基本信息
杜海峰 男 博导 中国科学院化学研究所
电子邮件: haifengdu@iccas.ac.cn
通信地址: 北京海淀区中关村北一街2号
邮政编码: 100190
电子邮件: haifengdu@iccas.ac.cn
通信地址: 北京海淀区中关村北一街2号
邮政编码: 100190
招生信息
招生专业
070303-有机化学
招生方向
选择性合成方法学不对称催化
教育背景
2001-09--2004-07 中国科学院上海有机化学研究所 理学博士学位1998-09--2001-07 南开大学化学系 理学硕士学位1994-09--1998-07 南开大学化学系 学士
工作经历
工作简历
2008-10~现在, 中国科学院化学研究所, 研究员2004-09~2008-10,美国科学拉多州立大学, 博士后
教授课程
有机化学
专利与奖励
奖励信息
(1) 国家自然科学基金杰出青年基金, 国家级, 2018(2) 中国化学会青年手性化学奖, 其他, 2018(3) 中国均相催化青年奖, 其他, 2017(4) Asian Core Program Letureship Award, 其他, 2015(5) 国家自然科学基金优秀青年基金, 国家级, 2012(6) 中国科学院“****”, 院级, 2010
出版信息
发表论文
[1] 杜海峰. Asymmetric Hydrogenations of Acyclic α,β-Unsaturated Ketones with Chiral Frustrated Lewis Pairs (FLPs). JOURNAL OF ORGANIC CHEMISTRY[J]. 2023, 88: 16038-16042, [2] Cui, Guangyu, Feng, Xiangqing, Du, Haifeng. B(C6F5)(3)-catalyzed metal-free hydrogenation of 2-oxazolones. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2023, 21(3): 499-502, http://dx.doi.org/10.1039/d2ob01950g.[3] 杜海峰. Chiral Dienes: A Unique Class of Ligands in Asymmetric Catalysis. CHEMICAL REVIEWS[J]. 2023, 123: 875-876, http://dx.doi.org/10.1021/acs.chemrev.2c00850.[4] Yu, Kuai, Meng, Wei, Feng, Xiangqing, Du, Haifeng. Asymmetric Hydrogenation of Hydrazones with Chiral Boranes. ORGANIC LETTERS[J]. 2023, 25(20): 3607-3610, http://dx.doi.org/10.1021/acs.orglett.3c00843.[5] Gao, Bochao, Han, Zaiqi, Meng, Wei, Feng, Xiangqing, Du, Haifeng. Asymmetric Reduction of Quinolines: A Competition between Enantioselective Transfer Hydrogenation and Racemic Borane Catalysis. JOURNAL OF ORGANIC CHEMISTRY[J]. 2023, 88: 3335-3339, http://dx.doi.org/10.1021/acs.joc.2c02905.[6] Gao, Bochao, Meng, Wei, Feng, Xiangqing, Du, Haifeng. Regenerable Dihydrophenanthridine via Borane-Catalyzed Hydrogenation for the Asymmetric Transfer Hydrogenation of Benzoxazinones. ORGANIC LETTERS[J]. 2022, 24(22): 3955-3959, http://dx.doi.org/10.1021/acs.orglett.2c013143955Org.[7] Liu, Ting, Feng, Xiangqing, Du, Haifeng. Asymmetric hydrosilylations of N-sulfonyl ketimines and vicinal diimines with chiral boranes. TETRAHEDRON LETTERS[J]. 2022, 111: 154202, http://dx.doi.org/10.1016/j.tetlet.2022.154202.[8] Han, Caifang, Meng, Wei, Feng, Xiangqing, Du, Haifeng. Asymmetric Intramolecular Hydroalkoxylation of 2-Vinylbenzyl Alcohols with Chiral Boro-Phosphates. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2022, 61(21): http://dx.doi.org/10.1002/anie.202200100.[9] Feng, Xiangqing, Meng, Wei, Du, Haifeng. Chiral Dienes: From Ligands to FLP Catalysts. CHINESE JOURNAL OF CHEMISTRY[J]. 2022, 40(9): 1109-1116, http://dx.doi.org/10.1002/cjoc.202100854.[10] Dai Yun, Meng Wei, Feng Xiangqing, Du Haifeng. Chiral FLP-catalyzed asymmetric hydrogenation of 3-fluorinated chromones.. Chemical Communations[J]. 2022, 58: 1558-1560, [11] Yu Kuai, Feng Xiangqing, Du Haifeng. Asymmetric hydrogenation of TIPS-protected oximes with chiral boranes. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2022, 20(18): 3708-3711, http://dx.doi.org/10.1039/d2ob00602b.[12] Chen, Jingjing, Meng, Wei, Feng, Xiangqing, Du, Haifeng. Asymmetric Hydrogenation by Relay Catalysis with FLPs and CPAs: Stereodivergent Synthesis of 3-Substituted Flavanones. JOURNAL OF ORGANIC CHEMISTRY[J]. 2022, 87(15): 10544-10549, http://dx.doi.org/10.1021/acs.joc.2c01278.[13] 冯向青, 杜海峰. 2021年度诺贝尔化学奖:大道至简. 大学化学[J]. 2022, 37(1): 1-5, http://lib.cqvip.com/Qikan/Article/Detail?id=7106623027.[14] Han Caifang, Feng Xiangqing, Du Haifeng. Asymmetric Halocyclizations of 2-Vinylbenzyl Alcohols with Chiral FLPs. ORGANIC LETTERS[J]. 2021, 23(19): 7325-7329, http://dx.doi.org/10.1021/acs.orglett.1c02361.[15] 冯向青, 杜海峰. 手性锑(V)阴/阳离子对催化的不对称转移氢化反应. 有机化学[J]. 2021, [16] Wang, Qiaotian, Meng, Wei, Feng, Xiangqing, Du, Haifeng. B(C6F5)(3)-Catalyzed Hydroboration of Alkenes with N-Heterocyclic Carbene Boranes via B-H Bond Activation. CHINESE JOURNAL OF CHEMISTRY[J]. 2021, 39(4): 918-926, https://www.webofscience.com/wos/woscc/full-record/WOS:000634319800015.[17] Xiangqing Feng, Haifeng Du. Shi Epoxidation: A Great Shortcut to Complex Compounds. CHINESE JOURNAL OF CHEMISTRY[J]. 2021, 39(7): 2016-2026, [18] Chen, Jingjing, Gao, Bochao, Feng, Xiangqing, Meng, Wei, Du, Haifeng. Relay Catalysis by Achiral Borane and Chiral Phosphoric Acid in the Metal-Free Asymmetric Hydrogenation of Chromones. ORGANIC LETTERS[J]. 2021, 23(21): 8565-8569, http://dx.doi.org/10.1021/acs.orglett.1c03286.[19] Gao, Bochao, Feng, Xiangqing, Meng, Wei, Du, Haifeng. Asymmetric Hydrogenation of Ketones and Enones with Chiral Lewis Base Derived Frustrated Lewis Pairs. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2020, 59(11): 4498-4504, https://www.webofscience.com/wos/woscc/full-record/WOS:000509412000001.[20] Meng, Wei, Feng, Xiangqing, Du, Haifeng. Asymmetric Catalysis with Chiral Frustrated Lewis Pairs. CHINESE JOURNAL OF CHEMISTRY[J]. 2020, 38(6): 625-634, http://lib.cqvip.com/Qikan/Article/Detail?id=7102529627.[21] Zhao, Weiwei, Zhang, Zijia, Feng, Xiangqing, Yang, Jing, Du, Haifeng. Asymmetric Transfer Hydrogenation of N-Unprotected Indoles with Ammonia Borane. ORGANIC LETTERS[J]. 2020, 22(15): 5850-5854, http://dx.doi.org/10.1021/acs.orglett.0c01930.[22] Zhou, Qiwen, Meng, Wei, Feng, Xiangqing, Du, Haifeng, Yang, Jing. Chiral phosphoric acid catalyzed asymmetric transfer hydrogenation of bulky aryl ketones with ammonia borane. TETRAHEDRON LETTERS[J]. 2020, 61(3): http://dx.doi.org/10.1016/j.tetlet.2019.151394.[23] Weiwei Zhao, Xiangqing Feng, Jing Yang, Haifeng Du. Asymmetric transfer hydrogenations of β-N-substituted enamino esters with ammonia borane. TETRAHEDRON LETTERS. 2019, 60(17): 1193-1196, http://dx.doi.org/10.1016/j.tetlet.2019.03.060.[24] 王桥天, 韩彩芳, 冯向青, 杜海峰. 手性螺环骨架硼烷催化酮的不对称硅氢化反应. 有机化学[J]. 2019, 39(8): 2257-2263, http://lib.cqvip.com/Qikan/Article/Detail?id=7002791170.[25] Wang, Qiaotian, Feng, Xiangqing, Meng, Wei, Du, Haifeng. B(C6F5)(3)-catalyzed divergent cyanosilylations of chromones dependent on temperature. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2019, 17(36): 8354-8357, https://www.webofscience.com/wos/woscc/full-record/WOS:000487021800005.[26] Liu, Xiaoqin, Wang, Qiaotian, Han, Caifang, Feng, Xiangqing, Du, Haifeng. Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of Ketones. CHINESE JOURNAL OF CHEMISTRY[J]. 2019, 37(7): 663-666, http://lib.cqvip.com/Qikan/Article/Detail?id=7002884889.[27] Zhou, Qiwen, Feng, Xiangqing, Yang, Jing, Du, Haifeng. Asymmetric Transfer Hydrogenations of beta-Enamine Cyanide with Chiral Ammonia Borane. CHINESE JOURNAL OF ORGANIC CHEMISTRY[J]. 2019, 39(8): 2218-2225, http://apps.webofknowledge.com/CitedFullRecord.do?product=UA&colName=WOS&SID=5CCFccWmJJRAuMzNPjj&search_mode=CitedFullRecord&isickref=WOS:000486906400013.[28] 周启文, 冯向青, 杨晶, 杜海峰. 基于手性氨硼烷的β-烯胺腈不对称转移氢化反应. 有机化学[J]. 2019, 39(8): 2188-2195, http://lib.cqvip.com/Qikan/Article/Detail?id=7002791161.[29] Dai, Yun, Feng, Xiangqing, Du, Haifeng. B(C6F5)-Catalyzed Highly Stereoselective Hydrogenation of Unfunctionalized Tetrasubstituted Olefins. ORGANIC LETTERS[J]. 2019, 21(17): 6884-6887, [30] Wang, Qiaotian, Chen, Jingjing, Feng, Xiangqing, Du, Haifeng. B(C6F5)(3)-catalyzed transfer hydrogenations of imines with Hantzsch esters. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2018, 16(9): 1448-1451, http://dx.doi.org/10.1039/c8ob00023a.[31] Zhou, Qiwen, Meng, Wei, Yang, Jing, Du, Haifeng. A Continuously Regenerable Chiral Ammonia Borane for Asymmetric Transfer Hydrogenations. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2018, 57(37): 12111-12115, https://www.webofscience.com/wos/woscc/full-record/WOS:000443675700049.[32] Nie, Yanzhao, Wang, Pei, Du, Haifeng, Meng, Wei, Yang, Jing. An efficient strategy for achieving controlled ring-opening polymerization of O-carboxyanhydrides via amine initiation in collaboration with metal-alkoxide catalysis. POLYMER CHEMISTRY[J]. 2018, 9(40): 5014-5023, https://www.webofscience.com/wos/woscc/full-record/WOS:000448347900008.[33] Han, Caifang, Zhang, E, Feng, Xiangqing, Wang, Shoufeng, Du, Haifeng. B(C6F5)(3)-catalyzed metal-free hydrogenations of 2-quinolinecarboxylates. TETRAHEDRON LETTERS[J]. 2018, 59(14): 1400-1403, http://dx.doi.org/10.1016/j.tetlet.2018.02.057.[34] Meng, Wei, Feng, Xiangqing, Du, Haifeng. Frustrated Lewis Pairs Catalyzed Asymmetric Metal-Free Hydrogenations and Hydrosilylations. ACCOUNTS OF CHEMICAL RESEARCH[J]. 2018, 51(1): 191-201, [35] Nie, Yanzhao, Zhi, Xinmei, Du, Haifeng, Yang, Jing. Zn(OAc)(2)-Catalyzing Ring-Opening Polymerization of N-Carboxyanhydrides for the Synthesis of Well-Defined Polypeptides. MOLECULES[J]. 2018, 23(4): http://dx.doi.org/10.3390/molecules23040760.[36] Liu, Xiaoqin, Liu, Ting, Meng, Wei, Du, Haifeng. Asymmetric hydrogenation of imines with chiral alkene- derived boron Lewis acids. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2018, 16(45): 8686-8689, https://www.webofscience.com/wos/woscc/full-record/WOS:000451074500003.[37] Liu, Xiaoqin, Liu, Ting, Meng, Wei, Du, Haifeng. Highly Stereoselective Metal-Free Hydrogenations of Pyrrolo1,2-aquinoxalines. ORGANIC LETTERS[J]. 2018, 20(18): 5653-5656, https://www.webofscience.com/wos/woscc/full-record/WOS:000445711500029.[38] Li, Songlei, Meng, Wei, Du, Haifeng. Asymmetric Transfer Hydrogenations of 2,3-Disubstituted Quinoxalines with Ammonia Borane. ORGANIC LETTERS[J]. 2017, 19(10): 2604-2606, https://www.webofscience.com/wos/woscc/full-record/WOS:000402023500037.[39] Zhang, Hongyuan, Nie, Yanzhao, Zhi, Xinmei, Du, Haifeng, Yang, Jing. Controlled ring-opening polymerization of alpha-amino acid N-carboxy-anhydride by frustrated amine/borane Lewis pairs. CHEMICAL COMMUNICATIONS[J]. 2017, 53(37): 5155-5158, https://www.webofscience.com/wos/woscc/full-record/WOS:000400858400019.[40] Ji, Yue, Feng, GuangShou, Chen, MuWang, Shi, Lei, Du, Haifeng, Zhou, YongGui. Iridium-catalyzed asymmetric hydrogenation of cyclic iminium salts. ORGANIC CHEMISTRY FRONTIERS[J]. 2017, 4(6): 1125-1129, http://cas-ir.dicp.ac.cn/handle/321008/151911.[41] Ren, Xiaoyu, Han, Caifang, Feng, Xiangqing, Du, Haifeng. A Borane-Catalyzed Metal-Free Hydrosilylation of Chromones and Flavones. SYNLETT[J]. 2017, 28(18): 2421-2424, https://www.webofscience.com/wos/woscc/full-record/WOS:000417908200011.[42] Wei, Simin, Feng, Xiangqing, Du, Haifeng. A metal-free hydrogenation of 3-substituted 2H-1,4-benzoxazines. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2016, 14(34): 8026-8029, http://ir.iccas.ac.cn/handle/121111/35243.[43] Ren, Xiaoyu, Du, Haifeng. Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of 1,2-Dicarbonyl Compounds. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2016, 138(3): 810-813, https://www.webofscience.com/wos/woscc/full-record/WOS:000369044400025.[44] Li, Songlei, Li, Gen, Meng, Wei, Du, Haifeng. A Frustrated Lewis Pair Catalyzed Asymmetric Transfer Hydrogenation of Imines Using Ammonia Borane. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2016, 138(39): 12956-12962, https://www.webofscience.com/wos/woscc/full-record/WOS:000384952100039.[45] 杜海峰. 不饱和烃高效转化中的前沿科学问题研究立项报告. 科技资讯[J]. 2016, 14(20): 179-180, http://lib.cqvip.com/Qikan/Article/Detail?id=7000041124.[46] Wang, Wei, Meng, Wei, Du, Haifeng. B(C6F5)(3)-catalyzed metal-free hydrogenation of 3,6-diarylpyridazines. DALTON TRANSACTIONS[J]. 2016, 45(14): 5945-5948, [47] Zhou, Qiwen, Zhang, Lanqiong, Meng, Wei, Feng, Xiangqing, Yang, Jing, Du, Haifeng. Borane-Catalyzed Transfer Hydrogenations of Pyridines with Ammonia Borane. ORGANIC LETTERS[J]. 2016, 18(20): 5189-5191, https://www.webofscience.com/wos/woscc/full-record/WOS:000386187300001.[48] Wang, Wei, Feng, Xiangqing, Du, Haifeng. Borane-catalyzed metal-free hydrogenation of 2,7-disubstituted 1,8-naphthyridines. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2016, 14(28): 6683-6686, https://www.webofscience.com/wos/woscc/full-record/WOS:000379432600007.[49] Zhang, Zhenhua, Du, Haifeng. A Highly cis-Selective and Enantioselective Metal-Free Hydrogenation of 2,3-Disubstituted Quinoxalines. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2015, 54(2): 623-626, https://www.webofscience.com/wos/woscc/full-record/WOS:000347238800043.[50] Liu, Yongbing, Hu, Lianrui, Chen, Hui, Du, Haifeng. An Alkene-Promoted Borane-Catalyzed Highly Stereoselective Hydrogenation of Alkynes to Give Z- and E-Alkenes. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2015, 21(8): 3495-3501, https://www.webofscience.com/wos/woscc/full-record/WOS:000349664300045.[51] Li, Gen, Feng, Xiangqing, Du, Haifeng. Palladium-catalyzed asymmetric allylic amination of racemic butadiene monoxide with isatin derivatives. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2015, 13(20): 5826-5830, http://ir.iccas.ac.cn/handle/121111/28086.[52] Zhu, Xiaxia, Du, Haifeng. A chiral borane catalyzed asymmetric hydrosilylation of imines. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2015, 13(4): 1013-1016, https://www.webofscience.com/wos/woscc/full-record/WOS:000347229500007.[53] Feng, Xiangqing, Du, Haifeng. Application of Chiral Olefin Ligands in Asymmetric Catalysis. CHINESE JOURNAL OF ORGANIC CHEMISTRY[J]. 2015, 35(2): 259-272, http://dx.doi.org/10.6023/cjoc201409026.[54] Li, Gen, Liu, Yongbing, Du, Haifeng. B(C6F5)(3)-catalyzed metal-free hydrogenation of naphthylamines. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2015, 13(10): 2875-2878, http://ir.iccas.ac.cn/handle/121111/28228.[55] Liu, Yilin, Feng, Xiangqing, Du, Haifeng. Asymmetric synthesis of axially chiral anilides by Pd-catalyzed allylic substitutions with P/olefin ligands. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2015, 13(1): 125-132, https://www.webofscience.com/wos/woscc/full-record/WOS:000345923800014.[56] Zhang, Zhenhua, Du, Haifeng. Cis-Selective and Highly Enantioselective Hydrogenation of 2,3,4-Trisubstituted Quinolines. ORGANIC LETTERS[J]. 2015, 17(11): 2816-2819, http://ir.iccas.ac.cn/handle/121111/27963.[57] Ren, Xiaoyu, Li, Gen, Wei, Simin, Du, Haifeng. Facile Development of Chiral Alkenylboranes from Chiral Diynes for Asymmetric Hydrogenation of Silyl Enol Ethers. ORGANICLETTERS[J]. 2015, 17(4): 990-993, http://ir.iccas.ac.cn/handle/121111/28214.[58] Zhu, Xiaxia, Du, Haifeng. A Highly Stereoselective Metal-Free Hydrogenation of Diimines for the Synthesis of Cis-Vicinal Diamines. ORGANIC LETTERS[J]. 2015, 17(12): 3106-3109, http://ir.iccas.ac.cn/handle/121111/27957.[59] Zhang, Zhenhua, Du, Haifeng. Enantioselective Metal-Free Hydrogenations of Disubstituted Quinolines. ORGANIC LETTERS[J]. 2015, 17(24): 6266-6269, http://ir.iccas.ac.cn/handle/121111/29537.[60] Wei, Simin, Du, Haifeng. A Highly Enantioselective Hydrogenation of Silyl Enol Ethers Catalyzed by Chiral Frustrated Lewis Pairs. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2014, 136(35): 12261-12264, https://www.webofscience.com/wos/woscc/full-record/WOS:000341226000017.[61] Feng, Xiangqing, Du, Haifeng. Metal-free asymmetric hydrogenation and hydrosilylation catalyzed by frustrated Lewis pairs. TETRAHEDRON LETTERS[J]. 2014, 55(51): 6959-6964, http://dx.doi.org/10.1016/j.tetlet.2014.10.138.[62] Zhuang, Minyang, Du, Haifeng. Chiral Bronsted acid catalyzed enantioselective intermolecular allylic aminations. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2014, 12(26): 4590-4593, https://www.webofscience.com/wos/woscc/full-record/WOS:000337139800008.[63] Liu Yongbing, Du Haifeng. Frustrated Lewis Pair Catalyzed Asymmetric Hydrogenation. ACTA CHIMICA SINICA[J]. 2014, 72(7): 771-777, https://www.webofscience.com/wos/woscc/full-record/WOS:000340842000003.[64] Feng, Xiangqing, Nie, Yanzhao, Zhang, Lanqiong, Yang, Jing, Du, Haifeng. Rh(I)-catalyzed asymmetric 1,2-additions of arylboronic acids to isatins with chiral sulfur-alkene hybrid ligands. TETRAHEDRON LETTERS[J]. 2014, 55(33): 4581-4584, http://dx.doi.org/10.1016/j.tetlet.2014.06.074.[65] Liu, Yilin, Du, Haifeng. Pd-Catalyzed Asymmetric Allylic Alkylations of 3-Substituted Indoles Using Chiral P/Olefin Ligands. ORGANIC LETTERS[J]. 2013, 15(4): 740-743, https://www.webofscience.com/wos/woscc/full-record/WOS:000315254500006.[66] Zhuang Minyang, Du Haifeng. Asymmetric Rearrangement of Racemic Epoxides Catalyzed by Chiral Bronsted Acids. ORG. BIOMOL. CHEM.[J]. 2013, 11(9): 1460-1462, http://ir.iccas.ac.cn/handle/121111/28583.[67] Liu, Yongbing, Du, Haifeng. Metal-Free Borane-Catalyzed Highly Stereoselective Hydrogenation of Pyridines. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2013, 135(35): 12968-12971, https://www.webofscience.com/wos/woscc/full-record/WOS:000330163100012.[68] Liu, Yongbing, Du, Haifeng. Chiral Dienes as "Ligands" for Borane-Catalyzed Metal-Free Asymmetric Hydrogenation of Imines. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2013, 135(18): 6810-6813, https://www.webofscience.com/wos/woscc/full-record/WOS:000318839300018.[69] Feng, Xiangqing, Hie, Yanzhao, Yang, Jing, Du, Haifeng. Rh(I)-Catalyzed Asymmetric 1,2-Addition to alpha-Diketones with Chiral Sulfur-Alkene Hybrid Ligands. ORGANIC LETTERS[J]. 2012, 14(2): 624-627, https://www.webofscience.com/wos/woscc/full-record/WOS:000299238600051.[70] Liu, Yilin, Cao, Ziping, Du, Haifeng. Asymmetric Allylic Alkylation of Pyrroles and 4,7-Dihydroindoles with Alkene-Phosphine Ligands. JOURNAL OF ORGANIC CHEMISTRY[J]. 2012, 77(9): 4479-4483, https://www.webofscience.com/wos/woscc/full-record/WOS:000303492300034.[71] Liu, Zhaoqun, Feng, Xiangqing, Du, Haifeng. Rhodium-Catalyzed Asymmetric Formal Cycloadditions of Racemic Butadiene Monoxide with Imines. ORGANIC LETTERS[J]. 2012, 14(12): 3154-3157, https://www.webofscience.com/wos/woscc/full-record/WOS:000305205300059.[72] Feng, Xiangqing, Du, Haifeng. Synthesis of Chiral Olefin Ligands and their Application in Asymmetric Catalysis. ASIAN JOURNAL OF ORGANIC CHEMISTRY[J]. 2012, 1(3): 204-213, https://www.webofscience.com/wos/woscc/full-record/WOS:000325946900001.[73] Feng, Xiangqing, Wang, Yazhou, Wei, Beibei, Yang, Jing, Du, Haifeng. Simple N-Sulfinyl-Based Chiral Sulfur-Olefin Ligands for Rhodium-Catalyzed Asymmetric 1,4-Additions. ORGANIC LETTERS[J]. 2011, 13(13): 3300-3303, https://www.webofscience.com/wos/woscc/full-record/WOS:000291920800004.[74] Wang, Yazhou, Feng, Xiangqing, Du, Haifeng. Kinetic Resolution of Hindered Morita-Baylis-Hillman Adducts by Rh(I)-Catalyzed Asymmetric 1,4-Addition/beta-Hydroxyelimination. ORGANIC LETTERS[J]. 2011, 13(18): 4954-4957, https://www.webofscience.com/wos/woscc/full-record/WOS:000294703900052.[75] Cao, Ziping, Liu, Zhaoqun, Liu, Yilin, Du, Haifeng. Pd-Catalyzed Asymmetric Allylic Etherizations with Oximes by Chiral Alkene-Phosphine Ligands. JOURNAL OF ORGANIC CHEMISTRY[J]. 2011, 76(15): 6401-6406, https://www.webofscience.com/wos/woscc/full-record/WOS:000293252600061.[76] Feng, Xiangqing, Wei, Beibei, Yang, Jing, Du, Haifeng. Chiral N-tert-butanesulfinyl alpha,beta-unsaturated ketimine: a simple and highly effective olefin/sulfinimide hybrid ligand for asymmetric 1,4-additions. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2011, 9(17): 5927-5929, https://www.webofscience.com/wos/woscc/full-record/WOS:000293756800003.[77] Cao, Ziping, Liu, Yilin, Liu, Zhaoqun, Feng, Xiangqing, Zhuang, Minyang, Du, Haifeng. Pd-Catalyzed Asymmetric Allylic Alkylation of Indoles and Pyrroles by Chiral Alkene-Phosphine Ligands. ORGANIC LETTERS[J]. 2011, 13(9): 2164-2167, https://www.webofscience.com/wos/woscc/full-record/WOS:000289956700006.[78] Liu, Zhaoqun, Cao, Ziping, Du, Haifeng. Highly effective chiral phosphorus amidite-olefin ligands for palladium-catalyzed asymmetric allylic substitutions. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2011, 9(15): 5369-5372, https://www.webofscience.com/wos/woscc/full-record/WOS:000292983400011.[79] Liu, Zhaoqun, Du, Haifeng. Development of Chiral Terminal-Alkene-Phosphine Hybrid Ligands for Palladium-Catalyzed Asymmetric Allylic Substitutions. ORGANIC LETTERS[J]. 2010, 12(13): 3054-3057, https://www.webofscience.com/wos/woscc/full-record/WOS:000279070100042.[80] Wang, Yazhou, Du, Haifeng. A Copper(II)-Mediated Regioselective Cyclization-Acetoxylation of 6,8-Dien-1-ones for the Synthesis of Functionalized Cyclopentanes. JOURNAL OF ORGANIC CHEMISTRY[J]. 2010, 75(10): 3503-3506, http://dx.doi.org/10.1021/jo100413p.[81] Cao, Ziping, Du, Haifeng. Development of Binaphthyl-Based Chiral Dienes for Rhodium(I)-Catalyzed Asymmetric Arylation of N,N-Dimethylsulfamoyl-Protected Aldimines. ORGANIC LETTERS[J]. 2010, 12(11): 2602-2605, http://dx.doi.org/10.1021/ol1008087.[82] Wang, Yazhou, Hu, Xichao, Du, Haifeng. Vicinal-Diamine-Based Chiral Chain Dienes as Ligands for Rhodium(I)-Catalyzed Highly Enantioselective Conjugated Additions. ORGANIC LETTERS[J]. 2010, 12(23): 5482-5485, http://dx.doi.org/10.1021/ol1023536.[83] Hu, Xichao, Cao, Ziping, Liu, Zhaoqun, Wang, Yazhou, Du, Haifeng. One Step Synthesis of Chiral Olefins via Asymmetric Diamination and their Applications as Ligands for Rhodium(I)-Catalyzed 1,4-Additions. ADVANCED SYNTHESIS & CATALYSIS[J]. 2010, 352(4): 651-655, https://www.doi.org/10.1002/adsc.200900693.[84] Hu, Xichao, Zhuang, Minyang, Cao, Ziping, Du, Haifeng. Simple Chiral Chain Dienes as Ligands for Rh(I)-Catalyzed Conjugated Additions. ORGANIC LETTERS[J]. 2009, 11(20): 4744-4747, http://dx.doi.org/10.1021/ol901949n.
科研活动
科研项目
( 1 ) “受阻路易斯酸碱对”催化的不对称氢化反应研究, 主持, 国家级, 2016-01--2019-12( 2 ) 分子识别与选择性合成, 参与, 国家级, 2016-01--2021-12( 3 ) 烯烃的不对称转化与功能, 主持, 国家级, 2013-01--2015-12( 4 ) 基于亚磺酰胺硫手性的新型手性硫烯烃配体研究, 主持, 国家级, 2012-01--2015-12( 5 ) 末端烯烃作为配位基团的新型手性烯膦配体研究, 主持, 国家级, 2011-01--2013-12( 6 ) 新型手性烯烃配体的设计、合成及应用研究, 主持, 国家级, 2009-01--2011-12( 7 ) 不饱和烃高效转化中的前沿科学问题, 参与, 国家级, 2011-01--2015-12( 8 ) 手性催化的重要科学基础, 参与, 国家级, 2010-01--2014-12( 9 ) 不对称催化, 主持, 国家级, 2019-01--2023-12( 10 ) 新型手性氢转移试剂研究, 主持, 国家级, 2019-01--2021-12
参与会议
(1)Frustrated Lewis Pairs in Asymmetric Catalysis 2018-06-22(2)基于氨基硼烷的不对称转移氢化反应 中国化学会第31届学术年会 2018-05-05(3)Frustrated Lewis Pairs Catalyzed Metal-Free Asymmetric Hydrogenations and Hydrosilylations 2017-10-06(4)无金属催化氢化及硅氢化反应研究 第十五届全国均相催化学术讨论会 2017-09-26(5)Frustrated Lewis Pairs Catalyzed Metal-Free Hydrogenations and Hydrosilylations 2016-10-16(6)Frustrated Lewis Pairs Catalyzed Metal-Free Hydrogenations and Hydrosilylations 第十八届中国科协年会,绿色化学与洁净能源论坛 2016-09-24(7)Borane-Catalyzed Hydrogenation and Hydrosilylation 2016-09-04(8)Frustrated Lewis Pairs Catalyzed Metal-Free Hydrogenations and Hydrosilylations 中国化学会第30届学术年会 2016-07-04(9)Frustrated Lewis Pairs Catalyzed Metal-Free Hydrogenations and Hydrosilylations 2016-06-23
指导学生
已指导学生
胡惜朝 博士研究生 070303-有机化学
曹子平 博士研究生 070303-有机化学
王亚洲 博士研究生 070303-有机化学
冯向青 博士研究生 070303-有机化学
刘钊群 博士研究生 070303-有机化学
刘益林 博士研究生 070303-有机化学
庄敏阳 博士研究生 070303-有机化学
刘勇兵 博士研究生 070303-有机化学
李根 博士研究生 070303-有机化学
朱霞霞 博士研究生 070303-有机化学
张振华 博士研究生 070303-有机化学
王为 博士研究生 070303-有机化学
魏思敏 博士研究生 070303-有机化学
李松磊 博士研究生 070303-有机化学
任小雨 博士研究生 070303-有机化学
现指导学生
王桥天 博士研究生 070303-有机化学
陈晶晶 硕士研究生 070303-有机化学
高博超 博士研究生 070303-有机化学
刘婷 硕士研究生 070303-有机化学
戴赟 博士研究生 070303-有机化学
崔光宇 硕士研究生 070303-有机化学
刘晓芹 博士研究生 070303-有机化学