General

Dr. Yu Gong, Shanghai  Institute of Applied Physics, Chinese Academy of Sciences
Email: gongyu@sinap.ac.cn
Mailing address: 2019 Jialuo Rd., Shanghai, 201800, China
Zip code: 201800

Research Areas

Our research interests focus on the chemsitry invovled in thorium-uranium fuel cycle, including the chemistry of actinide and fission product that affects the operation of molten salt reactor, the separation behaviors between fission product and actinide, the performance of  fission product and actinide when they are reused as new fuels and in other areas such as energy, enviroment and health. By using a number of synthetic, spectroscopic and electrochemical methods, we try to get a comprehensive understanding regarding the effects of actinide and fission product on a series of processes, and how their behaviors are correlated with the structures of these complexes in molten salt and other medium. The research results will help improve the safety of molten salt reactor while in operation, develop more efficient strategies for actinide-fission product separation under molten salt enviroment and open new areas for the applications of actinide and fission products,

Education

2010-07, Ph. D. in physical chemistry, Fudan University, Shanghai, China
2005-07, B. S in chemistry, Fudan University, Shanghai, China

Experience

   
Work Experience

2015-02~now, Professor, Department of Radiochemistry, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, China.

2014-09~2014-11, Visiting Scientist, Department of Chemistry, University of Virginia, Charlottesville, VA, USA

2012-02~2014-08, Postdoctoral Fellow, Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA
2010-08~2012-01, Research Associate, Department of Chemistry, University of Virginia, Charlottesville, VA, USA

Teaching Experience

Frontiers in actinide chemistry

Publications

   
Papers

    • (1) Mass spectrometric and theoretical study on the formation of uranyl hydride from uranyl carboxylate, Physical Chemistry Chemical Physics, 2021, 通讯作者
      (2) On the Structures of Thorium Fluoride and Oxyfluoride Anions in Molten FLiBe and FLiNaK, The Journal of Physical Chemistry B, 2021, 通讯作者
      (3) HMNTA Complexes of Tetravalent Metal Ions: on the Roles of Carbonyl Oxygen and Amine Nitrogen in the Stabilization of Gas-Phase M(HMNTA)24+ (M = Zr, Hf, Th and U) Complexes, Journal of the American Society for Mass Spectrometry, 2021, 通讯作者
      (4) Photoluminescence of LaI3 Switched On and Off by Association and Dissociation of Non-Luminescent Tetrahydrofuran, Dalton Transactions, 2021, 通讯作者
      (5) Vanadium, Niobium and Tantalum Complexes with Terminal Sulfur Radical Ligands, Dalton Transactions, 2021, 通讯作者
      (6) Oxo-sulfido molybdenum and tungsten fluorides with M-O and M-S multiple bonds, Physical Chemistry Chemical Physics, 2021, 通讯作者
      (7) Influence of Fluoride Ions on the Speciation and Electrochemical Behavior of Th(IV) in Molten LiCl-KCl with a Copper Electrode, Journal of The Electrochemical Society, 2021, 通讯作者
      (8) A Simple Molten Salt Route to Crystalline β-MoB2 Nanosheets with High Activity for Hydrogen Evolution Reaction, Inorganic Chemistry, 2021, 通讯作者
      (9) Molten Salt Synthesis of Samarium Borides with Controllable Stoichiometry and Morphology, Journal of Alloys and Compounds, 2021, 通讯作者
      (10) Sulfur-substituted uranyl stabilized by fluoride ligands: matrix preparation of U(O)(S)F2 via oxidation of U(0) by SOF2, Chemical Communications, 2020, 通讯作者
      (11) Sulfur Dioxide Complexes of Main-Group Elements: from SO20 to SO2- and SO22- upon Coordination to Aluminum and Silicon Difluorides, Inorganic Chemistry, 2020, 通讯作者
      (12) End-On Cyanogen Complexes of Iridium, Palladium and Platinum, Inorganic Chemistry, 2020, 通讯作者
      (13) Complexation of Ln3+ with Pyridine-2,6-Dicarboxamide: Formation of the 1:2 Complexes in Solution and Gas Phase, Inorganic Chemistry, 2020, 通讯作者
      (14) Raman Spectroscopic and Theoretical Study of Scandium Fluoride and Oxyfluoride Anions in Molten FLiNaK, The Journal of Physical Chemistry B, 2020, 通讯作者
      (15) Synthesis of a Dinuclear Europium (III) Complex through Deprotonation and Oxygen-Atom Transfer of Trimethylamine N-Oxide, Dalton Transactions, 2019, 通讯作者
      (16) Electrochemical Separation of Uranium from Lanthanide (La, Eu, Gd) Fluorides in Molten LiCl-KCl, Separation and Purification Technology, 2019, 通讯作者
      (17) Bidentate SO2 Complexes of Zirconium and Hafnium Difluorides with Highly Activated S-O Bonds, The Journal of Physical Chemistry A, 2019, 通讯作者
      (18) Side-On OMoF2(η2-SO) and OWF2(η2-SO) Complexes Featuring Peroxo-Like Sulfur Monoxide Ligand, Inorganic Chemistry, 2019, 通讯作者
      (19) Infrared Spectroscopic and Theoretical Studies of the 3d Transition Metal Oxyfluoride Molecules, Inorganic Chemistry, 2019, 通讯作者
      (20) End-on Oxygen Bound Sulfur Monoxide Complex of Titanium Oxyfluoride, Inorganic Chemistry, 2019, 通讯作者
      (21) Tetrapositive Hafnium-Diamide Complexes in the Gas Phase: Formation, Structure and Reaction, Journal of the American Society for Mass Spectrometry, 2019, 通讯作者
      (22) Efficient Removal of Azo-Dyes in Aqueous Solution by CeB6 Nanocrystals, ACS Applied Nano Materials, 2019, 通讯作者
      (23) Formation of Cerium and Neodymium Isocyanides in the Reactions of Cyanogen with Ce and Nd Atoms in Argon Matrices, The Journal of Physical Chemistry A, 2019, 通讯作者
      (24) Side-On Sulfur Monoxide Complexes of Tantalum, Niobium, and Vanadium Oxyfluorides, Inorganic Chemistry, 2019, 通讯作者
      (25) Coordination Structures of the Uranyl(VI)−Diamide Complexes: ACombined Mass Spectrometric, EXAFS Spectroscopic, and Theoretical Study, Inorganic Chemistry, 2019, 通讯作者
      (26) Bidentate Sulfur Dioxide Complexes of Scandium, Yttrium, and Lanthanum Difluorides, Inorganic Chemistry, 2019, 通讯作者
      (27) Electrochemical and Raman Spectroscopic Investigations on the Speciation and Behavior of Chromium Ions in Fluoride Doped Molten LiCl-KCl, Journal of The Electrochemical Society, 2019, 通讯作者
      (28) Infrared Spectroscopic and Theoretical Studies of Group 3 Metal Isocyanide Molecules, The Journal of Physical Chemistry A, 2018, 通讯作者
      (29) Infrared Spectra of the SO2F2 Anion in Solid Argon and Neon, The Journal of Physical Chemistry A, 2018, 通讯作者
      (30) Formation and Characterization of Zr4+ Stabilized by Neutral Tridentate Ligands in the Gas Phase, Journal of the American Society for Mass Spectrometry, 2018, 通讯作者
      (31) Formation and Fragmentation Chemistry of Tripositive Ln(TMGA)33+ Complexes in the Gas Phase, Journal of the American Society for Mass Spectrometry, 2017, 通讯作者
      (32) Formation and Characterization of Homoleptic Thorium Isocyanide Complexes, Inorganic Chemistry, 2017, 通讯作者
      (33) Electrochemical behavior and electrowinning of uranium(IV) from FLiNaK molten salt, Journal of Radioanalytical and Nuclear Chemistry, 2017, 通讯作者
      (34) Infrared Spectroscopic and Theoretical Studies on the OMF2 and, The Journal of Physical Chemistry A, 2017, 通讯作者
      (35) Matrix Infrared Spectra of Manganese and Iron Isocyanide, The Journal of Physical Chemistry A, 2017, 通讯作者
      (36) Coordination Structure and Fragmentation Chemistry of the, The Journal of Physical Chemistry A, 2017, 通讯作者
      (37) Detection and Electronic Structure of Naked Actinide Complexes: Rhombic-Ring (AnN)2 Molecules Stabilized by Delocalized π-Bonding, Journal of the American Chemical Society, 2016, 第 4 作者
      (38) The evaporation behaviors of rare-earth-doped FLiNaK melts during low-pressure distillation, Journal of Radioanalytical and Nuclear Chemistry, 2016, 通讯作者
      (39) Synthesis and hydrolysis of uranyl, neptunyl, and plutonyl gas-phase complexes exhibiting discrete actinide-carbon bonds, Organometallics, 2016, 第 3 作者
      (40) Electrospray production and collisional dissociation oflanthanide/methylsulfonyl anion complexes: Sulfur dioxide anionas a ligand., Int. J. Mass. Spectrom., 2015, 第 1 作者
      (41) Reactions of Laser-Ablated U Atoms with HCN: Infrared Spectra in Solid Argon and Quantum Chemical Calculations for HUNC, Eur. J. Inorg. Chem., 2015, 第 1 作者
      (42) Synthesis and Structures of Plutonyl Nitrate Complexes: Is Plutonium Heptavalent in PuO3(NO3)2- ?, Inorg. Chem., 2015, 第 3 作者
      (43) Gas Phase Uranyl Activation: Formation of a Uranium Nitrosyl Complex from Uranyl Azide, J. Am. Chem. Soc., 2015, 第 1 作者
      (44) Reactions of laser-ablated U atoms with (CN)2: infrared spectra and electronic structure calculations of UNC, U(NC)2, and U(NC)4 in solid argon, Chem. Commun., 2015, 第 1 作者
      (45) Infrared Spectra and Electronic Structure Calculations for the NUN(NN)1-5 and NU(NN)1-6 Complexes in Solid Argon, Inorganic Chemistry, 2014, 第 3 作者
      (46) Reactions of Lanthanide Atoms with Oxygen Difluoride and the Role of the Ln Oxidation State, Inorganic Chemistry, 2014, 第 5 作者
      (47) Tetrapositive Plutonium, Neptunium, Uranium and Thorium Coordination Complexes: Chemistry Revealed by Electron Transfer and Collision Induced Dissociation, J. Phys. Chem. A, 2014, 第 1 作者
      (48) Activation of Gas-Phase Uranyl: From an Oxo to a Nitrido Complex, J. Phys. Chem. A, 2014, 第 1 作者
      (49) Infrared Spectra and Electronic Structure Calculations for NN Complexes with U, UN, and NUN in Solid Argon, Neon, and Nitrogen, J. Phys. Chem. A, 2014, 第 3 作者
      (50) Crown Ether Complexes of Uranyl, Neptunyl and Plutonyl: Hydration Differentiates Inclusion versus Outer-Coordination, Inorg. Chem., 2014, 第 1 作者
      (51) Dissociation of Diglycolamide Complexes of Ln3+ (Ln = La-Lu) and An3+ (An = Pu, Am, Cm): Redox Chemistry of 4f and 5f Elements in the Gas Phase Parallels Solution Behavior, Inorg. Chem., 2014, 第 1 作者
      (52) A Tetrapositive Metal Ion in the Gas Phase: Thorium(IV) Coordinated by Neutral Tridentate Ligands, Angew. Chem. Int. Ed., 2013, 第 1 作者
      (53) Formation and Characterization of the Uranyl−SO2 Complex, UO2(CH3SO2)(SO2)−, J. Phys. Chem. A, 2013, 第 1 作者
      (54) Experimental and Theoretical Studies on the Fragmentation of Gas-Phase Uranyl−,, J. Phys. Chem. A, 2013, 第 1 作者
      (55) Infrared Spectra and Electronic Structure Calculations for the NUN(NN)1-5 and, Inorg. Chem., 2013, 第 3 作者
      (56) Matrix Infrared Spectroscopic and Theoretical of the Difluoroamino Metal Fluoride Molecules: F2NMF (M = Cu, Ag, Au), Inorganic Chemistry, 2012, 第 1 作者
      (57) Methane to Methanol Conversion Induced by Thorium Oxide through the CH3Th(O)H Intermediate in Solid Argon, Inorganic Chemistry, 2012, 第 1 作者
      (58) Reactions of Group 3 Metals with OF2: Infrared Spectroscopic and Theoretical Investigations of the Group 3 Oxydifluoride OMF2 and Oxyfluoride OMF Molecules, Journal of Physical Chemistry A, 2012, 第 1 作者
      (59) Infrared spectroscopic and theoretical studies of the OTiF2, OZrF2 and OHfF2 molecules with terminal oxo ligands, Dalton Transactions, 2012, 第 1 作者
      (60) Formation of Metal Oxyfluorides from Specific Metal Reactions with Oxygen Difluoride: Infrared Spectroscopic and Theoretical Investigations of the OScF2 Radical and OScF with Terminal Single and Triple Sc=O Bonds, Chemistry - A European Journal, 2012, 第 1 作者
      (61) Spectroscopic Observation of a Group 12 Oxyfluoride: A Matrix-Isolation and Quantum-Chemical Investigation of Mercury Oxyfluorides, Angewandte Chemie, International Edition, 2012, 第 3 作者
      (62) Infrared Spectroscopic and Theoretical Investigations of the OUF2 and OThF2 Molecules with Triple Oxo Bond Character, Inorganic Chemistry, 2012, 第 1 作者
      (63) Infrared Spectra of Rh12C and Rh13C in Solid Neon and Solid Argon, Chemical Physics Letters, 2012, 第 1 作者
      (64) Reactions of Late Lanthanide Metal Atoms and Methanol in Solid Argon: A Matrix Isolation Infrared Spectroscopic and Theoretical Study, Journal of Physical Chemistry A, 2011, 第 1 作者
      (65) Matrix Infrared Spectra and Theoretical Studies of Thorium Oxide Species: ThOx and Th2Oy, Journal of Physical Chemistry A, 2011, 第 2 作者
      (66) Matrix infrared spectroscopic and density functional theoretical investigations on thorium and uranium atom reactions with dimethyl ether, Dalton Transactions, 2011, 第 1 作者
      (67) Matrix Infrared Spectroscopic and Theoretical Studies on the Reactions of Scandium, Yttrium, and Lanthanide Metal Atoms with Dimethyl Ether, Journal of Physical Chemistry A, 2011, 第 1 作者
      (68) Infrared Spectra and Quantum Chemical Calculations of the Bridge-Bonded HC(F)LnF2 (Ln = La-Lu) Complexes, Organometallics, 2011, 第 1 作者
      (69) Matrix Infrared Spectroscopic and Theoretical Investigations of Uranium Atom and Methanol Reaction Products, Inorganic Chemistry, 2011, 第 1 作者
      (70) Is rhodium tetroxide in the formal oxidation state VIII stable? a quantum chemical and matrix isolation investigation of rhodium oxides, Theoretical Chemistry Accounts, 2011, 第 1 作者
      (71) Infrared spectrum of the CH3OCH2 radical in solid argon, Journal of Physical Chemistry A, 2011, 第 1 作者
      (72) Water Adsorption on Platinum Dioxide and Dioxygen Complex: matrix Isolation Infrared Spectroscopic and Theoretical Study of Three PtO2-H2O Complexes, ChemPhysChem, 2010, 第 1 作者
      (73) Chemistry on Single Atoms: Spontaneous Hydrogen Production from Reactions of Transition-Metal Atoms with Methanol at Cryogenic Temperatures, Angewandte Chemie, International Edition, 2010, 第 3 作者
      (74) Formation and Characterization of Magnesium Bisozonide and Carbonyl Complexes in Solid Argon, Journal of Physical Chemistry A, 2010, 第 2 作者
      (75) Formation and Characterization of the Iridium Tetroxide Molecule with Iridium in the Oxidation State +VIII, Angewandte Chemie, International Edition, 2009, 第 1 作者
      (76) Formation and characterization of the CuO5, CuO4 and CuO4- complexes in solid argon, Physical Chemistry Chemical Physics, 2009, 第 1 作者
      (77) Infrared Spectra of Oxygen-Rich Yttrium and Lanthanum Dioxygen/Ozonide Complexes in Solid Argon, Journal of Physical Chemistry A, 2009, 第 1 作者
      (78) Spectroscopic Characterization of a Copper(III) Trisuperoxide Complex Bearing Both Side-On and End-On Ligands, Journal of Physical Chemistry A, 2009, 第 1 作者
      (79) Infrared Spectra of Transition-Metal Dioxide Anions: MO2- (M = Rh, Ir, Pt, Au) in Solid Argon, Journal of Physical Chemistry A, 2009, 第 1 作者
      (80) Is the FeO2- Anion Bent or Linear?, Journal of Physical Chemistry A, 2009, 第 1 作者
      (81) Spectroscopic and Theoretical Studies of Transition Metal Oxides and Dioxygen, Chem. Rev., 2009, 第 1 作者
      (82) Formation and Characterization of Two FeO3 Isomers in Solid Argon, Journal of Physical Chemistry A, 2008, 第 1 作者
      (83) Matrix Infrared Spectra and Density Functional Calculations of TiO3 and TiO5 in Solid Argon, Journal of Physical Chemistry A, 2008, 第 1 作者
      (84) Noble-Gas-Induced Disproportionation Reactions: Facile Superoxo-to-Peroxo Conversion on Chromium Dioxide, Journal of Physical Chemistry A, 2008, 第 3 作者
      (85) Matrix isolation infrared spectroscopic and theoretical study of the hydrolysis of boron dioxide in solid argon, Journal of Physical Chemistry A, 2008, 第 1 作者
      (86) Formation and Characterization of Mononuclear and Dinuclear Manganese Oxide-Dioxygen Complexes in Solid Argon, Journal of Physical Chemistry A, 2008, 第 1 作者
      (87) Formation and Characterization of the Photochemically Interconvertible Side-On and End-On Bonded Dioxygen-Iron Dioxide Complexes in Solid Argon, Journal of Physical Chemistry A, 2007, 第 1 作者
      (88) Formation and characterization of the oxygen-rich scandium oxide/dioxygen complexes ScOn (n = 4, 6, 8) in solid argon, Journal of Physical Chemistry A, 2007, 第 1 作者
      (89) Matrix isolation infrared spectroscopic and theoretical study of noble gas coordinated dipalladium-dioxygen complexes, Chemical Physics, 2007, 第 2 作者
      (90) Matrix Isolation Infrared Spectroscopic and Theoretical Study of Dinuclear Chromium Oxide Clusters: Cr2On (n = 2, 4, 6) in Solid Argon, Journal of Physical Chemistry A, 2007, 第 3 作者
      (91) Formation and Characterization of the Oxygen-Rich Hafnium Dioxygen Complexes: OHf(η2-O2)(η2-O3), Hf(η2-O2)3, and Hf(η2-O2)4, Journal of Physical Chemistry A, 2007, 第 1 作者
      (92) Formation and Characterization of the Tetranuclear Scandium Nitride: Sc4N4, Journal of Physical Chemistry A, 2007, 第 1 作者
      (93) Interconvertible Side-On- and End-On-Bonded Oxo-Superoxo Titanium Ozonide Complexes, Journal of Physical Chemistry A, 2007, 第 1 作者
      (94) Remarkable dinitrogen activation and cleavage by the Gd dimer: from dinitrogen complexes to ring and cage nitrides, Angewandte Chemie, International Edition, 2007, 第 3 作者
      (95) Matrix Isolation Infrared Spectroscopic and Theoretical Study of Group IV Metal Oxide Clusters: M2O2 and M2O4, Journal of Physical Chemistry A, 2007, 第 1 作者
      (96) Infrared Spectra of Chlorinated Ethylene Cations: C2Cl4+, C2HCl3+, 1,1-C2H2Cl2+, and trans-C2H2Cl2+ in Solid Argon, Journal of Physical Chemistry A, 2007, 第 2 作者
      (97) Matrix Isolation Infrared Spectroscopic and Theoretical Study of Noble Gas Coordinated Rhodium-Dioxygen Complexes, Journal of Physical Chemistry A, 2007, 第 2 作者
  • 科研活动


Research Interests

1. Molten salt based synthesis and spectroscopy

2. Mass spectrometry and spectroscopy of actinide and lanthanide molecules and ions

3. Synthesis of novel actinide and lanthanide compounds with unique chemical bonds

4. Separation of lanthanide and actinide in molten salt by advanced stratogies

Conferences

  1. Generation IV International Forum, GIF, Mar. 12-13, 2019, Sydney, Australia.

  2. SAMOFAR European Research Project Technical Meeting, Jul 4-5, 2018, Karlsruhe, Germany.

  3. 253rd ACS National Meeting & Exposition, Apr. 6, 2017, San Francisco, CA, United States.

  4. 2016 Nuclear Fuel Cycle Assessment Workshop. Jul. 20, 2016, Nashville, TN, United States.

Students

已指导学生

杨甜宏  硕士研究生  070301-无机化学  

陈秀婷  博士研究生  070301-无机化学  

魏睿  博士研究生  070301-无机化学  

王晨阳  博士研究生  070301-无机化学  

李杨娟  博士研究生  070301-无机化学  

刘西艳  博士研究生  070301-无机化学  

胡靖雯  硕士研究生  070301-无机化学  

熊志欣  博士研究生  070301-无机化学  

冷德基  硕士研究生  070301-无机化学  

现指导学生

万松朋  硕士研究生  082703-核技术及应用  

文君  硕士研究生  082701-核能科学与工程  

林恩佑  博士研究生  070301-无机化学  

曹满鑫  博士研究生  070301-无机化学  

何清秀  博士研究生  070301-无机化学