Prof. Dr. Goldbach Andreas
PhD Supervisor
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
Zhongshan Road 457, Shahekou District
Dalian, China, 116023
Telephone: +86 411 8437 9647
Email: goldbach@dicp.ac.cn
Research Areas
Membrane reactors are promising, energy-saving devices for sustainable chemical production schemes. Highly active and selective catalysts are needed for membrane reactors. Therefore they are the focal point of our current research. This includes catalyst preparation, characterization, catalytic and kinetic studies on:
1. Catalysts for hydrogen production
Noble metal catalysts supported on nanostructured reducible oxides and apatites for water-gas shift and steam reforming reactions.
2. Catalysts for selective oxidation reactions
Noble metal catalysts supported on TS-1 zeolites and nanostructured oxides for olefin oxidation. e.g. propylene conversion to propylene oxide and acrolein.
3. Catalytic mechanisms
In situ studies using e.g. FTIR, XPS and synchrotron based X-ray absorption spectroscopy (XAS) in combination with kinetic analyses.
4. Membrane reactors
Research on membrane-assisted propylene epoxidation, water-gas shift and steam reforming using hydrogen selective metal membranes.Education
1984-1989 Chemistry, Georg-August-University, Göttingen,
1989 – 1993 PhD(获博士学位)in Physical Chemistry, Philipps-University, Marburg, Germany
Honors & Distinctions
Friendship Award of Liaoning Province (2017)
Publications
[1] Kinetics of the Reactions of CH2 (X 3B1) with HCl and HBr
A. Goldbach, F. Temps, H. Gg. Wagner, Ber. Bunsenges. Phys. Chem. 94 (1990) 1367
[2] Streuung von Kaliumclustern in Molekularstrahlen
A. Goldbach, PhD thesis, Marburg (1993)
[3] Size-dependent Trends in the Scattering of Small Potassium Clusters by Water Molecules
A. Goldbach, F. Hensel, K. Rademann, Z. Naturforsch. 49a (1994) 1067
[4] Formation of potassium oxide clusters by seeded supersonic expansion
A. Goldbach, F. Hensel, K. Rademann, Int. J. Mass. Spec. Ion Processes 148 (1995) L5
[5] The Formation of Se2-: A New Resonance Raman Feature in the Photochemistry of Zeolite-Encapsulated Selenium
A. Goldbach, L. Iton, M. Grimsditch, M.-L. Saboungi, J. Am. Chem. Soc. 118 (1996) 2004
[6] Photoinduced Formation of Selenium Molecules in Zeolites: A Resonant Raman Spectroscopy Study
A. Goldbach, L. Iton, M. Grimsditch, M.-L. Saboungi, J. Phys. Chem. B 101 (1997) 330
[7] Semiconductors in the disordered state: From bulk to nanoscale
P. Armand, A. Goldbach, C. Cramer, R. Csencsits, L. E. Iton, D. L. Price,
M.-L. Saboungi, J. Non-Cryst. Solids, 205-207 (1996) 797-802.
[8] On the Formation of Isolated Se8 Rings in Zeolites
A. Goldbach, L. Iton, M.-L. Saboungi, Chem. Phys. Lett. 281 (1997) 69-73.
[9] Optical Spectroscopy on Se8 Clusters and Se Chains Embedded in Zeolite Matrices
A. Goldbach, M.-L. Saboungi, Ber. Bunsenges. Phys. Chem. 101 (1997) 1660
[10] Vibrational Frequencies of Small Selenium Molecules
S. Kohara, A. Goldbach, N. Koura, M.-L. Saboungi, L. A. Curtiss, Chem. Phys. Lett. 287 (1998) 282
[11] The Clusters Cd22+ and Cd42+ in Zeolite A
A. Goldbach, P. D. Barker, P. A. Anderson, P. P. Edwards Chem. Phys. Lett. 292 (1998) 137
[12] On the Constituents of Aqueous Polyselenide Electrolytes: A Combined Theoretical and Raman Spectroscopic Study
A. Goldbach, J. Johnson, D. Meisel, L. A. Curtiss, M.-L. Saboungi, J. Am. Chem. Soc. 121 (1999) 4461
[13] Stabilization of Selenium in Zeolites - An Anomalous X-Ray Scattering Study
A. Goldbach, M.-L. Saboungi, L. Iton, D. L. Price, Chem. Comm. 1999 997
[14] Short and intermediate-range atomic structure of glassy and liquid As2Se3 - An anomalous x-ray scattering study
S. Hosokawa, A. Goldbach, M. Boll, F. Hensel, Physica Status Solidi (b), 215 (1999) 785
[15] Oxidation of Aqueous Polyselenide Solutions - A Mechanistic Pulse Radiolysis Study
A. Goldbach, M.-L. Saboungi,* J. A. Johnson, A. R. Cook, D. Meisel, J. Phys. Chem. A 104 (2000) 4011
[16] An Approach to Band Gap Alignment in Confined Semiconductors
A. Goldbach, M.-L. Saboungi,* L. Iton, D. L. Price, J. Chem. Phys. 115 (2001) 11254
[17] 77Se and 87Rb Solid State NMR study of the Structure of Rb2[Pd(Se4)2]×Se8
A. Goldbach, F. Fayon, T. Vosegaard, M.Wachhold, M. Kanatzidis, D. Massiot, and
M.-L. Saboungi,* Inorg. Chem. 42 (2003) 6996
[18] Optical spectroscopy on Se clusters and chains confined in zeolites
A. Goldbach and M.-L. Saboungi,* Eur. J. Phys. E 12 (2003) 185
[19] An Air-Stable Selenium/Zeolite Nanocomposite
A. Goldbach, L. Iton, M. Grimsditch, and M.-L. Saboungi,* Chem. Mater. 16 (2004) 5107.
[20] Low-Temperature H2 and N2 transport through thin Pd0.66Cu0.34Hx layers
X. Pan,* M. Kilgus, and A. Goldbach,* Catal. Today 104 (2005) 225-230.
[21] Selenium/Zeolite Y Nanocomposites
A. Goldbach* and M.-L. Saboungi, Acc. Chem. Res. 38 (2005) 705.
[22] PdC formation in ultra-thin Pd membranes during separation of H2/CO mixtures
H. Li, A. Goldbach,* W. Li, H. Xu, J. Membr. Sci. 299 (2007) 130-137.
[23] Segregation and H2 transport rate control in body-centered cubic PdCu membranes
L. Yuan, A. Goldbach,* H. Xu, J. Phys. Chem. B 111 (2007) 10952.
[24] Real-time monitoring of metal deposition and segregation phenomena during preparation of PdCu membranes
L. Yuan, A. Goldbach,* H. Xu, J. Membr. Sci. 322 (2008) 39-45.
[25] On CH4 decomposition during separation from H2 mixtures with thin Pd membranes
H. Li, A. Goldbach,* W. Li, H. Xu, J. Membr. Sci. 324 (2008) 95-101.
[26] CO2 decomposition over Pd membrane surfaces
H. Li, A. Goldbach,* W. Li, H. Xu, J. Phys. Chem. B 112 (2008) 12182.
[27] Permeation hysteresis in PdCu membranes
L. Yuan, A. Goldbach,* H. Xu, J. Phys. Chem. B 112 (2008) 12692.
[28] Nanocomposite materials: Semiconductors in zeolites
A. Goldbach, M.-L. Saboungi, in: Nanomaterials: Inorganic and Bioinorganic Perspectives; edited by C. M. Lukehart, R. A. Scott. Chichester, UK: John Wiley & Sons, Ltd., 2008, pp 649-658.
[29] Impact of support mass flow resistance on low-temperature H2 permeation characteristics of a Pd95Ag5/Al2O3 composite membrane
G. Zeng, A. Goldbach,* H. Xu, J. Membr. Sci. 326 (2009) 681-687.
[30] Defect sealing in Pd membranes via point-plating
G. Zeng, A. Goldbach,* H. Xu, J. Membr. Sci. 328 (2009) 6-10.
[31] Water gas shift reaction in a Pd membrane reactor over Pt/Ce0.6Zr0.4O2 catalyst
Y. Bi, H. Xu,* W. Li, A. Goldbach,* Int. J. Hydrogen Energy 34 (2009) 2965-2971.
[32] Development of hydrogen membrane reactors for CO2 capture
J. W. Dijkstra, D. Jansen, R. W. van den Brink, T. A. Peters, M. Stange, R. Bredesen, A. Goldbach, H. Xu, A. Gottschalk, S. Tlatlik, A. Doukelis, in: Carbon Dioxide Capture for Storage in Deep Geological Formations, Volume 3, edited by L.I. Eide, CPL Press (2009).
[33] Hydrogen membrane reactors for CO2 capture
D. Jansen,* J. W. Dijkstra, R. W. van den Brink, T. A. Peters, M. Stange, R. Bredesen, A. Goldbach, H. Xu, A. Gottschalk, A. Doukelis, Energy Procedia 1 (2009) 253-260.
[34] Direct H2O2 synthesis over Pd membranes at elevated temperatures
L. Shi, A. Goldbach,* G. Zeng, H. Xu, J. Membr. Sci. 348 (2010) 160-166.
[35] Impact of the fcc/bcc phase transition on the homogeneity and behavior of PdCu membranes
A. Goldbach,* L. Yuan, H. Xu,* Separ. Purif. Technol. 73 (2010) 65-70.
[36] Preparation and performance of thin-layered PdAu/ceramic composite membranes
L. Shi, A. Goldbach,* G. Zeng and H. Xu,* Int. J. Hydrogen Energy 35 (2010) 4201-4208.
[37] H2O2 synthesis over PdAu membranes
L. Shi, A. Goldbach,* G. Zeng and H. Xu, Catal. Today 156 (2010) 118-123.
[38] Structure of a prototypic ionic liquid: Ethyl-methylimidazolium bromide
B. Aoun, A. Goldbach, S. Kohara, J.-F. Wax, M. Gonzales and M.-L. Saboungi,* J. Phys. Chem. B 114 (2010) 11623.
[39] High-flux H2 separation membranes from (Pd/Au)n nanolayers
L. Shi, A. Goldbach,* and H. Xu, Int. J. Hydrogen Energy 36 (2011) 2281-2284.
[40] Nanoscale heterogeneity in alkyl-methylimidazolium bromide ionic liquids
B. Aoun, A. Goldbach, M. Gonzalez, S. Kohara, D. Price, and M.-L. Saboungi,* J. Chem. Phys. 134 (2011) 104509.
[41] Sour water-gas shift reaction over Pt/CeO2 catalysts
B. Liu, A. Goldbach,* H.Y. Xu*, Catal. Today 171 (2011) 304-311.
[42] On alloying and low-temperature stability of thin, supported PdAg membranes
G. Zeng, A. Goldbach,* L. Shi, H. Xu*, Int. J. Hydrogen Energy 37 (2012) 6012-6019.
[43] Compensation Effect in H2 Permeation Kinetics of PdAg Membranes
G. Zeng, A. Goldbach,* L. Shi, H. Xu, J. Phys. Chem. C 116 (2012) 18101.
[44] Hydrogen-induced high-temperature segregation in palladium silver membranes
G. Zeng, H. Jia, A. Goldbach,* L. Zhao, S. Miao, L.Shi, C. Sun, H. Xu,* Phys. Chem. Chem. Phys. 16 (2014) 25330.
[45] Structural and permeation kinetic correlations in PdCuAg membranes
L. Zhao, A. Goldbach,* C. Bao, H. Xu, ACS Appl. Mater. Interfaces, 6 (2014) 22408-22416.
[46] Evaluation of Pd composite membrane for pre-combustion CO2 capture
A. Goldbach,* F. Bao, C. Qi, C. Bao, L. Zhao, C. Hao, C. Jiang, H. Xu,* Int. J. Greenhouse Gas Control 33 (2015) 69-76.
[47] Structure and activity of flame made ceria supported Rh and Pt water gas shift catalysts
G. Cavusoglu, D. Miao, H. Lichtenberg,* H. W. P. Carvalho, H. Xu, A. Goldbach, J.-D. Grunwaldt, Appl. Catal. A, 504 (2015) 381-390.
[48] Sulfur inhibition of PdCu membranes in the presence of concentration polarization
L. Zhao, A. Goldbach,* C. Bao, H. Xu,* J. Membr. Sci. 496 (2015) 301-309.
[49] Platinum/apatite water-gas shift catalysts
D. Miao, A. Goldbach,* H. Xu, ACS Catal. 6 (2016) 775-783.
[50] Tailoring palladium alloy membranes for hydrogen separation from sulfur contaminated gas streams
L. Zhao, A. Goldbach,* H. Xu, J. Membr. Sci. 507 (2016) 55-62.
[51] Flame made ceria supported noble metal catalysts for efficient H2 production via the water gas shift reaction
G. Cavusoglu, H. Lichtenberg, A. Gaur, A. Goldbach, J.-D. Grunwaldt,* J. Phys. Conf. Ser., 712 (2016) 012065.
[52] In situ characterization of catalysts and membranes in a microchannel under high-temperature water gas shift reaction conditions
G. Cavusoglu, F. Dallmann, H. Lichtenberg, A. Goldbach, R. Dittmeyer, J.-D. Grunwaldt,* J. Phys. Conf. Ser., 712 (2016) 012054.
[53] Facile Synthesis of highly active Rh/Al2O3 steam reforming catalysts with preformed support by flame spray pyrolysis
J. Yu, Z. Zhang, F. Dallmann, J. Zhang, D. Miao,H. Xu, A. Goldbach,* R. Dittmeyer,* Appl. Catal. B, 198 (2016) 171-179.
[54] Water-Gas Shift Reaction over Platinum/Strontium Apatite Catalysts
D. Miao, G. Cavusoglu, H. Lichtenberg, J. Yu, H. Xu, J.-D. Grunwaldt, A. Goldbach,* Appl. Catal. B, 202 (2017) 587-596.
[55] Permeation and in situ XRD studies on PdCuAu membranes under H2
H. Jia, A. Goldbach,* C. Zhao, G. R. Castro, C. Sun,* H. Xu, J. Membr. Sci. 529 (2017) 142-149.
[56] Low-temperature stability of body-centered cubic PdCu membranes
C. Zhao, A. Goldbach,* H. Xu, J. Membr. Sci. 542 (2017) 60-67.
[57] High-temperature stability of Pd alloy membranes containing Cu and Au
H. Jia, P. Wu, G. Zeng,* E. Salas Colera, A. Serrano, G. R. Castro, H. Xu, C. Sun, A. Goldbach,* J. Membr. Sci. 544 (2017) 151-160.
[58] Support mass transfer resistance of Pd/ceramic composite membranes in the presence of sweep gas
C. Zhao, A. Caravella,* H. Xu, A. Brunetti, G. Barbieri, A. Goldbach,* J. Membr. Sci. 550 (2018) 365-376.
[59] Duplex Pd/ceramic/Pd composite membrane for sweep gas-enhanced CO2 capture
C. Zhao, H. Xu, A. Goldbach,* J. Membr. Sci. 563 (2018) 388-397.
[60] Efficient H2 production via membrane-assisted ethanol steam reforming over Ir/CeO2 catalyst
H. Jia,* J. Zhang, J. Yu, X. Yang, H. Xu, C. Sun, W. Shen, A. Goldbach,* Int. J. Hydrogen Energy 44 (2019) 24733-24745.
Patents
Collaboration
与相关领域多个国际知名院校和研究团队建立了合作关系,与欧洲同步辐射中心、上海同步辐射中心等也建立了长期的合作关系,参与了两届欧盟项目。
Students
姓 名 | 毕业论文答辩时间 | 学位 | 获奖情况 | 去向 |
袁立详 | 2008.8 | 博士 |
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李 慧 | 2008.8 | 博士 |
| 大连化物所研究员,中科院**** |
曾高峰 | 2009.9 | 博士 |
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史 蕾 | 2010.5 | 博士 |
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刘 冰 | 2011.5 | 博士 |
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赵玲芳 | 2016.5 | 博士 | 三好学生 研究生国家奖学金 优秀毕业生 | 新奥集团 |
苗登云 | 2017.5 | 博士 | 三好学生 延长石油博士生奖学金三等奖 | 大连化物所博士后 |
张 哲 | 2017.5 | 工程硕士 |
| 大连Intel公司 |
贾海园 | 2017.11 | 博士 |
| 齐鲁工业大学 |
赵辰阳 | 2018.04 | 博士 | 三好学生 DICP-Varsal技术创新奖 | 中石化青岛安全工程研究院 |
张青婷 | 在读 | 硕博连读生 |
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杨贺 | 在读 | 博士生 |
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