基本信息
付年凯  男  博导  中国科学院化学研究所
email: funiankai@iccas.ac.cn
address: 海淀区中关村北一街2号
postalCode: 100190

招生信息

   
招生专业
070303-有机化学
招生方向
有机电化学合成

教育背景

2009-09--2014-07   中国科学院化学研究所   理学博士学位
2005-09--2009-07   湖北大学   学士学位

工作经历

   
工作简历
2016-08~2019-09,美国康奈尔大学, 博士后
2014-07~2016-07,中国科学院化学研究所, 助理研究员
2009-09~2014-07,中国科学院化学研究所, 理学博士学位
2005-09~2009-07,湖北大学, 学士学位

教授课程

高等有机化学导论

专利与奖励

   
奖励信息
(1) Blavatnik Regional Awards for Young Scientists Finalist in Chemistry, 其他, 2018
(2) Reaxys PhD Prize Finalist, 其他, 2012

出版信息

   
发表论文
(1) Radical-Based Convergent Paired Electrolysis, CHEMISTRY-A EUROPEAN JOURNAL, 2023, 通讯作者
(2) Free Carboxylic Acids: The Trend of Radical Decarboxylative Functionalization, EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2023, 通讯作者
(3) Electrochemical N-heteroarene carboxylation: Reactor-dependent site selectivity, CHEM, 2023, 第 2 作者
(4) Taming Challenging Radical-Based Convergent Paired Electrolysis with Dual-Transition-Metal Catalysis, SYNLETT, 2023, 通讯作者
(5) Electrophotochemical Metal-Catalyzed Enantioselective Decarboxylative Cyanation, CHEMISTRY-A EUROPEAN JOURNAL, 2023, 通讯作者
(6) Electrochemical Metal-Catalyzed Azidoesterification of Alkenes, EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2023, 通讯作者
(7) Electrophotochemical Metal-Catalyzed Decarboxylative Coupling of Aliphatic Carboxylic Acids, CHEMISTRY-A EUROPEAN JOURNAL, 2022, 通讯作者
(8) Electrochemical Diazidation of Alkenes Catalyzed by Manganese Porphyrin Complexes with Second-Sphere Hydrogen-Bond Donors, ACS CATALYSIS, 2022, 第 6 作者
(9) Pairing Iron and Nickel Catalysis for Electrochemical Esterification of Aryl Halides with Carbazates, ORGANIC LETTERS, 2022, 通讯作者
(10) Electrophotochemical Decarboxylative Azidation of Aliphatic Carboxylic Acids, ACS CATALYSIS, 2022, 通讯作者
(11) Reaching the Full Potential of Electroorganic Synthesis by Paired Electrolysis, CHEMICAL RECORD, 2021, 通讯作者
(12) A time of transition: Stories from starting a new research program in 2020, ISCIENCE, 2021, 第 1 作者
(13) Catalytic Asymmetric Electrochemical alpha-Arylation of Cyclic beta-Ketocarbonyls with Anodic Benzyne Intermediates, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 第 3 作者
(14) Dual electrocatalysis enables enantioselective hydrocyanation of conjugated alkenes, NATURE CHEMISTRY, 2020, 第 2 作者
(15) Harnessing Radical Chemistry via Electrochemical Transition Metal Catalysis, ISCIENCE, 2020, 通讯作者
(16) Catalyzing Electrosynthesis: A Homogeneous Electrocatalytic Approach to Reaction Discovery, ACCOUNTSOFCHEMICALRESEARCH, 2020, 第 2 作者
(17) New Bisoxazoline Ligands Enable Enantioselective Electrocatalytic Cyanofunctionalization of Vinylarenes, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 第 1 作者
(18) Mn-Catalyzed Electrochemical Chloroalkylation of Alkenes, ACS CATALYSIS, 2019, 第 1 作者
(19) Three-Component Chlorophosphinoylation of Alkenes via Anodically Coupled Electrolysis, SYNLETT, 2019, 第 2 作者
(20) Catalytic asymmetric enamine protonation reaction, ORGANIC & BIOMOLECULAR CHEMISTRY, 2018, 第 1 作者
(21) A general, electrocatalytic approach to the synthesis of vicinal diamines, NATURE PROTOCOLS, 2018, 第 1 作者
(22) Synthesis of Chlorotrifluoromethylated Pyrrolidines by Electrocatalytic Radical Ene-Yne Cyclization, CHEMISTRY-A EUROPEAN JOURNAL, 2018, 第 5 作者
(23) Electrocatalytic Difunctionalization of Olefins as a General Approach to the Synthesis of Vicinal Diamines, SYNLETT, 2018, 第 2 作者
(24) Electrochemical Azidooxygenation of Alkenes Mediated by a TEMPO–N 3 Charge-Transfer Complex, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 第 5 作者
(25) Anodically Coupled Electrolysis for the Heterodifunctionalization of Alkenes, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 第 3 作者
(26) Asymmetric hydroazidation of alpha-substituted vinyl ketones catalyzed by chiral primary amine, CHINESE CHEMICAL LETTERS, 2017, 第 2 作者
(27) Catalytic Asymmetric Electrochemical Oxidative Coupling of Tertiary Amines with Simple Ketones, ORGANIC LETTERS, 2017, 第 1 作者
(28) Asymmetric hydroazidation of α-substituted vinyl ketones catalyzed by chiral primary amine, CHINESE CHEMICAL LETTERS, 2017, 第 2 作者
(29) Electrocatalytic Radical Dichlorination of Alkenes with Nucleophilic Chlorine Sources, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 第 1 作者
(30) Metal-catalyzed electrochemical diazidation of alkenes, SCIENCE, 2017, 第 1 作者
(31) Chiral Primary Amine Catalyzed Asymmetric Tandem Reduction-Michael Addition-Protonation Reaction between Alkylidene Meldrum's Acid and -Substituted Vinyl Ketones, SYNTHESIS-STUTTGART, 2015, 通讯作者
(32) Chiral Primary Amine Catalyzed Asymmetric Michael Addition of Malononitrile to alpha-Substituted Vinyl Ketone, ORGANIC LETTERS, 2015, 第 1 作者
(33) Pushing the Limits of Aminocatalysis: Enantioselective Transformations of alpha-Branched beta-Ketocarbonyls and Vinyl Ketones by Chiral Primary Amines, ACCOUNTS OF CHEMICAL RESEARCH, 2015, 第 2 作者
(34) Asymmetric sulfa-Michael addition to α-substituted vinyl ketones catalyzed by chiral primary amine, ORG. LETT., 2014, 第 1 作者
(35) Chiral primary amine catalysed asymmetric conjugate addition of azoles to α-substituted vinyl ketones, ORG. CHEM. FRONT., 2014, 第 1 作者
(36) Asymmetric Sulfa-Michael Addition to alpha-Substituted Vinyl Ketones Catalyzed by Chiral Primary Amine, ORGANIC LETTERS, 2014, 第 1 作者
(37) Chiral primary amine catalysed asymmetric conjugate addition of azoles to alpha-substituted vinyl ketones, ORGANIC CHEMISTRY FRONTIERS, 2014, 通讯作者
(38) Chiral Primary-Amine-Catalyzed Conjugate Addition to alpha-Substituted Vinyl Ketones/Aldehydes: Divergent Stereocontrol Modes on Enamine Protonation, CHEMISTRY-A EUROPEAN JOURNAL, 2013, 第 1 作者
(39) Chiral Primary Amine Catalyzed Enantioselective Protonation via an Enamine Intermediate, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 第 1 作者
(40) Chiral Primary Amine Catalyzed Asymmetric Epoxidation of alpha-Substituted Acroleins, EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 第 2 作者
(41) Chiral Primary-Tertiary-Diamine-Bronsted Acid Salt Catalyzed Syn-Selective Cross-Aldol Reaction of Aldehydes, JOURNAL OF ORGANIC CHEMISTRY, 2010, 第 2 作者

科研活动

   
科研项目
( 1 ) 自由基机理的不对称电化学反应研究, 负责人, 国家任务, 2021-01--2024-12