General
李杲 男 汉族 大连化学物理研究所
Email: gaoli@dicp.ac.cn
Telephone: 041182463017
Address: 大连市中山路457号
Postcode:

Research Areas

Preparation and Catalytic Applications of Metal Nanoclusters (Au, Pd, Pt, Ag, Ni, etc).


Education

 2005–2011: Ph.D. Applied Chemistry, Shanghai Jiaotong University (SJTU), China.

  2000 – 2004: B.S. Chemistry, Hunan Normal University (HNU), China.


Experience

   
Work Experience

2015–present: Professor, State Key Laboratory of Catalysis (SKLC), Dalian Institute of Chemical Physics (DICP), China.

2014–2015: Associated Professor, SKLC, China.

2011–2014: Research Associate, Advisor: Prof. Rongchao Jin, Carnegie Mellon University, USA. 


Honors & Distinctions



Publications

1.      Y. Zhang, X. Yang, Y. Zhou, G. Li,* Z. Li, C. Liu, M. Bao,* W. Shen,* Selective Hydrogenation of C=C bond in a, β–Unsaturated Aldehydes and Ketones over Pd-Au Clusters of 1.8 nm. Nanoscale, 2016, 8, 18626–18629. DOI: 10.1039/C6NR07013B.

2.      Z. Li, H.  Abroshanc, C. Liu, G. Li, A Critical Review on the Catalytic Applications of Non-Metallic Gold Nanoclusters: Selective Oxidation, Hydrogenation, and Coupling Reactions. Curr. Org. Chem. 2016,  (invited review).

3.      Zhimin Li, Xiujuan Yang, Chao Liu, Jin Wang, Gao Li*, Effects of Doping in 25-Atom Bimetallic Nanocluster Catalysts for Carbon−Carbon Coupling Reaction of Iodoanisole and Phenylacetylene. Pro. Nat. Sci.: Mater. Inter. 2016, 26, 477–482. (invited paper)

4.      Chunyang Yan, Chao Liu*, Hadi Abroshan, Zhimin Li, Renhua Qiu*, Gao Li*, Surface Modification of Adamantane-Terminated Gold Nanoclusters Using Cyclodextrins. Phy. Chem. Chem. Phy. 2016, 18, 23358–23364.

5.      Gao Li*, Hadi Abroshan, Chong Liu, Shuo Zhuo, Zhimin Li, Yan Xie, Hyung J. Kim, Nathaniel L. Rosi, Rongchao Jin*, Tailoring the Electronic and Catalytic Properties of Au25 Nanoclusters via Ligand Engineering. ACS Nano 2016, 10, 7998–8005.

6.      Haijun Chen,    Chao Liu, Min Wang, Chaofeng Zhang, Gao Li*, Feng Wang*, Thermally robust silica-enclosed Au25 nanocluster and its catalysis. Chin. J. Catal. 2016, 37, 1787–1793. (invited paper)

7.      Y. Chen, C. Liu, H. Abroshan, J. Wang, Z. Li, G. Li*, M. Haruta, Phosphine/Phenylacetylide-Ligated Au Cluster for Multicomponent Coupling Reaction. J. Catal. 2016, 337, 287–294.

8.      Weili Li, Chao Liu, Hadi Abroshan, Qingjie Ge*, Xiujuan Yang, Hengyong Xu, Gao Li*, Catalytic CO Oxidation Using Bimetallic MxAu25-x Clusters: A Combined Experimental and Computational Study on Doping Effects. J. Phys. Chem. C 2016, 120, 10261−10267.

9.      Yongdong Chen, Jin Wang, Chao Liu, Zhimin Li, Gao Li*, Kinetically controlled synthesis of Au­102(SPh)44 nanoclusters and catalytic application. Nanoscale 2016, 8, 10059–10065. Cover paper.

10.    Hadi Abroshan, Gao Li, Jizhi Lin, Hyung J. Kim, Rongchao Jin*, Molecular mechanism on the activation of Au25(SCH2CH2Ph)18 nanoclusters by imidazolium-based ionic liquids for catalysis. J. Catal. 2016, 337, 72–79.

11.   Chao Liu, Hadi Abroshan, Chunyang Yan, Gao Li*, Masatake Haruta, One-pot synthesis of Au11(PPh2Py)7Br3 for the highly chemoselective hydrogenation of nitrobenzadehyde. ACS Catal. 2016, 6, 9299. Highlighted by “http://www.x-mol.com/news/1710”.

12.   Jizhi Lin, H. Abroshan, Chao Liu, Manzhou Zhu, Gao Li*, M. Haruta, Sonogashira cross-coupling on the Au(111) and Au(100) facets of gold nanorod catalysts: Experimental and computational investigation. J. Catal. 2015, 330, 354–361.

13.   Chao Liu, Jizhi Lin, Yangwei Shi, Gao Li*, Efficient synthesis of Au99(SPh)42 nanoclusters. Nanoscale 2015, 7, 59875990.

14.   Jizhi Lin, Weili Li, Chao Liu, Pan Huang, Manzhou Zhu, Qingjie Ge, Gao Li*, One-phase controlled synthesis of Au25 nanospheres and nanorods from 1.3 nm Au:PPh3 nanoparticles: the ligand effects. Nanoscale 2015, 7, 1366313670.

15.   Chao Liu, Chunyang Yan, Jizhi Lin, Changlin Yu, Jiahui huang, and Gao Li*, One-Pot Synthesis of Au144(SCH2Ph)60 Nanoclusters and Catalytic Application. J. Mater. Chem. A 2015, 3, 2016720173. Selected as Hot Paper.

16.   Gao Li, Hadi Abroshan, Yuxiang Chen, Rongchao Jin*, Hyung J. Kim*, Experimental and mechanistic understanding of aldehyde hydrogenation using Au25 nanoclusters with lewis-acids: Unique sites for catalytic reactions. J. Am. Chem. Soc. 2015, 137, 14295–14304.

17.    Gao Li, Rongchao Jin*, Atomic level tuning of the catalytic properties: Doping effects of 25-atom bimetallic nanoclusters on styrene oxidation. Catal. Today 2016, DOI: 10.1016/j.cattod.2015.11.019.


Students

现指导学生

周洋  硕士研究生  070304-物理化学  

付雪梅  硕士研究生  070304-物理化学  

郑凯  博士研究生  070304-物理化学