基本信息
高希珂  男  博导  中国科学院上海有机化学研究所
电子邮件: gaoxk@sioc.ac.cn
通信地址: 上海市零陵路345号
邮政编码: 200032

研究领域

有机分子功能材料化学




招生信息

每年招收研究生2-3名

招生专业
070305-高分子化学与物理
070303-有机化学
招生方向
非苯芳烃化学(薁化学)
有机光电功能材料化学
有机生物功能材料化学

教育背景

2005-09--2008-07   中国科学院化学研究所   博士
学历
-- 研究生
学位
-- 博士

教授课程

有机π功能分子材料化学

申请专利

     
奖励信息
(1) 硫杂萘二酰亚胺类高性能n-型有机半导体材料, 二等奖, 省级, 2020
(2) 上海市科技系统青年五四奖章, , 省级, 2016
(3) 中国科学院上海分院青年五四奖章, , 院级, 2015
(4) 中国科学院青年创新促进会首批优秀会员, 院级, 2015
(5) 中国科学院卢嘉锡青年人才奖, , 院级, 2013
专利成果
( 1 ) 一种2,3,6,7-四溴代萘四羧酸二酰亚胺化合物、制备及用途, 发明, 2009, 第 1 作者, 专利号: ZL201210019769.9
( 2 ) Sulfur Containing Heterocycle-Fused Naphthalene Tetracarboxylic Acid Diimide Derivatives, Preparation Method And Use Thereof, 发明, 2012, 第 1 作者, 专利号: US 8,471,021B2
( 3 ) 硫杂环稠合的萘二酰亚胺类化合物、制备方法和应用, 发明, 2011, 第 1 作者, 专利号: ZL201110225678.6
( 4 ) 含硒π扩展萘四羧酸二酰亚胺化合物、制法和应用, 发明, 2014, 第 1 作者, 专利号: 2014100407588
( 5 ) Sulfur Containing Heterocycle-Fused Naphthalene Tetracarboxylic Acid Diimide Derivatives, Preparation Method And Use Thereof, 发明, 2010, 第 1 作者, 专利号: JP5416282
( 6 ) 一锅法制备硫杂环稠合的萘二酰亚胺衍生物的方法, 发明, 2011, 第 1 作者, 专利号: ZL201110224812.0
( 7 ) Sulfur Containing Heterocycle-Fused Naphthalene Tetracarboxylic Acid Diimide Derivatives, Preparation Method And Use Thereof, 发明, 2012, 第 1 作者, 专利号: 10-1496931
( 8 ) 含2-(1,3-二硫/硒-2-亚基)乙氰共轭结构单元的萘二酰亚胺及其衍生物, 发明, 2014, 第 1 作者, 专利号: ZL2014104222896
( 9 ) 二噻吩并䓛二酰亚胺衍生物、其中间体、制备方法和应用, 发明, 2020, 第 1 作者, 专利号: 201710244321.X
( 10 ) 含有1,3-二硫-2-叶立德烯共轭单元的萘二酰亚胺衍生物、制备方法和应用, 发明, 2013, 第 1 作者, 专利号: ZL201310322972.8
( 11 ) 联薁二酰亚胺衍生物、其制备方法和应用, 发明, 2019, 第 1 作者, 专利号: 201610554416.7
( 12 ) 以萘四羧酸二酰亚胺为核的硫杂共轭化合物、制法和应用, 发明, 2009, 第 1 作者, 专利号: ZL200910197611.9
( 13 ) 硫杂环稠合的萘四羧酸二酰亚胺衍生物及制法和应用, 发明, 2010, 第 1 作者, 专利号: ZL201010207565.9
( 14 ) 一种含薁共轭聚合物、其中间体及应用, 发明, 2020, 第 1 作者, 专利号: 201711279898.0
( 15 ) Sulfur Containing Heterocycle-Fused Naphthalene Tetracarboxylic Acid Diimide Derivatives, Preparation Method And Use Thereof, 发明, 2018, 第 1 作者, 专利号: EU2492271

代表论文


1. Hanshen Xin, Bin Hou, Xike Gao.* Azulene-Based πFunct​ional Materials: Design, Synthesis, and Applications. Acc. Chem. Res. 2021, 54 , 1737-1753.

2.  Hanshen Xin, Jing Li, Ru-Qiang Lu, Xike Gao,* Timothy. M. Swager.* Azulene–Pyridine-Fused Heteroaromatics. J. Am. Chem. Soc. 2020, 142, 13598-13605.

3. Hanshen Xin, Congwu Ge, Xiaodi Yang, Honglei Gao, Xiaochun Yang, Xike Gao.* Biazulene diimides: a new building block for organic electronic materials. Chem. Sci. 2016, 7, 6701-6705. (Highlighted by Synfacts 2016, 12,1040)

4. Hanshen Xin, Congwu Ge, Xuechen Jiao, Xiaodi Yang, Kira Rundel, Christopher R. McNeill, Xike Gao.* Incorporation of 2,6-Connected Azulene Units into the Backbone of Conjugated Polymers: Towards High-Performance Organic Optoelectronic Materials. Angew. Chem. Int. Ed. 2018, 57, 1322-1326. (Highlighted by Synfacts 2018, 14, 0258 and Sci. China. Chem. 2018, 61, 973-974)

5. Hanshen Xin, Xike Gao.* Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog. ChemPlusChem. 2017, 82, 945-956. (Most accessed and cited paper, highlighted by Angew. Chem. Int. Ed. 2017, 56, 10018)

6. Yunbin Hu, Zhongli Wang, Xu Zhang, Xiaodi Yang, Congwu Ge, Lina Fu, Xike Gao.* A Class of Electron-Transporting Vinylogous Tetrathiafulvalenes Constructed by the Dimerization of Core-Expanded Naphthalenediimides. Org. Lett. 2017, 19, 468-471. (Highlighted by Synfacts 2017, 13, 0373)

7. Xueqian Zhao, Congwu Ge, Xiaodi Yang, Xike Gao.* Dithieno[3,2-a:3Dithieno[3,2-a:3’,2’-j][5,6,11,12]chrysene diimides and their Molecular Energy Levels Regulation. Mater. Chem. Front. 2017, 1, 1635-1640.

8. Honglei Gao, Congwu Ge, Bin Hou, Hanshen Xin, Xike Gao.* Incorporation of 1,3-Free-2,6-Connected Azulene Units into the Backbone of Conjugated Polymers: Improving Proton Responsiveness and Electrical Conductivity. ACS Macro Lett. 2019, 8, 1360-1364. (Highlighted by Synfacts 2019, 15,1374)

9. Xike Gao,* Chong-an Di,* Yunbin Hu, Xiaodi Yang, Hongyu Fan, Feng Zhang, Yunqi Liu, Hongxiang Li, Daoben Zhu. Core-expanded naphthalene diimides fused with 2-(1,3-dithiol-2-ylidene)malonitrile groups for high-performance, ambient-stable, solution-processed n-channel organic thin film transistors. J. Am. Chem. Soc. 2010, 132, 3697-3699.

10.  Fengjiao Zhang,# Yunbin Hu,# Torben, Schuettfort, Chong-an Di,* Xike Gao,* Christopher R McNeill,* Lars Thomsen, Stefan C B Mannsfeld, Wei Yuan, Henning Sirringhaus, Daoben Zhu.* Critical Role of Alkyl Chain Branching of Organic Semiconductors in Enabling Solution-Processed N-channel Organic Thin-film Transistors with Mobility of up to 3.50 cm2V-1s-1. J. Am. Chem. Soc. 2013, 135, 2338-2349. (# Co-first authors)


发表论文
(1) Azulene-Based π‑Functional Materials: Design, Synthesis, and Applications, Accounts of Chemical Research, 2021, 通讯作者
(2) Azulene-Based BN-Heteroaromatics, The Journal of Organic Chemistry, 2020, 85(1): 70-78., 2020, 通讯作者
(3) 基于硫杂萘二酰亚胺的席夫碱型聚合物电子传输材料基于硫杂萘二酰亚胺的席夫碱型聚合物电子传输材料, 功能高分子学报 2020, 33(2): 148-156., 2020, 通讯作者
(4) Rhodanine-Bridged Core-Expanded Naphthalene Diimide Derivatives for n-Type Semiconductors, Organic Materials 2020, 2, 165–172, 2020, 通讯作者
(5) Azulene–Pyridine-Fused Heteroaromatics, Journal of the American Chemical Society, 2020, 通讯作者
(6) Incorporation of 1,3-Free-2,6-Connected Azulene Units into the Backbone of Conjugated Polymers: Improving Proton Responsiveness and Electrical Conductivity, ACS Macro Letterss, 2019, 8(10): 1360-1364. , 2019, 通讯作者
(7) Dithieno[3,2-a:3′,2′-j][5,6,11,12]chrysene diimides: a versatile electron-deficient building block for polymeric semiconductors, Chemical Communications , 2019, 55(69): 10234-10237., 2019, 通讯作者
(8) Enantiopure versus racemic naphthalene diimide-based n-type organic semiconductors: effect on charge transport, Journal of Materials Chemistry C, 2019, 7(9): 2659-2665., 2019, 通讯作者
(9) From Homochiral Assembly to Heterochiral Assembly: A Leap in Charge Transport Properties of Binaphthol-Based Axially Chiral Materials, Langmuir, 2019, 35(18): 6188-6195., 2019, 通讯作者
(10) Incorporation of 2,6-Connected Azulene Units into the Backbone of Conjugated Polymers: Towards High-Performance Organic Optoelectronic Materials., Angew. Chem. Int. Ed. 2018, 57, 1322-1326., 2018, 通讯作者
(11) 6,6'-Diaryl-Substituted Biazulene Diimides for Solution-Processable High-Performance n-Type Organic Semiconductors., Mater. Chem. Front., 2018,2, 975-985, 2018, 通讯作者
(12) The role of halogen bonding in improving OFET performance of a naphthalenediimide derivative., Chin. Chem. Lett. 2018, 29, 423-428., 2018, 通讯作者
(13) Photoresponsive n-channel organic field-effect transistors based on a tri-component active layer., Chin. Chem. Lett. 2018, 29, 175-178., 2018, 通讯作者
(14) A Class of Electron-Transporting Vinylogous Tetrathiafulvalenes Constructed by the Dimerization of Core-Expanded Naphthalenediimides., Organic Letters, 2017, 19(3): 468-471., 2017, 通讯作者
(15) Application of direct (hetero)arylation in constructing conjugated small molecules and polymers for organic optoelectronic devices., Tetrahedron. Lett., 2017, 通讯作者
(16) Synthesis of largely π-extended naphthalenediimides via C–H activation towards highly soluble and narrow band-gap organic optoelectronic materials., Org. Chem. Front., 2017, 通讯作者
(17) Naphthalene Diimides Endcapped with Ethynylazulene:Molecular Design, Synthesis and Properties., Chin. J. Org. Chem., 2017, 通讯作者
(18) Dithieno[3,2-a:3′,2′-j][5,6,11,12]chrysene diimides and their molecular energy level regulation, Mater. Chem. Front., 2017, 通讯作者
(19) Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog, ChemPlusChem., 2017, 通讯作者
(20) Incorporation of benzothiadiazole into the backbone of 1,2,5,6-naphthalenediimide based copolymers, enabling much improved film crystallinity and charge carrier mobility., Poly. Chem., 2016, 通讯作者
(21) Biazulene Diimides: A New Building Block for Organic Electronic Materials., Chem. Sci., 2016, 通讯作者
(22) Controlled Growth of Ultrathin Film of Organic Semiconductors by Balancing the Competitive Processes in Dip-Coating for Organic Transistors., Langmuir., 2016, 通讯作者
(23) Fine-tuning the molecular energy levels by incorporating thiophene units onto the p-backbone of core-expanded naphthalene diimides., Chin. Chem. Lett., 2016, 通讯作者
(24) Photoresponsive organic field-effect transistors involving photochromic molecules., Chin. Chem. Lett., 2016, 通讯作者
(25) N-Channel Organic Transistors Processed from Halogen-Free Solvents: Solvent Effect on Thin-Film Morphology and Charge Transport., Chin. J. Chem., 2016, 通讯作者
(26) Bismuth Interfacial Doping of Organic Small Molecules for High Performance n-type Thermoelectric Materials., Angew. Chem. Int. Ed., 2016, 第 7 作者
(27) Scanning Kelvin Probe Microscopy Investigation of the Roleof Minority Carriers on theSwitching Characteristics ofOrganic Field-Effect Transistors, Adv. Mater., 2016, 第 5 作者
(28) Carbazolo[2,1-a]carbazole Diimide: A Building Block for Organic Electronic Materials., ChemPlusChem., 2015, 通讯作者
(29) Synthesis of Monolateral and Bilateral Sulfur-Heterocycle Fused Naphthalene Diimides (NDI) from Monobromo and Dibromo NDIs., Org. Chem. Front., 2015, 通讯作者
(30) High mobility organic semiconductors for field-effect transistors., Sci. China. Chem., 2015, 通讯作者
(31) Modulated Thermoelectric Properties of Organic Semiconductors Using Field-Effect Transistors, Adv. Funct. Mater., 2015, 第 5 作者
(32) Flexible suspended gate organic thin-film transistors for ultra-sensitive pressure detection, Nat. Commun., 2015, 第 4 作者
(33) Naphthalene Diimides Fused with 2-(1,3-dithiol-2-ylidene)acetonitrile: Strong Electron-Deficient Building Blocks for High-Performance n-Type Polymeric Semiconductors., ACS Macro Lett., 2014, 通讯作者
(34) Specific and Reproducible Gas Sensors Utilizing Gas-phase Chemical Reaction on Organic Transistors, Adv. Mater., 2014, 通讯作者
(35) Development of n-Type Organic Semiconductors for Thin Film Transistors: A Viewpoint of Molecular Design., J. Mater. Chem. C, 2014, 通讯作者
(36) Tuning the Charge Transport Property of Naphthalene Diimide Derivatives by Changing the Substituted Position of Fluorine Atom on Molecular Backbone., Chin. J. Chem., 2014, 通讯作者
(37) Tetracyanodibenzotetrathiafulvalene Diimides: Design, Synthesis and Property Study., J. Org. Chem. , 2013, 通讯作者
(38) 1,2,5,6-Naphthalenediimides-Based Donor?Acceptor Copolymers Designed from Isomer Chemistry for Organic Semiconducting Materials., Macromolecules., 2013, 通讯作者
(39) New Core-Expanded Naphthalene Diimides for n-Channel Organic Thin Film Transistors., Chin. J. Chem. , 2013, 通讯作者
(40) A facile synthesis of 2,3,6,7-tetrabromonaphthalene diimides toward new π-extended naphthalene diimides., Tetrahedron Lett., 2013, 通讯作者
(41) Ultra-Thin Film Organic Transistors: Precise Control of Semiconductor Thickness via Spin-coating., Adv. Mater. , 2013, 通讯作者
(42) Critical Role of Alkyl Chain Branching of Organic Semiconductors in Enabling Solution-Processed N-channel Organic Thin-film Transistors with Mobility of up to 3.50 cm2V-1s-1., J. Am. Chem. Soc., 2013, 通讯作者
(43) One-pot synthesis of core-expanded naphthalene diimides: enabling N-substituent modulation for diverse n-type organic materials. , Org. Lett. , 2012, 通讯作者
(44) All-Solution-Processed, High-Performance n-Channel Organic Transistors and Circuits: Toward Low-Cost Ambient Electronics, Adv. Mater. , 2011, 通讯作者
(45) Core-expanded naphthalene diimides fused with sulfur heterocycles and end-capped with electron-withdrawing groups for air-stable solution-processed n-channel organic thin film transistors. , Chem. Mater. , 2011, 通讯作者
(46) Core-expanded naphthalene diimides fused with 2-(1,3-dithiol-2-ylidene)malonitrile groups for high-performance, ambient-stable, solution-processed n-channel organic thin film transistors. , J. Am. Chem. Soc. , 2010, 通讯作者

指导学生

已指导学生

韩文杰  硕士研究生  070305-高分子化学与物理  

张文显  硕士研究生  085204-材料工程  

徐帅  硕士研究生  085204-材料工程  

黄金涛  硕士研究生  085204-材料工程  

高铁阵  硕士研究生  085204-材料工程  

辛涵申  博士研究生  070305-高分子化学与物理  

李建高  博士研究生  070303-有机化学  

陈铭  硕士研究生  070305-高分子化学与物理  

吴文婷  博士研究生  070305-高分子化学与物理  

现指导学生

黄金涛  博士研究生  070305-高分子化学与物理  

侯斌  博士研究生  070305-高分子化学与物理  

程杰  博士研究生  070305-高分子化学与物理  

姚怡明  硕士研究生  070305-高分子化学与物理  

向焌钧  博士研究生  070305-高分子化学与物理  

段超  博士研究生  070305-高分子化学与物理  

工作经历

   
工作简历
2014-03~现在, 中国科学院上海有机化学研究所, 研究员/课题组长
2012-12~2013-03,佐治亚理工学院, 访问学者
2008-10~2014-02,中国科学院上海有机化学研究所, 副研究员/课题组长