROCHEMICAL SOCIETY[J]. 2019, 166(6): D189-D191, [20] Zhu, TieJian, Huang, Wei, Li, QingNuan. Electrorefining of nickel from nickel-chromium alloy in molten LiCl-KCl. NUCLEAR SCIENCE AND TECHNIQUES[J]. 2019, 30(9): http://lib.cqvip.com/Qikan/Article/Detail?id=7002732780.
[21] TieJian Zhu, Wei Huang, QingNuan Li. Electrorefining of nickel from nickel–chromium alloy in molten LiCl–KCl. 核技术:英文版[J]. 2019, 30(9): 47-54, http://lib.cqvip.com/Qikan/Article/Detail?id=7002732780.
[22] 徐千惠, 朱铁建, 郑海洋, 蒋锋, 佘长锋, 黄卫, 李晴暖. ThF4-LiCl-KCl熔盐体系中F^-浓度对Th（Ⅳ）电解提取的影响. 辐射研究与辐射工艺学报[J]. 2018, 36(3): 27-34, http://lib.cqvip.com/Qikan/Article/Detail?id=675548465.
[23] Chen, Zi, She, Changfeng, Zheng, Haiyang, Huang, Wei, Zhu, Tiejian, Jiang, Feng, Gong, Yu, Li, Qingnuan. Electrochemical deposition of neodymium in LiF-CaF2 from Nd2O3 assisted by AlF3. ELECTROCHIMICA ACTA[J]. 2018, 261: 289-295, http://dx.doi.org/10.1016/j.electacta.2017.12.147.
[24] 王先彬, 龙德武, 朱铁建, 郑海洋, 蒋锋, 佘长锋, 黄卫, 李晴暖. Ln^3＋在LnF3-LiCl-KCl熔盐体系中的电化学行为. 核技术[J]. 2018, 41(6): 060301-1, http://lib.cqvip.com/Qikan/Article/Detail?id=675387099.
[25] 徐千惠, 朱铁建, 郑海洋, 蒋锋, 佘长锋, 黄卫, 李晴暖. ThF_4 -LiCl-KCl熔盐体系中F~-浓度对Th（IV）电解提取的影响. 辐射研究与辐射工艺学报[J]. 2018, 36(3): 030301-1, http://sciencechina.cn/gw.jsp?action=detail.jsp&internal_id=6261477&detailType=1.
[26] Han, Dong, She, ChangFeng, Peng, Jia, Jiang, Feng, Yang, Xu, Peng, Hao, Yang, Yang, Zheng, Haiyang, Wang, Xianbin, Xu, Qianhui, Wang, Chenyang, Zhu, Tiejian, Luo, Yan, Huang, Wei, Gong, Yu, Li, Qingnuan. Electrochemical Behavior of UO2F2 and Its Electrodeposition from UO2F2-FLiNaK Melt. JOURNAL OF THE ELECTROCHEMICAL SOCIETY[J]. 2018, 165(7): D301-D306, http://dx.doi.org/10.1149/2.0971807jes.
[27] Chen, Zi, She, Changfeng, Zheng, Haiyang, Huang, Wei, Zhu, Tiejian, Jiang, Feng, Gong, Yu, Li, Qingnuan. Study on the Electrochemical Co-Reduction of Gd(III) and Al(III) in LiF-CaF2 Melt. JOURNAL OF THE ELECTROCHEMICAL SOCIETY[J]. 2018, 165(9): D411-D416, https://www.webofscience.com/wos/woscc/full-record/WOS:000440924800093.
[28] 耿俊霞, 窦强, 王子豪, 杨洋, 黄卫, 付海英, 李文新, 吴国忠, 李晴暖. 钍基熔盐堆核能系统中熔盐的蒸馏纯化与分离. 核化学与放射化学[J]. 2017, 39(1): 36-42, http://lib.cqvip.com/Qikan/Article/Detail?id=671799081.
[29] Jiang, Feng, Huang, Wei, Zheng, Haiyang, Zhu, Tiejian, She, Changfeng, Gao, Size, Long, Dewu, Gong, Yu, Li, Qingnuan. Electrochemical behavior and electrowinning of uranium(IV) from FLiNaK molten salt. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY[J]. 2017, 311(3): 1891-1897, https://www.webofscience.com/wos/woscc/full-record/WOS:000398027800038.
[30] Huang Wei. Investigating the influence of F2 on U4+ in molten LiCl–KCl–UF4 system and electro-deposition of U. Journal of Radioanalytical and Nuclear Chemistry. 2017, [31] Zhu, Tiejian, Huang, Wei, Zheng, Haiyang, She, Changfeng, Jiang, Feng, Wang, Xianbin, Yu, Gong, Long, Dewu, Li, Qingnuan. Investigating the influence of F- on U4+ in molten LiCl-KCl-UF4 system and electro-deposition of U. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY[J]. 2017, 312(3): 479-485, https://www.webofscience.com/wos/woscc/full-record/WOS:000402173700004.
[32] Tian, Lifang, Huang, Wei, Jiang, Feng, Zheng, Haiyang, Zhu, Tiejian, She, Changfeng, Wang, Xianbin, Long, Dewu, Gong, Yu, Wu, Guozhong, Li, Qingnuan. Electrochemical Behavior of Graphite Anode in LiF-NaF-KF Eutectic with YF3. ELECTROCHIMICA ACTA[J]. 2017, 225: 392-398, http://dx.doi.org/10.1016/j.electacta.2016.12.165.
[33] Wang, Xianbin, Huang, Wei, Gong, Yu, Jiang, Feng, Zheng, Haiyang, Zhu, Tiejian, Long, Dewu, Li, Qingnuan. Electrochemical behavior of Th(IV) and its electrodeposition from ThF4-LiCl-KCl melt. ELECTROCHIMICA ACTA[J]. 2016, 196(-): 286-293, http://dx.doi.org/10.1016/j.electacta.2016.02.184.
[34] Huang, Wei, Tian, Lifang, She, Changfeng, Jiang, Feng, Zheng, Haiyang, Li, Wenxin, Wu, Guozhong, Long, Dewu, Li, Qingnuan. Electrochemical Behavior of Europium(III)-Europium(II) in LiF-NaF-KF Molten Salt. ELECTROCHIMICA ACTA[J]. 2014, 147: 114-120, http://dx.doi.org/10.1016/j.electacta.2014.08.119.
[35] Huang Lei, Huang Wei, Fu HaiYing, Wu GuoZhong, Guo ZhiJun, Wu WangSuo, Chen ShiMou. Influence of FeCl3 on radiation stability of ionic liquid BmimCl. CHINESE SCIENCE BULLETIN[J]. 2013, 58(10): 1150-1155, http://ir.ipe.ac.cn/handle/122111/13408.
[36] Ma, Jingyuan, Zou, Yang, Jiang, Zheng, Huang, Wei, Li, Jiong, Wu, Guozhong, Huang, Yuying, Xu, Hongjie. An in situ XAFS study-the formation mechanism of gold nanoparticles from X-ray-irradiated ionic liquid. PHYSICAL CHEMISTRY CHEMICAL PHYSICS[J]. 2013, 15(28): 11904-11908, http://dx.doi.org/10.1039/c3cp51743h.
[37] Huang Lei, Huang Wei, Fu HaiYing, Wu GuoZhong, Guo ZhiJun, Wu WangSuo. Extraction of Ce3+ Using CMPO-Ionic Liquid Systems. CHINESE JOURNAL OF INORGANIC CHEMISTRY[J]. 2012, 28(4): 669-673, http://www.irgrid.ac.cn/handle/1471x/748161.
[38] Chen, Shimou, Liu, Yusheng, Fu, Haiying, He, Yaxing, Li, Cheng, Huang, Wei, Jiang, Zheng, Wu, Guozhong. Unravelling the Role of the Compressed Gas on Melting Point of Liquid Confined in Nanospace. JOURNAL OF PHYSICAL CHEMISTRY LETTERS[J]. 2012, 3(8): 1052-1055, http://www.irgrid.ac.cn/handle/1471x/735476.
[39] Huang Lei, Huang Wei, Fu HaiYing, Wu GuoZhong, Guo ZhiJun, Wu WangSuo. Extraction of Ce3+ Using CMPO-Ionic Liquid Systems. CHINESE JOURNAL OF INORGANIC CHEMISTRY[J]. 2012, 28(4): 669-673, http://www.irgrid.ac.cn/handle/1471x/748161.
[40] Dai Binbin, Wang Qian, Ma Jingyuan, Li Jiong, Zhang Shuo, Huang Yuying, Huang Wei, Wu Guozhong, Zou Yang, Jiang Zheng, Xu Hongjie. XAFS study of Cu2+ in aqueous solution of CuBr2. NUCLEAR SCIENCE AND TECHNIQUES[J]. 2012, 23(3): 129-133, http://lib.cqvip.com/Qikan/Article/Detail?id=42756972.
[41] Huang, Wei, Chen, Shimou, Liu, Yusheng, Fu, Haiying, Wu, Guozhong. The controlled synthesis of stable gold nanoparticles in quaternary ammonium ionic liquids by simple heating. NANOTECHNOLOGY[J]. 2011, 22(2): http://www.irgrid.ac.cn/handle/1471x/455003.
[42] Liu YuSheng, Fu HaiYing, Tang ZhongFeng, Huang Wei, Wu GuoZhong. Melting Point and Structure of Ionic Liquid EMIMPF6 on the Surface of Nano-SiOx Particles. ACTA PHYSICO-CHIMICA SINICA[J]. 2011, 27(7): 1725-1729, https://www.webofscience.com/wos/woscc/full-record/WOS:000292877100027.
[43] 刘玉胜, 付海英, 唐忠锋, 黄卫, 吴国忠. 离子液体EMIMPF6】负载纳米SiOx表面的熔点及结构. 物理化学学报[J]. 2011, 27(7): 1725-1729, http://lib.cqvip.com/Qikan/Article/Detail?id=38332101.
[44] 王倩, 邹杨, 姜政, 黄卫, 张硕, 魏向军, 王建强, 马静远, 吴国忠, 黄宇营, 徐洪杰. 同步辐射XANES方法对FeCl3水溶液的研究. 中国科学：物理学、力学、天文学[J]. 2011, 41(1): 17-22, http://lib.cqvip.com/Qikan/Article/Detail?id=36683634.
[45] Huang, Wei, Chen, Shimou, Liu, Yusheng, Fu, Haiying, Wu, Guozhong. Fluoride ion yield and absorption spectral analysis of irradiated imidazolium-based room-temperature ionic liquids. RADIATION PHYSICS AND CHEMISTRY[J]. 2011, 80(4): 573-577, http://www.irgrid.ac.cn/handle/1471x/454914.
[46] Huang, Wei, Chen, Shimou, Fu, Haiying, Wu, Guozhong. Improvement of Radiation Resistance and an Estimate of Solvated Electron Yield of the Ionic Liquid BmimCl by the Addition of FeCl3. RADIATION RESEARCH[J]. 2010, 174(5): 650-657, http://www.corc.org.cn/handle/1471x/2408981.
[47] Zou, Yang, Xu, Hongjie, Wu, Guozhong, Jiang, Zheng, Chen, Shimou, Huang, Yuying, Huang, Wei, Wei, Xiangjun. Structural Analysis of ChCl(m)ZnCl2(n) Ionic Liquid by X-ray Absorption Fine Structure Spectroscopy. JOURNAL OF PHYSICAL CHEMISTRY B[J]. 2009, 113(7): 2066-2070, https://www.webofscience.com/wos/woscc/full-record/WOS:000263299400034.

   

（ 1 ） 氟盐中铀酰离子的形成机制和电化学性质研究, 主持, 国家级, 2017-01--2019-12
（ 2 ） 2017年中国科学院青年创新促进会, 主持, 部委级, 2017-01--2020-12
（ 3 ） 熔盐体系电解分离技术, 主持, 部委级, 2011-01--2020-12
（ 4 ） “变革性洁净能源关键技术与示范”先导专项, 参与, 部委级, 2018-04--2023-04
（ 5 ） 修缮购置专项-小动物成像平台, 参与, 部委级, 2021-01--2022-12

（1）乏燃料中镧锕元素的熔盐电化学分离技术研究   2020（第七届）全国同位素制备与应用技术交流会   2020-11-14
（2）Application of Electrochemical Technology in TMSR   2018-10-24
（3）Electrochemical behavior and electrolysis of U4+ in FLiBe Eutectic Salts   2017-07-02
（4）Electrochemical Extraction of Ans and REs from FLiNaK Eutectic Salts   2016-09-20
（5）Electrochemical behavior and separation of Th and U of TMSR fuel salt   2016-04-05

现指导学生

陈灏  硕士研究生  071011-生物物理学