基本信息
樊红军  男  博导  中国科学院大连化学物理研究所
电子邮件: fanhj@dicp.ac.cn
通信地址: 大连市中山路457号
邮政编码: 116023

研究领域

研究方向
1. 表面和均相催化反应的反应机理
2. 光催化及人工模拟光合作用
3. 团簇和金属有机化合物的结构与化学性质。
4. 自由基反应

研究手段:
理论和计算化学

招生信息

招收博士生1名。专业:物理化学。研究方向:理论和计算化学。

招生专业
070304-物理化学
招生方向
理论和计算化学
表面和团簇化学
金属有机化学

教育背景

2000-09--2004-09   University of Siegen, Germany   博士
1994-09--1997-07   中科院福建物质结构研究所   硕士
1990-09--1994-07   浙江大学   学士
学历

研究生

学位
博士
出国学习工作
2000年赴德国齐根大学(University of Siegen)学习并于2004年获博士学位,其后在德国哥廷根大学(University of Goettingen)从事访问学者研究。2005-2009年在美国印第安纳大学(Indiana University Bloomingtin)从事博士后研究。

工作经历

1997.7-2000.8中科院福建物质结构研究所,研究助理
2004.10-2005.3 University of Goettingen,访问学者
2005.4-2009.1 Indiana University Bloomingtin,博士后,research associate
工作简历
2009-02~现在, 中科院大连化学物理研究所, 研究员
2005-04~2009-01,Indiana University Bloomington, USA, 博士后
2004-10~2005-03,University of Goettingen, 访问学者
1997-07~2000-08,中科院福建物质结构研究所, 研究助理

出版信息

   
代表性论文
[1] Yahui Wang, Qihuang Huo, Hongjun Fan, Jiancheng Wang, Liping Chang. A theoretical study on structures of neutral (CuS)n (n=1–10) clusters and their interaction with Hg0. Fuel. 2022, 321: [2] 樊红军, 江陵. Ligand-Induced Tuning of the Electronic Structure of Rhombus Tetraboron Cluster. ChemPhysChem[J]. 2022, [3] 樊红军, 郭庆. Hydrogen Production on Pt/TiO2: Synergistic Catalysis between Pt Clusters and Interfacial Adsorbates. J. Phys. Chem. Lett.[J]. 2022, 13(14): 3182-3187, [4] 王彬力, 樊红军. Photocatalytic Activity and Hole-Scavenging Behaviors on Rutile TiO2(100) Surfaces: A Theoretical Study. J. Phys. Chem. C[J]. 2022, 126(2): 974-985, [5] Wang, Yahui, Huo, Qihuang, Fan, Hongjun, Wang, Jiancheng, Chang, Liping. Formation of Polysulfides from Consolidation of Cu Vacancies on CuS (001) Surfaces. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2021, 125(21): 11325-11335, [6] Wang, Kai, Wang, Binli, Liu, Xianghui, Fan, Hongjun, Liu, Yan, Li, Can. Palladium-catalyzed enantioselective linear allylic alkylation of vinyl benzoxazinanones: An inner-sphere mechanism. CHINESE JOURNAL OF CATALYSIS[J]. 2021, 42(7): 1227-1237, http://dx.doi.org/10.1016/S1872-2067(20)63751-2.
[7] Huang, Tingyu, Xu, Zhanwei, Yan, Peifang, Liu, Xiumei, Fan, Hongjun, Zhang, Z Conrad. Direct Partial Oxidation of Methane Catalyzed by an In Situ Generated Active Au(III) Complex at Low Temperature in Ionic Liquids. ORGANOMETALLICS[J]. 2021, 40(3): 370-382, https://www.webofscience.com/wos/woscc/full-record/WOS:000618663800010.
[8] 樊红军. Low-Temperature Aldol Condensation of Aldehydes on R‑TiO2(100)- (1 × 1): Exceptional Selectivity for α,β-Unsaturated Enal Production. J. Phys. Chem. Lett.. 2021, [9] 樊红军. Spectroscopic Identification of Transition-Metal M[η2‑(O,O)C] Species for Highly-Efficient CO2 Activation. J. Phys. Chem. Lett.. 2021, [10] Liu Tingting, Wu Kaikai, Wang Liandi, Fan Hongjun, Zhou YongGui, Yu Zhengkun, 刘婷婷. Assembled Multinuclear Ruthenium(II)-NNNN Complexes: Synthesis, Catalytic Properties, and DFT Calculations. ORGANOMETALLICS[J]. 2020, 39(1): 93-104, https://www.webofscience.com/wos/woscc/full-record/WOS:000507429400015.
[11] 樊红军. Pyrolysis behaviors of coal-related model compounds catalyzed by pyrite, Fuel. Fuel. 2020, [12] Yu, ChangBin, Wang, HengDing, Song, Bo, Shen, HongQiang, Fan, HongJun, Zhou, YongGui. Reversal of diastereoselectivity in palladium-arene interaction directed hydrogenative desymmetrization of 1,3-diketones. SCIENCE CHINA-CHEMISTRY[J]. 2020, 63(2): 215-221, http://lib.cqvip.com/Qikan/Article/Detail?id=7101121170.
[13] Zhou, Yang, Li, Lu, Jin, Lijun, Zhu, Jialong, Li, Jiangang, Li, Yang, Fan, Hongjun, Hu, Haoquan. Effect of functional groups on volatile evolution in coal pyrolysis process with in-situ pyrolysis photoionization time-of-flight mass spectrometry. FUEL[J]. 2020, 260: https://www.webofscience.com/wos/woscc/full-record/WOS:000491885400021.
[14] Wang, HengDing, Fan, HongJun. Silylium ion mediated 2+2 cycloaddition leads to 4+2 Diels-Alder reaction products. COMMUNICATIONS CHEMISTRY[J]. 2020, 3(1): http://dx.doi.org/10.1038/s42004-020-00373-2.
[15] Xu, ZhenZhen, Fan, HongJun. A theoretical investigation on the structures of (NH3)center dot(H2SO4)center dot(H2O)(0-14) clusters. INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY[J]. 2019, 119(7): http://cas-ir.dicp.ac.cn/handle/321008/166014.
[16] Xu, Wei, Fan, Hongjun. Kinetics of reaction RH + O-2 = R + HO2 (RH = normal C1-C14 alkanes): A DFT investigation. FUEL[J]. 2018, 234: 1165-1172, http://cas-ir.dicp.ac.cn/handle/321008/167012.
[17] 樊红军. Synthesis of Chiral Trispirocyclic Oxindoles via Organic-Base/ Au(I)-Catalyzed Sequential Reaction. ACS Catal.. 2018, [18] Li, Gang, Li, Lu, Jin, Lijun, Tang, Zichao, Fan, Hongjun, Hu, Haoquan. Methyl substitution effect in pyrolysis of coal-based model compound isomers. FUEL PROCESSING TECHNOLOGY[J]. 2018, 178: 371-378, http://dx.doi.org/10.1016/j.fuproc.2018.07.020.
[19] Wang, Ruimin, Fan, Hongjun. The location of excess electrons on H2O/TiO2(110) surface and its role in the surface reactions. MOLECULAR PHYSICS[J]. 2018, 116(2): 171-178, http://cas-ir.dicp.ac.cn/handle/321008/168944.
[20] Zhao, Zhi, Kong, Xiangtao, Yuan, Qinqin, Xie, Hua, Yang, Dong, Zhao, Jijun, Fan, Hongjun, Jiang, Ling. Coordination-induced CO2 fixation into carbonate by metal oxides. PHYSICAL CHEMISTRY CHEMICAL PHYSICS[J]. 2018, 20(29): 19314-19320, http://cas-ir.dicp.ac.cn/handle/321008/166806.
[21] Geng, Zhenhua, Jin, Xianchi, Wang, Ruimin, Chen, Xiao, Guo, Qing, Ma, Zhibo, Dai, Dongxu, Fan, Hongjun, Yang, Xueming. Low-Temperature Hydrogen Production via Water Conversion on Pt/TiO2. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2018, 122(20): 10956-10962, https://www.webofscience.com/wos/woscc/full-record/WOS:000433403400031.
[22] Xu, Chenbiao, Wang, Ruimin, Xu, Fei, Guo, Qing, Wang, Xingan, Dai, Dongxu, Fan, Hongjun, Yang, Xueming. Enhanced Hydrogen Production from Methanol Photolysis on a Formate-Modified Rutile-TiO2(110) Surface. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2018, 122(25): 13774-13781, https://www.webofscience.com/wos/woscc/full-record/WOS:000437811500064.
[23] Li, Lu, Fan, Hongjun, Hu, Haoquan. Distribution of hydroxyl group in coal structure: A theoretical investigation. FUEL[J]. 2017, 189: 195-202, http://cas-ir.dicp.ac.cn/handle/321008/169770.
[24] 樊红军. The Mechanism of H2 and H2O Desorption from Bridging Hydroxyls of TiO2(110) surface. Cat. Sci. & Tech.. 2017, [25] Li, Liuyi, Li, Lu, Cui, Caiyan, Fan, Hongjun, Wang, Ruihu. Heteroatom-doped Carbon Spheres from Hierarchical Hollow Covalent Organic Framework Precursors for Metal-Free Catalysis. CHEMSUSCHEM[J]. 2017, 10(24): 4921-4926, http://cas-ir.dicp.ac.cn/handle/321008/168424.
[26] Liu, Zhiling, Xie, Hua, Zou, Jinghan, Fan, Hongjun, Tang, Zichao. Observation of promoted C-O bond weakening on the heterometallic nickel-silver: Photoelectron velocity-map imaging spectroscopy of AgNi(CO)n(-). JOURNAL OF CHEMICAL PHYSICS[J]. 2017, 146(24): https://www.webofscience.com/wos/woscc/full-record/WOS:000411113300015.
[27] Yang, Wenshao, Wei, Dong, Jin, Xianchi, Xu, Chenbiao, Geng, Zhenhua, Guo, Qing, Ma, Zhibo, Dai, Dongxu, Fan, Hongjun, Yang, Xueming. Effect of the Hydrogen Bond in Photoinduced Water Dissociation: A Double-Edged Sword. JOURNAL OF PHYSICAL CHEMISTRY LETTERS[J]. 2016, 7(4): 603-608, http://cas-ir.dicp.ac.cn/handle/321008/148389.
[28] Bian, Guangling, Yang, Shiwei, Huang, Huayin, Zong, Hua, Song, Ling, Fan, Hongjun, Sun, Xiaoqiang. Chirality sensing of tertiary alcohols by a novel strong hydrogen-bonding donor - selenourea. CHEMICAL SCIENCE[J]. 2016, 7(2): 932-938, http://cas-ir.dicp.ac.cn/handle/321008/148395.
[29] Guo Qing Zhou Chuanyao Ma Zhibo Ren Zefeng Fan Hongjun Yang Xueming. Elementary photocatalytic chemistry on TiO2 surfaces. 2016, 45(13): 3701-3730, [30] YingDuan, 李璐, MuWangChen, 余长斌, 樊红军, 周永贵. Homogenous Pd-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles: Scope and Mechanistic Studies(合作). Journal of the American Chemical Society[J]. 2014, 136(21): 7688-, http://cas-ir.dicp.ac.cn/handle/321008/143891.
[31] Guo, Xiaoguang, Fang, Guangzong, Li, Gang, Ma, Hao, Fan, Hongjun, Yu, Liang, Ma, Chao, Wu, Xing, Deng, Dehui, Wei, Mingming, Tan, Dali, Si, Rui, Zhang, Shuo, Li, Jianqi, Sun, Litao, Tang, Zichao, Pan, Xiulian, Bao, Xinhe. Direct, Nonoxidative Conversion of Methane to Ethylene, Aromatics, and Hydrogen. SCIENCE[J]. 2014, 344(6184): 616-619, http://ir.iphy.ac.cn/handle/311004/59658.
[32] Fan Hongjun, Alison R Fout, Brad C Bailey, Maren Pink, MuHyun Baik, Daniel J Mindiola. Understanding intermolecular C–F bond activation by a transient titanium neopentylidyne: experimental and theoretical studies on the competition between 1,2-CF bond addition and 2 + 2-cycloadditionβ-fluoride elimination. Dalton Transactions[J]. 2013, 42(12): 4163-, http://159.226.238.44/handle/321008/119441.
[33] Guo, Qing, Xu, Chenbiao, Yang, Wenshao, Ma, Zhibo, Dai, Dongxu, Minton, Timothy K, Fan, Hongjun, Yang, Xueming. Stepwise photocatalytic dissociation of methanol and water on TiO2(110). ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETYnull. 2012, 243: https://www.webofscience.com/wos/woscc/full-record/WOS:000324503203508.
[34] 樊红军. Three-coordinate NiII: tracing the origin of an unusual, facile Si-C(sp3) bond cleavage in [(tBu2PCH2SiMe2)2N]Ni+. J. Am. Chem. Soc. 2011, [35] Wang, DuoSheng, Ye, ZhiShi, Chen, QingAn, Zhou, YongGui, Yu, ChangBin, Fan, HongJun, Duan, Ying. Highly Enantioselective Partial Hydrogenation of Simple Pyrroles: A Facile Access to Chiral 1-Pyrrolines. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2011, 133(23): 8866-8869, http://dx.doi.org/10.1021/ja203190t.
[36] Chen QingAn, Wang DuoSheng, Zhou YongGui, Duan Ying, Fan HongJun, Yang Yan, Zhang Zhang. Convergent asymmetric disproportionation reactions: metal/Brønsted acid relay catalysis for enantioselective reduction of quinoxalines.. Journal of the American Chemical Society. 2011, http://kns.cnki.net/KCMS/detail/detail.aspx?QueryID=0&CurRec=1&recid=&FileName=SJPD12102000276438&DbName=SJPD_01&DbCode=SJPD&yx=&pr=&URLID=&bsm=.
[37] Zhou, Chuanyao, Ren, Zefeng, Tan, Shijing, Ma, Zhibo, Mao, Xinchun, Dai, Dongxu, Fan, Hongjun, Yang, Xueming, LaRue, Jerry, Cooper, Russell, Wodtke, Alec M, Wang, Zhuo, Li, Zhenyu, Wang, Bing, Yang, Jinlong, Hou, Jianguo. Site-specific photocatalytic splitting of methanol on TiO2(110). CHEMICAL SCIENCE[J]. 2010, 1(5): 575-580, http://159.226.238.44/handle/321008/141924.
[38] Wu, Xia, Qin, Zhengbo, Xie, Hua, Cong, Ran, Wu, Xiaohu, Tang, Zichao, Fan, Hongjun. Photoelectron Imaging and Theoretical Studies of Group 11 Cyanides MCN (M = Cu, Ag, Au). JOURNAL OF PHYSICAL CHEMISTRY A[J]. 2010, 114(49): 12839-12844, http://159.226.238.44/handle/321008/141952.

科研活动

   
科研项目
( 1 ) 择优基金, 主持, 部委级, 2011-01--2013-12
( 2 ) 973项目"中低阶煤分级转化联产低碳燃料和化学品的基础研究", 参与, 国家级, 2011-01--2014-12
( 3 ) 大连化学物理研究所计划, 主持, 市地级, 2009-01--2012-12
( 4 ) 自然科学基金面上项目“二氧化钛表面醇类等小分子的光解机理研究", 主持, 国家级, 2012-01--2015-12
( 5 ) 多孔催化材料:合成、电子化学和表面催化, 参与, 国家级, 2013-01--2017-12
( 6 ) 甲烷无氧直接制乙烯和芳烃及其机理研究, 主持, 市地级, 2014-12--2017-11
( 7 ) 二氧化钛表面脱氢机理的理论研究, 主持, 国家级, 2017-01--2020-12
( 8 ) 煤及显微组分中弱键合结构表征以及集总结构模型的构建, 主持, 国家级, 2016-07--2021-06
( 9 ) 能源化学转化的本质与调控, 参与, 部委级, 2016-01--2020-12
( 10 ) 黑色二氧化钛纳米材料的结构和产氢机制的理论研究, 主持, 国家级, 2019-01--2022-12
( 11 ) 电-热-催化耦合甲烷直接转化应用基础研究, 主持, 部委级, 2018-10--2020-09
( 12 ) 人工模拟光合作用Mn4CaO5-团簇结构与反应机理的理论研究, 主持, 国家级, 2021-01--2023-12

指导学生

已指导学生

王锐敏  博士研究生  070304-物理化学  

现指导学生

王彬力  博士研究生  070304-物理化学  

林浩  博士研究生  070304-物理化学