基本信息
郭晓光 男 大连化学物理研究所
电子邮件:xguo@dicp.ac.cn
通信地址:大连市中山路457号大连化物所催化基础国家重点实验室
邮政编码:116023
电子邮件:xguo@dicp.ac.cn
通信地址:大连市中山路457号大连化物所催化基础国家重点实验室
邮政编码:116023
研究领域
主要从事天然气的高效利用、C-H键活化和纳米多相催化。
1) 高温催化材料及机理研究
从分子、原子级别研制与构建新型高温催化材料,运用先进的原位分析手段和模拟计算过程,研究高温过程中催化剂的反应及失活机制。在此研究基础上,针对反应的速控步可控构建高稳定性的新型催化材料。
2) 甲烷及低碳烃的催化转化
研究甲烷、低碳烃的无氧或有氧(指氧化剂)催化转化;研究甲烷和低碳烃的无氧或有氧共催化转化;研究高选择性的C-H键活化、识别定位目标C-H键、催化剂构建。利用原位表征技术,研究有氧或无氧过程中的催化活化机制和C-C链增长机制。
1) 高温催化材料及机理研究
从分子、原子级别研制与构建新型高温催化材料,运用先进的原位分析手段和模拟计算过程,研究高温过程中催化剂的反应及失活机制。在此研究基础上,针对反应的速控步可控构建高稳定性的新型催化材料。
2) 甲烷及低碳烃的催化转化
研究甲烷、低碳烃的无氧或有氧(指氧化剂)催化转化;研究甲烷和低碳烃的无氧或有氧共催化转化;研究高选择性的C-H键活化、识别定位目标C-H键、催化剂构建。利用原位表征技术,研究有氧或无氧过程中的催化活化机制和C-C链增长机制。
工作经历
2019.7-至今,中国科学院大连化学物理研究所, 正高级工程师
2012-12~2019-07,中国科学院大连化学物理研究所, 副研究员
2010-09~2012-10,中国科学院大连化学物理研究所502组, 博士后
2010-03~2010-08,中国科学院兰州化学物理研究所, 助理研究员
专利与奖励
专利成果
[1] 包信和, 郭晓光, 潘秀莲, 方光宗, 戴丹, 柳海涛, 谭大力, 于洪飞. 一种临氢条件下催化转化甲烷制烯烃、芳烃和氢气中的方法. CN 111333479 B, 2021-08-31.[2] 包信和, 郭晓光, 潘秀莲, 方光宗, 戴丹, 柳海涛, 谭大力, 于洪飞. 一种共催化转化甲烷和乙烷制烯烃、芳烃和氢气中的方法. CN 111333477 A, 2020-06-26.[3] 包信和, 郭晓光, 潘秀莲, 方光宗, 戴丹, 柳海涛, 谭大力, 于洪飞. 一种蒸汽催化转化甲烷制烯烃、芳烃和氢气中的方法. CN 111333478 B, 2021-11-16.[4] 包信和, 郝建旗, 方光宗, 郭晓光, 皮埃尔·亨利·施瓦赫, 潘秀莲. 一种氢助甲烷活化制备烯烃和芳烃的方法. CN: CN111320518B, 2021-08-31.[5] 包信和, 郭晓光, 方光宗, 潘秀莲, 孟敬恒, 于琴琴, 谭大力. 一种催化反应器构型及制备和在无氧条件下催化甲烷直接合成乙烯的方法. CN: CN107335386A, 2017-11-10.[6] 包信和, 郭晓光, 方光宗, 于琴琴, 谭大力. 一种金属元素晶格掺杂Si基材料催化剂的制备方法及甲烷无氧制乙烯的方法. CN: CN106914243A, 2017-07-04.[7] 包信和, 叶益凡, 郭晓光. 一种光伏多晶硅切割废料作为催化剂无氧条件直接转化甲烷制乙烯、芳烃和氢气的方法. CN: CN105481626A, 2016-04-13.[8] 包信和, 蔡凡, 郭晓光. 金属掺杂分子筛催化转化甲烷无氧直接制乙烯的方法. CN: CN105566047A, 2016-05-11.[9] 包信和, 方光宗, 郭晓光, 赵侦超, 谭大力. 一种微孔分子筛择形甲烷无氧直接制乙烯的方法及催化剂. CN: CN104909975A, 2015-09-16.[10] 包信和, 郭晓光, 方光宗, 邓德会, 马昊, 谭大力. 一种甲烷无氧直接制烯烃的方法及其催化剂. CN: CN104148101A, 2014-11-19.[11] 包信和, 郭晓光, 方光宗, 邓德会, 马昊, 谭大力. 一种甲烷直接制备烯烃、芳烃和氢气的催化剂和反应应用. 201310046659.6, 2013-02-06.[12] 谭大力, 郭晓光, 马书启, 傅强, 包信和. 一种可视流化床微反应装置. CN: CN103769013A, 2014-05-07.[13] 谭大力, 郭晓光, 马书启, 傅强, 包信和. 一种计算机监控的高通量多功能微反应系统. CN: CN103777027A, 2014-05-07.[14] 傅强, 郭晓光, 包信和. 一种多组分纳米催化剂的制备方法. CN: CN103706376A, 2014-04-09.[15] Oxygen-free direct conversion of methane and catalysts thereof. 2020-07-07.[16] Oxygen-free direct conversion of methane and catalysts therefor. 2018-06-21.[17] 包信和, 郭晓光, 潘秀莲, 于洪飞, 由灏盛, 夏维东, 陈仙辉. 一种焦耳热耦合催化天然气和CO2 干气重整制合成气的方法. CN: CN116514062A, 2023-08-01.[18] 包信和, 郭晓光, 潘秀莲, 于洪飞, 由灏盛. 一种焦耳热耦合金属催化反应器无氧催化转化甲烷制烯烃、芳烃和氢气的方法. CN: CN116553994A, 2023-08-08.[19] 包信和, 夏维东, 郭晓光, 陈仙辉, 潘秀莲, 于洪飞. 一种热等离子体耦合催化天然气和CO2 干气重整制合成气的方法. CN: CN114733477A, 2022-07-12.[20] 包信和, 郭晓光, 潘秀莲, 于洪飞. 一种金属催化反应器及其制备与在天然气和CO2 干气重整制合成气中的应用. CN: CN114768746A, 2022-07-22.[21] 包信和, 郭晓光, 潘秀莲, 于洪飞. 一种使用气体还原剂催化石灰石还原分解制熟料并联产富含CO/H2 的方法. CN: CN115403282A, 2022-11-29.[22] 包信和, 郭晓光, 潘秀莲, 于洪飞. 一种使用固体还原剂催化石灰石还原分解制熟料并联产CO的方法. CN: CN115403286A, 2022-11-29.
出版信息
发表论文
[1] Nature Communications. 2023, [2] Fuel. 2023, [3] Ni, Wenpeng, Liu, Zhixiao, Guo, Xiaoguang, Zhang, Yan, Ma, Chao, Deng, Yijie, Zhang, Shiguo. Dual single-cobalt atom-based carbon electrocatalysts for efficient CO2-to-syngas conversion with industrial current densities. APPLIED CATALYSIS B-ENVIRONMENTAL[J]. 2021, 291: http://dx.doi.org/10.1016/j.apcatb.2021.120092.[4] Ni, Wenpeng, Gao, Yang, Lin, Yue, Ma, Chao, Guo, Xiaoguang, Wang, Shuangyin, Zhang, Shiguo. Nonnitrogen Coordination Environment Steering Electrochemical CO2-to-CO Conversion over Single-Atom Tin Catalysts in a Wide Potential Window. ACSCATALYSIS[J]. 2021, 11(9): 5212-5221, http://dx.doi.org/10.1021/acscatal.0c05514.[5] Hao, Jianqi, Schwach, Pierre, Li, Lulu, Guo, Xiaoguang, Weng, Junben, Zhang, Hailei, Shen, Hao, Fang, Guangzong, Huang, Xin, Pan, Xiulian, Xiao, Chunlei, Yang, Xueming, Bao, Xinhe. Direct experimental detection of hydrogen radicals in non-oxidative methane catalytic reaction. JOURNAL OF ENERGY CHEMISTRY[J]. 2021, 52(1): 372-376, http://sciencechina.cn/gw.jsp?action=detail.jsp&internal_id=6916422&detailType=1.[6] Sun, Tian, Liu, Piao, Zhang, Yan, Chen, Zhengjian, Zhang, Ce, Guo, Xiaoguang, Ma, Chao, Gao, Yang, Zhang, Shiguo. Boosting the electrochemical water splitting on Co3O4 through surface decoration of epitaxial S-doped CoO layers. CHEMICAL ENGINEERING JOURNAL[J]. 2020, 390: http://dx.doi.org/10.1016/j.cej.2020.124591.[7] Hao, Jianqi, Schwach, Pierre, Fang, Guangzong, Guo, Xiaoguang, Zhang, Hailei, Shen, Hao, Huang, Xin, Eggart, Daniel, Pan, Xiulian, Bao, Xinhe. Enhanced Methane Conversion to Olefins and Aromatics by H-Donor Molecules under Nonoxidative Condition. ACS CATALYSIS[J]. 2019, 9(10): 9045-9050, http://dx.doi.org/10.1021/acscatal.9b01771.[8] Sun Jinwei, Wang Yujiang, Zou Haikui, Guo Xiaoguang, Wang Zhoujun. Ni catalysts supported on nanosheet and nanoplate γ-Al2O3 for carbon dioxide methanation. JOURNAL OF ENERGY CHEMISTRY[J]. 2019, 29(2): 3-7, http://lib.cqvip.com/Qikan/Article/Detail?id=84828190504849574850484850.[9] Sun, Jinwei, Wang, Yujiang, Zou, Haikui, Guo, Xiaoguang, Wang, Zhoujun. Ni catalysts supported on nanosheet and nanoplate gamma-Al2O3 for carbon dioxide methanation. JOURNAL OF ENERGY CHEMISTRY[J]. 2019, 29: 3-7, http://cas-ir.dicp.ac.cn/handle/321008/166456.[10] Ni, Wenpeng, Gao, Yang, Zhang, Yi, Younus, Hussein A, Guo, Xiaoguang, Ma, Chao, Zhang, Yan, Duan, Junfei, Zhang, Jiaheng, Zhang, Shiguo. O-Doping Boosts the Electrochemical Oxygen Reduction Activity of a Single Fe Site in Hydrophilic Carbon with Deep Mesopores. ACS APPLIED MATERIALS & INTERFACES[J]. 2019, 11(49): 45825-45831, https://www.webofscience.com/wos/woscc/full-record/WOS:000502689000048.[11] Shang, Jianpeng, Guo, Xiaoguang, Li, Zuopeng, Deng, Youquan. CO2 activation and fixation: highly efficient syntheses of hydroxy carbamates over Au/Fe2O3. GREEN CHEMISTRY[J]. 2016, 18(10): 3082-3088, http://www.irgrid.ac.cn/handle/1471x/1111699.[12] Wu, Haihua, Li, Haobo, Zhao, Xinfei, Liu, Qingfei, Wang, Jing, Xiao, Jianping, Xie, Songhai, Si, Rui, Yang, Fan, Miao, Shu, Guo, Xiaoguang, Wang, Guoxiong, Bao, Xinhe. Highly doped and exposed Cu(I)-N active sites within graphene towards efficient oxygen reduction for zinc-air batteries. ENERGY & ENVIRONMENTAL SCIENCE[J]. 2016, 9(12): 3736-3745, http://dx.doi.org/10.1039/c6ee01867j.[13] Changyong Sun, Guangzong Fang, Xiaoguang Guo, Yuanli Hu, Shuqi Ma, Tianhua Yang, Jie Han, Hao Ma, Dali Tan, Xinhe Bao. Methane dehydroaromatization with periodic CH4-H2 switch:A promising process for aromatics and hydrogen. 能源化学:英文版[J]. 2015, 24(3): 257-263, http://lib.cqvip.com/Qikan/Article/Detail?id=665016794.[14] 刘贡钢, 余林遇, 朱玉超, 郭晓光, 周永华, 叶红齐. 草簇状石墨烯片限域Pd纳米粒子及其催化应用. 催化学报[J]. 2015, 36(2): 148-152, http://lib.cqvip.com/Qikan/Article/Detail?id=663714957.[15] Liu Gonggang, Yu Linyu, Zhu Yuchao, Guo Xiaoguang, Zhou Yonghua, Ye Hongqi. 草簇状石墨烯片限域Pd纳米粒子及其催化应用. 催化学报[J]. 2015, 36(2): 148-152, http://lib.cqvip.com/Qikan/Article/Detail?id=663714957.[16] 包信和. A comparative study in structure and reactivity of "FeOx-on-Pt" and "NiOx-on-Pt" catalysts. SCIENCE CHINA CHEMISTRY[J]. 2015, 58(1): 162-168, https://www.webofscience.com/wos/woscc/full-record/WOS:000347697700018.[17] 包信和. Methane Dehydroaromatization with periodic CH4 - H2 switch: A Promising Process for Aromatics and Hydrogen. JOURNAL OF ENERGY CHEMISTRY[J]. 2015, 24(3): 257-263, http://dx.doi.org/10.1016/S2095-4956(15)60309-6.[18] 穆仁涛, 傅强, 郭晓光, 许学俊, 谭大力, 包信和. A comparative study in structure and reactivity of"FeOx-on-Pt" and "NiOx-on-Pt" catalysts . 中国科学 化学[J]. 2015, 58: 162, http://cas-ir.dicp.ac.cn/handle/321008/147838.[19] Liu, Gonggang, Yu, Linyu, Zhu, Yuchao, Guo, Xiaoguang, Zhou, Yonghua, Ye, Hongqi. Pd confined in grass-like graphene layers on monolithic cordierite as the catalyst for hydrogenation of 4-carboxybenzaldehyde. CHINESE JOURNAL OF CATALYSIS[J]. 2015, 36(2): 148-152, http://dx.doi.org/10.1016/S1872-2067(14)60256-4.[20] 郭晓光, 方光宗, 马昊, 于良, 潘秀莲, 包信和. Direct conversion of methane to ethylene with no oxidants. 2nd international conference on clean energy science. 2014, http://cas-ir.dicp.ac.cn/handle/321008/143515.[21] 郭晓光, GuangzongFang, 李刚, HaoMa, 樊红军, LiangYu, ChaoMa, XingWu, DehuiDeng, MingmingWei, DaliTan, RuiSi, ShuoZhang, JianqiLi, LitaoSun, 唐紫超, 潘秀莲, 包信和. Direct; Nonoxidative Conversion of Methane to Ethylene; Aromatics; and Hydrogen(合作). SCIENCE[J]. 2014, 344(6184): 616, http://cas-ir.dicp.ac.cn/handle/321008/143892.[22] Guo, Xiaoguang, Fang, Guangzong, Li, Gang, Ma, Hao, Fan, Hongjun, Yu, Liang, Ma, Chao, Wu, Xing, Deng, Dehui, Wei, Mingming, Tan, Dali, Si, Rui, Zhang, Shuo, Li, Jianqi, Sun, Litao, Tang, Zichao, Pan, Xiulian, Bao, Xinhe. Direct, nonoxidative conversion of methane to ethylene, aromatics, and hydrogen. Science[J]. 2014, 344(6184): 616-619, http://dx.doi.org/10.1126/science.1253150.[23] Fu, Qiang, Yao, Yunxi, Guo, Xiaoguang, Wei, Mingming, Ning, Yanxiao, Liu, Hongyang, Yang, Fan, Liu, Zhi, Bao, Xinhe. Reversible structural transformation of FeOx nanostructures on Pt under cycling redox conditions and its effect on oxidation catalysis. PHYSICAL CHEMISTRY CHEMICAL PHYSICS[J]. 2013, 15(35): 14708-14714, http://dx.doi.org/10.1039/c3cp52587b.[24] Ma, Shuqi, Guo, Xiaoguang, Zhao, Lingxiao, Scott, Susannah, Bao, Xinhe. Recent progress in methane dehydroaromatization: From laboratory curiosities to promising technology. JOURNAL OF ENERGY CHEMISTRY[J]. 2013, 22(1): 1-20, http://lib.cqvip.com/Qikan/Article/Detail?id=44987859.[25] Xu, Xuejun, Fu, Qiang, Guo, Xiaoguang, Bao, Xinhe. A Highly Active "NiO-on-Au" Surface Architecture for CO Oxidation. ACS CATALYSIS[J]. 2013, 3(8): 1810-1818, http://dx.doi.org/10.1021/cs400197t.[26] Guo, Xiaoguang, Fu, Qiang, Ning, Yanxiao, Wei, Mingming, Li, Mingrun, Zhang, Shuo, Jiang, Zheng, Bao, Xinhe. Ferrous Centers Confined on Core-Shell Nanostructures for Low-Temperature CO Oxidation. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2012, 134(30): 12350-12353, http://dx.doi.org/10.1021/ja3038883.[27] Xu, Hong, Fu, Qiang, Guo, Xiaoguang, Bao, Xinhe. Architecture of Pt-Co Bimetallic Catalysts for Catalytic CO Oxidation. CHEMCATCHEM[J]. 2012, 4(10): 1645-1652, http://dx.doi.org/10.1002/cctc.201200255.[28] 傅强, 郭晓光, 慕仁涛, 宁艳晓, 姚云喜, 徐红, 谭大力, 包信和. ″Oxide-on-metal″ catalytic systems for low temperature oxidation reactions: from model systems to supported nanocatalyts. 15TH INTERNATIONAL CONGRESS OF CATALYSIS. 2012, 141, http://159.226.238.44/handle/321008/117204.[29] Guo, Xiaoguang, Shang, Jianpeng, Li, Jian, Wang, Liguo, Ma, Yubo, Shi, Feng, Deng, Youquan. Green and Practical Synthesis of Carbamates from Ureas and Organic Carbonates. SYNTHETIC COMMUNICATIONS[J]. 2011, 41(8): 1102-1111, http://www.irgrid.ac.cn/handle/1471x/522799.[30] Mu, Rentao, Guo, Xiaoguang, Fu, Qiang, Bao, Xinhe. Oscillation of Surface Structure and Reactivity of PtNi Bimetallic Catalysts with Redox Treatments at Variable Temperatures. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2011, 115(42): 20590-20595, http://dx.doi.org/10.1021/jp206517r.[31] 慕仁涛, 傅强, 郭晓光, 谭大力, 包信和. The reactivity of Pt-Ni bimetellic catalysts modulated by alternating H2-O2 program. INTERNATIONAL CONFERENCE ON CLEAN ENERGY SCIENCE 2011. 2011, 153, http://159.226.238.44/handle/321008/117293.[32] 慕仁涛, 傅强, 郭晓光, 谭大力, 包信和. The reactivity of Pt-Ni bimetellic catalysts modulated by alternating H2-O2 program. ABSTRACT BOOK. 2011, 153-0, http://159.226.238.44/handle/321008/116122.[33] Guo Xiaoguang, Shang Jianpeng, Li Jian, Wang Liguo, Ma Yubo, Shi Feng, Deng Youquan. Atom-economy Synthesis of N-Substituted Carbamate from Urea Derivative and Dimethyl Carbonate Catalyzed by La/SiO2: Characterization and Activity. CHINESE JOURNAL OF CHEMISTRY[J]. 2010, 28(2): 164-170, http://www.irgrid.ac.cn/handle/1471x/522793.[34] Guo, Xiaoguang, Shang, Jianpeng, Ma, Xiangyuan, Li, Jian, Zhang, Hongzhe, Cui, ***, Shi, Feng, Deng, Youquan. Synthesis of dialkyl hexamethylene-1,6-dicarbamate from 1,6-hexamethylenediamine and alkyl carbamate over FeCl3 as catalyst. CATALYSIS COMMUNICATIONS[J]. 2009, 10(8): 1248-1251, http://dx.doi.org/10.1016/j.catcom.2009.01.031.[35] 张宏哲, 郭晓光, 张庆华, 马昱博, 邓友全. 非光气法制备1,6-己二氨基甲酸丁酯. 石油化工[J]. 2008, 37(10): 1064-1069, http://lib.cqvip.com/Qikan/Article/Detail?id=28427289.[36] Zhang, Hongzhe, Guo, Xiaoguang, Zhang, Qinghua, Ma, Yubo, Zhou, Hancheng, Li, Jian, Wang, Liguo, Deng, Youquan. Synthesis of dialkyl hexamethylenedicarbamate from 1,6-hexamethylenediamine and alkyl carbamate over Y(NO3)(3)center dot 6H(2)O catalyst. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL[J]. 2008, 296(1-2): 36-41, http://www.corc.org.cn/handle/1471x/2385523.
科研活动
科研项目
( 1 ) 界面限域的Pt基双组分催化体系在低温水汽变换过程中的研究, 负责人, 国家任务, 2012-01--2014-12( 2 ) 《乙炔法聚氯乙烯生产过程的高效、节能、减排科学基础 》课题三子课题, 参与, 国家任务, 2012-01--2016-12( 3 ) 甲烷无氧制乙烯、芳烃和氢气, 负责人, 中国科学院计划, 2013-06--2017-12( 4 ) 甲烷无氧制乙烯单铁活性中心的原位XAFS研究, 负责人, 国家任务, 2016-01--2018-12( 5 ) 微介孔复合分子筛限域的单分散Fe(Mo)催化体系无氧直接转化甲烷制乙烯, 负责人, 国家任务, 2015-01--2018-12( 6 ) 先进材料同步辐射 X 射线多维度原位研究平台, 参与, 国家任务, 2017-11--2022-07( 7 ) 等离子体强化煤裂解制高值化学品, 负责人, 中国科学院计划, 2022-03--2024-12