General

Hao Du, Doctoral Supervisor, Full professor of Institute of Process Engineering, CAS

E-mail address: hdu@ipe.ac.cn
Address: Zhongguancun Beiertiao 1hao, Haidian, Beijing, China
Zip code:100190​

Research Areas

(1) Hydrometallurgy

(2) Surface chemistry

(3) Green chemical process design 

(4) Electrochemistry

(5) Advanced oxidation process 

Education

2002-09--2007-11   The University of Utah  (Ph.D)
2000-09--2002-08   South Dakota School of Mines and Technology (MD)
1993-09--1997-06   University of Science & Technology Beijing  (Bachelor)

Publications

Papers

(1) Self-ancho ring dendritic ternary vanadate compound on graphene nanoflake as high-performance conversion-type anode for lithium ion batteries, Nano Energy, 2016, 通讯作者
(2) Vibrational spectra and molecular dynamics of hydrogen peroxide molecules at quartz/water interfaces, Journal of Molecular Structure, 2016, 通讯作者
(3) The electrowinning of vanadium oxide from alkaline solution, Hydrometallurgy, 2016, 通讯作者
(4) The surface of lead activation in amyl xanthate flotation of quartz, International Journal of Mineral Processing, 2016, 通讯作者
(5) Electrochemical processes for the environmental remediation of toxic Cr(VI): A review, Electrochimica Acta, 2016, 第 2 作者
(6) Tuning ɑ-Fe2O3 nanotube arrays for the oxygen reduction reaction in alkaline media, RSC Advances, 2016, 第 3 作者
(7) Electrochemical Cr(III) Oxidation and Mobilization by In Situ Generated Reactive Oxygen Species in Alkaline Solution, Journal of The Electrochemical Society, 2016, 第 3 作者
(8) Solubility investigations in the NaOH-Na3VO4-Na2CrO4-Na2CO3-H2O at (40 and 80) ℃, Fluid Phase Equlib, 2016, 第 3 作者
(9) Scalable and template-free synthesis of nanostructured Na1.08V6O15 as high-performance cathode material for lithium-ion batteries, Materials Research Bulletin, 2016, 第 4 作者
(10) Reactive extraction of sodium hydroxide from alkali solutions for the separation of sodium and aluminum - Part I. Effect of extractant, Hydrometallurgy, 2015, 第 4 作者
(11) Structure and Diffusivity of Oxygen in Concentrated Alkali Hydroxide Solutions: A Molecular Dynamics Simulation Study, Acta Phys. Chim. Sin., 2015, 通讯作者
(12) Reactive extraction of sodium hydroxide from alkali solutions for the separation of sodium and aluminum — Part II. Effect of diluent, Hydrometallurgy, 2015, 通讯作者
(13) Electrochemical decomposition of vanadium slag in concentrated NaOH solution, Hydrometallurgy, 2015, 通讯作者
(14) The influence of KOH concentration, oxygen partial pressure and temperature on the oxygen reduction reaction at Pt electrodes, Journal of Electroanalytical Chemistry, 2015, 通讯作者
(15) Template-free synthesis of Na0.95V3O8 nanobelts with improved cycleability as high-rate cathode material for rechargeable lithium ion batteries, Ceramics International, 2015, 第 2 作者
(16) Flotation chemistry of soluble salt minerals: From ion hydration to colloid adsorption, Minerals and Metallurgical Processing, 2014, 第 1 作者
(17) Additive-free synthesis of V4O7 hierarchical structures as high performance      cathodes for lithium ion batteries, Chem Commun (Camb), 2014, 通讯作者
(18) Hollow carbon nanofiber as stabilizer for in-situ TiO2/VO2 co-impregnation with high rate performance and ultra-long cycling life as lithium-ion battery anode, Journal of Materials Chemistry A, 2014, 通讯作者
(19) Research and prospect on extraction of vanadium from vanadium slag by liquid oxidation technologies, Trans. Nonferrous Met. Soc. China, 2014, 通讯作者
(20) Effect of Alkali Concentration, Oxygen Partial Pressure and Temperature on Oxygen Reduction Reaction on Pt Electrode in NaOH Solution, Acta Physico - Chimica Sinica, 2014, 通讯作者
(21) 钒渣焙烧-水热碱浸提钒, 过程工程学报, 2014, 通讯作者
(22) Surface Chemistry Aspects of Bastnaesite Flotation with Octyl Hydroxamate, International Journal of Mineral Processing, 2014, 第 2 作者
(23) A new metallurgical process for the clean utilization of chromite ore, International Journal of Mineral Processing, 2014, 第 4 作者
(24) Re: Vanadium exposure-induced neurobehavioral alterations among Chinese workers Li et al, NeuroToxicology, 2014, 第 2 作者
(25) Extraction technology of vanadium and chromium from vanadium slags in presence of activated carbon, Chinese Journal of Nonferrous Metals, 2014, 通讯作者
(26) Mechanism of vanadium extraction from vanadium-bearing slags using alkaline hydrothermal process, Chinese Journal of Nonferrous Metals, 2014, 通讯作者
(27) 亚熔盐法高铬钒渣钒铬高效同步提取工艺研究, 钢铁钒钛, 2014, 通讯作者
(28) Molecular features of water films created with bubbles at silica surfaces, Surface Innovations, 2014, 第 4 作者
(29) A clean and efficient leaching process for chromite ore, Minerals Engineering, 2014, 第 3 作者
(30) Electrochemical enhanced oxidative decomposition of chromite ore in highly concentrated KOH solution, Minerals Engineering, 2014, 第 2 作者
(31) 40℃和70℃下三元体系NH4HCO3-NH4VO3-H2O中NH4HCO3溶解度的测定, 化工进展, 2014, 第 4 作者
(32) NaOH溶液中碱浓度、氧气压力以及温度对Pt电极上氧气还原反应的影响, 物理化学学报, 2014, 通讯作者
(33) 活性炭强化钒渣中钒、铬提取技术, 中国有色金属学报, 2014, 第 3 作者
(34) Application of METSIM in Process Design of the Cleaner Chromate Production Using Sub-molten Salt, International Journal of Bio-Science and Bio-Technology, 2013, 通讯作者
(35) Thermal hydrolysis synthesis and characterization of monoclinic metahewettite CaV6O16.3H2O, Journal of Wuhan University of Technology (Materials Science Edition), 2013, 通讯作者
(36) Kinetics analysis of decomposition of vanadium slag by KOH sub-molten salt method, Transactions of Nonferrous Metals Society of China, 2013, 通讯作者
(37) METSIM在亚熔盐法钒渣清洁生产工艺流程设计中的应用, 过程工程学报, 2013, 通讯作者
(38) METSIM在亚熔盐铬盐清洁生产工艺流程设计中的应用, 过程工程学报, 2013, 通讯作者
(39) Solubility Investigations in the Quaternary NaOH-Na3VO4-Na2CrO4-H2O System at (40 and 80), Fluid Phase Equilibria, 2013, 第 4 作者
(40) An investigation on the kinetics of chromium dissolution from Philippine chromite ore at high oxygen pressure in KOH sub-molten salt solution, Hydrometallurgy, 2013, 通讯作者
(41) A novel method to extract vanadium and chromium from vanadium slag using molten NaOH-NaNO3 binary system, AICHE Journal, 2013, 第 2 作者
(42) Surface chemistry considerations in the flotation of rare-earth and other semisoluble salt minerals, Minerals and Metallurgical Processing, 2013, 第 2 作者
(43) Solubility data for the KOH-K2CO3-K3VO4-H2O system at (313.15 and 353.15) K, Journal of Chemical and Engineering Data, 2013, 第 2 作者
(44) Solubility data for the quaternary KOH-K3VO4-K2CrO4-H2O system at (40 and 80) ℃,  Journal of Chemical and Engineering Data, 2013, 第 2 作者
(45) 钒酸钾钙化沉钒法制备钒酸钙的研究, 过程工程学报, 2013, 第 4 作者
(46) 钒渣中钒铬提取技术研究进展, 矿产综合利用, 2013, 第 4 作者
(47) 钙掺杂钒青铜超级电容器电极材料的制备及其性能, 过程工程学报, 2013, 通讯作者
(48) 钒渣在KOH亚熔盐介质中的溶出行为, 中国有色金属学报, 2013, 第 2 作者
(49) Comparison Study of the Electrochemical Behavior of Vanadate in NaOH and KOH Solutions, Advanced Materials Research, 2012, 通讯作者
(50) A novel method of leaching vanadium from extracted vanadium residue using sodium sub-molten salt medium, Advanced Materials Research, 2012, 通讯作者
(51) The Application of METSIM in Hydrometallurgy Process: A Case Study, Advanced Materials Research, 2012, 通讯作者
(52) The redox behavior of vanadium in alkaline solutions by cyclic voltammetry method, Electrochimica Acta, 2012, 通讯作者
(53) Indirect Electrochemical Cr(III) Oxidation in KOH Solutions at an Au Electrode: The Role of Oxygen Reduction Reaction, Journal of Physical Chemistry B, 2012, 通讯作者
(54) Surface charge and wetting characteristics of layered silicate minerals, Advances in Colloid and Interface Science, 2012, 第 3 作者
(55) Equilibrium Data of the KOH-K3VO4-Ca(OH)2-H2O System at (313.2 and 353.2) K, Journal of Chemical and Engineering Data, 2012, 第 3 作者
(56) The anisotropic characteristics of natural fibrous sepiolite as revealed by contact angle, surface free energy, AFM and molecular dynamics simulation, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2012, 第 2 作者
(57) Effect of lithium ions on copper nanoparticle size, shape, and distribution, Journal of Nanotechnology, 2012, 第 4 作者
(58) KOH介质多元体系中铬酸钾与钒酸钾的高效结晶分离, 过程工程学报, 2012, 第 3 作者
(59) 新型钒材料研究进展, 钢铁钒钛, 2012, 第 3 作者
(60) 亚熔盐法钒渣高效清洁提钒技术, 钢铁钒钛, 2012, 第 2 作者
(61) 钒渣NaOH亚熔盐法提钒工艺研究, 中国稀土学报, 2012, 通讯作者
(62) Modulated Cr(III) oxidation in KOH solutions at a gold electrode: Competition between disproportionation and stepwise electron transfer, Electrochimica Acta, 2011, 通讯作者
(63) Solubility in the Quaternary Na2O-V2O5-CaO-H2O System at (40 and 80) degrees C, Journal of Chemical and Engineering Data, 2011, 第 2 作者
(64) Understanding the role of ion interactions in soluble salt flotation with alkylammonium and alkylsulfate collectors, Advances in Colloid and Interface Science, 2011, 第 2 作者
(65) Molecular dynamics simulations of metal-cyanide complexes: Fundamental considerations in gold hydrometallurgy, Hydrometallurgy, 2011, 第 3 作者
(66) 含钒尾渣NaOH亚熔盐浸出提钒, 过程工程学报, 2011, 第 4 作者
(67) 含钒钢渣中钒在KOH亚熔盐介质中溶出行为, 过程工程学报, 2011, 第 4 作者
(68) Solubility Data for the NaOH-NaNO3-Na3VO4-Na2CrO4-H2O System at (40 and 80) ℃, Journal of Chemical and Engineering Data, 2010, 第 4 作者
(69) Isopiestic Study of the Na2CrO4-H2O System at 353.15 K: Prediction of the Solubility of Na2CrO4 in Aqueous NaOH Solutions, Industrial and Engineering Chemistry Research, 2010, 第 3 作者
(70) Phase Equilibria in the NaOH-NaNO3-Na2CrO4-H2O System, Journal of Chemical and Engineering Data, 2010, 第 4 作者
(71) Decomposition of chromite ore by oxygen in molten NaOH-NaNO3, International Journal of Mineral Processing, 2010, 第 4 作者
(72) Phase Diagrams for the Ternary Na2O-Al2O3-H2O System at (150 and 180) ℃, Journal of Chemical and Engineering Data, 2010, 第 3 作者
(73) Phase Equilibria in the NaOH-Na2CrO4-Na2CO3-H2O System, Journal of Chemical and Engineering Data, 2010, 第 3 作者
(74) Comparison of the Oxygen Reduction Reaction between NaOH and KOH Solutions on a Pt Electrode: The Electrolyte-Dependent Effect, Journal of Physical Chemistry B, 2010, 第 2 作者
(75) Alumina recovery from spent Bayer liquor by methanol, Transactions of Nonferrous Metals Society of China, 2010, 第 3 作者
(76) Effect of mechanical activation on alkali leaching of chromite ore, Transactions of Nonferrous Metals Society of China, 2010, 第 3 作者
(77) Surface chemistry features in the flotation of KCl, Minerals Engineering, 2010, 第 2 作者
(78) States of Adsorbed Dodecyl Amine and Water at a Silica Surface As Revealed by Vibrational Spectroscopy, Langmuir, 2010, 第 3 作者
(79) Solubility of Al2O3 in the Na2O-Al2O3-H2O-CH3OH System at (30 and 60) degrees C, Journal of Chemical and Engineering Data, 2010, 第 3 作者
(80) 碱性介质多元体系中钒酸钠结晶分离, 过程工程学报, 2010, 第 4 作者
(81) Improved precipitation of gibbsite from sodium aluminate solution by adding methanol, Hydrometallurgy, 2009, 第 3 作者

Patents

( 1 ) 一种氢氧化钠溶液常压分解钒渣的方法, 发明, 2012, 第 2 作者, 专利号: 201010034088.0
( 2 ) 一种从钒渣分解液中分离钒铬的方法, 发明, 2013, 第 1 作者, 专利号: 201110061488.5
( 3 ) 一种铬铁矿浸出提铬的方法, 发明, 2015, 第 1 作者, 专利号: 201310719091.X
( 4 ) 一种低温常压流化分解铬铁矿的方法, 发明, 2015, 第 1 作者, 专利号: 201310722901.7
( 5 ) 一种铬铁矿加压浸出制备铬酸钾的新工艺, 发明, 2015, 第 3 作者, 专利号: 201310316632.4
( 6 ) 一种钒渣无钠焙烧清洁高效回收钒的方法, 发明, 2014, 第 3 作者, 专利号: 201310537813.X
( 7 ) 一种含钒原料焙烧后熟料碳铵溶液浸出提钒的方法, 发明, 2014, 第 2 作者, 专利号: 201410220685.0
( 8 ) 含硫酸钠废水的除钠方法, 发明, 2014, 第 5 作者, 专利号: 201410121293.9
( 9 ) 钒钛磁铁矿提钒尾渣脱钠的方法, 发明, 2014, 第 5 作者, 专利号: 201410121291.X
( 10 ) 一种控温式流动薄层和频光谱电化学原位反应池, 发明, 2015, 第 1 作者, 专利号: 201420464160.7
( 11 ) 一种从钒渣铵浸溶液中结晶分离偏钒酸铵的方法, 发明, 2015, 第 1 作者, 专利号: 201410419444.9
( 12 ) 一种电解制备二氧化钒粉体的方法, 发明, 2012, 第 2 作者, 专利号: 201210073258.5
( 13 ) 一种由钒酸盐制备含钙钒氧化物的方法, 发明, 2014, 第 1 作者, 专利号: 201110061487.0
( 14 ) 一种由提钒尾渣回收钒的方法, 发明, 2013, 第 1 作者, 专利号: 201110185395.3
( 15 ) 一种用高碱度的氢氧化钠介质从含钒钢渣中提取钒的方法, 发明, 2013, 第 4 作者, 专利号: 201110007715.6
( 16 ) 一种钒渣加压浸出清洁生产钒酸钠的方法, 发明, 2014, 第 1 作者, 专利号: 201210004460.2
( 17 ) 一种氢氧化钾溶液中电化学分解铬铁矿提取铬的方法, 发明, 2013, 第 2 作者, 专利号: 201210592788.0
( 18 ) 一种氢氧化钾溶液中电化学分解钒渣同步提取钒铬的方法, 发明, 2013, 第 1 作者, 专利号: 201210592749.0
( 19 ) 一种含钒原料焙烧后熟料氨浸提钒的方法, 发明, 2014, 第 1 作者, 专利号: 201410162944.9
( 20 ) 一种控温式流动薄层和频光谱电化学原位反应池, 发明, 2014, 第 1 作者, 专利号: 201420464160.7
( 21 ) 一种氢氧化钾溶液常压分解钒渣的方法, 发明, 2011, 第 2 作者, 专利号: 201010149783.1
( 22 ) 一种氢氧化钠熔盐分解含铬钒渣的方法, 发明, 2013, 第 2 作者, 专利号: 201010034087.6
( 23 ) 一种液相氧化分解钒渣的方法, 发明, 2013, 第 2 作者, 专利号: 201010034089.5
( 24 ) 一种氢氧化钠溶液分解提钒尾渣回收钒的方法, 发明, 2013, 第 4 作者, 专利号: 201110199634.0
( 25 ) 一种氢氧化钠溶液添加含碳物质常压分解钒渣的方法, 发明, 2012, 第 1 作者, 专利号: 201210004910.8
( 26 ) 含钒炉渣中钒价态的测定方法, 发明, 2014, 第 4 作者, 专利号: 201210068493.
( 27 ) 一种三氧化二钒粉体的制备方法, 发明, 2013, 第 1 作者, 专利号: 201310053222.5
( 28 ) 一种氢氧化钠溶液中电化学强化钒渣分解同步提取钒铬的方, 发明, 2013, 第 1 作者, 专利号: 201310295919.3
( 29 ) 一种低温低浓度氢氧化钾溶液中电化学分解钒渣同步提取钒铬的方法, 发明, 2013, 第 2 作者, 专利号: 201310295928.2
( 30 ) 一种高纯二氧化钛的清洁生产方法, 发明, 2015, 第 3 作者, 专利号: 201410767931.4
( 31 ) 一种氢氧化铁吸附脱除铬酸钠浸出液中钒的方法, 发明, 2014, 第 3 作者, 专利号: 201410287528.1
( 32 ) 一种含钒原料低温焙烧提钒的方法, 发明, 2016, 第 1 作者, 专利号: 201610178360.X
( 33 ) 一种草酸铵浸出含钒原料焙烧熟料提钒的方法, 发明, 2016, 第 1 作者, 专利号: 201610121140.3
( 34 ) 一种电化学检测装置及其处理方法和用途, 发明, 2015, 第 1 作者, 专利号: 201510769882.2
( 35 ) 一种含钒焙烧熟料碳铵溶液低温常压浸出提钒的方法, 发明, 2015, 第 1 作者, 专利号: 201510184898.7
( 36 ) 一种低温常压提取钒渣中钒和铬的方法, 发明, 2015, 第 1 作者, 专利号: 201510763421.4
( 37 ) 一种草酸铵浸出含钒原料熟料提钒的方法, 发明, 2016, 第 2 作者, 专利号: 201610121802.7
( 38 ) 一种磷酸铵浸出含钒原料熟料提钒的方法, 发明, 2016, 第 3 作者, 专利号: 201610121082.4
( 39 ) 一种磷酸铵浸出含钒原料焙烧熟料提钒的方法, 发明, 2016, 第 2 作者, 专利号: 201610121159.8

Research Interests

Currrent research interests are

Hydrometallurgy, surface chemistry, electrochemistry, and green chemical process design.

Students

已指导学生

吕页清  博士研究生  081702-化学工艺  

冯曼  博士研究生  081702-化学工艺  

现指导学生

韩晨捷  硕士研究生  081701-化学工程  

王亚茹  博士研究生  081701-化学工程