研究方向：

1.过渡金属配（簇）合物催化剂的合成与催化研究；

2.绿色化学CO₂气体的催化转化；

3.金属有机催化有机小分子的活化与转化。

　　本课题组主要开展过渡金属配位化学、金属有机催化化学和有机小分子活化与催化等方向的研究，开发以过渡金属配合物为主的新型配合物催化剂，用于活化气体小分子和有机小分子，生成有经济价值的化学品；并且此研究基础上，探索反应机理，开展设计合成金属配合物催化剂，催化合成药物化学品的研究。

070301-无机化学
070303-有机化学

过渡金属配（簇）合物催化剂的合成与催化研究；
绿色化学CO2气体的催化转化；
金属有机催化有机小分子的活化与转化

2004-09--2008-07   英国诺丁汉大学化学系   博士
2000-09--2003-07   中科院福建物质结构研究所   硕士
1995-09--1999-07   武汉大学化学系   学士

博士研究生

理学博士

   

2012-08~现在, 中国科学院福建物质结构研究所, 研究员
2008-03~2012-08,美国哈佛大学化学与生物化学系, 博士后
1999-10~2004-07,中国科学院福建物质结构研究所, 研究实习员

   

（ 1 ） 一种三苯基膦烯丙基卤化钯化合物及其衍生物的制备和应用, 专利授权, 2020, 第 1 作者, 专利号: CN111116666B

（ 2 ） 一种1-(2-吡啶基)-吡唑-3-甲酸及其衍生物的合成方法, 专利授权, 2020, 第 1 作者, 专利号: CN109369617B

（ 3 ） 一种稠环吡啶化合物及其衍生物的制备和应用, 发明专利, 2022, 第 1 作者, 专利号: ZL202111076421.9

（1） Iodine-Mediated Heterocyclization for Synthesis of Alkylthio-1,3,5-triazine from N-alkylpyridinium Salts and NH4SCN, The Journal of Organic Chemistry, 2024, 通讯作者
（2） Direct transformation of nitriles to cyanide using chloride anion as catalyst, Chemical Communications, 2024, 通讯作者
（3） π-Extension of Indoles Using Acrolein Linker: Synthesis of Indolo[3,2-a]carbazole-6-carbaldehydes and Racemosin B, Organic Letters, 2023, 通讯作者
（4） Copper-Catalyzed Oxidative [3 + 2] Cycloaddition of N-Alkyl Pyri-dinium Salts to Imidazo[1,2 a]pyridines, The Journal of Organic Chemistry, 2023, 通讯作者
（5） Iodine-Mediated Pyridine Ring Expansion for the Construction of Azepines, ORGANIC LETTERS, 2022, 通讯作者
（6） Copper(II)-Catalyzed Selective CAr-H Bond Formylation: Synthesis of Dialdehyde Aniline, Frontiers in Chemistry, 2022, 通讯作者
（7） Solvent-Free Strategy for Direct Access to Versatile Quaternary Ammonium Salts with Complete Atom Economy, ChemSusChem, 2022, 通讯作者
（8） Synthesis of methylene-bridged α,β-unsaturated ketones: α-Csp3–H methylenation of aromatic ketones using Selectfluor as a mild oxidant, Org. Biomol. Chem, 2022, 通讯作者
（9） Copper(II)-Dioxygen Facilitated Activation of Nitromethane: Nitrogen Donors for the Synthesis of Substituted 2-Hydroxyimino-2-phenylacetonitriles and Phthalimides, FRONTIERS IN CHEMISTRY, 2021, 通讯作者
（10） Selectfluor facilitated bridging of indoles to bis(indolyl)methanes using methyl tert-butyl ether as a new methylene precursor, ORGANIC & BIOMOLECULAR CHEMISTRY, 2021, 通讯作者
（11） A three-component iodine-catalyzed oxidative coupling reaction: a heterodifunctionalization of 3-methylindoles, ORGANIC & BIOMOLECULAR CHEMISTRY, 2021, 通讯作者
（12） Aqueous CO2 fixation: construction of pyridine skeletons in cooperation with ammonium cations, GREEN CHEMISTRY, 2021, 通讯作者
（13） Copper(II)-hydroxide facilitated C-C bond formation: the carboxamido pyridine system versus the methylimino pyridine system, DALTON TRANSACTIONS, 2020, 通讯作者
（14） Temperature controlled condensation of nitriles: efficient and convenient synthesis of beta-enaminonitriles, 4-aminopyrimidines and 4-amidinopyrimidines in one system, RSC ADVANCES, 2020, 通讯作者
（15） Temperature controlled condensation of nitriles: efficient and convenient synthesis of benaminonitriles, 4-aminopyrimidines and 4- amidinopyrimidines in one system, RSC Advance, 2020, 通讯作者
（16） Utilization of nitriles as the nitrogen source: practical and economical construction of 4-aminopyrimidine and beta-enaminonitrile skeletons, ORGANIC CHEMISTRY FRONTIERS, 2019, 通讯作者
（17） Copper(II) facilitated decarboxylation for the construction of pyridyl-pyrazole skeletons, INORGANIC CHEMISTRY FRONTIERS, 2019, 通讯作者
（18） Real-time monitoring of intracellular nitric oxide using a long-wavelength-emitting probe via one-photon or two-photon excitation, JOURNAL OF MATERIALS CHEMISTRY C, 2019, 通讯作者
（19） Base induced C-CN bond cleavage at room temperature: a convenient method for the activation of acetonitrile, INORGANIC CHEMISTRY FRONTIERS, 2019, 通讯作者
（20） Nickel-catalyzed direct formation of the C-S bonds of aryl sulfides from arylsulfonyl chlorides and aryl iodides using Mn as a reducing agent, ORGANIC CHEMISTRY FRONTIERS, 2017, 通讯作者
（21） Experimental and mechanistic insights into copper(II)-dioxygen catalyzed oxidative N-dealkylation of N-(2-pyridylmethyl)phenylamine and its derivatives, ORGANIC & BIOMOLECULAR CHEMISTRY, 2017, 通讯作者
（22） Experimental and mechanistic insights into copper(II)–dioxygen catalyzed oxidative N-dealkylation of N-(2-pyridylmethyl)phenylamine and its derivativesinsights into copper(II)–dioxygen catalyzed oxidative, Org. Biomol. Chem., 2017, 第 1 作者
（23） Syntheses and Crystal Structures of the First Row Transition Metals with 1,6-Bis(2＇-pyridyl)-2,5-dithiahexane, Syntheses and Crystal Structures of the First Row Transition Metals with 1,6-Bis(2＇-pyridyl)-2,5-dithiahexane, 结构化学, 2016, 第 5 作者
（24） Five-heterocyclic-biphosphinesubstituted Fe-only Hydrogenase Mimic: Synthesis, Characterization and Properties, CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 第 4 作者
（25） Syntheses and Crystal Structures of the First Row Transition Metals with 1，6-Bis（2’-pyridyl）-2，5-dithiahexane简, 结构化学, 2016, 第 5 作者
（26） Synthesis and mechanism study of a dimeric tetranuclear carbonate-bridged copper(II) complex resulting from CO2 fixation by controlling O2 concentration, INORGANIC CHEMISTRY COMMUNICATIONS, 2016, 通讯作者
（27） Syntheses and Crystal Structures of the First Row Transition Metals with 1,6-Bis(2’-pyridyl)-2,5-dithiahexane, CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 第 5 作者
（28） Five-heterocyclic-biphosphine-substituted Fe-only Hydrogenase Mimic: Synthesis,Characterization and Properties, Five-heterocyclic-biphosphine-substituted Fe-only Hydrogenase Mimic: Synthesis,Characterization and Properties, 结构化学, 2016, 第 4 作者
（29） Synthesis of a Hexagonal Molecular Nickel-wheel, Synthesis of a Hexagonal Molecular Nickel-wheel, CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 通讯作者
（30） Synthesis of a Hexagonal Molecular Nickel-wheel, Synthesis of a Hexagonal Molecular Nickel-wheel, 结构化学, 2015, 第 6 作者
（31） Thermodynamics and high-pressure kinetics of a fast carbon dioxide fixation reaction by a (2,6-pyridinedicarboxamidato-hydroxo) nickel(II) complex, DALTON TRANSACTIONS, 2014, 
（32） Activation of Nitromethane to Cyanide by a Mononuclear Cu(Ⅱ) Complex, Activation of Nitromethane to Cyanide by a Mononuclear Cu(Ⅱ) Complex, 结构化学, 2014, 第 3 作者
（33） Activation of Nitromethane to Cyanide by a Mononuclear Cu(II) Complex, CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 通讯作者
（34） Synthesis of Binucleating Macrocycles and their Nickel(II) Hydroxo- and Cyano-Bridged Complexes with Divalent Ions: Anatomical Variation of Ligand Features, INORGANIC CHEMISTRY, 2012, 第 2 作者
（35） Kinetics and mechanistic analysis of an extremely rapid carbon dioxide fixation reaction, PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2011, 第 1 作者
（36） Fast Carbon Dioxide Fixation by 2,6-Pyridinedicarboxamidato-nickel(II)-hydroxide Complexes: Influence of Changes in Reactive Site Environment on Reaction Rates, INORGANIC CHEMISTRY, 2011, 第 1 作者
（37） Redox Non-Innocence of Thioether Crowns: Spectroelectrochemistry and Electronic Structure of Formal Nickel(III) Complexes of Aza-Thioether Macrocycles, CHEMISTRY-A EUROPEAN JOURNAL, 2011, 第 2 作者
（38） Reactions of the Terminal Ni II –OH Group in Substitution and Electrophilic Reactions with Carbon Dioxide and Other Substrates: Structural Definition of Binding Modes in an Intramolecular Ni II …Fe II Bridged Site, Journal of the American Chemical Society, 2010, 第 1 作者
（39） Cleavage of Ni-S-Ni Bridges in Dinuclear Nickel(II) Dithiolate Pincer Complexes and Related Reactions, Inorg. Chem., 2009, 第 1 作者
（40） Crystallographic, Electrochemical, and Electronic Structure Studies of the Mononuclear Complexes of Au(I)/(II)/(III) with 9aneS(2)O (9aneS(2)O=1-oxa-4,7-dithiacyclononane), INORGANIC CHEMISTRY, 2008, 第 1 作者
（41） Electronic structure of the mononuclear Ag(II) complex Ag(18aneS(4)O(2))(2+) (18aneS(4)O(2)=1,10-dioxa-4,7,13,16-tetrathiacyclooctadecane), CHEMICAL COMMUNICATIONS, 2008, 第 1 作者
（42） Synthesis and Structure of a New Dimanganese Complex Mn2(μ-OAc)2(phen)4(ClO4)2, Synthesis and Structure of a New Dimanganese Complex Mn2(μ-OAc)2(phen)4(ClO4)2, 结构化学, 2006, 第 3 作者
（43） Synthesis and Strutural Characterization of {Mn(phen)2(OAc)(H2O)ClO4}2.H2O, Synthesis and Strutural Characterization of {Mn(phen)2(OAc)(H2O)ClO4}2.H2O, 结构化学, 2003, 第 3 作者
（44） Synthesis and Structural Characterization of Mn(phen)2(H2O)2(OAc)2.6H2O, Synthesis and Structural Characterization of Mn(phen)2(H2O)2(OAc)2·6H2O, 结构化学, 2003, 第 2 作者
（45） 模拟Mn酶活性中心的簇（配）合物的合成、结构及性质研究, 2003, 第 1 作者
（46） Synthesis and Structural Characterization of Mononuclear Mn~(II) Picolilato Complex Mn(2-C_5H_4NCOO)_2(H_2O)_2·1/2CH_3CN, Chinese Journal of Structural Chemistry, 2002, 第 2 作者

（1） 专章： Cluster Compounds, 书名： Modern Inorganic Synthetic Chemistr, Elsevier, 2017-07, 第 2 作者

   

（ 1 ） ****, 主持, 市地级, 2012-09--2015-09
（ 2 ） 国家基金面上项目, 主持, 国家级, 2014-01--2017-12

已指导学生

刘海雄  硕士研究生  085216-化学工程  

陈帅  硕士研究生  070301-无机化学  

汤昌泉  博士研究生  070303-有机化学  

现指导学生

相仕群  博士研究生  070301-无机化学  

范伟斌  博士研究生  070301-无机化学  

郭世维  硕士研究生  085204-材料工程