070303-有机化学
070305-高分子化学与物理

环境友好型高分子的催化合成

2007-09--2013-01   中国科学院长春应用化学研究所   博士学位
2003-09--2007-06   东北师范大学   学士学位

   

2016-01~2016-12,Colorado State University, Research Scientist
2013-01~2015-12,Colorado State University, Postdoc Research Fellow

高分子化学与物理

   

（1） Thieme Chemistry Journal Award, 其他, 2022
（2） 上海市科技系统“青年五四奖章”, 市地级, 2021
（3） 上海市科技系统三八红旗手, 市地级, 2020
（4） 中国化学会高分子青年学者奖, 国家级, 2019
（5） 上海市青年科技启明星计划, , 市地级, 2019
（6） 美国总统绿色化学挑战奖Presidential Green Chemistry Challenge Award, 国家级, 2015

（ 1 ） Ring-Opening Polymerization Methods and Recyclable Biorenewalble Polyesters, 发明专利, 2016, 第 2 作者, 专利号: PCT/US2016/026961

（ 2 ） Recyclable Biopolymers from Chemical Ring-Opening Polymerization of Five-Membered Heterocyclic Monomers by Basic Catalysts, 发明专利, 2016, 第 2 作者, 专利号: USPTO assigned Application No.: 62298236

（ 3 ） Method of Producing Polyesters from Acrylic Monomers and Products, 发明专利, 2014, 第 2 作者, 专利号: USPTO assigned Application No.: 62031596

（ 4 ） 一种环烯烃共聚物及其制备发法, 发明专利, 2012, 第 2 作者, 专利号: CN201210140493.X

   

[1] Xia Yongliang, Yuan Pengjun, Zhang Yanping, Sun Yangyang, 洪缪. Converting Non-strained γ-Valerolactone and Derivatives into Sustainable Polythioesters via Isomerization-driven Cationic Ring-opening Polymerization of Thionolactone Intermediate. Angewandte Chemie International Edition[J]. 2023, [2] Wang Xing, Zhang Yanping, 洪缪. Insights into the interaction between bis(aryloxide)alkylaluminum and N-heterocyclic carbene: from abnormal Lewis adduct to Frustrated Lewis pair for efficient polymerizations of biomass- derived acrylic monomers. Polymer Chemistry[J]. 2023, [3] Sun Yangyang, Carpentier Ambre, Zhang Yixin, Weng Biwei, Ling Yaoyao, Maron Laurent, Hong Miao. Stereospecific Polymerization of Bulk Methacylates using Organocatalyst in Strong Donating Solvent via Self-controlled Mechanism. Macromolecules[J]. 2022, [4] Yuan, Pengjun, Sun, Yangyang, Xu, Xiaowei, Luo, Yi, Hong, Miao. Towards high-performance sustainable polymers via isomerization-driven irreversible ring-opening polymerization of five-membered thionolactones. NATURE CHEMISTRY[J]. 2022, 14(3): 294-+, http://dx.doi.org/10.1038/s41557-021-00817-9.
[5] Zhang Zhenhua, wang xing, Hong Miao. Zinc-mediated Allylation-lactonization One-pot Reaction to Methylene Butyrolactones: Renewable Monomers for Sustainable Acrylic Polymers with Closed-loop Recyclability. ACS Polymers Au[J]. 2022, [6] Zhang, ZhenHua, Wang, Xing, Wang, XiaoJun, Li, Yuesheng, Hong, Miao. Tris(2,4-difluorophenyl)borane/Triisobutylphosphine Lewis Pair: A Thermostable and Air/Moisture-Tolerant Organic Catalyst for the Living Polymerization of Acrylates. MACROMOLECULES[J]. 2021, 54(18): 8495-8502, http://dx.doi.org/10.1021/acs.macromol.1c01356.
[7] Wang, Xing, Hong, Miao. Precise Control of Molecular Weight and Stereospecificity in Lewis Pair Polymerization of Semifluorinated Methacrylates: Mechanistic Studies and Stereocomplex Formation. MACROMOLECULES[J]. 2020, 53(12): 4659-4669, https://www.webofscience.com/wos/woscc/full-record/WOS:000543743000007.
[8] Wang, XiaoJun, Hong, Miao. Lewis-Pair-Mediated Selective Dimerization and Polymerization of Lignocellulose-Based beta-Angelica Lactone into Biofuel and Acrylic Bioplastic. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2020, 59(7): 2664-2668, https://www.webofscience.com/wos/woscc/full-record/WOS:000505822400001.
[9] Liu, Xia, Hong, Miao, Falivene, Laura, Cavallo, Luigi, Chen, Eugene Y X. Closed-Loop Polymer Upcycling by Installing Property-Enhancing Comonomer Sequences and Recyclability. MACROMOLECULES[J]. 2019, 52(12): 4570-4578, https://www.webofscience.com/wos/woscc/full-record/WOS:000473248200018.
[10] 袁鹏俊, 洪缪. “非张力环”γ-丁内酯及其衍生物开环聚合的研究进展. 高分子学报[J]. 2019, 327-337, http://lib.cqvip.com/Qikan/Article/Detail?id=71708866504849574852484849.
[11] Yuan, Pengjun, Hong, Miao. Ring-opening Polymerizations of the "Non-strained" gamma-Butyrolactone and Its Derivatives: An Overview and Outlook. ACTA POLYMERICA SINICA[J]. 2019, 50(4): 327-337, [12] Hong, Miao, Chen, Eugene Y X. Future Directions for Sustainable Polymers. TRENDS IN CHEMISTRYnull. 2019, 1(2): 148-151, http://apps.webofknowledge.com/CitedFullRecord.do?product=UA&colName=WOS&SID=5CCFccWmJJRAuMzNPjj&search_mode=CitedFullRecord&isickref=WOS:000521129600004.
[13] Liu, Xia, Hong, Miao. Transesterification by air/moisture-tolerant bifunctional organocatalyst to produce 'nonstrained' gamma-butyrolactone-based aliphatic copolyesters: Turning a bane into a boon. EUROPEAN POLYMER JOURNAL[J]. 2019, 121: https://www.webofscience.com/wos/woscc/full-record/WOS:000504504800055.
[14] Xia Liu, Miao Hong. Transesterification by air/moisture-tolerant bifunctional organocatalyst to produce ‘nonstrained’ γ-butyrolactone-based aliphatic copolyesters: Turning a bane into a boon. EUROPEAN POLYMER JOURNAL. 2019, 121: http://dx.doi.org/10.1016/j.eurpolymj.2019.109277.
[15] Wang, Xiaojun, Zhang, Yixin, Hong, Miao. Controlled and Efficient Polymerization of Conjugated Polar Alkenes by Lewis Pairs Based on Sterically Hindered Aryloxide-Substituted Alkylaluminum. MOLECULES[J]. 2018, 23(2): https://doaj.org/article/5719039f07724d439c90fa021d25e36d.
[16] Li, Hui, Ai, BaiRu, Hong, Miao. Stereoselective ring-opening polymerization of rac-lactide by bulky chiral and achiral N-heterocyclic carbenes. CHINESE JOURNAL OF POLYMER SCIENCE[J]. 2018, 36(2): 231-236, http://lib.cqvip.com/Qikan/Article/Detail?id=71709075504849564850484952.
[17] Chen, Jiawei, Hong, Miao, Chen, Eugene Y X. Lewis Pair Polymerization for New Reactivity and Structure in Polymer Synthesis. MOLECULES[J]. 2018, 23(4): https://doaj.org/article/3fe860742f184402bebb143ac5c8f3c1.
[18] Hui Li, Bai-Ru Ai, Miao Hong. Stereoselective Ring-opening Polymerization of rac-Lactide by Bulky Chiral and Achiral N-heterocyclic Carbenes. 高分子科学：英文版[J]. 2018, 36(2): 231-236, http://lib.cqvip.com/Qikan/Article/Detail?id=71709075504849564850484952.
[19] Hong, Miao, Chen, Jiawei, Chen, Eugene Y X. Polymerization of Polar Monomers Mediated by Main-Group Lewis Acid-Base Pairs. CHEMICAL REVIEWSnull. 2018, 118(20): 10551-10616, https://www.webofscience.com/wos/woscc/full-record/WOS:000448754700007.
[20] Hong Mou. Nonstrained’ γ‑Butyrolactone-Based Copolyesters: Copolymerization Characteristics and Composition-Dependent (Thermal, Eutectic, Cocrystallization, and Degradation) Properties. Macromolecules. 2017, [21] Wang, Yang, Bailey, Travis S, Hong, Miao, Chen, Eugene Y X. Stereoregular Brush Polymers and Graft Copolymers by Chiral Zirconocene-Mediated Coordination Polymerization of P3HT Macromers. POLYMERS[J]. 2017, 9(4): https://www.webofscience.com/wos/woscc/full-record/WOS:000401719700025.
[22] Wang, Yang, Hong, Miao, Bailey, Travis S, Chen, Eugene Y X. Brush Polymer of Donor-Accepter Dyads via Adduct Formation between Lewis Base Polymer Donor and All Carbon Lewis Acid Acceptor. MOLECULES[J]. 2017, 22(9): https://doaj.org/article/115111597a27417494628ad8880708b9.
[23] Hong, Miao, Chen, Eugene Y X. Chemically recyclable polymers: a circular economy approach to sustainability. GREEN CHEMISTRYnull. 2017, 19(16): 3692-3706, https://www.webofscience.com/wos/woscc/full-record/WOS:000407637800001.
[24] Hong, Miao, Tang, Xiaoyan, Newell, Brian S, Chen, Eugene Y X. "Nonstrained" gamma-Butyrolactone-Based Copolyesters: Copolymerization Characteristics and Composition-Dependent (Thermal, Eutectic, Cocrystallization, and Degradation) Properties. MACROMOLECULES[J]. 2017, 50(21): 8469-8479, https://www.webofscience.com/wos/woscc/full-record/WOS:000415911100018.
[25] Hong, Miao, Chen, Eugene Y X. Completely recyclable biopolymers with linear and cyclic topologies via ring-opening polymerization of gamma-butyrolactone. NATURE CHEMISTRY[J]. 2016, 8(1): 42-49, https://www.webofscience.com/wos/woscc/full-record/WOS:000366675400010.
[26] Hong, Miao, Tang, Xiaoyan, Falivene, Laura, Caporaso, Lucia, Cavallo, Luigi, Chen, Eugene Y X. Proton-Transfer Polymerization by N-Heterocyclic Carbenes: Monomer and Catalyst Scopes and Mechanism for Converting Dimethacrylates into Unsaturated Polyesters. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2016, 138(6): 2021-2035, [27] Hong Mou. Towards Truly Sustainable Polymers: Metal-Free Recyclable Polyester from Biorenewable Non-Strained gamma-Butyrolactone. Angew. Chem. Int. Ed.. 2016, [28] Hong, Miao, Chen, Eugene Y X. Polymeric carbon Lewis base-acid adducts: poly(NHC-C-60). POLYMER CHEMISTRY[J]. 2015, 6(10): 1741-1750, https://www.webofscience.com/wos/woscc/full-record/WOS:000350641400008.
[29] Hong, Miao, Chen, Eugene Y X. Proton-Transfer Polymerization (HTP): Converting Methacrylates to Polyesters by an N-Heterocyclic Carbene. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2014, 53(44): 11900-11906, https://www.webofscience.com/wos/woscc/full-record/WOS:000344050700034.
[30] Hong Mou. Coordination Ring-opening Copolymerization of Naturally Renewable α-Methylene-γ-butyrolactone into Unsaturated Polyesters. Macromolecules. 2014, [31] Hong, Miao, Cui, Lei, Liu, Sanrong, Li, Yuesheng. Synthesis of Novel Cyclic Olefin Copolymer (COC) with High Performance via Effective Copolymerization of Ethylene with Bulky Cyclic Olefin. MACROMOLECULES[J]. 2012, 45(13): 5397-5402, http://www.irgrid.ac.cn/handle/1471x/639894.
[32] Hong, Miao, Liu, JingYu, Li, BaiXiang, Li, YueSheng. Facile Functionalization of Polyethylene via Click Chemistry. MACROMOLECULES[J]. 2011, 44(14): 5659-5665, http://www.irgrid.ac.cn/handle/1471x/423384.
[33] Hong, Miao, Wang, YongXia, Mu, HongLiang, Li, YueSheng. Efficient Synthesis of Hydroxylated Polyethylene via Copolymerization of Ethylene with 5-Norbornene-2-methanol using Bis(beta-enaminoketonato)titanium Catalysts. ORGANOMETALLICS[J]. 2011, 30(17): 4678-4686, http://www.irgrid.ac.cn/handle/1471x/423191.

   

（ 1 ） ****, 负责人, 国家任务, 2017-01--2019-12
（ 2 ） 绿色高分子的催化合成, 负责人, 研究所自选, 2017-01--2020-01
（ 3 ） 手性螺旋高分子的催化合成, 负责人, 研究所自选, 2017-01--2020-01
（ 4 ） 上海市青年科技启明星计划(A类), 负责人, 地方任务, 2019-01--2021-12
（ 5 ） 不对称聚合制备手性螺旋高分子, 负责人, 国家任务, 2017-01--2020-12
（ 6 ） 含硫(硒)的可回收高性能高分子材料的可控合成, 负责人, 国家任务, 2020-01--2023-12
（ 7 ） 基于五元环内酯催化合成可持续性高分子材料, 负责人, 地方任务, 2022-04--2025-03

已指导学生

王小军  博士研究生  070303-有机化学  

现指导学生

王星  博士研究生  070303-有机化学  

王娇  硕士研究生  070305-高分子化学与物理  

许宏鑫  硕士研究生  070305-高分子化学与物理  

张兆森  硕士研究生  085600-材料与化工  

刘禹辰  硕士研究生  085600-材料与化工  

夏永亮  博士研究生  070303-有机化学  

麦浣媚  硕士研究生  070305-高分子化学与物理  

邹林芳  硕士研究生  070305-高分子化学与物理  

周榆钦  博士研究生  070303-有机化学