基本信息

黄德光  男  博导  中国科学院福建物质结构研究所

1999年武汉大学有机化学学士学位;19992004物构所学习与工作,从事生物酶锰簇化合物的合成与性质研究,2003年物构所物理化学硕士学位,导师刘秋田和陈昌能研究员;20042008英国The University of Nottingham无机化学博士学位,导师Prof. Martin Schroder,从事不常见价态Ag(II), Au(II), Ni(III)等大环硫醚化合物的合成、电化学、及最外层单电子的电子顺磁共振(EPR)研究。20082012美国Harvard University化学与化学生物系博士后,导师Prof. R. H. Holm,从事一氧化碳脱氢酶[Ni-OH-Fe]活性点的结构模拟与化学合成,以及二氧化碳的活化研究。2012/08现在,承担中科院海西研究院“****”和国家科学基金项目,在物构所开展过渡金属配合物催化剂合成、配合物活化气体小分子、金属有机催化等研究工作。目前已经在PNAS, J.Am.Chem.Soc., Green Chemistry, ChemSusChem, Org.Lett., Chem.Commun., Inorg.Chem., Inorg.Chem.Front. Org.Chem.Front.等国际化学刊物上以发表论文多篇。

电子邮件: dhuang@fjirsm.ac.cn
通信地址: 福州市杨桥西路155号化学楼911室
邮政编码: 350002

研究领域

研究方向:

1.过渡金属配(簇)合物催化剂的合成与催化研究;

2.绿色化学CO2气体的催化转化;

3.金属有机催化有机小分子的活化与转化。


招生信息

  本课题组主要开展过渡金属配位化学、金属有机催化化学和有机小分子活化与催化等方向的研究,开发以过渡金属配合物为主的新型配合物催化剂,用于活化气体小分子和有机小分子,生成有经济价值的化学品;并且此研究基础上,探索反应机理,开展设计合成金属配合物催化剂,催化合成药物化学品的研究。

招生专业
070301-无机化学
070303-有机化学
招生方向
过渡金属配(簇)合物催化剂的合成与催化研究;
绿色化学CO2气体的催化转化;
金属有机催化有机小分子的活化与转化

教育背景

2004-09--2008-07   英国诺丁汉大学化学系   博士
2000-09--2003-07   中科院福建物质结构研究所   硕士
1995-09--1999-07   武汉大学化学系   学士
学历
博士研究生
学位
理学博士

工作经历

   
工作简历
2012-08~现在, 中国科学院福建物质结构研究所, 研究员
2008-03~2012-08,美国哈佛大学化学与生物化学系, 博士后
1999-10~2004-07,中国科学院福建物质结构研究所, 研究实习员

专利与奖励

   
专利成果
( 1 ) 一种三苯基膦烯丙基卤化钯化合物及其衍生物的制备和应用, 专利授权, 2020, 第 1 作者, 专利号: CN111116666B

( 2 ) 一种1-(2-吡啶基)-吡唑-3-甲酸及其衍生物的合成方法, 专利授权, 2020, 第 1 作者, 专利号: CN109369617B

( 3 ) 一种稠环吡啶化合物及其衍生物的制备和应用, 发明专利, 2022, 第 1 作者, 专利号: ZL202111076421.9

出版信息


发表论文
(1) Iodine-Mediated Heterocyclization for Synthesis of Alkylthio-1,3,5-triazine from N-alkylpyridinium Salts and NH4SCN, The Journal of Organic Chemistry, 2024, 通讯作者
(2) Direct transformation of nitriles to cyanide using chloride anion as catalyst, Chemical Communications, 2024, 通讯作者
(3) π-Extension of Indoles Using Acrolein Linker: Synthesis of Indolo[3,2-a]carbazole-6-carbaldehydes and Racemosin B, Organic Letters, 2023, 通讯作者
(4) Copper-Catalyzed Oxidative [3 + 2] Cycloaddition of N-Alkyl Pyri-dinium Salts to Imidazo[1,2 a]pyridines, The Journal of Organic Chemistry, 2023, 通讯作者
(5) Iodine-Mediated Pyridine Ring Expansion for the Construction of Azepines, ORGANIC LETTERS, 2022, 通讯作者
(6) Copper(II)-Catalyzed Selective CAr-H Bond Formylation: Synthesis of Dialdehyde Aniline, Frontiers in Chemistry, 2022, 通讯作者
(7) Solvent-Free Strategy for Direct Access to Versatile Quaternary Ammonium Salts with Complete Atom Economy, ChemSusChem, 2022, 通讯作者
(8) Synthesis of methylene-bridged α,β-unsaturated ketones: α-Csp3–H methylenation of aromatic ketones using Selectfluor as a mild oxidant, Org. Biomol. Chem, 2022, 通讯作者
(9) Copper(II)-Dioxygen Facilitated Activation of Nitromethane: Nitrogen Donors for the Synthesis of Substituted 2-Hydroxyimino-2-phenylacetonitriles and Phthalimides, FRONTIERS IN CHEMISTRY, 2021, 通讯作者
(10) Selectfluor facilitated bridging of indoles to bis(indolyl)methanes using methyl tert-butyl ether as a new methylene precursor, ORGANIC & BIOMOLECULAR CHEMISTRY, 2021, 通讯作者
(11) A three-component iodine-catalyzed oxidative coupling reaction: a heterodifunctionalization of 3-methylindoles, ORGANIC & BIOMOLECULAR CHEMISTRY, 2021, 通讯作者
(12) Aqueous CO2 fixation: construction of pyridine skeletons in cooperation with ammonium cations, GREEN CHEMISTRY, 2021, 通讯作者
(13) Copper(II)-hydroxide facilitated C-C bond formation: the carboxamido pyridine system versus the methylimino pyridine system, DALTON TRANSACTIONS, 2020, 通讯作者
(14) Temperature controlled condensation of nitriles: efficient and convenient synthesis of beta-enaminonitriles, 4-aminopyrimidines and 4-amidinopyrimidines in one system, RSC ADVANCES, 2020, 通讯作者
(15) Temperature controlled condensation of nitriles: efficient and convenient synthesis of benaminonitriles, 4-aminopyrimidines and 4- amidinopyrimidines in one system, RSC Advance, 2020, 通讯作者
(16) Utilization of nitriles as the nitrogen source: practical and economical construction of 4-aminopyrimidine and beta-enaminonitrile skeletons, ORGANIC CHEMISTRY FRONTIERS, 2019, 通讯作者
(17) Copper(II) facilitated decarboxylation for the construction of pyridyl-pyrazole skeletons, INORGANIC CHEMISTRY FRONTIERS, 2019, 通讯作者
(18) Real-time monitoring of intracellular nitric oxide using a long-wavelength-emitting probe via one-photon or two-photon excitation, JOURNAL OF MATERIALS CHEMISTRY C, 2019, 通讯作者
(19) Base induced C-CN bond cleavage at room temperature: a convenient method for the activation of acetonitrile, INORGANIC CHEMISTRY FRONTIERS, 2019, 通讯作者
(20) Nickel-catalyzed direct formation of the C-S bonds of aryl sulfides from arylsulfonyl chlorides and aryl iodides using Mn as a reducing agent, ORGANIC CHEMISTRY FRONTIERS, 2017, 通讯作者
(21) Experimental and mechanistic insights into copper(II)-dioxygen catalyzed oxidative N-dealkylation of N-(2-pyridylmethyl)phenylamine and its derivatives, ORGANIC & BIOMOLECULAR CHEMISTRY, 2017, 通讯作者
(22) Experimental and mechanistic insights into copper(II)–dioxygen catalyzed oxidative N-dealkylation of N-(2-pyridylmethyl)phenylamine and its derivativesinsights into copper(II)–dioxygen catalyzed oxidative, Org. Biomol. Chem., 2017, 第 1 作者
(23) Syntheses and Crystal Structures of the First Row Transition Metals with 1,6-Bis(2'-pyridyl)-2,5-dithiahexane, Syntheses and Crystal Structures of the First Row Transition Metals with 1,6-Bis(2'-pyridyl)-2,5-dithiahexane, 结构化学, 2016, 第 5 作者
(24) Five-heterocyclic-biphosphinesubstituted Fe-only Hydrogenase Mimic: Synthesis, Characterization and Properties, CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 第 4 作者
(25) Syntheses and Crystal Structures of the First Row Transition Metals with 1,6-Bis(2’-pyridyl)-2,5-dithiahexane简, 结构化学, 2016, 第 5 作者
(26) Synthesis and mechanism study of a dimeric tetranuclear carbonate-bridged copper(II) complex resulting from CO2 fixation by controlling O2 concentration, INORGANIC CHEMISTRY COMMUNICATIONS, 2016, 通讯作者
(27) Syntheses and Crystal Structures of the First Row Transition Metals with 1,6-Bis(2’-pyridyl)-2,5-dithiahexane, CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 第 5 作者
(28) Five-heterocyclic-biphosphine-substituted Fe-only Hydrogenase Mimic: Synthesis,Characterization and Properties, Five-heterocyclic-biphosphine-substituted Fe-only Hydrogenase Mimic: Synthesis,Characterization and Properties, 结构化学, 2016, 第 4 作者
(29) Synthesis of a Hexagonal Molecular Nickel-wheel, Synthesis of a Hexagonal Molecular Nickel-wheel, CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 通讯作者
(30) Synthesis of a Hexagonal Molecular Nickel-wheel, Synthesis of a Hexagonal Molecular Nickel-wheel, 结构化学, 2015, 第 6 作者
(31) Thermodynamics and high-pressure kinetics of a fast carbon dioxide fixation reaction by a (2,6-pyridinedicarboxamidato-hydroxo) nickel(II) complex, DALTON TRANSACTIONS, 2014, 
(32) Activation of Nitromethane to Cyanide by a Mononuclear Cu(Ⅱ) Complex, Activation of Nitromethane to Cyanide by a Mononuclear Cu(Ⅱ) Complex, 结构化学, 2014, 第 3 作者
(33) Activation of Nitromethane to Cyanide by a Mononuclear Cu(II) Complex, CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 通讯作者
(34) Synthesis of Binucleating Macrocycles and their Nickel(II) Hydroxo- and Cyano-Bridged Complexes with Divalent Ions: Anatomical Variation of Ligand Features, INORGANIC CHEMISTRY, 2012, 第 2 作者
(35) Kinetics and mechanistic analysis of an extremely rapid carbon dioxide fixation reaction, PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2011, 第 1 作者
(36) Fast Carbon Dioxide Fixation by 2,6-Pyridinedicarboxamidato-nickel(II)-hydroxide Complexes: Influence of Changes in Reactive Site Environment on Reaction Rates, INORGANIC CHEMISTRY, 2011, 第 1 作者
(37) Redox Non-Innocence of Thioether Crowns: Spectroelectrochemistry and Electronic Structure of Formal Nickel(III) Complexes of Aza-Thioether Macrocycles, CHEMISTRY-A EUROPEAN JOURNAL, 2011, 第 2 作者
(38) Reactions of the Terminal Ni II –OH Group in Substitution and Electrophilic Reactions with Carbon Dioxide and Other Substrates: Structural Definition of Binding Modes in an Intramolecular Ni II …Fe II Bridged Site, Journal of the American Chemical Society, 2010, 第 1 作者
(39) Cleavage of Ni-S-Ni Bridges in Dinuclear Nickel(II) Dithiolate Pincer Complexes and Related Reactions, Inorg. Chem., 2009, 第 1 作者
(40) Crystallographic, Electrochemical, and Electronic Structure Studies of the Mononuclear Complexes of Au(I)/(II)/(III) with 9aneS(2)O (9aneS(2)O=1-oxa-4,7-dithiacyclononane), INORGANIC CHEMISTRY, 2008, 第 1 作者
(41) Electronic structure of the mononuclear Ag(II) complex Ag(18aneS(4)O(2))(2+) (18aneS(4)O(2)=1,10-dioxa-4,7,13,16-tetrathiacyclooctadecane), CHEMICAL COMMUNICATIONS, 2008, 第 1 作者
(42) Synthesis and Structure of a New Dimanganese Complex Mn2(μ-OAc)2(phen)4(ClO4)2, Synthesis and Structure of a New Dimanganese Complex Mn2(μ-OAc)2(phen)4(ClO4)2, 结构化学, 2006, 第 3 作者
(43) Synthesis and Strutural Characterization of {Mn(phen)2(OAc)(H2O)ClO4}2.H2O, Synthesis and Strutural Characterization of {Mn(phen)2(OAc)(H2O)ClO4}2.H2O, 结构化学, 2003, 第 3 作者
(44) Synthesis and Structural Characterization of Mn(phen)2(H2O)2(OAc)2.6H2O, Synthesis and Structural Characterization of Mn(phen)2(H2O)2(OAc)2·6H2O, 结构化学, 2003, 第 2 作者
(45) 模拟Mn酶活性中心的簇(配)合物的合成、结构及性质研究, 2003, 第 1 作者
(46) Synthesis and Structural Characterization of Mononuclear Mn~(II) Picolilato Complex Mn(2-C_5H_4NCOO)_2(H_2O)_2·1/2CH_3CN, Chinese Journal of Structural Chemistry, 2002, 第 2 作者
发表著作
(1) 专章: Cluster Compounds, 书名: Modern Inorganic Synthetic Chemistr, Elsevier, 2017-07, 第 2 作者

科研活动

   
科研项目
( 1 ) ****, 主持, 市地级, 2012-09--2015-09
( 2 ) 国家基金面上项目, 主持, 国家级, 2014-01--2017-12

指导学生

已指导学生

刘海雄  硕士研究生  085216-化学工程  

陈帅  硕士研究生  070301-无机化学  

汤昌泉  博士研究生  070303-有机化学  

现指导学生

相仕群  博士研究生  070301-无机化学  

范伟斌  博士研究生  070301-无机化学  

郭世维  硕士研究生  085204-材料工程