070303-有机化学

金属有机化学
烯烃聚合
能源化学

2004-08--2009-08   美国北卡罗来纳大学   博士

   

2012-02~现在, 中国科学院上海有机化学研究所, 研究员
2009-08~2012-02,美国伊利诺伊大学, 博士后
2004-08~2009-08,美国北卡罗来纳大学, 博士

物理有机化学

   

（1） 张江国家自主创新示范区杰出创新创业人才, 特等奖, 市地级, 2021
（2） 中国化学会物理有机化学青年奖, 特等奖, 部委级, 2019
（3） 中国化学会-赢创化学创新奖-杰出青年科学家奖, 特等奖, 部委级, 2018
（4） 陈嘉庚青年科学奖（化学）, 特等奖, 国家级, 2018
（5） 上海市第九届青年科技英才奖, 特等奖, 省级, 2018
（6） 中国均相催化青年奖, 特等奖, 部委级, 2017
（7） 中科院上海分院第五届十大“杰出青年科技创新人才”奖, 特等奖, 院级, 2016
（8） 中科院－沙特基础工业公司导师科研奖, 特等奖, 其他, 2016

   

（1） Iridium-Catalyzed Enantioselective Transfer Hydrogenation of 1,1-Dialkylethenes with Ethanol: Scope and Mechanism, J. Am. Chem. Soc., 2024, 第 10 作者  通讯作者
（2） Chloroiridium Complexes of Biaryl-Based Diphosphines for Thermal Catalytic Transfer Dehydrogenation of Hindered 1,1-Disubstituted Ethanes., ACS Catal., 2024, 第 6 作者
（3） Beyond Conventional Degradation: Catalytic Solutions for Polyolefin Upcycling., CCS Chemistry, 2024, 第 7 作者  通讯作者
（4） Coupling CO 2 Electroreduction to CO with alkyne Alkoxycarbonylation, ORGANIC LETTERS, 2024, 第 5 作者  通讯作者
（5） Site- and Enantioselective Homobenzylic C(sp 3 )-H Borylation via Dehydrogenation of Alkyl Chains, ORGANIC LETTERS, 2024, 第 3 作者  通讯作者
（6） Alkene Cyclopropanation with gem -Dichloroalkanes Catalyzed by (PNN)Co Complexes: Scope and Mechanism, ACS CATALYSIS, 2024, 第 3 作者  通讯作者
（7） Iridium-Catalyzed Enantioselective Transfer Hydrogenation of 1,1-Dialkylethenes with Ethanol: Scope and Mechanism, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 第 11 作者  通讯作者
（8） 二硼二氯甲烷作为通用试剂化学发散性构建偕二硼烷, Diborodichloromethane as Versatile Reagent for Chemodivergent Synthesis of gem-Diborylalkanes, 有机化学, 2024, 第 2 作者
（9） Palladium-Catalyzed Remote Hydrosulfonamidation of Alkenes: Access to Primary N -Alkyl Sulfamides by the SuFEx Reaction, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 第 7 作者
（10） Chloroiridium Complexes of Biaryl-Based Diphosphines for Thermal Catalytic Transfer Dehydrogenation of Hindered 1,1-Disubstituted Ethanes, ACS CATALYSIS, 2024, 第 6 作者  通讯作者
（11） Enantioselective Synthesis of Oxa-Spirosilanes via Dual Dehydrogenative Silylation of C(sp 3 )-H Bonds Catalyzed by Chiral Pincer Iridium Complexes, ORGANOMETALLICS, 2024, 第 5 作者  通讯作者
（12） Electrochemical epoxidation of alkene with high faradaic efficiencies using water as an oxygen source, GREEN CHEMISTRY, 2024, 第 5 作者  通讯作者
（13） Thermally Robust and Highly Active PCP Cobalt(II) Catalyst for Linear-Selective Hydroboration of Terminal and Internal Olefins., ACS Catal., 2023, 第 6 作者
（14） Thermally Robust and Highly Active PCP Cobalt(II) Catalyst for Linear-Selective Hydroboration of Terminal and Internal Olefins, ACS CATALYSIS, 2023, 第 6 作者  通讯作者
（15） Oxidative Dehydrogenation of Alkanes through Homogeneous Base Metal Catalysis, CHEMICAL RECORD, 2023, 第 3 作者  通讯作者
（16） Iridium-Catalyzed Asymmetric Transfer Hydrogenation of 1-Aryl-1-alkylethenes with Ethanol, ORGANIC LETTERS, 2023, 第 4 作者  通讯作者
（17） A New Paradigm in Pincer Iridium Chemistry: PCN Complexes for (De)Hydrogenation Catalysis and Beyond, Acc. Chem. Res., 2022, 第 4 作者  通讯作者
（18） Selective Dehydrogenation of Small and Large Molecules by a Chloroiridium Catalyst., Sci. Adv., 2022, 第 6 作者  通讯作者
（19） A New Paradigm in Pincer Iridium Chemistry: PCN Complexes for (De)Hydrogenation Catalysis and Beyond, ACCOUNTS OF CHEMICAL RESEARCH, 2022, 第 4 作者  通讯作者
（20） Breaking Conventional Site Selectivity in C-H Bond Activation: Selective spi versus spe Silylation by a Pincer-Based Pocket, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 第 10 作者  通讯作者
（21） Thio-imino-tetrahydroacridine Iron Complexes for Ethylene Polymerization, ORGANOMETALLICS, 2022, 第 4 作者  通讯作者
（22） Undirected, Asymmetric Alkyl Group Functionalizations through Alkane Dehydrogenation, ORGANIC LETTERS, 2022, 第 5 作者  通讯作者
（23） 让塑料和我们的生活更相宜, 科技视界, 2022, 第 2 作者
（24） Iridium-Catalyzed Selective trans-Semihydrogenation of 1,3-Enynes with Ethanol: Access to ( E,E )-1,4-Diarylbutadienes, ORGANIC LETTERS, 2022, 第 4 作者  通讯作者
（25） Iridium-Catalyzed Selective trans-Semihydrogenation of 1,3-Enynes with Ethanol: Access to (E,E)-1,4-Diarylbutadienes, ORGANIC LETTERS, 2022, 第 4 作者  通讯作者
（26） Ru-Catalyzed Site-Selective Aliphatic C-H Bond Silylation of Amides and Carbamides, ORGANOMETALLICS, 2021, 第 4 作者  通讯作者
（27） Iron Catalyzed Isomerization of ��-Alkyl Styrenes to Access Trisubstituted Alkenes, CHINESE JOURNAL OF CHEMISTRY, 2021, 第 3 作者
（28） An Amine-Assisted Ionic Monohydride Mechanism Enables Selective Alkyne cis-Semihydrogenation with Ethanol: From Elementary Steps to Catalysis, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 第 4 作者  通讯作者
（29） Ruthenium-Catalyzed Dual Dehydrogenative Silylation of C(sp(3))-H Bonds: Access to Diverse Silicon-Centered Spirocycles, ORGANIC LETTERS, 2021, 第 4 作者  通讯作者
（30） Chiral Iridium Complexes of Anionic NCP Pincer Ligand for Asymmetric Transfer Hydrogenation of 1,1-Diarylethenes with Ethanol, ORGANIC LETTERS, 2021, 第 6 作者  通讯作者
（31） Iron-Catalyzed Regio- and Stereoselective Hydrosilylation of 1,3-Enynes To Access 1,3-Dienylsilanes, ORGANIC LETTERS, 2021, 第 4 作者  通讯作者
（32） Pincer Iron Hydride Complexes for Alkene Isomerization: Catalytic Approach to Trisubstituted (Z)-Alkenyl Boronates, ACS CATALYSIS, 2021, 第 7 作者  通讯作者
（33） Site-Selective Acceptorless Dehydrogenation of Aliphatics Enabled by Organophotoredox/Cobalt Dual Catalysis, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 第 5 作者  通讯作者
（34） N-Bridged Pincer Iridium Complexes for Highly Efficient Alkane Dehydrogenation and the Relevant Linker Effects, ACS CATALYSIS, 2020, 第 6 作者  通讯作者
（35） 基于马来酰亚胺的不对称硅氢化一步实现碳手性、轴手性的构建, Single-Step Construction of Carbon Chirality and Axial Chirality by Enantioselective Hydrosilylation of Maleimides, 有机化学, 2020, 第 2 作者
（36） Double-Linear Insertion Mode of alpha,omega-Dienes Enabled by Thio-imino-quinoline Iron Catalyst, ACS CATALYSIS, 2020, 第 8 作者  通讯作者
（37） Single-Step Construction of Carbon Chirality and Axial Chirality by Enantioselective Hydrosilylation of Maleimides, CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2020, 第 2 作者  通讯作者
（38） Dehydrogenation of Primary Alkyl Azides to Nitriles Catalyzed by Pincer Iridium/Ruthenium Complexes, CHEMCATCHEM, 2020, 第 5 作者  通讯作者
（39） Cobalt-Catalyzed Regio- and Stereoselective Hydroboration of Allenes, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 第 5 作者  通讯作者
（40） Ruthenium-Catalyzed Hydrodefluorination with Silane as the Directing and Reducing Group, ORGANIC LETTERS, 2020, 第 4 作者  通讯作者
（41） A BEt3-Base Catalyst for Amide Reduction with Silane, JOURNAL OF ORGANIC CHEMISTRY, 2019, 第 6 作者  通讯作者
（42） Ligand controlled cobalt catalyzed regiodivergent 1,2-hydroboration of 1,3-dienes, SCIENCE CHINA Chemistry, 2019, 第 4 作者  通讯作者
（43） Cobalt-Catalyzed Asymmetric Hydrogenation of Vinylsilanes with a Phosphine-Pyridine-Oxazoline Ligand: Synthesis of Optically Active Organosilanes and Silacycles, ORGANOMETALLICS, 2019, 第 7 作者  通讯作者
（44） Cobalt-Catalyzed Regio- and Enantioselective Markovnikov 1,2-Hydrosilylation of Conjugated Dienes, ACS CATALYSIS, 2019, 第 5 作者  通讯作者
（45） 聚乙烯废塑料温和降解, 科技纵览, 2019, 第 1 作者
（46） Transfer Hydrogenation of Alkenes Using Ethanol Catalyzed by a NCP Pincer Iridium Complex: Scope and Mechanism, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 第 6 作者  通讯作者
（47） 过渡金属分子催化的烷烃转化进展, Transition-metal complex-catalyzed alkane functionalization, 科学通报, 2018, 第 2 作者
（48） Thermal, Catalytic Conversion of Alkanes to Linear Aldehydes and Linear Amines., JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 第 3 作者  通讯作者
（49） Mixed Diboration of Alkynes Catalyzed by LiOH: Regio- and Stereoselective Synthesis of cis-1,2-Diborylalkenes, ORGANIC LETTERS, 2018, 第 3 作者  通讯作者
（50） An Agostic Iridium Pincer Complex as a Highly Efficient and Selective Catalyst for Monoisomerization of 1-Alkenes to trans-2-Alkenes, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 第 5 作者  通讯作者
（51） Manganese-Catalyzed Asymmetric Hydrosilylation ofAryl Ketones, ACS OMEGA, 2017, 第 4 作者  通讯作者
（52） Advances in Base-Metal-Catalyzed Alkene Hydrosilylation, ACS CATALYSIS, 2017, 第 2 作者  通讯作者
（53） Pincer Ruthenium Catalyzed Intramolecular Silylation of C(sp(2))-H Bonds, SYNLETT, 2017, 第 4 作者  通讯作者
（54） Phosphine-Iminoquinoline Iron Complexes for Ethylene Polymerization and Copolymerization, ORGANOMETALLICS, 2017, 第 5 作者  通讯作者
（55） Pincer cobalt complex-catalyzed Z-selective hydrosilylation of terminal alkynes, ORGANIC CHEMISTRY FRONTIERS, 2017, 第 4 作者  通讯作者
（56） Identifying a cobalt catalyst for highly selective hydrosilylation of allenes, ORGANIC CHEMISTRY FRONTIERS, 2017, 第 4 作者  通讯作者
（57） Light-alkane functionalization and polyethylene degradation, ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 第 1 作者
（58） Ruthenium-Catalyzed Site-Selective Intramolecular Silylation of Primary C-H Bonds for Synthesis of Sila-Heterocycles, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 第 4 作者  通讯作者
（59） Stereoselective Synthesis of Trisubstituted Alkenes via Cobalt-Catalyzed Double Dehydrogenative Borylations of 1-Alkenes, ACS CATALYSIS, 2017, 第 5 作者  通讯作者
（60） A highly efficient catalytic alpha-alkylation of unactivated amides using primary alcohols, TETRAHEDRON LETTERS, 2016, 第 6 作者  通讯作者
（61） A Pincer Ruthenium Complex for Regioselective C-H Silylation of Heteroarenes, ORGANIC LETTERS, 2016, 第 5 作者  通讯作者
（62） Efficient and selective degradation of polyethylenes into liquid fuels and waxes under mild conditions, SCIENCE ADVANCES, 2016, 第 5 作者  通讯作者
（63） Cobalt-Catalyzed Borylation of Aryl Halides and Pseudohalides, ORGANOMETALLICS, 2016, 第 7 作者  通讯作者
（64） Conversion of alkanes to linear alkylsilanes using an iridium-iron-catalysed tandem dehydrogenation-isomerization-hydrosilylation, NATURE CHEMISTRY, 2016, 第 2 作者  通讯作者
（65） Conversion of alkanes to linear alkylsilanes using an iridium-iron-catalysed tandem dehydrogenation-isomerization-hydrosilylation., NATURE CHEMISTRY, 2016, 第 2 作者  通讯作者
（66） Catalytic alkane transfer-dehydrogenation by PSCOP iridium pincer complexes, POLYHEDRON, 2016, 第 6 作者  通讯作者
（67） Synthesis of Pincer Hydrido Ruthenium Olefin Complexes for Catalytic Alkane Dehydrogenation, ORGANOMETALLICS, 2016, 第 5 作者  通讯作者
（68） Cobalt-Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 第 3 作者  通讯作者
（69） Synthesis of 1,1-diboronate esters by cobalt-catalyzed sequential hydroboration of terminal alkynes, ORGANIC CHEMISTRY FRONTIERS, 2016, 第 2 作者  通讯作者
（70） Base-Metal-Catalyzed Regiodivergent Alkene Hydrosilylations, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 第 4 作者  通讯作者
（71） Catalytic alkane dehydrogenations, Science Bulletin, 2015, 第 5 作者
（72） Pincer iron and cobalt complexes for cataltyic alkene hydrofunctionalizations, ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 第 1 作者
（73） A General and Mild Catalytic alpha-Alkylation of Unactivated Esters Using Alcohols, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 第 5 作者  通讯作者
（74） Synthesis and characterization of a tetradentate PNCP iridium complex for catalytic alkane dehydrogenation, SCIENCE CHINA Chemistry, 2015, 第 2 作者  通讯作者
（75） Iron-catalyzed asymmetric hydrosilylation of ketones, CHEMICAL COMMUNICATIONS, 2015, 第 4 作者  通讯作者
（76） A General, Practical Triethylborane-Catalyzed Reduction of Carbonyl Functions to Alcohols, CHEMISTRY-A EUROPEAN JOURNAL, 2015, 第 3 作者  通讯作者
（77） Synthesis of 1,1,1-Tris(boronates) from Vinylarenes by Co-Catalyzed Dehydrogenative Borylations-Hydroboration., JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 第 2 作者  通讯作者
（78） A General and Mild Catalytic �����Alkylation of Unactivated Esters Using Alcohols, ANGEWANDTE CHEMIE INTERNATIONAL EDITION, 2015, 
（79） Iridium complexes of new NCP pincer ligands: catalytic alkane dehydrogenation and alkene isomerization, CHEM. COMMUN., 2014, 第 6 作者
（80） Selective synthesis of secondary benzylic (Z)-allylboronates by Fe-catalyzed 1,4-hydroboration of 1-aryl-substituted 1,3-dienes, ORG. CHEM. FRONT., 2014, 第 6 作者
（81） Selective synthesis of secondary benzylic (Z)-allylboronates by Fe-catalyzed 1,4-hydroboration of 1-aryl-substituted 1,3-dienes, ORGANIC CHEMISTRY FRONTIERS, 2014, 第 6 作者
（82） Cationic Palladium(II) Complexes of Phosphine-Sulfonamide Ligands: Synthesis, Characterization, and Catalytic Ethylene Oligomerization, ORGANOMETALLICS, 2014, 第 5 作者
（83） Iridium complexes of new NCP pincer ligands: catalytic alkane dehydrogenation and alkene isomerization, CHEMICAL COMMUNICATIONS, 2014, 第 5 作者  通讯作者
（84） Selective Catalytic Transfer Dehydrogenation of Alkanes and Heterocycles by an Iridium Pincer Complex, ANGEW. CHEM.-INT. EDIT., 2014, 第 4 作者
（85） A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane, ANGEW. CHEM.-INT. EDIT., 2014, 第 4 作者
（86） Cobalt-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Aryl Alkenes, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 第 4 作者  通讯作者
（87） Selective Catalytic Transfer Dehydrogenation of Alkanes and Heterocycles by an Iridium Pincer Complex, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 第 4 作者  通讯作者
（88） Cobalt-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Aryl Alkenes, J. AM. CHEM. SOC., 2014, 第 4 作者
（89） A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 第 4 作者  通讯作者
（90） Phosphinite-Iminopyridine Iron Catalysts for Chemoselective Alkene Hydrosilylation, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 第 7 作者
（91） Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 第 4 作者  通讯作者
（92） Iron-Catalyzed Alkene Hydroboration with Pinacolborane, SYNLETT, 2013, 第 2 作者  通讯作者
（93） Iridium-Catalyzed Selective alpha-Alkylation of Unactivated Amides with Primary Alcohols, ORGANIC LETTERS, 2013, 第 5 作者  通讯作者
（94） Olefin Isomerization by Iridium Pincer Catalysts. Experimental Evidence for an eta(3)-Allyl Pathway and an Unconventional Mechanism Predicted by DFT Calculations, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 第 2 作者
（95） Copper(I) Enolate Complexes in a-Arylation Reactions: Synthesis, Reactivity, and Mechanism, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 第 1 作者
（96） Olefin Isomerization by Iridium Pincer Catalysts. Experimental Evidence for an �� 3 -Allyl Pathway and an Unconventional Mechanism Predicted by DFT Calculations, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 第 2 作者
（97） Reactions of phosphinites with oxide surfaces: a new method for anchoring organic and organometallic complexes, DALTON TRANSACTIONS, 2011, 第 2 作者
（98） Breaking Conventional Site Selectivity in C���H Bond Activation: Selective sp3 versus sp2 Silylation by a Pincer-Based Pocket, J. Am. Chem. Soc., 2011, 第 10 作者  通讯作者
（99） Ligand exchanges and selective catalytic hydrogenation in molecular single crystals, NATURE, 2010, 第 1 作者
（100） Efficient Heterogeneous Dual Catalyst Systems for Alkane Metathesis, ADVANCED SYNTHESIS & CATALYSIS, 2010, 第 1 作者
（101） N-H Activation of Hydrazines by Iridium(I). Double N-H Activation To Form Iridium Aminonitrene Complexes, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 第 1 作者
（102） Evaluation of Molybdenum and Tungsten Metathesis Catalysts for Homogeneous Tandem Alkane Metathesis, ORGANOMETALLICS, 2009, 第 5 作者
（103） Highly Active and Recyclable Heterogeneous Iridium Pincer Catalysts for Transfer Dehydrogenation of Alkanes, ADVANCED SYNTHESIS & CATALYSIS, 2009, 第 1 作者

   

（ 1 ） 过渡金属催化的饱和烃类物质升级转换, 负责人, 国家任务, 2024-05--2028-12
（ 2 ） 烷烃温和选择性催化脱氢和转化, 负责人, 地方任务, 2023-12--2026-11
（ 3 ） 金属高效催化偶联的理论与应用, 负责人, 中国科学院计划, 2023-12--2028-11
（ 4 ） 金属介导碳氢活化（脱氢）启动的C-C/O键选择性活化转化, 负责人, 国家任务, 2023-01--2027-12
（ 5 ） 大宗高分子材料的催化循环和升级回收, 负责人, 国家任务, 2022-01--2026-12
（ 6 ） 金属有机化学和催化, 负责人, 国家任务, 2015-01--2017-12
（ 7 ） 基于Csp3-Csp3（H）键断裂与重组的有机合成新反应, 参与, 国家任务, 2015-01--2019-12
（ 8 ） 含乙烯基的极性单体和非极性单体的配位共聚及其机理研究, 负责人, 国家任务, 2013-01--2016-12