生物基热固性树脂的设计合成及功能化研究；生物基热固化和UV光固化涂料设计与制备；生物基高性能苯并恶嗪树脂的设计与制备

   

070305-高分子化学与物理

生物基环氧树脂，生物基苯并恶嗪，可降解热固性树脂、可重塑热固性树脂

2015-07--2018-06   中国科学院宁波材料技术与工程研究所   博士研究生
2012-07--2015-06   河北大学   硕士研究生
2006-09--2009-07   河北石油职业技术大学   学生

   

2021-01~现在, 中国科学院宁波材料技术与工程研究所, 副研究员
2017-07~2020-12,中国科学院宁波材料技术与工程研究所, 博士后/助理研究员
2009-08~2012-06,巴陵石化环氧树脂事业部, 技术工人

   

[1] 代金月, 王帅朋, 刘小青, 朱锦. 一种基于有机多元酸的光固化树脂及其制备方法与应用. CN: CN111978444B, 2022-03-08.

[2] 代金月, 刘小青, 腾娜. 生物基A2+B3型超支化环氧树脂前驱体、改性组合物、其制备方法与应用. CN: CN112851911A, 2021-05-28.

[3] 代金月, 刘小青, 腾娜. A3+B2型超支化环氧树脂前驱体、改性组合物、其制备方法与应用. CN: CN112851912A, 2021-05-28.

[4] 刘小青, 代金月, 腾娜, 彭云燕. 一种基于天然黄酮类化合物的生物基本征阻燃环氧树脂前驱体及其制备方法和应用. CN: CN110922394B, 2021-04-06.

[5] 刘小青, 刘敬楷, 代金月, 王静刚. 无卤阻燃环氧树脂前驱体、模塑料制品、其制法和应用. CN: CN111777744B, 2020-12-11.

[6] 刘小青, 代金月, 腾娜. 无卤阻燃型不饱和聚酯组合物、聚酯制品、其制法与应用. CN: CN111777642B, 2020-12-11.

[7] 刘小青, 江艳华, 腾娜, 代金月. 含磷化合物、环氧树脂组合物、模塑料制品、制法及应用. CN: CN111777641B, 2020-12-11.

[8] 刘小青, 代金月, 腾娜, 刘敬楷. 无卤阻燃型环氧树脂组合物、模塑料制品、其制法与应用. CN: CN111777746B, 2020-12-11.

[9] 刘小青, 代金月, 腾娜. 无卤阻燃型丙烯酸树脂组合物、模塑料制品、制法与应用. CN: CN111808233B, 2020-12-11.

[10] 刘小青, 代金月, 刘敬楷. 无卤阻燃环氧树脂前驱体、组合物、模塑料制品、制法及应用. CN: CN111793091A, 2020-10-20.

[11] 代金月, 腾娜, 王帅朋, 刘小青. 一种基于大豆苷元的生物基主链型苯并噁嗪树脂及其制备方法和应用. CN: CN110894274A, 2020-03-20.

[12] 王静刚, 刘小青, 慎昂, 张小琴, 代金月, 江艳华, 朱锦. 呋喃基共聚酯及其制备方法. CN: CN110591064A, 2019-12-20.

[13] 慎昂, 王静刚, 刘小青, 张小琴, 孙藜源, 代金月, 朱锦. 含酰亚胺结构的共聚酯及其制备方法. CN: CN110229320A, 2019-09-13.

[14] 王静刚, 刘小青, 慎昂, 张小琴, 代金月, 江艳华, 朱锦. 呋喃基共聚酯及其制备方法. CN: CN109810247A, 2019-05-28.

[15] 张小琴, 王静刚, 刘小青, 孙藜源, 代金月, 江艳华, 朱锦. 呋喃二甲酸共聚酯及其制备方法. CN: CN109810248A, 2019-05-28.

[16] 代金月, 腾娜, 刘小青, 王静刚, 朱锦. 一种基于天然酚类单体的生物基阻燃环氧树脂前驱体及其制备方法和应用. CN: CN109734684A, 2019-05-10.

[17] 王静刚, 刘小青, 张小琴, 孙藜源, 代金月, 朱锦. 呋喃二甲酸共聚酯及其制备方法. CN: CN109721716A, 2019-05-07.

[18] 刘敬楷, 代金月, 刘小青, 朱锦, 王静刚, 王帅朋. 一种无卤阻燃生物基环氧树脂前驱体及其制备方法和应用. CN: CN109651595A, 2019-04-19.

[19] 代金月, 刘小青, 腾娜, 朱锦. 一种含环状酰胺结构的生物基环氧树脂前驱体及其制备方法和应用. CN: CN109384775A, 2019-02-26.

[20] 代金月, 刘小青, 腾娜, 朱锦. 基于天然氨基酸的生物基环氧树脂及其制备方法和应用. CN: CN109384748A, 2019-02-26.

[21] 池得权, 刘斐, 代金月, 翟承凯, 那海宁, 朱锦. 一种热塑性聚酯弹性体及其制备方法. CN: CN109134835A, 2019-01-04.

[22] 代金月, 腾娜, 彭云燕, 刘小青, 朱锦. 一种基于天然异黄酮化合物的生物基阻燃环氧树脂前驱体及其制备方法和应用. CN: CN108559061A, 2018-09-21.

[23] 代金月, 刘小青, 彭云燕, 腾娜, 朱锦. 一种基于厚朴衍生物的苯并恶嗪树脂单体及其制备方法和应用. CN: CN108484519A, 2018-09-04.

[24] 代金月, 刘小青, 腾娜, 彭云燕, 朱锦. 一种基于大豆衍生物的生物基苯并恶嗪前驱体及其制备方法和应用. CN: CN108440561A, 2018-08-24.

[25] 代金月, 刘小青, 腾娜, 池得权, 朱锦. 一种含有苯并恶嗪结构的呋喃二甲酸聚酯及其制备方法和应用. CN: CN107573496A, 2018-01-12.

[26] 代金月, 刘小青, 马松琪, 腾娜, 沈潇斌, 江艳华, 朱锦. 一种基于丁香酚的有机硅苯并恶嗪树脂预聚物及其制备方法和应用. CN: CN107417870A, 2017-12-01.

[27] 王胜, 马松琪, 代金月, 沈潇斌, 韦静静, 刘小青, 朱锦. 一种基于席夫碱结构的生物基丙烯酸酯及其制备方法和应用. CN: CN106916083A, 2017-07-04.

[28] 沈潇斌, 代金月, 刘小青, 朱锦. 一种呋喃基二胺型苯并噁嗪树脂及其制备方法和应用. CN: CN106674214A, 2017-05-17.

[29] 代金月, 刘小青, 马松琪, 腾娜, 江艳华, 朱丽霞, 朱锦. 一种基于丁香酚的UV光学树脂单体及其制备方法和应用. CN: CN106631942A, 2017-05-10.

[30] 王静刚, 代金月, 刘小青, 张若愚, 朱锦. 一种生物基不饱和聚酯及其制备方法和应用. CN: CN106432701A, 2017-02-22.

[31] 王胜, 马松琪, 代金月, 沈潇斌, 李鹏, 刘小青, 朱锦. 三种基于呋喃环结构的生物基环氧树脂及其制备方法和应用. CN: CN105949438A, 2016-09-21.

[32] 代金月, 刘小青, 马松琪, 朱锦, 王静刚, 沈潇斌, 腾娜. 一种基于丁香酚的多官能团不饱和单体、制备方法及其应用. CN: CN105503674A, 2016-04-20.

   

[1] Lu, Guangming, Wang, Xuezhen, Teng, Na, Hu, Jingyuan, Zhang, Liyue, Dai, Jinyue, Xu, Yongjia, Mahmud, Sakil, Liu, Xiaoqing. Bio-based Epoxy Thermoset Containing Stilbene Structure with Ultrahigh T-g and Excellent Flame Retardancy. POLYMER-KOREA[J]. 2021, 45(4): 581-591, http://dx.doi.org/10.7317/pk.2021.45.4.581.

[2] Hu, Jingyuan, Wang, Chunhong, Dai, Jinyue, Teng, Na, Wang, Shuaipeng, Zhang, Liyue, Jiang, Yaming, Liu, Xiaoqing. Epoxy resin with excellent ultraviolet resistance and mechanical properties derived from renewable camphoric acid. POLYMERS FOR ADVANCED TECHNOLOGIES[J]. 2021, 32(9): 3701-3713, http://dx.doi.org/10.1002/pat.5390.

[3] Wang, Shuaipeng, Dai, Jinyue, Teng, Na, Hu, Jingyuan, Zhao, Weiwei, Liu, Xiaoqing. Synthesis of Mechanically Robust and Self-Healing UV-Curable Materials from Renewable Feedstock. ACS SUSTAINABLE CHEMISTRY & ENGINEERING[J]. 2020, 8(45): 16842-16852, https://www.webofscience.com/wos/woscc/full-record/WOS:000592788800013.

[4] Wang, Shuaipeng, Teng, Na, Dai, Jinyue, Liu, Jingkai, Cao, Lijun, Zhao, Weiwei, Liu, Xiaoqing. Taking advantages of intramolecular hydrogen bonding to prepare mechanically robust and catalyst-free vitrimer. POLYMER[J]. 2020, 210: http://dx.doi.org/10.1016/j.polymer.2020.123004.

[5] Liu, Jingkai, Dai, Jinyue, Wang, Shuaipeng, Peng, Yunyan, Cao, Lijun, Liu, Xiaoqing. Facile synthesis of bio-based reactive flame retardant from vanillin and guaiacol for epoxy resin. COMPOSITES PART B-ENGINEERING[J]. 2020, 190: http://dx.doi.org/10.1016/j.compositesb.2020.107926.

[6] Wang, Shuaipeng, Wu, Yonggang, Dai, Jinyue, Teng, Na, Peng, Yunyan, Cao, Lijun, Liu, Xiaoqing. Making organic coatings greener: Renewable resource, solvent-free synthesis, UV curing and repairability. EUROPEAN POLYMER JOURNAL[J]. 2020, 123: http://dx.doi.org/10.1016/j.eurpolymj.2019.109439.

[7] Mahmud, Sakil, Long, Yu, Wang, Jinggang, Dai, Jinyue, Zhang, Ruoyu, Zhu, Jin. Waste Cellulose Fibers Reinforced Polylactide Toughened by Direct Blending of Epoxidized Soybean Oil. FIBERS AND POLYMERS[J]. 2020, 21(12): 2949-2961, https://www.webofscience.com/wos/woscc/full-record/WOS:000602558200024.

[8] Peng, Yunyan, Liu, Yuan, Dai, Jinyue, Cao, Lijun, Liu, Xiaoqing. A sustainable strategy for remediation of oily sewage: Clean and safe. SEPARATION AND PURIFICATION TECHNOLOGY[J]. 2020, 240: http://dx.doi.org/10.1016/j.seppur.2020.116592.

[9] Teng, Na, Yang, Shimin, Dai, Jinyue, Wang, Shuaipeng, Zhao, Jun, Zhu, Jin, Liu, Xiaoqing. Making Benzoxazine Greener and Stronger: Renewable Resource, Microwave Irradiation, Green Solvent, and Excellent Thermal Properties. ACS SUSTAINABLE CHEMISTRY & ENGINEERING[J]. 2019, 7(9): 8715-8723, https://www.webofscience.com/wos/woscc/full-record/WOS:000467351200075.

[10] Liu, Yuan, Cao, Lijun, Luo, Jun, Peng, Yunyan, Ji, Qing, Dai, Jinyue, Zhu, Jin, Liu, Xiaoqing. Biobased Nitrogen- and Oxygen-Codoped Carbon Materials for High-Performance Supercapacitor. ACS SUSTAINABLE CHEMISTRY & ENGINEERING[J]. 2019, 7(2): 2763-+, https://www.webofscience.com/wos/woscc/full-record/WOS:000456631800102.

[11] Jinyue Dai, Na Teng, Jingkai Liu, Jianxiang Feng, Jin Zhu, Xiaoqing Liu. Synthesis of bio-based fire-resistant epoxy without addition of flame retardant elements. Composites Part B. 2019, 179: http://dx.doi.org/10.1016/j.compositesb.2019.107523.

[12] Dai, Jinyue, Teng, Na, Liu, Jingkai, Feng, Jianxiang, Zhu, Jin, Liu, Xiaoqing. Synthesis of bio-based fire-resistant epoxy without addition of flame retardant elements. COMPOSITES PART B-ENGINEERING[J]. 2019, 179: http://dx.doi.org/10.1016/j.compositesb.2019.107523.

[13] Peng, Yunyon, Dai, Jinyue, Liu, Yuan, Cao, Lijun, Zhu, Jin, Liu, Xiaoqing. Bio-Based Polybenzoxazine Modified Melamine Sponges for Selective Absorption of Organic Solvent in Water. ADVANCED SUSTAINABLE SYSTEMS[J]. 2019, 3(3): 
[14] Liu, Jingkai, Cao, Lijun, Dai, Jinyue, Xia, Dasha, Peng, Yunyan, Wang, Shuaipeng, Liu, Yuan, Liu, Xiaoqing. Regulating the performance of polybenzoxazine via the regiochemistry of amide substituents. POLYMER[J]. 2019, 181: http://dx.doi.org/10.1016/j.polymer.2019.121807.

[15] Dai, Jinyue, Peng, Yunyan, Teng, Na, Liu, Yuan, Liu, Chuanchuan, Shen, Xiaobin, Mahmud, Sakil, Zhu, Jin, Liu, Xiaoqing. High-Performing and Fire-Resistant Biobased Epoxy Resin from Renewable Sources. ACS SUSTAINABLE CHEMISTRY & ENGINEERING[J]. 2018, 6(6): 7589-7599, http://ir.nimte.ac.cn/handle/174433/17449.

[16] 朱丽霞, 代金月, 陈来, 王玉彬, 朱锦, 那海宁. 基于双咪唑离子介质制备高抗菌性聚氨酯的研究. 化工新型材料[J]. 2018, 46(3): 111-114, http://lib.cqvip.com/Qikan/Article/Detail?id=674924714.

[17] Shen, Xiaobin, Cao, Lijun, Liu, Yuan, Dai, Jinyue, Liu, Xiaoqing, Zhu, Jin, Du, Shiyu. How Does the Hydrogen Bonding Interaction Influence the Properties of Polybenzoxazine? An Experimental Study Combined with Computer Simulation. MACROMOLECULES[J]. 2018, 51(13): 4782-4799, http://ir.nimte.ac.cn/handle/174433/17322.

[18] Dai, Jinyue, Yang, Shimin, Teng, Na, Liu, Yuan, Liu, Xiaoqing, Zhu, Jin, Zhao, Jun. Synthesis of Eugenol-Based Silicon-Containing Benzoxazines and Their Applications as Bio-Based Organic Coatings. COATINGS[J]. 2018, 8(3): http://ir.nimte.ac.cn/handle/174433/16767.

[19] Dai, Jinyue, Teng, Na, Peng, Yunyan, Liu, Yuan, Cao, Lijun, Zhu, Jin, Liu, Xiaoqing. Biobased Benzoxazine Derived from Daidzein and Furfurylamine: Microwave-Assisted Synthesis and Thermal Properties Investigation. CHEMSUSCHEM[J]. 2018, 11(18): 3175-3183, http://dx.doi.org/10.1002/cssc.201801404.

[20] Dai, Jinyue, Teng, Na, Shen, Xiaobin, Liu, Yuan, Cao, Lijun, Zhu, Jin, Liu, Xiaoqing. Synthesis of Biobased Benzoxazines Suitable for Vacuum-Assisted Resin Transfer Molding Process via Introduction of Soft Silicon Segment. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH[J]. 2018, 57(8): 3091-3102, http://ir.nimte.ac.cn/handle/174433/16794.

[21] Liu, Yuan, Li, Chao, Dai, JinYue, Jiang, YanHua, Liu, XiaoQing, Zhu, Jin. Synthesis of multifunctional monomers from rosin for the properties enhancement of soybean-oil based thermosets. SCIENCE CHINA-TECHNOLOGICAL SCIENCES[J]. 2017, 60(9): 1332-1338, http://ir.nimte.ac.cn/handle/174433/13655.

[22] Dai, Jinyue, Ma, Songqi, Zhu, Lixia, Wang, Sheng, Yang, Lijing, Song, Zhenlun, Liu, Xiaoqing, Zhu, Jin. UV-thermal dual cured anti-bacterial thiol-ene networks with superior performance from renewable resources. POLYMER[J]. 2017, 108: 215-222, http://dx.doi.org/10.1016/j.polymer.2016.11.068.

[23] Wang, Sheng, Ma, Songqi, Xu, Chenxiang, Liu, Yuan, Dai, Jinyue, Wang, Zongbao, Liu, Xiaoqing, Chen, Jing, Shen, Xiaobin, Wei, Jingjing, Zhu, Jin. Vanillin-Derived High-Performance Flame Retardant Epoxy Resins: Facile Synthesis and Properties. MACROMOLECULES[J]. 2017, 50(5): 1892-1901, http://ir.nimte.ac.cn/handle/174433/13941.

[24] Shen, Xiaobin, Liu, Xiaoqing, Dai, Jinyue, Liu, Yuan, Zhang, Yajie, Zhu, Jin. How Does the Hydrogen Bonding Interaction Influence the Properties of Furan-Based Epoxy Resins. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH[J]. 2017, 56(38): 10929-10938, http://ir.nimte.ac.cn/handle/174433/13607.

[25] 代金月, 朱锦, 刘小青, 刘渊, 沈潇斌. 聚苯并恶嗪树脂中的电子效应研究. 2017, 1-, http://ir.nimte.ac.cn/handle/174433/16661.

[26] Liu Yuan, Dai Jinyue, Wang Sheng, Luo Jun, Shen Xiaobin, Sun Liyuan, Jiang Yanhua, Wang Jinggang, Liu, Chunyan, Liu Xiaoqing, Zhu Jin. Eugenol-based Organic Silicone Epoxy Resin and Its Curing Kinetics. JOURNAL OF POLYMER MATERIALS[J]. 2017, 34(3): 565-578, http://ir.nimte.ac.cn/handle/174433/17506.

[27] Liu, Yuan, Dai, Jinyue, Liu, Xiaoqing, Luo, Jun, You, Shusen, Zhu, Jin, Ma, Songqi, Jia, Zhen. Bio-Based Epoxy Resins Derived From Eugenol With Low Dielectric Constant. JOURNAL OF ELECTRONIC PACKAGING[J]. 2017, 139(3): http://ir.nimte.ac.cn/handle/174433/13663.

[28] 沈潇斌, 朱锦, 刘小青, 刘渊, 腾娜, 代金月. 含硅柔性苯并恶嗪树脂制备与性能研究. 2017, 1-, http://ir.nimte.ac.cn/handle/174433/16653.

[29] Shen, Xiaobin, Liu, Xiaoqing, Wang, Jinggang, Dai, Jinyue, Zhu, Jin. Synthesis of an Epoxy Monomer from Bio-Based 2,5-Furandimethanol and Its Toughening via Diels-Alder Reaction. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH[J]. 2017, 56(30): 8508-8516, http://ir.nimte.ac.cn/handle/174433/13691.

[30] Shen, Xiaobin, Dai, Jinyue, Liu, Yuan, Liu, Xiaoqing, Zhu, Jin. Synthesis of high performance polybenzoxazine networks from bio-based furfurylamine: Furan vs benzene ring. POLYMER[J]. 2017, 122: 258-269, http://dx.doi.org/10.1016/j.polymer.2017.06.075.

[31] Dai, Jinyue, Ma, Songqi, Teng, Na, Dai, Xinyan, Shen, Xiaobin, Wang, Sheng, Liu, Xiaoqing, Zhu, Jin. 2,5-Furandicarboxylic Acid- and Itaconic Acid-Derived Fully Biobased Unsaturated Polyesters and Their Cross-Linked Networks. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH[J]. 2017, 56(10): 2650-2657, http://ir.nimte.ac.cn/handle/174433/13937.

[32] 代金月, 马松琪, 刘小青, 江艳华, 朱锦. 一种含丙烯酸酯类双键有机磷阻燃剂的制备与表征. 塑料助剂[J]. 2016, 39-41, http://lib.cqvip.com/Qikan/Article/Detail?id=669439272.

[33] 代金月. Soybean oil-based UV-curable coatings strengthened by crosslink agent derived from itaconic acid together with 2-hydroxyethyl methacrylate phosphat. Progress In Organic Coatings. 2016, 

   

（ 1 ） 基于苯并噁嗪树脂的3D打印模具专用料开发, 负责人, 企业委托, 2021-03--2021-12
（ 2 ） 电子封装环氧树脂工程技术中心, 负责人, 企业委托, 2021-01--2024-01
（ 3 ） 基于天然异黄酮的聚苯并嗪涂料的制备及其海洋防污性能研究, 负责人, 地方任务, 2019-11--2022-11
（ 4 ） 分子内氢键对可重塑环氧树脂力学性能和重塑效率的影响研究, 负责人, 国家任务, 2021-01--2023-12
（ 5 ） 低成本、高性能本征抗菌涂层的开发及应用示范, 负责人, 其他任务, 2022-04--2023-11

（1）本征阻燃型生物基环氧树脂的合成与性能研究   2019年全国高分子学术论文报告会   2019-10-15
（2）High Performance Thermosetting Resins Derived from Renewable Daidzein   第十届国际绿色复合材料研讨会   2018-11-06