070303-有机化学

受阻路易斯酸碱对催化不对称反应
理论有机化学

2007-09--2012-06   天津大学   理学博士
2002-09--2006-06   山西大学   理学学士

   

2017-03~现在, 中国科学院化学研究所, 副研究员
2014-07~2017-03,中国科学院化学研究所, 助理研究员
2012-07~2014-07,北京大学化学与分子工程学院, 博士后
2007-09~2012-06,天津大学, 理学博士
2002-09~2006-06,山西大学, 理学学士

有机化学实验（生物专业）
有机化学实验（化学专业）
有机化学
有机化学习题课
有机化学实验（材料专业）
有机化学习题课-1

   

（1） 中科院化学所优秀职工, , 研究所（学校）, 2018

   

（1） Sulfonium-Based Precise Alkyl Transposition Reactions, Science Advances, 2023, 通讯作者
（2） Asymmetric catalysis with FLPs, Chemical Society Reviews, 2023, 第 2 作者
（3） Asymmetric Hydrogenation of Hydrazones with Chiral Boranes, ORGANIC LETTERS, 2023, 第 2 作者
（4） Asymmetric Reduction of Quinolines: A Competition between Enantioselective Transfer Hydrogenation and Racemic Borane Catalysis, JOURNAL OF ORGANIC CHEMISTRY, 2023, 第 3 作者
（5） Regenerable Dihydrophenanthridine via Borane-Catalyzed Hydrogenation for the Asymmetric Transfer Hydrogenation of Benzoxazinones, ORGANIC LETTERS, 2022, 第 2 作者
（6） A perylene five-membered ring diimide for organic semiconductors and p-expanded conjugated molecules, Chemical Communication, 2022, 第 5 作者
（7） Asymmetric Intramolecular Hydroalkoxylation of 2-Vinylbenzyl Alcohols with Chiral Boro-Phosphates, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 第 2 作者
（8） Chiral Dienes: From Ligands to FLP Catalysts, Chiral Dienes: From Ligands to FLP Catalysts, CHINESE JOURNAL OF CHEMISTRY, 2022, 第 2 作者
（9） Chiral FLP-catalyzed asymmetric hydrogenation of 3-fluorinated chromones., Chemical Communations, 2022, 第 2 作者
（10） Asymmetric Hydrogenation by Relay Catalysis with FLPs and CPAs: Stereodivergent Synthesis of 3-Substituted Flavanones, JOURNAL OF ORGANIC CHEMISTRY, 2022, 第 2 作者
（11） High Efficiency Catalyst of Modified Y Molecular Sieve by Rare Earth La3+ Catalyzed the Synthesis of Cyclohexylbenzene from Benzene and Cyclohexene, CATALYSISLETTERS, 2022, 第 3 作者
（12） B(C_(6)F_(5))_(3)-Catalyzed Hydroboration of Alkenes with N-Heterocyclic Carbene Boranes via B-H Bond Activation, B(C6F5)(3)-Catalyzed Hydroboration of Alkenes with N-Heterocyclic Carbene Boranes via B-H Bond Activation, CHINESE JOURNAL OF CHEMISTRY, 2021, 第 2 作者
（13） Relay Catalysis by Achiral Borane and Chiral Phosphoric Acid in the Metal-Free Asymmetric Hydrogenation of Chromones, ORGANIC LETTERS, 2021, 通讯作者
（14） Rapid, controlled ring-opening polymerization of salicylic acid o-carboxyanhydride for poly(salicylate) synthesis, POLYMER CHEMISTRY, 2021, 通讯作者
（15） Asymmetric Catalysis with Chiral Frustrated Lewis Pairs, Asymmetric Catalysis with Chiral Frustrated Lewis Pairs, CHINESE JOURNAL OF CHEMISTRY, 2020, 第 1 作者
（16） Asymmetric Hydrogenation of Ketones and Enones with Chiral Lewis Base Derived Frustrated Lewis Pairs, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 通讯作者
（17） Substrate-Induced Dimerization Assembly of Chiral Macrocycle Catalysts toward Cooperative Asymmetric Catalysis, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 第 4 作者
（18） Dicycloheptaijkl,uvwxrubicene with Two Pentagons and Two Heptagons as a Stable and Planar Non-benzenoid Nanographene, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 第 4 作者
（19） Chiral phosphoric acid catalyzed asymmetric transfer hydrogenation of bulky aryl ketones with ammonia borane, TETRAHEDRON LETTERS, 2020, 第 2 作者
（20） Modification of Molecular Sieves USY and Their Application in the Alkylation Reaction of Benzene with Cyclohexene, CHEMISTRYSELECT, 2020, 第 3 作者
（21） Asymmetric Hydrogenations of Ketones and Enones with Chiral Lewis Base-Led Frustrated Lewis Pairs, Angewandte Chemie International Edition, 2020, 通讯作者
（22） Dicyclohepta[ijkl,uvwx]rubicene with Two Pentagons and Two Heptagons as a New Stable and Planar Non-Benzenoid Nanographene, ANGEWANDTECHEMIEINTERNATIONALEDITION, 2019, 第 1 作者
（23） B(C6F5)(3)-catalyzed divergent cyanosilylations of chromones dependent on temperature, ORGANIC & BIOMOLECULAR CHEMISTRY, 2019, 通讯作者
（24） A Continuously Regenerable Chiral Ammonia Borane for Asymmetric Transfer Hydrogenations, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 第 2 作者
（25） An efficient strategy for achieving controlled ring-opening polymerization of O-carboxyanhydrides via amine initiation in collaboration with metal-alkoxide catalysis, POLYMER CHEMISTRY, 2018, 通讯作者
（26） Frustrated Lewis Pairs Catalyzed Asymmetric Metal-Free Hydrogenations and Hydrosilylations, ACCOUNTS OF CHEMICAL RESEARCH, 2018, 第 1 作者
（27） Asymmetric hydrogenation of imines with chiral alkene- derived boron Lewis acids, ORGANIC & BIOMOLECULAR CHEMISTRY, 2018, 通讯作者
（28） Highly Stereoselective Metal-Free Hydrogenations of Pyrrolo1,2-aquinoxalines, ORGANIC LETTERS, 2018, 通讯作者
（29） Asymmetric Transfer Hydrogenations of 2,3-Disubstituted Quinoxalines with Ammonia Borane, ORGANIC LETTERS, 2017, 通讯作者
（30） C-2-Symmetric Chiral Bisoxazolines as Hydrogen-Bond-Acceptor Catalysts in Enantioselective Aldol Reaction of beta-Carbonyl Acids with Trifluoroacetaldehyde Hemiacetals, ORGANIC LETTERS, 2016, 第 4 作者
（31） A Frustrated Lewis Pair Catalyzed Asymmetric Transfer Hydrogenation of Imines Using Ammonia Borane, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 通讯作者
（32） B(C6F5)(3)-catalyzed metal-free hydrogenation of 3,6-diarylpyridazines, DALTON TRANSACTIONS, 2016, 第 2 作者
（33） Borane-Catalyzed Transfer Hydrogenations of Pyridines with Ammonia Borane, ORGANIC LETTERS, 2016, 第 3 作者
（34） C2-Symmetric Chiral Bisoxazolines as Hydrogen-Bond-Acceptor Catalysts in Enantioselective Aldol Reaction of β-Carbonyl Acids with Trifluoroacetaldehyde Hemiacetals, Organic Letters, 2016, 第 1 作者
（35） A density functional study of chiral phosphoric acid-catalyzed direct arylation of trifluoromethyl ketone and diarylation of methyl ketone: reaction mechanism and the important role of the CF3 group, ORGANIC & BIOMOLECULAR CHEMISTRY, 2014, 第 2 作者
（36） Hydrogen-Bond-Directed Enantioselective Decarboxylative Mannich Reaction of -Ketoacids with Ketimines: Application to the Synthesis of Anti-HIV Drug DPC083, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 第 4 作者
（37） Mild-Condition Synthesis of Allenes from Alkynes and Aldehydes Mediated by Tetrahydroisoquinoline (THIQ), JOURNAL OF ORGANIC CHEMISTRY, 2013, 第 5 作者
（38） CuI-Catalyzed C1-Alkynylation of Tetrahydroisoquinolines (THIQs) by A(3) Reaction with Tunable Iminium Ions, ORGANIC LETTERS, 2013, 第 2 作者
（39） Allenoate-derived 1,5-, 1,7-, and 1,9-zwitterions as highly versatile coupling-partners for phosphine-triggered cycloaddition reactions, CHEMICAL SCIENCE, 2012, 第 1 作者
（40） A Facile Parallel Synthesis of Trifluoroethyl-Substituted Alkynes, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 第 2 作者
（41） Enantioselective Base-Free Electrophilic Amination of Benzofuran-2(3H)-ones: Catalysis by Binol-Derived P-Spiro Quaternary Phosphonium Salts, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 第 3 作者
（42） Catalytic Enantioselective Alkynylation of Trifluoromethyl Ketones: Pronounced Metal Fluoride Effects, Observation and Practical Implications of Zinc-to-Titanium Trans-Metalation, Angewandte Chemie International Edition, 2011, 第 1 作者
（43） The Long-Arm Effect: Influence of Axially Chiral Phosphoramidite Ligands on the Diastereo- and Enantioselectivity of the Tandem 1,4-Addition/Fluorination, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 第 2 作者

   

（ 1 ） 基于手性Lewis碱的新“受阻Lewis酸碱对”催化体系研究, 负责人, 国家任务, 2019-01--2022-12
（ 2 ） 理论计算辅助FLP催化CO2分子还原反应研究, 负责人, 国家任务, 2016-01--2018-12
（ 3 ） P-K反应催化物种理论研究及新型手性磺酸配体的发展, 负责人, 其他国际合作项目, 2013-09--2014-07

（1）The Rediscovery of ‘Frustrated’ Lewis Pairs   2019京津化学沙龙   2019-10-05
（2）The Application of Ammonia Boranes in Asymmetric Transfer Hydrogenations   第二届国际硼化学会议   2019-07-14