1. 光电催化分解水制氢研究

研究光阳极和光阴极表面助催化剂等界面功能层对界面电荷传输、电荷分离及光电催化分解水性能重要影响，探究界面电荷传输机制，以建立高效的光电催化分解水制氢体系。

2. 仿生光电催化合成高值化学品

模拟自然光合作用暗反应，进行高效光电催化C/N小分子、NAD辅酶氢化还原研究，合成NADH辅酶及氨基酸等高值化学品。

   

080501-材料物理与化学
070304-物理化学

(光)电催化小分子转化制备太阳能燃料

2009-09--2015-07   中国科学院大连化学物理研究所   博士学位
2005-09--2009-07   中南大学   学士学位

2005年9月-2009年7月，中南大学，学士

2009年9月-2015年7月，中科院大连化学物理研究所，博士

   

2017-07~现在, 中国科学院大连化学物理研究所, 副研究员
2015-07~2017-06,中国科学院大连化学物理研究所, 助理研究员

   

（ 1 ） 还原型辅酶及其类似物再生催化剂以及制备方法、应用, 发明专利, 2021, 第 3 作者, 专利号: CN113058621A

（ 2 ） 光合作用与(光)电催化联用系统分离式分解水制氢方法, 专利授权, 2018, 第 3 作者, 专利号: CN108118358A

（ 3 ） 一种规模化太阳能光催化-光电催化分解水制氢的方法, 专利授权, 2017, 第 5 作者, 专利号: CN107012474A

（ 4 ） 一种光电催化氧化Ce（Ⅲ）得到Ce（Ⅳ）的方法及其Ce（Ⅳ）和应用, 发明专利, 2017, 第 4 作者, 专利号: CN106319553A

（ 5 ） 一种提高窄禁带半导体光阳极光电催化放氧反应稳定性的方法, 发明专利, 2015, 第 5 作者, 专利号: CN104709874A

（ 6 ） 一种光阳极-光伏电池耦合的双光照完全光驱动分解水制氢方法, 发明专利, 2015, 第 2 作者, 专利号: CN104711627A

（ 7 ） 光电催化反应器、连续深度处理废水的反应系统及应用, 发明专利, 2022, 第 3 作者, 专利号: 202211340571.0

（ 8 ） 一种杂化催化剂和制备方法及应用, 发明专利, 2023, 第 3 作者, 专利号: 202311719747.8

   

（1） Synergy Between Metal and Molecular Catalysts for (Photo)electrocatalytic 1,4-NADH Regeneration, J. Phy. Chem. C, 2024, 
（2） Promoting C-C Coupling for CO2 Reduction on Cu2O Electrocatalysts with Atomically Dispersed Rh Atoms, Chem. Commun., 2024, 
（3） Amino Acid Synthesis through C-N Coupling between a-Ketoacids and Hydroxylamine from Nitrate Reduction, ACS Catalysis, 2024, 
（4） Photoelectrocatalytic NADH Regeneration and Imine Hydrogenation, Sci. Sin. Chim., 2024, 
（5） A Coupled System of Ni3S2 and Rh Complex with Biomimetic Function for Electrocatalytic 1,4-NAD(P)H Regeneration, J. Am. Chem. Soc., 2024, 
（6） Selective Electrosynthesis of Ethanol via Asymmetric C-C Coupling in Tandem CO2 Reduction, ACS Catal., 2024, 第 9 作者
（7） CO2 Fixation with Aryl Bromide Towards Carboxylic Acid Enabled by Bifunctional CuAg Electrocatalyst, ACS Catal., 2023, 第 3 作者
（8） A synchronous defluorination-oxidation process for efficient mineralization of fluoroarenes with photoelectrocatalysis, Chinese J Catal., 2023, 第 5 作者
（9） Simultaneous Improvemen t in Hole Storage and Interfacial Catalysis over Ni-Fe Oxyhydroxide Modified Tantalum Nitride Photoanodes, ACS Catal., 2023, 第 2 作者
（10） Boosting Electrocatalytic Nitrate Reduction to Ammonia via Promoting Water Dissociation, ACS Catal., 2023, 
（11） Regioselective Reduction of NAD+ to 1,4-NADH with a Bioinspired Metal Sulfide Electrocatalyst, ChemCatChem, 2023, 第 8 作者  通讯作者
（12） Electrocatalytic NAD+ Reduction via Hydrogen-Atom-Coupled Electron Transfer, Chemical Science, 2022, 第 2 作者
（13） Charge Separation by Creating Band Bending in Metal-Organic Frameworks for Improved Photocatalytic Hydrogen Evolution, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 第 5 作者
（14） Relation between Water Oxidation Activity and Coordination Environment of C,N-Coordinated Mononuclear Co Catalyst, ACS CATALYSIS, 2022, 第 9 作者
（15） Understanding the factors governing the water oxidation reaction pathway of mononuclear and binuclear cobalt phthalocyanine catalysts, CHEMICAL SCIENCE, 2022, 第 4 作者
（16） Coupling effect between hole storage and interfacial charge transfer over ultrathin CoPi-modified hematite photoanodes, DALTON TRANSACTIONS, 2022, 第 2 作者
（17） Interfacial Microenvironment Modulation Boosting Electron Transfer between Metal Nanoparticles and MOFs for Enhanced Photocatalysis, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 第 6 作者
（18） Precise fabrication of single-atom alloy co-catalyst with optimal charge state for enhanced photocatalysis, Precise fabrication of single-atom alloy co-catalyst with optimal charge state for enhanced photocatalysis, NATIONAL SCIENCE REVIEW, 2021, 第 6 作者
（19） A Hydrogen Farm Strategy for Scalable Solar Hydrogen Production with Particulate Photocatalysts, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 第 2 作者
（20） 光电催化分解水和还原CO2研究进展, Progress of photoelectrocatalytic water splitting and CO2 reduction, 科技导报, 2020, 第 1 作者
（21） Carbon nitride embedded with transition metals for selective electrocatalytic CO2 reduction, APPLIED CATALYSIS B-ENVIRONMENTAL, 2020, 第 1 作者
（22） Incorporating Transition-Metal Phosphides Into Metal-Organic Frameworks for Enhanced Photocatalysis, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 第 5 作者
（23） Integrating a redox flow battery into a z-scheme water splitting system for enhancing the solar energy conversion efficiency, ENERGY & ENVIRONMENTAL SCIENCE, 2019, 第 6 作者
（24） Water Oxidation Catalysts for Artificial Photosynthesis, ADVANCED MATERIALS, 2019, 第 2 作者
（25） Crystallographic-Orientation-Dependent Charge Separation of BiVO4 for Solar Water Oxidation, ACSENERGYLETTERS, 2019, 第 6 作者
（26） Artificial photosynthesis systems for catalytic water oxidation, WATER OXIDATION CATALYSTS, 2019, 第 2 作者
（27） Mimicking the Key Functions of Photosystem II in Artificial Photosynthesis for Photoelectrocatalytic Water Splitting, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 第 2 作者
（28） Photoelectrochemical regeneration of all vanadium redox species for construction of a solar rechargeable flow cell, JOURNAL OF ENERGY CHEMISTRY, 2018, 第 3 作者
（29） Amorphous Multi-elements Electrocatalysts with Tunable Bifunctionality toward Overall Water Splitting, ACS CATALYSIS, 2018, 第 3 作者
（30） Amorphous Multi-elements Electrocatalysts with Tunable Bifunctionality towards Overall Water Splitting, ACS Catalysis, 2018, 第 1 作者
（31） Photoelectrochemical regeneration of all vanadium redox species for construction of a solar rechargeable flow cell, Photoelectrochemical regeneration of all vanadium redox species for construction of a solar rechargeable flow cell, 能源化学：英文版, 2018, 第 3 作者
（32） Correction to photoelectrocatalytic water splitting: significance of cocatalysts, electrolyte, and interfaces (vol 7, pg 675, 2017), ACS CATALYSIS, 2017, 第 1 作者
（33） Biomimetic electron transport via multiredox shuttles from photosystem ii to a photoelectrochemical cell for solar water splitting, ENERGY & ENVIRONMENTAL SCIENCE, 2017, 第 3 作者
（34） CoOx nanoparticle anchored on sulfonated-graphite as efficient water oxidation catalyst, CHEMICAL SCIENCE, 2017, 第 2 作者
（35） Photoelectrocatalytic Water Splitting: Significance of Cocatalysts, Electrolyte, and Interfaces, ACS CATALYSIS, 2017, 第 1 作者
（36） Promoting Charge Separation and Injection by Optimizing the Interfaces of GaN:ZnO Photoanode for Efficient Solar Water Oxidation, ACS APPLIED MATERIALS & INTERFACES, 2017, 第 7 作者
（37） Integrating a dual-silicon photoelectrochemical cell into a redox ���ow battery for unassisted photocharging, Nat. Commun., 2016, 第 1 作者
（38） In Situ Electrodeposited Indium Nanocrystals for E���cient CO2 Reduction to CO with Low Overpotential, ACS Catal., 2016, 第 1 作者
（39） Bridging surface states and current-potential response over hematite-based photoelectrochemical water oxidation, RSC ADVANCES, 2016, 第 4 作者
（40） Insight into the charge transfer in particulate ta3n5 photoanode with high photoelectrochemical performance, CHEMICAL SCIENCE, 2016, 第 3 作者
（41） Substrate-electrode interface engineering by an electron-transport layer in hematite photoanode, ACS APPLIED MATERIALS & INTERFACES, 2016, 第 1 作者
（42） Integrating a dual-silicon photoelectrochemical cell into a redox flow battery for unassisted photocharging, NATURE COMMUNICATIONS, 2016, 第 6 作者
（43） In situ electrodeposited indium nanocrystals for efficient co2 reduction to co with low overpotential, ACS CATALYSIS, 2016, 第 1 作者
（44） Abnormal Effects of Cations (Li+, Na+, and K+) on Photoelectrochemical and Electrocatalytic Water Splitting, JOURNAL OF PHYSICAL CHEMISTRY B, 2015, 第 1 作者
（45） Direct electron transfer from photosystem II to hematite in a hybrid photoelectrochemical cell, CHEMICAL COMMUNICATIONS, 2015, 第 5 作者
（46） Efficient Hole Extraction from a Hole-Storage-Layer-Stabilized Tantalum Nitride Photoanode for Solar Water Splitting, CHEMISTRY-A EUROPEAN JOURNAL, 2015, 第 5 作者
（47） Photoelectrochemical water splitting promoted with a disordered surface layer created by electrochemical reduction., ACS APPLIED MATERIALS & INTERFACES, 2015, 第 3 作者
（48） J PHYS CHEM B, 2015, 
（49） Conversion of Biomass Derivatives to Electricity in Photo Fuel Cells using Undoped and Tungsten-doped Bismuth Vanadate Photoanodes, CHEMSUSCHEM, 2015, 第 3 作者
（50） Synergetic Effect of Conjugated Ni(OH)2/IrO2 Cocatalyst on Titanium-Doped Hematite Photoanode for Solar Water Splitting, JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 第 3 作者
（51） Efficient Photoelectrochemical Water Splitting without External Bias, the 4th international symposium on solar fuels and solar cells & the 3rd dnl conference on clean energy, 2014, 第 1 作者
（52） Photoelectrochemical Overall Water Splitting Using Co-borate/BiVO4 Photoanode with Minimized Bias, gordon reseach conference:renewable fuels for the future, 2014, 第 1 作者
（53） A Tantalum Nitride Photoanode Modified with a Hole-Storage Layer for Highly Stable Solar Water Splitting, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 第 6 作者
（54） Solar-to-hydrogen efficiency exceeding 2.5% achieved for overall water splitting with an all earth-abundant dual-photoelectrode, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 第 1 作者
（55） Solar-to-hydrogen Efficiency Exceeding 2.5% Achieved for Overall Water Splitting with All Earth-abundant Dual-photoelectrode, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 第 1 作者
（56） Enhancement of visible-light-driven O-2 evolution from water oxidation on WO3 treated with hydrogen, JOURNAL OF CATALYSIS, 2013, 第 7 作者
（57） Nitrogen-doped tantalum-based layered oxides for solar water splitting under visible light irradiation, the 6th asia-pacific congress on catalysis　, 2013, 第 3 作者
（58） Nitrogen-doped layered oxide Sr5Ta4O15-xNx for water reduction and oxidation under visible light irradiation, JOURNAL OF MATERIALS CHEMISTRY A, 2013, 第 3 作者
（59） Visible light driven overall water splitting using cocatalyst/BiVO4 photoanode with minimized bias, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 第 1 作者
（60） Visible Light Photoelectrochemical Water Oxidation on CoBOx Modified BiVO4 Photoanode, THE 3RD INTERNATIONAL SYMPOSIUM ON SOLAR CELLS AND SOLAR FUELS, 2012, 第 1 作者
（61） Electrode-electrolyte interface engineering in photoelectrocatalytic water spliting, 第 1 作者

   

（ 1 ） 一碳化合物生物转化制备燃料与化学品技术, 参与, 国家任务, 2021-12--2024-11
（ 2 ） （光）电催化硝酸根和有机酸C-N偶联合成氨基酸, 负责人, 国家任务, 2024-01--2027-12
（ 3 ） 光生载流子传输机制与表面反应机理, 负责人, 国家任务, 2023-12--2028-11
（ 4 ） 大功率高效碱水电解制氢及转化利用, 参与, 中国科学院计划, 2023-10--2028-09
（ 5 ） 中科院青年创新促进会会员, 负责人, 中国科学院计划, 2022-01--2025-12
（ 6 ） 光电催化人工光合成制备高值化学品, 负责人, 地方任务, 2023-11--2025-10

（1）光电催化制备燃料及化学品   第3届女催化科学家论坛   2023-11-17
（2）光电催化水氧化光反应及还原暗反应制备高值化学品   第21届全国催化会   2023-07-21
（3）光电催化界面电荷传输及CO2还原研究，第20届全国催化会   第20届全国催化会   2021-10-15
（4）光电催化分解水之光阳极界面电荷传输研究   第18届全国青年催化会   2021-07-09
（5）Significance of Interface Engineering and Charge Transfer for Photoelectrocatalytic Water splitting,   2019-08-04
（6）Interface Engineering in Photoelectrocatalytic Water Splitting   2016-07-09
（7）Electrode-electrolyte and Substrate-electrode Interface Engineering in Photoelectrocatalytic Water Splitting   2016-07-03
（8） Effects of the Electrolyte on the Electrode-electrolyte Interface and Photoelectrochemical Water Oxidation   2015-05-30

现指导学生

乔亚飞  硕士研究生  070304-物理化学