有机液流电池，新型高性能储能电池

   

080501-材料物理与化学
081701-化学工程

电化学、储能技术、液流电池
有机化学、有机活性材料

2009-09--2014-07   中科院大连化学物理研究所   硕博连读
2005-09--2009-07   哈尔滨工程大学   本科 学士学位

   

2021-01~现在, 中科院大连化学物理研究所, 研究员
2020-11~2021-01,中科院大连化学物理研究所, 副研究员
2016-08~2020-09,美国德州大学奥斯汀分校, 博士后
2014-10~2016-04,北京纳米能源与系统研究所, 博士后

   

（ 1 ） 一种复合电极的制备方法, 发明专利, 2016, 第 2 作者, 专利号: CN105869909A

（ 2 ） 电氧化合成一维纳米氧化物结构的制备方法, 发明专利, 2016, 第 3 作者, 专利号: CN105780087A

（ 3 ） 一种掺杂氧化铁纳米棒催化剂的制备方法, 发明专利, 2016, 第 3 作者, 专利号: CN105498773A

（ 4 ） 一种自支撑催化层的制备方法, 发明专利, 2015, 第 2 作者, 专利号: CN104716340A

（ 5 ） 一种多孔氧化铁纳米棒阵列的制备方法, 发明专利, 2015, 第 2 作者, 专利号: CN104628042A

（ 6 ） 一种纳米六边形氧化铁的制备方法, 发明专利, 2014, 第 4 作者, 专利号: CN103880091A

（ 7 ） 一种Au修饰TiO 2 纳米棒阵列光阳极的制备方法, 发明专利, 2014, 第 4 作者, 专利号: CN103872174A

（ 8 ） 一种Au修饰TiO 2 纳米棒阵列光阳极的制备方法, 发明专利, 2014, 第 4 作者, 专利号: CN103872174A

（ 9 ） 一种用于光电解用的α-Fe 2 O 3 光阳极的制备方法, 发明专利, 2014, 第 4 作者, 专利号: CN103726090A

（ 10 ） 一种复合电极的制备方法, 发明专利, 2014, 第 2 作者, 专利号: CN103526227A

（ 11 ） 一种有序化电极的制备方法, 发明专利, 2013, 第 2 作者, 专利号: CN103165908A

（ 12 ） 用于燃料电池膜电极催化剂层制备的浆料及其制备, 发明专利, 2013, 第 2 作者, 专利号: CN103165913A

（ 13 ） 一种光电解池分解水产氢并在线分离装置, 发明专利, 2013, 第 3 作者, 专利号: CN103159297A

（ 14 ） 一种联苯胺类化合物及其制备方法和在液流电池中的应用, 发明专利, 2022, 第 3 作者, 专利号: 202211589830.3

（ 15 ） 一种联苯胺基锂类化合物及其制备方法和在锂离子电池中的应用, 发明专利, 2022, 第 3 作者, 专利号: 202211590014.4

（ 16 ） 一种萘型化合物及其制备和包含其的液流电池, 发明专利, 2023, 第 2 作者, 专利号: PCTCN2023137677

（ 17 ） 一种氮杂蒽醌类化合物及其制备方法和在液流电池中的应用, 发明专利, 2023, 第 3 作者, 专利号: 2023112652556

（ 18 ） 一种浆料型锂离子电池, 发明专利, 2022, 第 1 作者, 专利号: 2022115775553

（ 19 ） 一类吩噻嗪衍生物及其制备和在液流电池体系中的应用, 发明专利, 2023, 第 1 作者, 专利号: 2023112617961

   

[1] Advanced Functional Materials. 2024,   通讯作者  
[2] Nature Sustainability. 2024,   通讯作者  
[3] Chemical Society Reviews. 2023,   通讯作者  
[4] 陈海生, 李泓, 徐玉杰, 陈满, 王亮, 戴兴建, 徐德厚, 唐西胜, 李先锋, 胡勇胜, 马衍伟, 刘语, 苏伟, 王青松, 陈军, 卓萍, 肖立业, 周学志, 冯自平, 蒋凯, 尉海军, 唐永炳, 陈人杰, 刘亚涛, 张宇鑫, 林曦鹏, 郭欢, 张涵, 张长昆, 胡东旭, 容晓晖, 张熊, 金凯强, 姜丽华, 彭煜民, 刘世奇, 朱轶林, 王星, 周鑫, 欧学武, 庞全全, 俞振华, 刘为, 岳芬, 李臻, 宋振, 王志峰, 宋文吉, 林海波, 李杰才, 易斌, 李福军, 潘新慧, 李丽, 马一鸣, 李煌. 2022年中国储能技术研究进展. 储能科学与技术. 2023, 第 29 作者12(5): 1516-1552, http://lib.cqvip.com/Qikan/Article/Detail?id=7109833128.
[5] 张永辉, 傅杰, 李先锋, 张长昆. 原位表征技术在水系有机液流电池中的研究进展. 储能科学与技术[J]. 2023, 第 4 作者12(9): 2971-2984, http://lib.cqvip.com/Qikan/Article/Detail?id=7110476627.
[6] Zhang, Yonghui, Li, Fan, Li, Tianyu, Zhang, Mengqi, Yuan, Zhizhang, Hou, Guangjin, Fu, Jie, Zhang, Changkun, Li, Xianfeng. Insights into an air-stable methylene blue catholyte towards kW-scale practical aqueous organic flow batteries. ENERGY & ENVIRONMENTAL SCIENCE[J]. 2023, 第 8 作者  通讯作者  16(1): 231-240, 
[7] Angewandte Chemie International Edition. 2023,   通讯作者  
[8] Zhao, Ziming, Zhang, Changkun, Li, Xianfeng. Opportunities and challenges of organic flow battery for electrochemical energy storage technology. JOURNAL OF ENERGY CHEMISTRY[J]. 2022, 第 2 作者  通讯作者  67(4): 621-639, http://apps.webofknowledge.com/CitedFullRecord.do?product=UA&colName=WOS&SID=5CCFccWmJJRAuMzNPjj&search_mode=CitedFullRecord&isickref=WOS:000780442500002.
[9] Li, Tianyu, Zhang, Changkun, Li, Xianfeng. Machine learning for flow batteries: opportunities and challenges. CHEMICAL SCIENCE[J]. 2022, 第 2 作者  通讯作者  13(17): 4740-4752, http://dx.doi.org/10.1039/d2sc00291d.
[10] Chen, Dongju, Liu, Guangyu, Liu, Jie, Zhang, Changkun, Yuan, Zhizhang. Porous polybenzimidazole membranes with positive charges enable an excellent anti-fouling ability for vanadium-methylene blue flow battery. JOURNAL OF ENERGY CHEMISTRY[J]. 2022, 第 4 作者68(5): 247-254, http://dx.doi.org/10.1016/j.jechem.2021.12.011.
[11] Zhang, Changkun, Chen, Hui, Qian, Yumin, Dai, Gaole, Zhao, Yu, Yu, Guihua. General Design Methodology for Organic Eutectic Electrolytes toward High-Energy-Density Redox Flow Batteries. ADVANCED MATERIALS[J]. 2021, 第 1 作者33(15): https://www.webofscience.com/wos/woscc/full-record/WOS:000626638800001.
[12] Zhang, Changkun, Niu, Zhihui, Bae, Jiwoong, Zhang, Leyuan, Zhao, Yu, Yu, Guihua. Polyeutectic-based stable and effective electrolytes for high-performance energy storage systems. ENERGY & ENVIRONMENTAL SCIENCE[J]. 2021, 第 1 作者14(2): 931-939, http://dx.doi.org/10.1039/d0ee03100c.
[13] Zhang, Changkun, Zhang, Leyuan, Yu, Guihua. Eutectic Electrolytes as a Promising Platform for Next-Generation Electrochemical Energy Storage. ACCOUNTS OF CHEMICAL RESEARCH[J]. 2020, 第 1 作者53(8): 1648-1659, http://dx.doi.org/10.1021/acs.accounts.0c00360.
[14] Ding, Yu, Zhang, Changkun, Zhang, Leyuan, Zhou, Yangen, Yu, Guihua. Pathways to Widespread Applications: Development of Redox Flow Batteries Based on New Chemistries. CHEM. 2019, 第 2 作者5(8): 1964-1987, http://dx.doi.org/10.1016/j.chempr.2019.05.010.
[15] Zhang, Changkun, Qian, Yumin, Ding, Yu, Zhang, Leyuan, Guo, Xuelin, Zhao, Yu, Yu, Guihua. Biredox Eutectic Electrolytes Derived from Organic Redox-Active Molecules: High-Energy Storage Systems. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2019, 第 1 作者58(21): 7045-7050, http://dx.doi.org/10.1002/anie.201902433.
[16] Zhang, Changkun, Niu, Zhihui, Peng, Sangshan, Ding, Yu, Zhang, Leyuan, Guo, Xuelin, Zhao, Yu, Yu, Guihua. Phenothiazine-Based Organic Catholyte for High-Capacity and Long-Life Aqueous Redox Flow Batteries. ADVANCED MATERIALS[J]. 2019, 第 1 作者31(24): http://dx.doi.org/10.1002/adma.201901052.
[17] Ding, Yu, Zhang, Changkun, Zhang, Leyuan, Zhou, Yangen, Yu, Guihua. Molecular engineering of organic electroactive materials for redox flow batteries. CHEMICAL SOCIETY REVIEWS. 2018, 第 2 作者47(1): 69-103, https://www.webofscience.com/wos/woscc/full-record/WOS:000419218700004.
[18] Yu, Guihua. Recent progress and prospects of next-generation redox flow batteries. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2018, 256: https://www.webofscience.com/wos/woscc/full-record/WOS:000447600005405.
[19] Zhang, Changkun, Zhang, Leyuan, Ding, Yu, Guo, Xuelin, Yu, Guihua. Eutectic Electrolytes for High-Energy-Density Redox Flow Batteries. ACS ENERGY LETTERS[J]. 2018, 第 1 作者3(12): 2875-2883, http://dx.doi.org/10.1021/acsenergylett.8b01899.
[20] Ding, Yu, Zhang, Changkun, Zhang, Leyuan, Wei, Haiyan, Li, Yafei, Yu, Guihua. Insights into Hydrotropic Solubilization for Hybrid Ion Redox Flow Batteries. ACS ENERGY LETTERS[J]. 2018, 第 2 作者3(11): 2641-2648, https://www.webofscience.com/wos/woscc/full-record/WOS:000450374600001.
[21] Zhang, Changkun, Ding, Yu, Zhang, Leyuan, Wang, Xuelan, Zhao, Yu, Zhang, Xiaohong, Yu, Guihua. A Sustainable Redox-Flow Battery with an Aluminum-Based, Deep-Eutectic-Solvent Anolyte. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2017, 第 1 作者56(26): 7454-7459, https://www.webofscience.com/wos/woscc/full-record/WOS:000403017000019.
[22] Zhang, Leyuan, Zhang, Changkun, Ding, Yu, RamirezMeyers, Katrina, Yu, Guihua. A Low-Cost and High-Energy Hybrid Iron-Aluminum Liquid Battery Achieved by Deep Eutectic Solvents. JOULE[J]. 2017, 第 2 作者1(3): 623-633, http://dx.doi.org/10.1016/j.joule.2017.08.013.
[23] Jiang, Shangfeng, Yi, Baolian, Zhang, Changkun, Liu, Sa, Yu, Hongmei, Shao, Zhigang. Vertically aligned carbon-coated titanium dioxide nanorod arrays on carbon paper with low platinum for proton exchange membrane fuel cells. JOURNALOFPOWERSOURCES[J]. 2015, 第 3 作者276(1): 80-88, http://dx.doi.org/10.1016/j.jpowsour.2014.11.093.
[24] Zhang, Changkun, Yu, Hongmei, Fu, Li, Xiao, Yu, Gao, Yuan, Li, Yongkun, Zeng, Yachao, Jia, Jia, Yi, Baolian, Shao, Zhigang. An Oriented Ultrathin Catalyst Layer Derived from High Conductive TiO2 Nanotube for Polymer Electrolyte Membrane Fuel Cell. ELECTROCHIMICA ACTA[J]. 2015, 第 1 作者153(1): 361-369, http://dx.doi.org/10.1016/j.electacta.2014.10.090.
[25] Gao, Yuan, Hou, Ming, Shao, Zhigang, Zhang, Changkun, Qin, Xiaoping, Yi, Baolian. Highly effective oxygen reduction activity and durability of antimony-doped tin oxide modified PtPd/C electrocatalysts. RSC ADVANCES[J]. 2015, 第 4 作者5(85): 69479-69486, http://cas-ir.dicp.ac.cn/handle/321008/146482.
[26] Gao, Yuan, Hou, Ming, Shao, Zhigang, Zhang, Changkun, Qin, Xiaoping, Yi, Baolian. Highly effective oxygen reduction activity and durability of antimony-doped tin oxide modified PtPd/C electrocatalysts. RSC ADVANCES[J]. 2015, 第 4 作者5(85): 69479-69486, http://cas-ir.dicp.ac.cn/handle/321008/146482.
[27] Yang, Donglei, Yu, Hongmei, Li, Guangfu, Zhao, Yun, Liu, Yanxi, Zhang, Changkun, Song, Wei, Shao, Zhigang. Fine microstructure of high performance electrode in alkaline anion exchange membrane fuel cells. JOURNAL OF POWER SOURCES[J]. 2014, 第 6 作者267: 39-47, http://dx.doi.org/10.1016/j.jpowsour.2014.04.053.
[28] Fu, Li, Yu, Hongmei, Zhang, Changkun, Shao, Zhigang, Yi, Baolian. Cobalt Phosphate Group Modified Hematite Nanorod Array as Photoanode for Efficient Solar Water Splitting. ELECTROCHIMICA ACTA[J]. 2014, 第 3 作者136: 363-369, http://dx.doi.org/10.1016/j.electacta.2014.05.094.
[29] Zhang, Changkun, Yu, Hongmei, Fu, Li, Gao, Yuan, Jia, Jia, Jiang, Shangfeng, Yi, Baolian, Shao, Zhigang. A novel ultra-thin catalyst layer based on wheat ear-like catalysts for polymer electrolyte membrane fuel cells. RSC ADVANCES[J]. 2014, 第 1 作者4(102): 58591-58595, http://cas-ir.dicp.ac.cn/handle/321008/144414.
[30] Yuan Gao, Ming Hou, Zhigang Shao, Changkun Zhang, Xiaoping Qin, Baolian Yi. Preparation and characterization of Ti0.7Sn0.3O2 as catalyst support for oxygen reduction reaction. 能源化学：英文版[J]. 2014, 第 4 作者23(3): 331-337, http://lib.cqvip.com/Qikan/Article/Detail?id=50200133.
[31] Fu, Li, Yu, Hongmei, Li, Yongkun, Zhang, Changkun, Wang, Xunying, Shao, Zhigang, Yi, Baolian. Ethylene glycol adjusted nanorod hematite film for active photoelectrochemical water splitting. PHYSICAL CHEMISTRY CHEMICAL PHYSICS[J]. 2014, 第 4 作者16(9): 4284-4290, http://www.irgrid.ac.cn/handle/1471x/858857.
[32] Gao, Yuan, Hou, Ming, Shao, Zhigang, Zhang, Changkun, Qin, Xiaoping, Yi, Baolian. Preparation and characterization of Ti0.7Sn0.3O2 as catalyst support for oxygen reduction reaction. JOURNAL OF ENERGY CHEMISTRY[J]. 2014, 第 4 作者23(3): 331-337, http://lib.cqvip.com/Qikan/Article/Detail?id=50200133.
[33] Li, Yongkun, Yu, Hongmei, Zhang, Changkun, Fu, Li, Li, Guangfu, Shao, Zhigang, Yi, Baolian. Enhancement of photoelectrochemical response by Au modified in TiO2 nanorods. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY[J]. 2013, 第 3 作者38(29): 13023-13030, http://dx.doi.org/10.1016/j.ijhydene.2013.03.122.
[34] Li, Yongkun, Yu, Hongmei, Zhang, Changkun, Song, Wei, Li, Guangfu, Shao, Zhigang, Yi, Baolian. Effect of water and annealing temperature of anodized TiO2 nanotubes on hydrogen production in photoelectrochemical cell. ELECTROCHIMICA ACTA[J]. 2013, 第 3 作者107: 313-319, http://dx.doi.org/10.1016/j.electacta.2013.05.090.
[35] Zhang, Changkun, Yu, Hongmei, Li, Yongkun, Fu, Li, Gao, Yuan, Song, Wei, Shao, Zhigang, Yi, Baolian. Simple synthesis of Pt/TiO2 nanotube arrays with high activity and stability. JOURNAL OF ELECTROANALYTICAL CHEMISTRY[J]. 2013, 第 1 作者701: 14-19, http://dx.doi.org/10.1016/j.jelechem.2013.04.012.
[36] Zhang, Changkun, Yu, Hongmei, Li, Yongkun, Gao, Yuan, Zhao, Yun, Song, Wei, Shao, Zhigang, Yi, Baolian. Supported Noble Metals on Hydrogen-Treated TiO2 Nanotube Arrays as Highly Ordered Electrodes for Fuel Cells. CHEMSUSCHEM[J]. 2013, 第 1 作者  通讯作者  6(4): 659-666, http://www.irgrid.ac.cn/handle/1471x/721091.
[37] 张长昆, 俞红梅, 李永坤, 付丽, 宋微, 邵志刚, 衣宝廉. Supported Pt catalysts on TiO2 nanotube arrays for fuel cells. INTERNATIONAL CONFERENCE ON ELECTROCHEMICAL MATERIALS AND TECHNOLOGIES FOR CLEAN SUSTAINABLE ENERGY. 2013, 第 1 作者97, http://159.226.238.44/handle/321008/116860.
[38] Zhang, Changkun, Yu, Hongmei, Li, Yongkun, Fu, Li, Gao, Yuan, Song, Wei, Shao, Zhigang, Yi, Baolian. Highly stable ternary tin-palladium-platinum catalysts supported on hydrogenated TiO2 nanotube arrays for fuel cells. NANOSCALE[J]. 2013, 第 1 作者5(15): 6834-6841, http://159.226.238.44/handle/321008/137936.
[39] Li, Yongkun, Yu, Hongmei, Zhang, Changkun, Fu, Li, Li, Guangfu, Shao, Zhigang, Yi, Baolian. Electrodeposition of Ni oxide on TiO2 nanotube arrays for enhancing visible light photoelectrochemical water splitting. JOURNAL OF ELECTROANALYTICAL CHEMISTRY[J]. 2013, 第 3 作者688: 228-231, http://dx.doi.org/10.1016/j.jelechem.2012.10.023.
[40] 李永坤, 俞红梅, 张长昆, 李光福, 付丽, 衣宝廉, 邵志刚. Enhancement of photoelectrochemical response by Au modified in TiO2 nanorods. 12TH INTERNATIONAL CONFERENCE ON CLEAN ENERGY. 2012, 第 3 作者56, http://159.226.238.44/handle/321008/117132.
[41] Zhang, Changkun, Yu, Hongmei, Li, Yongkun, Song, Wei, Yi, Baolian, Shao, Zhigang. Preparation of Pt catalysts decorated TiO2 nanotube arrays by redox replacement of Ni precursors for proton exchange membrane fuel cells. ELECTROCHIMICA ACTA[J]. 2012, 第 1 作者80: 1-6, http://dx.doi.org/10.1016/j.electacta.2012.05.162.

   

（ 1 ） 水系有机液流电池吩噻嗪类活性分子设计及其储能特性的调控, 负责人, 国家任务, 2023-01--2026-12
（ 2 ） 浆料流体储能电池的跨尺度关联及电堆设计, 负责人, 国家任务, 2023-01--2028-12
（ 3 ） 新一代液流电池储能技术, 负责人, 国家任务, 2022-11--2026-10
（ 4 ） 高功率密度碱性锌铁液流电池电堆的研究开发, 负责人, 地方任务, 2022-09--2025-08

现指导学生

杨贺然  博士研究生  080501-材料物理与化学  

许晓璇  硕士研究生  085600-材料与化工  

徐越  博士研究生  080501-材料物理与化学  

封婷宇  硕士研究生  080501-材料物理与化学  

钟盛连  硕士研究生  085600-材料与化工  

张梦琪  博士研究生  081701-化学工程