070303-有机化学

不对称催化机理研究

2011-09--2016-07   北京大学   理学博士
2006-09--2010-07   江苏大学   理学学士

   

2022-09~现在, 中国科学院化学研究所, 项目研究员
2022-02~2022-08,中国科学院化学研究所, 高级访问学者
2021-08~2022-01,北京大学, 研究助理
2018-01~2021-07,斯克利普斯研究所, 博士后
2016-07~2017-12,康奈尔大学, 博士后
2011-09~2016-07,北京大学, 理学博士
2006-09~2010-07,江苏大学, 理学学士

   

（1） Asymmetric synthesis of chiral seven-membered NHCs, their transition metal complexes and application in asymmetric catalysis, Synthesis, 2023, 
（2） C1-对称手性NHC 配体的不对称合成及其催化性能研究, 化学学报, 2023, 
（3） Asymmetric transfer hydrogenation of naphthol and phenol derivatives with cooperative heterogeneous and homogeneous catalysis, CCS Chem., 2023, 第 2 作者
（4） Tunable unsymmetrical chiral N-heterocyclic carbene ligands for highly diastereo- and enantioselective copper-catalyzed tandem borylative cyclization: ligand controlled diastereoselectivity reversal, CCS Chem., 2023, 第 6 作者
（5） Cobalt-Electrocatalytic HAT for Functionalization of Unsaturated C���C Bonds, Nature, 2022, 第 12 作者
（6） Ru-Catalyzed Enantioselective Hydrogenation of 2-Pyridyl Substituted Alkenes and Substrate-Mediated H/D Exchange, ACS Catal., 2022, 第 1 作者
（7） Kinetic and Thermodynamic Considerations in the Rh-Catalyzed Enantioselective Hydrogenation of 2-Pyridyl Substituted Alkenes, ACS Catal., 2022, 第 1 作者
（8） Electrochemical Nozaki���Hiyama���Kishi Coupling: Scope, Applications, and Mechanism, J. Am. Chem. Soc., 2021, 第 3 作者
（9） Probing Catalyst Speciation in Pd-MPAAM-Catalyzed Enantioselective C(sp3)-H Arylation: Catalyst Improvement via Destabilization of Off-Cycle Species, ACS Catal., 2021, 第 1 作者
（10） A P(V)-Platform for Oligonucleotide Synthesis., Science, 2021, 第 4 作者
（11） Pd-Catalyzed �����C(sp3)���H Fluorination of Free Amines, J. Am. Chem. Soc., 2020, 第 5 作者
（12） Rhodium-Catalyzed Intramolecular Carbosilylation of Alkynes via C(sp3)���Si Bond Cleavage, Org. Chem. Front., 2018, 第 4 作者
（13） Diastereo- and Enantioselective Formal [3+2] Cycloaddition of Cyclopropyl Ketones and Alkenes via Ti-Catalyzed Radical Redox Relay, J. Am. Chem. Soc., 2018, 第 1 作者
（14） Ti-Catalyzed Radical Alkylation of Secondary and Tertiary Alkyl Chlorides Using Michael Acceptors, J. Am. Chem. Soc., 2018, 第 2 作者
（15） Formation of Cyclopenta[c]pyridine Derivatives from 2,5-Disubstituted Pyrroles and 1,4-Dibromo-1,3-butadienes via Pyrrole-Ring One-Carbon Expansion, Org. Lett., 2017, 第 3 作者
（16） Radical Redox-Relay Catalysis: Formal [3+2] Cycloaddition of N���Acylaziridines and Alkenes, J. Am. Chem. Soc., 2017, 第 1 作者
（17） A DFT Study on Conversion of Aryl Iodides to Alkyl Iodides: Reductive Elimination of R���I from Alkylpalladium Iodide Complexes with Assesable ���-Hydrogens, Chem. Eur. J., 2016, 第 1 作者
（18） Cyclopentadiene-Phosphine/Palladium Catalyzed Synthesis of Indolizines from pyrrole and alkenyl or aryl dibromides, Org. Lett., 2015, 第 1 作者
（19） Combining Pd (��-allyl) Cp and PPh3 as a Unique Catalyst for Efficient Synthesis of Alkyliodo Indoles via C (sp3)���I Reductive Elimination, Org. Chem. Front., 2015, 第 1 作者
（20） Transition-Metal-Catalyzed Cleavage of C���N Single Bonds, Chem. Rev., 2015, 第 2 作者
（21） Transfer of Aryl Halide to Alkyl Halide: Reductive Elimination of Alkylhalide from Alkylpalladium Halide Containing syn-���-Hydrogens, Angew. Chem. Int. Ed., 2014, 第 1 作者
（22） Palladium-Catalyzed One-Pot Three- or Four-Component Coupling of Aryl Iodides, Alkynes, and Amines through C-N Bond Cleavage: Efficient Synthesis of Indole Derivatives, Chem. Eur. J., 2014, 第 1 作者
（23） 1,2,3,4-Tetrasubstituted Cyclopentadienes and Their Applications for Metallocenes: Efficient Synthesis through Zirconocene- and CuCl-Mediated Intermolecular Coupling of Two Alkynes and One Diiodomethane, Chem. Eur. J., 2013, 第 4 作者
（24） Cyclopentadiene���Phosphine/Palladium-Catalyzed Cleavage of C���N Bonds in Secondary Amines: Synthesis of Pyrrole and Indole Derivatives from Secondary Amines and Alkenyl or Aryl Dibromides, J. Am. Chem. Soc., 2012, 第 3 作者

   

（ 1 ） 海外YQ（院匹配）, 负责人, 中国科学院计划, 2023-03--2025-12
（ 2 ） 海外YQ, 负责人, 国家任务, 2023-03--2025-12
（ 3 ） 引进人才启动经费, 负责人, 研究所自主部署, 2022-09--2026-08

（1）Probing Mechanism of Asymmetric Hydrogenation by Using Reaction Kinetics Tools   2023-09-15
（2）反应动力学在不对称催化中的应用   第3届分子科学博士后学术年会   2023-06-03