基本信息
左智伟 男 博导 中国科学院上海有机化学研究所
电子邮件: zuozhw@sioc.ac.cn
通信地址: 上海市零陵路 345 号
邮政编码:
电子邮件: zuozhw@sioc.ac.cn
通信地址: 上海市零陵路 345 号
邮政编码:
招生信息
招生专业
070303-有机化学
招生方向
光催化,有机合成
教育背景
2007-09--2012-07 中科院上海有机化学研究所 博士2003-09--2007-07 南京大学化学化工学院 学士
工作经历
工作简历
2020-06~现在, 中科院上海有机化学研究所, 研究员2015-09~2020-06,上海科技大学, 研究员2013-03~2015-09,普林斯顿大学, 博士后2012-07~2013-03,中科院上海有机化学研究所, 助理研究员
专利与奖励
专利成果
[1] 左智伟, 李琦凡. 内酯类化合物及铈催化的内酯类化合物的合成方法. CN: CN114573541A, 2022-06-03.
出版信息
发表论文
[1] Ding, Jia, Luo, Shuaishuai, Xu, Yuanli, An, Qing, Yang, Yi, Zuo, Zhiwei. Selective oxidation of benzylic alcohols via synergistic bisphosphonium and cobalt catalysis. CHEMICAL COMMUNICATIONS[J]. 2023, 59(27): 4055-4058, http://dx.doi.org/10.1039/d3cc00532a.[2] Lu Wen, Jia Ding, Linfei Duan, Shun Wang, Qing An, Hexiang Wang, Zhiwei Zuo. Multiplicative enhancement of stereoenrichment by a single catalyst for deracemization of alcohols. Science[J]. 2023, 382(6669): 458-464, [3] Chang, Liang, Wang, Shun, An, Qing, Liu, Linxuan, Wang, Hexiang, Li, Yubo, Feng, Kaixuan, Zuo, Zhiwei. Resurgence and advancement of photochemical hydrogen atom transfer processes in selective alkane functionalizations. CHEMICAL SCIENCE[J]. 2023, 14(25): 6841-6859, http://dx.doi.org/10.1039/d3sc01118f.[4] An, Qing, Xing, YangYang, Pu, Ruihua, Jia, Menghui, Chen, Yuegang, Hu, Anhua, Zhang, ShuoQing, Yu, Na, Du, Jianbo, Zhang, Yanxia, Chen, Jinquan, Liu, Weimin, Hong, Xin, Zuo, Zhiwei. Identification of Alkoxy Radicals as Hydrogen Atom Transfer Agents in Ce-Catalyzed C-H Functionalization. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2022, [5] Chang, Liang, An, Qing, Duan, Lingfei, Feng, Kaixuan, Zuo, Zhiwei. Alkoxy Radicals See the Light: New Paradigms of Photochemical Synthesis. CHEMICAL REVIEWSnull. 2022, 122(2): 2429-2486, http://dx.doi.org/10.1021/acs.chemrev.1c00256.[6] Chen, Yuegang, Wang, Xin, He, Xu, An, Qing, Zuo, Zhiwei. Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2021, 143(13): 4896-4902, http://dx.doi.org/10.1021/jacs.1c00618.[7] Du, Jianbo, Yang, Xiaokun, Wang, Xin, An, Qing, He, Xu, Pan, Hui, Zuo, Zhiwei. Photocatalytic Aerobic Oxidative Ring Expansion of Cyclic Ketones to Macrolactones by Cerium and Cyanoanthracene Catalysis. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2021, 60(10): 5370-5376, http://dx.doi.org/10.1002/anie.202012720.[8] Wang, ChangCheng, Zhang, GuoXiang, Zuo, ZhiWei, Zeng, Rong, Zhai, DanDan, Liu, Feng, Shi, ZhangJie. Photo-induced deep aerobic oxidation of alkyl aromatics. SCIENCE CHINA-CHEMISTRY[J]. 2021, 64(9): 1487-1492, http://sciencechina.cn/gw.jsp?action=detail.jsp&internal_id=7059051&detailType=1.[9] 杜建波, 陈跃刚, 左智伟. 光促芳香烃甲基化反应研究进展. 有机化学[J]. 2020, 40(11): 3646-3655, http://lib.cqvip.com/Qikan/Article/Detail?id=7103741175.[10] An, Qing, Wang, Ziyu, Chen, Yuegang, Wang, Xin, Zhang, Kaining, Pan, Hui, Liu, Weimin, Zuo, Zhiwei. Cerium-Catalyzed C-H Functionalizations of Alkanes Utilizing Alcohols as Hydrogen Atom Transfer Agents. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2020, 142(13): 6216-6226, http://dx.doi.org/10.1021/jacs.0c00212.[11] Chen, Yilin, Du, Jianbo, Zuo, Zhiwei. Selective C-C Bond Scission of Ketones via Visible-Light-Mediated Cerium Catalysis. CHEM[J]. 2020, 6(1): 266-279, http://dx.doi.org/10.1016/j.chempr.2019.11.009.[12] Du, Jianbo, Chen, Yuegang, Zuo, Zhiwei. Recent Progress of Photocatalytic Methylation of Arenes. CHINESE JOURNAL OF ORGANIC CHEMISTRYnull. 2020, 40(11): 3646-3655, http://sciencechina.cn/gw.jsp?action=detail.jsp&internal_id=6867326&detailType=1.[13] Zhang, Kaining, Chang, Liang, An, Qing, Wang, Xin, Zuo, Zhiwei. Dehydroxymethylation of Alcohols Enabled by Cerium Photocatalysis. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2019, 141(26): 10556-10564, http://dx.doi.org/10.1021/jacs.9b05932.[14] Chang, Liang, Chen, Yilin, Zuo, Zhiwei. Dearomative 4+2 Cycloaddition of Pyridine via Energy-Transfer Catalysis. CHEMnull. 2019, 5(11): 2744-2746, [15] Cheng, Hao, Wang, Xin, Chang, Liang, Chen, Yilin, Chu, Lingling, Zuo, Zhiwei. Bisphosphonium salt: an effective photocatalyst for the intramolecular hydroalkoxylation of olefins. SCIENCE BULLETIN[J]. 2019, 64(24): 1896-1901, http://lib.cqvip.com/Qikan/Article/Detail?id=7100741842.[16] Hu, Anhua, Guo, JingJing, Pan, Hui, Zuo, Zhiwei. Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis. SCIENCE[J]. 2018, 361(6403): 668-+, https://www.webofscience.com/wos/woscc/full-record/WOS:000442818200036.[17] Hu, Anhua, Chen, Yilin, Guo, JingJing, Yu, Na, An, Qing, Zuo, Zhiwei. Cerium-Catalyzed Formal Cycloaddition of Cycloalkanols with Alkenes through Dual Photoexcitation. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2018, 140(42): 13580-13585, http://dx.doi.org/10.1021/jacs.8b08781.[18] Hu, Anhua, Guo, JingJing, Pan, Hui, Tang, Haoming, Gao, Zhaobo, Zuo, Zhiwei. delta-Selective Functionalization of Alkanols Enabled by Visible-Light-Induced Ligand-to-Metal Charge Transfer. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2018, 140(5): 1612-1616, http://dx.doi.org/10.1021/jacs.7b13131.[19] Guo, JingJing, Hu, Anhua, Zuo, Zhiwei. Photocatalytic alkoxy radical-mediated transformations. TETRAHEDRON LETTERS[J]. 2018, 59(22): 2103-2111, http://dx.doi.org/10.1016/j.tetlet.2018.04.060.[20] Zuo, Zhiwei, Gong, Huan, Li, Wei, Choi, Junwon, Fu, Gregory C, MacMillan, David W C. Enantioselective Decarboxylative Arylation of alpha-Amino Acids via the Merger of Photoredox and Nickel Catalysis. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2016, 138(6): 1832-1835, http://dx.doi.org/10.1021/jacs.5b13211.[21] Guo, JingJing, Hu, Anhua, Chen, Yilin, Sun, Jianfeng, Tang, Haoming, Zuo, Zhiwei. Photocatalytic C-C Bond Cleavage and Amination of Cycloalkanols by Cerium(III) Chloride Complex. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2016, 55(49): 15319-15322, https://www.doi.org/10.1002/anie.201609035.[22] Zi, Weiwei, Zuo, Zhiwei, Ma, Dawei. Intramolecular Dearomative Oxidative Coupling of Indoles: A Unified Strategy for the Total Synthesis of Indoline Alkaloids. ACCOUNTS OF CHEMICAL RESEARCHnull. 2015, 48(3): 702-711, https://www.webofscience.com/wos/woscc/full-record/WOS:000351326900022.[23] Zuo, Zhiwei, MacMillan, David W C. Decarboxylative Arylation of alpha-Amino Acids via Photoredox Catalysis: A One-Step Conversion of Biomass to Drug Pharmacophore. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2014, 136(14): 5257-5260, https://www.webofscience.com/wos/woscc/full-record/WOS:000334572200020.[24] Chu, Lingling, Ohta, Chisa, Zuo, Zhiwei, MacMillan, David W C. Carboxylic Acids as A Traceless Activation Group for Conjugate Additions: A Three-Step Synthesis of (+/-)-Pregabalin. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2014, 136(31): 10886-10889, https://www.webofscience.com/wos/woscc/full-record/WOS:000340079800017.[25] Zuo, Zhiwei, Ahneman, Derek T, Chu, Lingling, Terrett, Jack A, Doyle, Abigail G, MacMillan, David W C. Merging photoredox with nickel catalysis: Coupling of alpha-carboxyl sp(3)-carbons with aryl halides. SCIENCE[J]. 2014, 345(6195): 437-440, https://www.webofscience.com/wos/woscc/full-record/WOS:000339655100039.[26] Xie, Weiqing, Zuo, Zhiwei, Zi, Weiwei, Ma, Dawei. Intramolecular Oxidative Coupling: Applications in Synthesis of Complex Indole Akaloid Scaffolds. CHINESE JOURNAL OF ORGANIC CHEMISTRY[J]. 2013, 33(5): 869-876, http://dx.doi.org/10.6023/cjoc201301035.[27] Xie Weiqing, Zuo Zhiwei, Zi Weiwei, Ma Dawei. Intramolecular Oxidative Coupling: Applications in Synthesis of Complex Indole Akaloid Scaffolds. CHINESE JOURNAL OF ORGANIC CHEMISTRY[J]. 2013, 33(5): 869-876, http://doi.org/10.6023/cjoc201301035.[28] 谢卫青, 王鹤翔, 范峰, 田俊山, 左智伟, 资伟伟, 高锟, 马大为. Diastereoselective construction of continuous all-carbon quaternary centers via intramolecular oxidative coupling reaction. TETRAHEDRON LETT.[J]. 2013, 54(33): 4392-4396, http://dx.doi.org/10.1016/j.tetlet.2013.05.146.[29] Xie, Weiqing, Wang, Hexiang, Fan, Feng, Tian, Junshan, Zuo, Zhiwei, Zi, Weiwei, Gao, Kun, Ma, Dawei. Diastereoselective construction of continuous all-carbon quaternary centers via intramolecular oxidative coupling reaction. TETRAHEDRON LETTERS[J]. 2013, 54(33): 4392-4396, http://dx.doi.org/10.1016/j.tetlet.2013.05.146.[30] Zuo, Zhiwei, Ma, Dawei. Synthetic Studies toward Communesins. ISRAEL JOURNAL OF CHEMISTRY[J]. 2011, 51(3-4): 434-441, http://www.irgrid.ac.cn/handle/1471x/583325.[31] Zuo, Zhiwei, Ma, Dawei. Enantioselective Total Syntheses of Communesins A and B. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2011, 50(50): 12008-12011, http://www.irgrid.ac.cn/handle/1471x/583331.[32] Zuo, Zhiwei, Xie, Weiqing, Ma, Dawei. Total Synthesis and Absolute Stereochemical Assignment of (-)-Communesin F. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2010, 132(38): 13226-13228, http://202.127.28.38/handle/331003/15625.
科研活动
科研项目
( 1 ) 光促环酮扩环反应应用于中环内酯 合成研究, 主持, 国家级, 2020-01--2023-12( 2 ) 铈催化的环醇碳碳键断裂-插入反应 研究, 主持, 国家级, 2018-01--2021-12
指导学生
已指导学生
陈奕霖 博士研究生 070303-有机化学
现指导学生
张凯宁 博士研究生 070303-有机化学
汤昊明 博士研究生 070303-有机化学