基本信息
余正坤  男  博导  中国科学院大连化学物理研究所
电子邮件： zkyu@dicp.ac.cn
通信地址： 辽宁省大连市中山路457号
邮政编码： 116023

研究领域

主要从事过渡金属催化的有机合成方法学与均相催化(不对称催化)化学研究。同时进行精细化工和医药中间体生产技术开发研究。 

惰性化学键的催化活化-导向有机合成方法学 
惰性化学键的活化与转化是有机化学研究的热点领域。我们侧重研究基于过渡金属催化的碳-氢键和碳-硫键活化的化学转化和官能团化，由此研究各种碳-碳键的形成反应，合成功能有机化合物。芳烃的直接芳基化、烯基化和吲哚的官能团化是我们研究的重点。研究相关的不对称催化合成。

高活性过渡金属配合物催化剂研究
研究含吡啶骨架的非膦N3型有机配体如2,6-二(吡唑基)吡啶、2-吡唑基-6-烯胺基吡啶和氮杂环卡宾(NHC)等配体。手性中心也可以被引入配体中。主要研究非对称N3型配体，其具有如下特征：三齿、除含有配位能力较好的吡啶氮原子以外同时含有一配位能力较强的配位原子与另一配位能力相对较弱的配位原子。对涉及配体解离的催化过程而言，有机金属配合物做催化剂时，配合物的稳定性（需要较强的配位中心与金属配位）与催化活性（要求具有相对较弱配位能力的配体容易解离）之间的平衡就要靠这样的多齿配体来维持。本课题主要研究合成配体的过渡金属配合物和笼状过渡金属配合物以及它们在有机催化反应（或超分子催化反应）中的应用。将手性基团引入配体分子中得到非膦手性配体，由此研究其过渡金属配合物催化剂促进的不对称催化反应

招生信息

本方向每年可以招收硕博连读研究生1人(本科起点）或硕士起点博士研究生1人。我们接受免试推荐的保送硕士研究生（有意向的应届本科毕业生需要在每年九月上旬左右递交申请材料），研究生实行硕博连读制。硕士起点博士研究生招生报名时间为每年12月份-来年2月份，来年3月中下旬参加入学考试（考试科目：英语，高等有机合成和有机化学反应机理），9月初入学。研究生在学期间免学费；在实验室工作期间，硕士研究生奖学金最低3400元/月以上，博士研究生奖学金最低5400元/月以上。

招生专业
070303-有机化学
招生方向
金属有机化学
有机合成
均相催化

教育背景

1992-09--1995-06   中国科学院大连化学物理研究所   理学博士学位
1989-09--1992-06   中国科学院大连化学物理研究所   理学硕士学位
1980-09--1984-07   华中师范大学   学士学位
出国学习工作

1995年10月-2003年1月：
2001年8月-2003年1月： 美国Wayne州立大学化学系，研究助手。
2000年8月-2001年7月： 日本国科学技术公司(JST)/早稻田大学化学系，JST研究员。
1998年11月-2000年7月： 美国Wayne州立大学化学系，博士后。
1997年1月-1998年10月： 美国能源部Ames实验室/Iowa州立大学化学系，博士后。
1995年10月-1996年12月： 德国Münster大学有机化学研究所，博士后。

学历
1992年8月-1995年7月： 中国科学院大连化学物理研究所，获理学博士学位。

1989年9月-1992年7月： 中国科学院大连化学物理研究所，获理学硕士学位。

1980年9月-1984年7月： 华中师范大学化学系，获理学学士学位。

学位
中国科学院大连化学物理研究所 -- 博士

工作经历

2022年12月-至今：中国科学院大连化学物理研究所首席研究员、二级研究员、博士生导师。

2019年10月--2022年12月：中国科学院大连化学物理研究所首席研究员、博士生导师。

2019年2月-2019年9月：中国科学院大连化学物理研究所研究员、博士生导师。

2003年2月-2019年1月： 中国科学院大连化学物理研究所研究员、研究组组长、博士生导师。2007年入选辽宁省“百千万人才工程”；**层次，2009年大连化物所科技创新奖(个人)、2010年和2013年入选大连市优秀专家。沈阳药科大学兼职教授,《化工中间体》杂志编委会委员，第22届国际有机金属化学大会分会主席（西班牙Zaragoza）。2016年获SABIC-CAS Scholarship，2019年国家自然科学基金委优青、面上项目现场评审专家。

2001年8月-2003年1月： 美国Wayne州立大学化学系，研究助手。

2000年8月-2001年7月： 日本国科学技术公司(JST)/早稻田大学化学系，JST研究员。

1998年11月-2000年7月： 美国Wayne州立大学化学系，博士后。

1997年1月-1998年10月： 美国能源部Ames实验室/Iowa州立大学化学系，博士后。

1995年10月-1996年12月： 德国Münster大学有机化学研究所，博士后。

1995年7月-1995年9月： 中国科学院大连化学物理研究所，助理研究员。 

1984年7月-1989年8月： 长沙空军第二航空工程学校，助理讲师。

工作简历
2003-02~现在, 中国科学院大连化学物理研究所, 研究员，研究组组长
2001-08~2003-01,美国Wayne州立大学化学系, 研究助手
2000-08~2001-07,日本国科学技术公司(JST)/早稻田大学化学系, JST研究员
1998-11~2000-07,美国Wayne州立大学化学系, 博士后
1997-01~1998-10,美国能源部Ames实验室/Iowa州立大学化学系, 博士后
1995-10~1996-12,德国Münster大学有机化学研究所, 博士后
1995-07~1995-09,中国科学院大连化学物理研究所, 助理研究员
1984-07~1989-08,长沙空军第二航空工程学校, 助理讲师

专利与奖励

1. C. H. Winter, Z. K.Yu, C.L. Dezelah IV, and A.N. Goldstein, "Methods of Filling a Feature on a Substrate with Copper Nanocrystals," U.S. Patent Number 6,897,151, Issued May 24, 2005.

2. C. H. Winter, Z. K. Yu, and C.L. Dezelah IV, "Copper Nanocrystals and Methods of Producing Same," U.S. Patent Number 6,887,297, Issued May 3, 2005.

3. 吴思忠，余正坤等，"一种1,2,4-丁三醇的合成方法", 中国专利公开号 CN1803747（公开日2006.7.19）。

4. 余正坤，吴思忠等，"一种N，N＇-二(磷酸二苯酯)哌嗪类阻燃剂及制备方法"，中国专利公开号CN1827624（公开日2006.9.6）。

5. 余正坤，郑兆艳等，"一种双环氮杂环荧光或磷光化合物的合成方法"，中国专利公开号CN101113150（公开日2010.5.12）。
 
6. 余正坤，吴小伟等，"制备β-γ不饱和酯的方法"，中国专利公开号CN101003456（公开日2010.10.6）。 


奖励信息
（1） SABIC-CAS导师科研奖, 部委级, 2016
（2） 大连市优秀专家, , 市地级, 2010
（3） 辽宁省自然科学奖（论文类）, 一等奖, 省级, 2009
（4） 选辽宁省“百千万人才工程”, , 省级, 2007
（5） 中国科学院“****”, , 院级, 2004
专利成果
（ 1 ） Methods of Filling a Feature on a Substrate with Copper Nanocrystals, 发明, 2005, 第 2 作者, 专利号: U.S. Patent Number 6,897,151
（ 2 ） Copper Nanocrystals and Methods of Producing Same, 发明, 2005, 第 2 作者, 专利号: U.S. Patent Number 6,887,297
（ 3 ） 一种1,2,4-丁三醇的合成方法, 发明, 2006, 第 2 作者, 专利号: CN1803747
（ 4 ） 一种N，N＇-二(磷酸二苯酯)哌嗪类阻燃剂及制备方法, 发明, 2006, 第 1 作者, 专利号: CN1827624
（ 5 ） 一种双环氮杂环荧光或磷光化合物的合成方法, 发明, 2010, 第 1 作者, 专利号: CN101113150
（ 6 ） 制备β-γ不饱和酯的方法, 发明, 2010, 第 1 作者, 专利号: CN101003456
（ 7 ） 一种二环吡啶酮衍生物的合成方法, 发明, 2012, 第 1 作者, 专利号: ZL 201010158000.6
（ 8 ） 一种蒽林并环衍生物及其合成方法, 发明, 2013, 第 1 作者, 专利号: ZL 200810013567.7
（ 9 ） 一种香兰素合成的方法, 发明, 2013, 第 1 作者, 专利号: ZL 200910187614.4
（ 10 ） 一种制备仲胺和叔胺的方法, 发明, 2013, 第 1 作者, 专利号: ZL 201010108370.9
（ 11 ） 一种经由伯胺脱氨制备仲胺的方法, 发明, 2013, 第 1 作者, 专利号: ZL 201110027053.9
（ 12 ） 一种铁催化炔基缩醛合成氯(溴)代烯基环化物的方法, 发明, 2014, 第 1 作者, 专利号: ZL 201010148371.6
（ 13 ） 一种制备亚胺的方法, 发明, 2014, 第 1 作者, 专利号: ZL 201110095903.9
（ 14 ） 一种多氯烷烃的合成方法, 发明, 2014, 第 1 作者, 专利号: ZL 201110282332.X
（ 15 ） 一种吡唑衍生物的制备方法, 发明, 2014, 第 1 作者, 专利号: ZL 201110031782.1
（ 16 ） 一种四取代烯烃及其吡唑衍生物的制备方法, 发明, 2015, 第 1 作者, 专利号: ZL 201310518573.9
（ 17 ） 银催化的双杂环分子的合成及具有荧光活性的双杂环分子, 发明, 2015, 第 1 作者, 专利号: ZL 201110342658.7
（ 18 ） 一种（3,5-双三氟甲基吡唑基)吡啶衍生物的合成方法, 发明, 2017, 第 1 作者, 专利号: ZL 201310616275.3
（ 19 ） 一种二环己基冠醚的合成方法, 发明, 2017, 第 1 作者, 专利号: ZL 201310691088.1

出版信息


Publication List (Zhengkun Yu-余正坤)

 

189. Liu, T. T.; Wang, Q. F.; Wang, L. D.; Wu, K. K. Assembled Porphyrin-Based Multinuclear Ruthenium(II)-NNNN Complex Catalysts for Transfer Hydrogenation of Ketones. Eur. J. Inorg. Chem. 2022, e202200610 (ASAP, online 12-22-2022).

188. Huang, Z. L.; Lin, J.; Ma, J.; Wang, L. D.; Zhou, Y.-G.*; Yu, Z. K.* Borane-Catalyzed, HFIP-Assisted Carbene Insertion into Internal Alkenyl C−H Bonds under Metal-Free Conditions. Adv. Synth. Catal. 2022, 364, 4333-4346.

187. Li, Y. L.; Jiang, W. C.; Lin, J.; Ma, J.; Xu, B.-H.; Zhou, Y.-G.*; Yu, Z. K.* Rhodium(III)-Catalyzed Triple Aryl/Alkenyl C−H Bond Activation of Aryl Enaminones to Access Naphtho[1,8-bc]pyrans. Org. Lett. 2022, 24, 7123-7127.

186. He, Y.; Huang, Z. L.; Ma, J.; Lin, J.; Zhou, Y.-G.*; Yu, Z. K.* Transition-Metal-Free Olefinic C-H Azidoalkylthiolation via C(sp3)−S Bond Cleavage of Vinylsulfonium Salts. Adv. Synth. Catal. 2022, 364, 3023-3034.

185. Lin, J.; Huang, Z. L.; Ma, J.; Xu, B.-H.; Zhou, Y.-G.*; Yu, Z. K.* Tunable Construction of Multisubstituted 1,3-Dienes and Allenes via a 1,4-Palladium Migration/Carbene Insertion Cascade. J. Org. Chem. 2022, 87, 12019-12035.

184. He, Y.; Huang, Z. L.; Wu, K. K.; Ma, J.; Zhou, Y.-G.*; Yu, Z. K.* Recent Advance in Transition-Metal-Catalyzed Carbene Insertion to C-H Bonds. Chem. Soc. Rev. 2022, 51, 2759-2852.

183. Huang, Z. L.; He, Y.; Wang, L. D.; Li, J. Y.; Xu, B.-H.; Zhou, Y.-G.*; Yu, Z. K.* Copper-Catalyzed [4+1] Annulation of Enaminothiones with Indoline-Based Diazo Compounds. J. Org. Chem. 2022, 87, 4424-4437.

182. Sun, R.; Guo, H.-Y.; Ma, S.-S.; Wang, Y.-F.; Yu, Z. K.; Xu, B.-H.* Ru(dppbsa)-Catalyzed Hydrodeoxygenation and Reductive Etherification of Ketones and Aldehydes. Org. Chem. Front. 2022, 9, 1943-1954.

181. Ma, S.-S.; Sun, R.; Zhang, Z.-H.; Yu, Z. K.; Zhang, S.-J.; Xu, B.-H.* Ruthenium-Catalysed Chemoselective Alkytation of Nitroarenes with Alkanols. Org. Chem. Front. 2021, 8, 6710-6719.

180. He, Y.; Huang, Z. L.; Ma, J.; Huang, F.; Lin, J.; Wang, H. M.;* Xu, B.-H.; Zhou, Y.-G.;* Yu, Z. K.* Palladium-Catalyzed Fluoroalkylation via C(sp3)-S Bond Cleavage of Vinylsulfonium Salts Under Air Atmosphere. Org. Lett. 2021, 23, 6110-6114.

179. Li, Y. L.; Liu, H. B.; Huang, Z. L.; He, Y.; Xu, B.-H.; Wang, H. M.;* Yu, Z. K.* Visible-Light-Driven, Palladium-Catalyzed Heck Reaction of Internal Vinyl Bromides with Styrenes. J. Org. Chem. 2021, 86, 8402-8413.

178. Li, Y. L.; Liu, H. B.; Huang, Z. L.; He, Y.; Wang, H. M.;* Yu, Z. K.* Palladium-Catalyzed Cross-Dehydrogenative-Coupling of Nitro-Substituted Internal Alkenes with Terminal Alkenes. Tetrahedron Lett. 2021, 82, 153396.

177. Ma, S.-S.; Jiang, B.-L.; Yu, Z. K.; Zhang, S.-J.; Xu, B.-H.* Cobalt-Catalyzed Chemoselective Transfer Hydrogenative Cyclization Cascade of Enone-Tethered Aldehydes. Org. Lett. 2021, 23, 3873-3878.

176. Gong, Y. F.; Geng, N. B.; Zhang, H.-J.;* Luo, Y.; Giesy, J. P.; Sun, S.; Wu, P.; Yu, Z. K.; Chen, J. P. Exposure to Short-Chain Chlorinated Paraffins Inhibited PPARa-Mediated Fatty Acid Oxidation and Stimulated Aerobic Glycolysis in vitro in Human Cells. Science of the Total Environment, 2021, 772, 144957.

 175. Lou, J.; Ma, J.; Xu, B.-H.; Zhou, Y.-G.;* Yu, Z. K.* Photoinduced, Copper-Catalyzed Three-Component Annulation of gem-Dialkylthio Enynes.

Org. Lett. 2020, 22, 5202-5206.

174. Lou, J.; Wang, Q. N.; Wu, P.; Wang, H. M.;* Zhou, Y.-G.;* Yu, Z. K.* Transition-Metal Mediated Carbon-Sulfur Bond Activation and Transformations: An Update.

Chem. Soc. Rev. 2020, 49, 4307-4359.

173. He, Y.; Lou, J.; Zhou, Y.-G.*; Yu, Z. K.* ZnCl2-Catalyzed [4+1] Annulation of Alkylthio-Substituted Enaminones and Enaminothiones with Sulfur Ylides. Chem. Eur. J. 2020, 26, 4941-4946.

    172. Huang, F.; Wu, P.; Yu, Z. K.* Copper(II)-Mediated Intramolecular Cyclopropanation of Ketene N,X-Acetals (X = S, O, N) under Mild Conditions. J. Org.           Chem. 2020, 85, 4373-4385.
    171. He, Y.; Lou, J.; Wu, P.; Zhou, Y.-G.;* Yu, Z. K.* Copper-Catalyzed Annulative Coupling of S,S-Disubstituted Enones with Diazo Compounds to Access               Highly Functionalized Thiophene Derivatives. J. Org. Chem. 2020, 85, 1044-1053.

    170. Liu, T. T.; Wu, K. K.; Wang, L. D.; Fan, H. J.;* Zhou, Y.-G.;* Yu, Z. K.* Assembled Multinuclear Ruthenium(II)-NNNN Complexes: Synthesis, Catalytic           Properties, and DFT Calculations.

Organometallics 2020, 39, 93-104.

169. Wu, P.; He, Y.; Wang, H. M.;* Zhou, Y.-G.;* Yu, Z. K.* Copper(II)-Catalyzed C-H Nitrogenation/Annulation Cascade of Ketene N,S-Acetals with Aryldiazonium Salts: A Direct Access to N-Substituted Triazole and Triazine Derivatives.

Org. Lett. 2020, 22, 310-315.

168. Wang, Q. N.; Chen, R. J.; Lou, J.; Zhang, D. H.; Zhou, Y.-G.;* Yu, Z. K.* Highly Regioselective C-H Alkylation of Alkenes through an Aryl to Vinyl 1,4-Palladium Migration/C-C Cleavage Cascade.

ACS Catal. 2019, 9, 11669-11675.

167. Lou, J.; Wang, Q. N.; Zhou, Y.-G.;* Yu, Z. K.* Rhodium(III)-Catalyzed Annulative Coupling of Sulfoxonium Ylides and Allenoates: An Arene C-H Activation/Cyclopropanation Cascade. Org. Lett. 2019, 21, 9217-9222.

166. Liu, T. T.; Wu, K. K.; Wang, L. D.; Yu, Z. K.* Potassium tert-Butoxide-Promoted Acceptorless Dehydrogenation of N-Heterocycles.

Adv. Synth. Catal. 2019, 361, 3958-3964.

165. Lou, J.; He, Y.; Li, Y. L.; Wang, H. M.;* Yu, Z. K.* Transition-Metal-Catalyzed Direct C-H Cyanoalkylation and Cyanoalkoxylation of Internal Alkenes via Radical C-C Bond Cleavage of Cycloketone Oxime Esters.

Adv. Synth. Catal. 2019, 361, 3787-3799.

164, Wang, Q. N.; Lou, J.; Huang, Z. L.; Yu, Z. K.* Rhodium(III)-Catalyzed Annulation of Acetophenone O-Acetyl Oximes with Allenoates through Arene C-H Activation: An Access to Isoquinolines. 

J. Org. Chem. 2019, 84, 2083-2092. 

163. He, Y.; Lou, J.; Wu, K. K.; Wang, H. M.;* Yu, Z. K.* Copper-Catalyzed Radical C-C Bond Cleavage and [4+1] Annulation Cascade of Cycloketone Oxime Esters with Enaminothiones.

J. Org. Chem. 2019, 84, 2178-2190. 

162. Gong, Y. F.; Zhang, H. J.; Geng, N. B.; Ren, X. Q.; Giesy, J. P.; Luo, Y.; Xing, L. G.; Wu, P.; Yu, Z. K.; Chen, J. P.* Short-Chain Chlorinated Parraffins (SCCPs) Disrupt Hepatic Fatty Acid Metabolism in Liver of Male Rat via Interacting with Peroxisome Proliferator-Activated Receptor a (PPARa).

Ecotox. Environ. Safety 2019, 181, 164-171.

161. Wang, Q. N.; Liu, Z. Q.; Lou, J.; Yu, Z. K.* Palladium-Catalyzed C-S Bond Cleavage with Allenoates: Synthesis of Tetrasubstituted 2-Alkenylfuran Derivatives. 

Org. Lett. 2018, 20, 6007-6011.

160. Lou, J.; Wang, Q. N.; He, Y.; Yu, Z. K.* A Simple Aliphatic Diamine Auxiliary for Palladium-Catalyzed Arylation of Unactivated β-C(sp3)-H Bonds. 

Adv. Synth. Catal. 2018, 360, 4571-4584.

159. Liu, Z. Q.; Wu, P.; He, Y.; Yang, T.; Yu, Z. K.* [4+1] Cycloaddition of Enaminothiones and Aldehyde N-Tosylhydrazones toward 3-Aminothiophenes. 

Adv. Synth. Catal. 2018, 360, 4381-4392.

158. Guo, T. L.; Huang, F.; Jiang, Q. B.; Yu, Z. K.* PIDA-Mediated Formal Olefinic C=C Bond Cleavage of a-Oxo Ketene N,N-Acetals toward Substituted Oxazolines. 

Chem. Eur. J. 2018, 24, 14368-14372.

157. Liu, T. T.; Wang, L. D.; Wu, K. K.; Yu, Z. K.* Manganese-Catalyzed β-Alkylation of Secondary Alcohols with Primary Alcohols under Phosphine-Free Conditions. 

ACS Catal. 2018, 8, 7201-7207.

156. Liu, Z. Q.; Gao, R. L.; Lou, J.; He, Y.; Yu, Z. K.* Metal-Free Selective Csp-Csp and Csp-Csp3 Bond Cleavages of N,S-Enynes toward Thiophene-Fused N-Heterocycles. 

Adv. Synth. Catal. 2018, 360, 3097-3108.

155. Jiang, Q. B.; Guo, T. L.; Gao, R. L.; Wang, Q. N.; Lou, J.; Yu, Z. K.* α,β-Unsaturated N-Acylindoles: An Alternative Class of Michael Acceptors and Their Application in Asymmetric Borylation. 

J. Org. Chem. 2018, 83, 7981-7993.

154. Liu, Z. Q.; Huang, F.; Wu, P.; Wang, Q. N.; Yu, Z. K.* Amide Bond Formation Assisted by Vicinal Alkylthio Migration in Enaminones: Metal and CO-Free Synthesis of α,β-Unsaturated Amides. 

J. Org. Chem. 2018, 83, 5731-5750.

153. Wang, Q. F.; Chai, H. N.; Yu, Z. K.* Acceptorless Dehydrogenation of N-Heterocycles and Secondary Alcohols by Ru(II)-NNC Complexes Bearing a Pyrazoyl-Indolyl-Pyridine Ligand. 

Organometallics 2018, 37, 584-591.

152. Chai, H. N.; Wang, L. D.; Liu, T. T.; Yu, Z. K.* A Versatile Ru(II)-NNP Complex Catalyst for the Synthesis of Multisubstituted Pyrroles and Pyridines. 

Organometallics 2017, 36, 4936-4942. 

151. Wang, Q. N.; Yang, X. G.; Wu, P.; Yu, Z. K.* Photoredox-Catalyzed C-H Arylation of Internal Alkenes to Tetrasubstituted Alkenes: Synthesis of Tamoxifen. 

Org. Lett. 2017, 19, 6248-6251.

150. Chai, H. N.; Liu, T. T.; Zheng, D. Y.; Yu, Z. K.* Cooperative N-H and CH2-Skeleton Effects on the Catalytic Activities of Bimetallic Ru(II)-NNN Complexes: Experimental and Theoretical Study. 

Organometallics 2017, 36, 4268-4277.

149. Wu, P.; Wu, K. K.; Wang, L. D.; Yu, Z. K.* Iron-Promoted Difunctionalization of Alkenes by Phenylselenylation/1,2-Aryl Migration. 

Org. Lett. 2017, 19, 5450-5453.

148. Wang, Q. F.; Chai, H. N.; Yu, Z. K.* Dimeric Ruthenium(II)-NNN Complex Catalysts Bearing a Pyrazolyl-Pyridylamino-Pyridine Ligand for Transfer Hydrogenation of Ketones and Acceptorless Dehydrogenation of Alcohols. 

Organometallics 2017, 36, 3638-3644.

147. Chai, H. N.; Liu, T. T.; Yu, Z. K.* NHTs Effect on the Enantioselectivity of Ru(II) Complex Catalysts Bearing a Chiral Bis(NHTs)-Substituted Imidazolyl-Oxazolinyl-Pyridine Ligand for Asymmetric Transfer Hydrogenation of Ketones. 

Organometallics 2017, 36, 4136-4144.

146. Liu, T. T.; Chai, H. N.; Wang, L. D.; Yu, Z. K.* Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones. 

Organometallics 2017, 36, 2914-2921.

145. Wang, Q. N.; Lou, J.; Wu, P.; Wu, K. K.; Yu, Z. K.* Iron-Mediated Oxidative C-H Alkylation of S,S-Functionalized Internal Olefins via C(sp2)-H/C(sp3)-H Cross-Coupling. 

Adv. Synth. Catal. 2017, 359, 2981-2998.

144. Huang, F.; Liu, Z. Q.; Wang, Q. N.; Lou, J.; Yu, Z. K.* Copper-Catalyzed Formal Carbene Migratory Insertion into Internal Olefinic C=C Bonds with N-Tosylhydrazones to Access Iminofuran and 2(3H)-Furanone Derivatives. 

Org. Lett. 2017, 19, 3660-3663.

143. Lou, J.; Wang, Q. N.; Wu, K. K.; Wu, P.; Yu, Z. K.* Iron-Catalyzed Oxidative C-H Functionalization of Internal Olefins for the Synthesis of Tetrasubstituted Furans. 

Org. Lett. 2017, 19, 3287-3290.

142. Liu, Z. Q.; Huang, F.; Lou, J.; Wang, Q. N.; Yu, Z. K.* Copper-Promoted Direct C-H Alkoxylation of S,S-Functionalized Internal Olefins with Alcohols. 

Org. Biomol. Chem. 2017, 15, 5535-5540.

141. Jiang, Q. B.; Guo, T. L.; Yu, Z. K.* Copper-Catalyzed Asymmetric Borylation: Construction of a Stereogenic Carbon Center Bearing Both CF3 and Organoboron Functional Groups. 

J. Org. Chem. 2017, 82, 1951-1960.

140. Wu, K. K.; He, W.; Sun, C. L.; Yu, Z. K.* Scalable Synthesis of Secondary and Tertiary Amines by Heterogeneous Pt-Sn/γ-Al2O3 Catalyzed N-Alkylation of Amines with Alcohols. 

Tetrahedron 2016, 72, 5816-5821.

139. Chai, H. N.; Wang, Q. F.; Liu, T. T.; Yu, Z. K.* Diruthenium(II)-NNN Pincer Complex Catalysts for Transfer Hydrogenation of Ketones. 

Dalton Trans. 2016, 45, 17843-17849.

138. Gao, Y.; Zhang, H. J.; Zou, L. L.; Wu, P.; Yu, Z. K.; Lu, X. B.; Chen, J. P.* Quantification of Short-Chain Chlorinated Paraffins by Deuterodechlorination Combined with Gas Chromatography-Mass Spectrometry. 

Environ. Sci. Technol. 2016, 50, 3746-3753.

137. Guo, T. L.; Jiang, Q. B.; Yu, Z. K.* Copper-Catalyzed Ring-Expansion/Thiolactonization via Azidation of Internal Olefinic C-H Bond Under Mild Conditions. 

Adv. Synth. Catal. 2016, 358, 3450-3457. 

136. Wu, K. K.; He, W.; Sun, C. L.; Yu, Z. K.* Bimetallic Pt–Sn/γ-Al2O3 Catalyzed β-Alkylation of Secondary Alcohols with Primary Alcohols under Solvent-Free Conditions. 

Tetrahedron Lett. 2016, 57, 4017-4020.  

135. Wang, Q. F.; Wu, K. K.; Yu, Z. K.* Ruthenium(III)-Catalyzed β-Alkylation of Secondary Alcohols with Primary Alcohols. 

Organmetallics 2016, 35, 1251-1256. 

134. Jiang, Q. B.; Guo, T. L.; Wu, K. K.; Yu, Z. K.* Rhodium(III)-Catalyzed sp2 C-H Addition to CF3-Substituted Unsaturated Ketones. 

Chem. Commun. 2016, 52, 2913-2915. 

133. Huang, F.; Liu, Z. Q.; Yu, Z. K.* C-Alkylation of Ketones and Related Compounds by Alcohols via Transition Metal-Catalyzed Dehydrogenation. 

Angew. Chem. Int. Ed. 2016, 55, 862-875. 

132. Geng, N. B.; Zhang, H. J.;* Zhang, B. Q.; Wu, P.; Wang, F. D.; Yu, Z. K.; Chen, J. P.* Effects of Short-Chain Chlorinated Paraffins Exposure on the Viability and Metabolism of Human Hepatoma HepG2 Cells. 

Environ. Sci. Technol. 2015, 49, 3076-3083.

131. Chai, H. N.; Liu, T. T.; Wang, Q. F.; Yu, Z. K.* Substituent Effect on the Catalytic Activity of Ru(II) Complexes Bearing a Pyridyl-Supported Pyrazolyl-Imidazolyl Ligand for Transfer Hydrogenation of Ketones. 

Organometallics 2015, 34, 5278-5284.

130. Guo, T. L.; Jiang, Q. B.; Yu, Z. K.* Palladium-Catalyzed Oxidative Annulation of in-situ Generated Enones to Pyrroles: A Concise Route to Functionalized Indoles. 

Org. Chem. Front. 2015, 2, 1361-1365.

129. Wu, K. K.; Wu, P.; Chen, J. P.; Sun, C. L.; Yu, Z. K.* Brønsted Acid-Promoted Cascade Alkylation/Cyclization of Pyrroles with N,N-Dimethylaminomethylene-glutaconic Acid Dinitrile: A Concise Route to Cyclopenta[b]pyrroles. 

Adv. Synth. Catal. 2015, 357, 3353-3358.

128. Yang, X. G.; Liu, Z. Q.; Sun, C. L.; Chen, J. P.; Yu, Z. K.* Palladium-Catalyzed Oxidative Cross-Coupling of α-Cyanoketene Dithioacetals with Olefins. 

Chem. Eur. J. 2015, 21, 14085-14094 (Hot Paper).

127. Yang, X. G.; Wu, K. K.; Yu, Z. K.* BF3×OEt2-Mediated Alkenylation of Pyrroles with α-Oxo Ketene Dithioacetals. 

Tetrahedron Lett. 2015, 56, 4490-4493.

126. Yang, X. G.; Wu, K. K.; Wu, P.; Chen, J. P.; Sun, C. L.; Yu, Z. K.* Brønsted Acid-Mediated Annulation of α-Oxo Ketene Dithioacetals to Pyrroles: Efficient Synthesis of Structurally Diverse Cyclopenta[b]pyrroles. 

Chem. Eur. J. 2015, 21, 9323-9327.

125. Wu, P.; Huang, F.; Lou, J.; Wang, Q. N.; Liu, Z. Q.; Yu, Z. K.* Brønsted Acid-Catalyzed Phenylselenenylation of Internal Olefins. 

Tetrahedron Lett. 2015, 56, 2488-2491.

124. Yang, Q.; Wang, Q. F.; Yu, Z. K.* Substitution of Alcohols by N-Nucleophiles via Transition Metal-Catalyzed Dehydrogenation. 

Chem. Soc. Rev. 2015, 44, 2305-2329.

123. Wu, P.; Wang, L. D.; Wu, K. K.; Yu, Z. K.* Brønsted Acid-Catalyzed PhSe Transfer versus Radical Aryl Transfer: Linear Codimerization of Styrenes and Internal Olefins. 

Org. Lett. 2015, 17, 868-871.

122. Yu, Z. K. Catalytic Carbon-Sulfur Bond Activation and Transformations in Homogeneous Catalysis for Unreactive Bond Activation. Edited by Zhang-Jie Shi. Wiley. 2015, P317-346.

121. Guo, T. L.; Jiang, Q. B.; Yu, L. K.; Yu, Z. K.* Synthesis of Chalcones via Domino Dehydrochlorination/Pd(OAc)2-Catalyzed Heck Reaction. 

Chin. J. Catal. 2015, 36, 78-85 (invited). 

120. Jiang, Q. B.; Guo, T. L.; Yu, Z. K.* Copper-Catalyzed Tandem (Asymmetric) Borylation of β-Chloroalkly Aryl Ketones and Related Compounds. 

ChemCatChem 2015, 7, 660-665. 

119. Guo, T. L.; Huang, F.; Yu, Z. K.* Indole Synthesis Through Transition Metal-Catalyzed C-H Activation. 

Tetrahedron Lett. 2015, 56, 296-302 (invited).

118. Yang, Q.; Xu, T. Y.; Yu, Z. K.* Iron-Mediated Carboarylation/Cyclization of Propargylanilines with Acetals: A Concise Route to Indeno[2,1-c]quinolines. 

Org. Lett. 2014, 16, 6310-6313.

117. Huang, F.; Wu, P.; Wang, L. D.; Chen, J. P.; Sun, C. L.; Yu, Z. K.* Copper-Mediated Intramolecular Oxidative C–H/C–H Cross-Coupling of a-Oxo Ketene N,S-Acetals for Indole Synthesis. 

J. Org. Chem. 2014, 79, 10553-10560. 

116. Huang, F.; Wu, P.; Wang, L. D.; Chen, J. P.; Sun, C. L.; Yu, Z. K.* Copper-Mediated Intramolecular Oxidative C-H/N-H Cross-Coupling of a-Alkenoyl Ketene N,S-Acetals to Pyrrolone Derivatives. 

Chem. Commun. 2014, 50, 12479-12481; 13395-13395. 

115. Wu, K. K.; Wu, P.; Wang, L. D.; Chen, J. P.; Sun, C. L.; Yu, Z. K.* Tunable Bronsted Acidity-Dependent Alkylation and Alkenylation of Indoles. 

Adv. Synth. Catal. 2014, 356, 3871-3880. 

114. Guo, T. L.; Jiang, Q. B.; Huang, F.; Chen, J. P.; Yu, Z. K.* Palladium-Catalyzed, Copper- Mediated Construction of Benzene Rings from the Reactions of Indoles with in-situ Generated Enones. 

Org. Chem. Front. 2014, 1, 707-711. 

113. Yang, Q.; Wu, P.; Chen, J. P.; Yu, Z. K.* Iron-Catalyzed Alkylation of α-oxo Ketene Dithioacetals. 

Chem. Commun. 2014, 50, 6337-6339. 

112. Jin, W. W.; Yang, Q.; Wu, P.; Chen, J. P.; Yu, Z. K.* Palladium-Catalyzed Oxidative Heck-Type Allylation of b,b-Disubstituted Enones with Allyl Carbonates. 

Adv. Synth. Catal. 2014, 356, 2097-2102.

111. Du, W. M.; Wang, Q. F.; Wang, L. D.; Yu, Z. K.* Ruthenium Complex Catalysts Supported by a Bis(trifluoromethyl)pyrazolyl-Pyridyl-Based NNN Ligand for Transfer Hydrogenation of Ketones. 

Organometallics 2014, 33, 974-982. 

110. Wang, Q. F.; Du, W. M.; Liu, T. T.; Chai, H. N.; Yu, Z. K.* Ruthenium(II)-NNN Complex Catalyzed Oppenauer-Type Oxidation of Secondary Alcohols. 

Tetrahedron Lett. 2014, 55, 1585-1588.

109. Mao, Z. F.; Huang, F.; Yu, H. F.; Chen, J. P.; Yu, Z. K.,* Xu, Z. Q. Copper-Catalyzed Trifluoromethylation of Internal Olefinic C-H Bonds: Efficient Routes to Trifluoromethylated Tetrasubstituted Olefins and N-Heterocycles. 

Chem. Eur. J. 2014, 20, 3439-3445.

108. Yang, Q.; Chai, H. N.; Liu, T. T.; Yu, Z. K.* Palladium-Catalyzed Cross-Coupling of Cyclopropylmethyl N-Tosylhydrazones with Aromatic Bromides: An Easy Access to Multisubstituted 1,3-Butadienes. 

Tetrahedron Lett. 2013, 54, 6485-6489.

107. Du, W. M.; Wu, P.; Wang, Q. F.; Yu, Z. K.* Ruthenium(II) Complex Catalysts Bearing a Pyridyl-Based Benzimidazolyl-Benzotriazolyl Ligand for Transfer Hydrogenation of Ketones. 

Organometallics 2013, 32, 3083-3090.

106. Du, W. M.; Wang, Q. F.; Yu, Z. K.* Ruthenium(II) Pyridyl-Based NNN Complex Catalysts for (Asymmetric) Transfer Hydrogenation of Ketones at Room Temperature. 

Chin. J. Catal. 2013, 34, 1373-1377.

105. Jiang, Q. B.; Guo, T. L.; Wang, Q. F.; Wu, P.; Yu, Z. K.* Rhodium(I)-Catalyzed Arylation of β-Chloro Ketones and Related Derivatives Through Domino Dehydrochlorination/Conjugate Addition. 

Adv. Synth. Catal. 2013, 355, 1874-1880.

104. Wang, L. D.; He, W.; Yu, Z. K.* Transition-Metal Mediated Carbon-Sulfur Bond Activation and Transformations. 

Chem. Soc. Rev. 2013, 42, 599-621.

103. Yang, Q.; Wang, L. D.; Guo, T. L.; Yu, Z. K.* FeCl3.6H2O-Catalyzed Alkenylation of Indoles with Aldehydes. 

J. Org. Chem. 2012, 77, 8355-8361.

102. Jin, W. W.; Wang, L. D.; Yu, Z. K.* A Highly Active Ruthenium(II) Pyrazolyl-Pyridyl- Pyrazole Complex Catalyst for Transfer Hydrogenation of Ketones. 

Organometallics 2012, 31, 5664-5667.

101. Du, W. M.; Wang, L. D.; Wu, P.; Yu, Z. K.* A Versatile Ruthenium(II) NNC Complex Catalyst for Transfer Hydrogenation of Ketones and Oppenauer-Type Oxidation of Alcohols. 

Chem. Eur. J. 2012, 18, 11550-11554.

100. Mao, Z. F.; Wang, Z.; Xu, Z. Q.*; Huang, F.; Yu, Z. K.*; Wang, R.* Copper(II)-Mediated Dehydrogenative Cross-Coupling of Heteroarenes. 

Org. Lett. 2012, 14, 3854-3857.

99. Ye, W. J.; Zhao, M.; Yu, Z. K.* Ruthenium(II) Pyrazolyl-Pyridyl-Oxazolinyl Complex Catalysts for Asymmetric Transfer Hydrogenation of Ketones. 

Chem. Eur. J. 2012, 18, 10843-10846.

98. Du, W. M.; Yu, Z. K.* Biomimetic In Situ Regeneration of Cofactors NAD(P)+ and NAD(P)H Models Hantzsch Esters and Dihydrophenanthridine. 
Synlett 2012, 23, 1300-1304.

97. Yu, Z. K.*; Jin, W. W.; Jiang, Q. B. Bronsted Acid Activation Strategy in Transition Metal- Catalyzed Asymmetric Hydrogenation of Unprotected N-H Imines, Enamines and N-Heteroaromatics. 

Angew. Chem. Int. Ed. 2012, 51, 6060-6072.

96. Dai, C.; Xu, Z. Q.*; Huang, F.; Yu, Z. K.*; Gao, Y.-F.* Lewis Acid-Catalyzed, Copper(II)- Mediated Synthesis of Heteroaryl Thioethers under Base-Free Conditions. 

J. Org. Chem. 2012, 77, 4414-4419.

95. He, W.; He, S. B.; Sun, C. L.; Wu, K. K.; Wang, L. D.; Yu, Z. K.* Heterogeneous Bimetallic Pt-Sn/γ-Al2O3 Catalyzed N-Alkylation of Amines: Efficient Synthesis of Secondary and Tertiary Amines. 

Chin. J. Catal. 2012, 33, 717-722.

94. Chintareddy, V. R.; Oshel, R. E.; Doll, K. M.; Yu, Z. K.; Wu, W.; Zhang, G. T.; Verkade, J. G.* Investigation of Conjugated Soybena Oil as Drying Oils and CLA Sources. 

J. Am. Oil Chem. Soc. 2012, 89, 1749-1762.

93. Gao, Y.; Zhang, H. J.; Chen, J. P.*; Zhang, Q.; Tian, Y. Z.; Qi, P. P.; Yu, Z. K. Optimized Cleanup Method for the Determination of Short Chain Polychlorinated n-Alkanes in Sediments by High Resolution Gas Chromatography/Electron Capture Negative Ion-Low Resolution Mass Spectrometry. 

Anal. Chim. Acta 2011, 703, 187-193.

92. Wang, L. D.; He, W.; Wu, K. K.; He, S. B.; Sun, C. L.; Yu, Z. K.* Heterogeneous Bimetallic Pt-Sn/gamma-Al2O3 Catalyzed Direct Synthesis of Diamines from N-Alkylation of Amines with Diols Through a Borrowing Hydrogen Strategy. 

Tetrahedron Lett. 2011, 52, 7103-7107.

91. Jin, W. W.; Yu, H. F.; Yu, Z. K.* Regioselective Synthesis of Multisubstituted Pyrazoles via Cyclocondensation of β-Thioalkyl-α,β-Unsaturated Ketones with Hydrazines. 

Tetrahedron Lett. 2011, 52, 5884-5887.

90. He, W.; Wang, L. D.; Sun, C. L.; Wu, K. K.; He, S. B.; Chen, J. P.; Yu, Z. K.* Pt-Sn/γ-Al2O3 Catalyzed Highly Efficient Direct Synthesis of Secondary and Tertiary Amines and Imines from the Reactions of Amines with Alcohols or Between Amines. 

Chem. Eur. J. 2011, 17, 13308-13317.

89. Xu, T. Y.; Yang, Q.; Ye, W. J.; Jiang, Q. B.; Xu, Z. Q.; Chen, J. P.; Yu, Z. K.* Substituent Dependent Iron-Mediated Tandem Cyclization of Diynes with Benzaldehyde Acetals to Highly Functionalized Indene Derivatives. 

Chem. Eur. J. 2011, 17, 10547-10551.

88. Jin, W. W.; Du, W. M.; Yang, Q.; Yu, H. F.; Chen, J. P.; Yu, Z. K.* Regio- and Stereoselective Synthesis of Multi-substituted Olefins and Conjugate Dienes by Using alpha-Oxo Ketene Dithioacetals as the Building Blocks. 

Org. Lett. 2011, 13, 4272-4275.

87. Luo, N.; Zheng, Z. Y.; Yu, Z. K.* Highly Regioselective [3+2] Annulation of Azomethine Imines with 1-Alkynyl Fischer Carbene Complexes to Functionalized N,N-Bicyclic Pyrazolidin-3-ones. 

Org. Lett. 2011, 13, 3384-3387.

86. Yang, F. Z.; Xu, Z. Q.*; Wang, Z.; Yu, Z. K.*; Wang, R.* Copper-Catalyzed Oxidative Arylation of Heteroarenes under Mild Conditions and Using Dioxygen as Sole Oxidant. 

Chem. Eur. J. 2011, 17, 6321-6325.

85. Ye, W. J.; Zhao, M.; Du, W. M.; Jiang, Q. B.; Wu, K. K.; Wu, P.; Yu, Z. K.* Highly Active Ruthenium(II) Complex Catalysts Bearing a Unsymmetrical NNN Ligand in (Asymmetric) Transfer Hydrogenation of Ketones. 

Chem. Eur. J. 2011, 17, 4737-4741.

84. Yu, H. F.; Jin, W. W.; Sun, C. L.; Chen, J. P.; Du, W. M.; He, S. B.; Yu, Z. K.* Palladium-Catalyzed Direct Cross-Coupling of Internal Alkenes with Terminal Alkenes to Functionalized 1,3-Butadienes via C-H Bond Activation: Efficient Synthesis of Bicyclic Pyridones. 

Angew. Chem. Int. Ed. 2010, 49, 5792-5797. 

83. Xu, T. Y; Yang, Q.; Li, D. P.; Dong, J. H.; Yu, Z. K.*; Li, Y. X.* Iron(III)-Catalyzed Cyclization of Alkynyl-aldehyde Acetals: Experimental and Computational Studies. 

Chem. Eur. J. 2010, 16, 9264-9272.

82. Luo, N.; Yu, Z. K.* RuCl3.xH2O-Catalyzed Direct Arylation of Arenes with Aryl Chlorides in the Presence of Triphenylphosphine. 

Chem. Eur. J. 2010, 16, 787-791.

81. Ye, W. J.; Luo, N.; Yu, Z. K.* Rhodium-Catalyzed Direct Alkenylation and Arylation of Arene C-H Bonds via Decarbonylation of Cinnamoyl Chlorides, Cinnamic Anhydrides and Poly(aroyl) Chlorides. 

Organometallics 2010, 29, 1049-1052.

80. Wu, X. W.; Yu, Z. K.* Metal and Phosgene-Free Synthesis of 1H-Quinazoline-2,4-diones by Selenium-Catalyzed Carbonylation of o-Nitrobenzamides. 

Tetrahedron Lett. 2010, 51, 1500-1503.

79. Wang, L. D.; Wu, X. W.; He, W.; Liu, Z. S.; Yu, Z. K.* Palladium-Catalyzed Carboxylation of 1,3-Butadiene to Methyl 3-Pentenoate. 

Chin. J. Catal. 2010, 31, 1044-1048 (invited).

78. Yu, H. F.; Yu, Z. K.* Direct Alkenylation of Indoles through Acid-mediated Substitution Reactions with a-Oxo Ketene Dithioacetals: Efficient Synthesis of Indole Alkaloids Meridianin Derivatives. 

Angew. Chem. Int. Ed. 2009, 48, 2929-2933.

77. Jin, W. W.; Yu, Z. K.;* He, W.; Ye, W. J.; Xiao, W.-J. Efficient Rh(I)-Catalyzed Direct Arylation and Alkenylation of Arene C-H Bonds via Decarbonylation of Benzoic and Cinnamic Anhydrides. 

Org. Lett. 2009, 11, 1317-1320.

76. Xu, T. Y.; Yu, Z. K.;* Wang, L. D. Iron-Promoted Cyclization/Halogenation of Alkynyl Diethyl Acetals. 

Org. Lett. 2009, 11, 2113-2116.

75. Li, Y.; Yu, Z. K.* Palladium-Catalyzed Carbonylative Cycloisomerization of γ-Propynyl- 1,3-diketones: A Concise Route to Polysubstituted Furans. 

J. Org. Chem. 2009, 74, 8904-8907.

74. Zeng, F. L.; Yu, Z. K.* Construction of Highly Active Ruthenium(II) NNN Complex Catalysts Bearing a Pyridyl-Supported Pyrazolyl-Imidazolyl Ligand for Transfer Hydrogenation of Ketones.

Organometallics 2009, 28, 1855-1862.

73. Zhao, M.; Yu, Z. K.;* Yan, S. G.; Li, Y. Room-Temperature Ru(II)-Catalyzed Transfer Hydrogenation of Ketones and Aldehydes in Air. 

Tetrahedron Lett. 2009, 50, 4624-4628.

72. Luo, N.; Yu, Z. K.* Multiple Reactivities of Dithranol Towards 1-Alkynyl Fischer Carbene Complexes (CO)5M=C(OEt)CºCPh (M = Cr, W)-Efficient Chemical Synthesis of Aromatic Polyketides. 

J. Organomet. Chem. 2009, 694, 3058-3067.

71. Zhao, M.; Yu, Z. K.;* Yan, S. G.; Li, Y. Ruthenium(II) Complex Catalysts Bearing a Pyridyl- Supported Pyrazolyl-Imine Ligand for Transfer Hydrogenation of Ketones. 

J. Organomet. Chem. 2009, 694, 3068-3075.

70. Tan, W. Q.; Yu, Z. K.;* Liu, B.; Wu, K. K.; Liu, Z. S.; Chen, J. Z. Synthesis and Structural Characterization of (CH2)n-Bridged Indenylpyrazoles and Their Cyclopentadienyl Nickel(II) Complexes. 

J. Organomet. Chem. 2009, 694, 199-206.

69. Tan, W. Q.; Yu, Z. K.;* He, W.; Wang, L. D.; Sun, J.; Chen, J. Z. A Toluene Guest in a Poly(heteronuclear) Complex Host of Ferrocenyl-(CH2)2-Bridged Bispyrazole. 

Organometallics 2008, 27, 4833-4836.

68. Zeng, F. L.; Yu, Z. K.* Ruthenium(II) Complexes Bearing a Pyridyl-Supported Pyrazolyl-N-Heterocyclic Carbene (NNC) Ligand and Their Catalytic Activity in Transfer Hydrogenation of Ketones. 

Organometallics 2008, 27, 6025-6028.

67. Zhao, X. D.; Yu, Z. K.* Rhodium-Catalyzed Regioselective C-H Functionalization via Decarbonylation of Acid Chlorides and C-H Bond Activation under Phosphine-Free Conditions. 

J. Am. Chem. Soc. 2008, 130, 8136-8137.

66. Li, Y.; Yu, Z. K.;* Wu, S. Z. Efficient Copper(II)-Catalyzed Addition of Activated Methylene Compounds to Alkenes. 

J. Org. Chem. 2008, 73, 5647-5650.

65. Zeng, F. L.; Yu, Z. K.* Exceptionally Efficient Unsymmetrical Ruthenium(II) NNN Complex Catalysts Bearing a Pyridyl-Based Pyrazolyl-Imidazolyl Ligand for Transfer Hydrogenation of Ketones. 

Organometallics 2008, 27, 2898-2901.

64. Zhao, X. D.; Yu, Z. K.;* Xu, T. Y.; Wu, P.; Yu, H. F. Novel Bronsted Acid-Catalyzed Three- Component Alkylations of Indoles with N-Phenylselenophthalimide and Styrenes. 

Org. Lett. 2007, 9, 5263-5266.

63. Li, Y.; Yu, Z. K.;* Alper, H.* Palladium (II)-Catalyzed Synthesis of Highly Substituted Endocyclic Enol Lactones via a Three-component Coupling Reaction. 

Org. Lett. 2007, 9, 1647-1649.

62. Tan, W. Q.; Zhao, X. D.; Yu, Z. K.* Synthesis and Structural Characterization of Ruthenium(II) Complexes Bearing Phosphine-Pyrazolyl Based Tripod Ligands. 

J. Organomet. Chem. 2007, 692, 5395-5402.

61. Yu, Z. K.;* Zeng, F. L.; Sun, X. J.; Deng, H. X.; Dong, J. H.; Chen, J. Z.; Wang, H. M.; Pei, C. X. Two Pseudo-N3 Ligands and the Catalytic Activity of Their Ruthenium Complexes in Transfer Hydrogenation and Hydrogenation of Ketones. 

J. Organomet. Chem. 2007, 692, 2306-2313.

60. Zheng, Z. Y.; Yu, Z. K.;* Luo, N.; Han, X. W. Tautomerism-Dependent Ring Construction of N-Heterocyclic Compounds from the Reactions of 1-Alkynyl Fischer Carbene Complexes and Substituted Pyrazolinones. 

J. Org. Chem. 2006, 71, 9695-9700. 

59. Li, Y.; Alper, H.;* Yu, Z. K.* Palladium-Catalyzed Regiospecific Aminocarbonylation of Alkynes in the Ionic Liquid [bmim][Tf2N]. 

Org. Lett. 2006, 8, 5199-5201.

58. Zeng, F. L.; Yu, Z. K.* Pyridyl-Supported Pyrazolyl-N-Heterocyclic Carbene (NHC) Ligands and the Catalytic Activity of Their Palladium Complexes in Suzuki-Miyaura Reactions. 

J. Org. Chem. 2006, 71, 5274-5281.

57. Zhao, X. D.; Alper, H.;* Yu, Z. K.* Stereoselective Hydroxycarbonylation of Vinyl Bromides to the Corresponding α,β-Unsaturated Carboxylic Acids in the Ionic Liquid [BMIM]PF6. 

J. Org. Chem. 2006, 71, 3988-3990.

56. Zheng, Z. Y.; Chen, J. Z.; Luo, N.; Yu, Z. K.;* Han, X. W. Efficient Demetalation of Fischer Alkoxy and Amino-biscarbene Complexes of Chromium via CO-Promoted Sulfuration and Selenylation. 

Organometallics 2006, 25, 5301-5310.

55. Yu, Z. K.;* Yan, S. G.; Zhang, G. T.; He, W.; Wang, L. D.; Li, Y.; Zeng, F. L. Proazaphosphatrane P(RNCH2CH2)3N (R = Me, iPr)-Catalyzed Isomerization of Allylaromatics, Allyl Phenyl Sulfide, Allyl Phenyl Sulfone, and bis-Allylmethylene Double Bond-Containing Compounds. 

Adv. Synth. Catal. 2006, 348, 111-117.

54. Liu, H.; Zhou, Y.-G.; Yu, Z. K.; Xiao, W.-J.;* Liu, S. H.; He, H. W. Efficient Catalytic Asymmetric Synthesis of a-Substituted Phenyloxyacetyloxy and Aroyloxy Phosphonates. 

Tetrahedron 2006, 62, 11207-11217.

53. Gu, K. C.; Yang, G.; Zhang, W. P.; Liu, X. M.; Yu, Z. K.; Han, X. W.;* Bao, X. H. Mechanistic Studies on Michael Type Addition by NMR Technique and DFT Methods: (CO)5W=C(OEt)CCPh as the Substrate. 

Chin. J. Inorg. Chem. 2006, 22, 1043-1048.

52. Zheng, Z. Y.; Yu, Z. K.;* Wang, L. D.; He, W.; Liu, Z. S.; Han, X. W. Biscarbene Complexes from the Reactions of O-Ethyl Lactim and 1-Alkynyl Fischer Carbene Complexes of Chromium and Tungsten. 

J. Organomet. Chem. 2006, 691, 5007-5015.

51. Zheng, Z. Y.; Chen, J. Z.; Yu, Z. K.;* Han, X. W. Oxidative Demetalation of Fischer Alkoxy Carbene Complexes with Stoichiometric Pyridine N-Oxide and NaBH4-Promoted Demetalation of Fischer Iminocarbene Complexes with Sulfur and Selenium. 

J. Organomet. Chem. 2006, 691, 3679-3692.

50. Sirimanne, C. T.; Yu, Z. K.; Heeg, M. J.; Winter, C. H.* Synthesis, Structure, and Bridge-Terminal Alkyl Exchange Kinetics of Pyrazolate-Bridged Dialuminum Complexes Containing Bridging n-Alkyl Groups. 

J. Organomet. Chem. 2006, 691, 2517-2527.

49. Gu, K. C.; Yang, G.; Zhang, W. P.; Liu, X. M.; Yu, Z. K.; Han, X. W.;* Bao, X. H. An Experimental-Theoretical Approach to the Kinetics and Mechanism of Michael Type Addition: α,β-Unsaturated Tungsten Fischer Carbene Complex as the Substrate. 

J. Organomet. Chem. 2006, 691, 1984-1992.

48. Sirimanne, C. T.; Zheng, W. J.; Yu, Z. K.; Heeg, M. J.; Winter, C. H.* Synthesis, Structure, and Bridge-Terminal Exchange Kinetics of Pyrazolate-Bridged Digallium and Diindium Complexes Containing Bridging Phenyl Groups. 

Organometallics 2005, 24, 6184-6193.

47. Zhao, X. D.; Yu, Z. K.;* Yan, S. G.; Wu, S. Z.; Liu, R.; He, W.; Wang, L. D. Ruthenium(III) Chloride Catalyzed Efficient Synthesis of Unsymmetrical Diorganyl Selenides via Cleavage of Dibenzyl and Diphenyl Diselenides in the Presence of Zinc. 

J. Org. Chem. 2005, 70, 7338-7341.

46. Deng, H. X.; Yu, Z. K.;* Dong, J. H.; Wu, S. Z. 2,6-Bis(3,5-dimethylpyrazol-1-yl)pyridine: A Useful Pseudo N3 Ligand in Efficient Ruthenium(II)-Catalyzed Transfer Hydrogenation of Ketones. 

Organometallics 2005, 24, 4110-4112.

45. Sun, X. J.; Yu, Z. K.;* Wu, S. Z.; Xiao, W.-J.* Base Effect, Inhibition of Catalytic Activity in Palladium-Catalyzed N-Heteroarylation of Pyrazoles with 2,6-Dibromopyridine. 

Organometallics 2005, 24, 2959-2963.

44. Zhao, X. D.; Yu, Z. K.;* Zeng, F. L.; Chen, J. Z.; Wu, X. W.; Wu, S. Z.; Xiao, W.-J.;* Zheng, Z. Y. Highly Efficient Route to Diselenides from the Reactions of Imines and Selenium in the Presence of Carbon Monoxide and Water. 

Adv. Synth. Catal. 2005, 347, 877-882.

43. Sun, X. J.; Yu, Z. K.;* Deng, H. X.; Wu, S. Z.; Dong, J. H. Palladium-Catalyzed Coupling of Pyrazoles with 2,6-Dibromopyridine. 

Chin. J. Catal. 2005, 26, 173-174.

42. Yang, Q.; Xiao, W.-J.;* Yu, Z. K.* Lewis Acid Assisted Ring-Closing Metathesis of Chiral Diallylamines: An Efficient Approach to Enantiopure Pyrrolidine Derivatives. 

Org. Lett. 2005, 7, 871-874.

41. Chen, J. Z.; Yu, Z. K.;* Zheng, Z. Y.; Gu, K. C.; Wu, S. Z.; Zeng, F. L.; Tan, W. Q.; Wu, X. W.; Xiao, W.-J.* Chemoselective Stepwise Demetallation of Unusually Stable Fischer Biscarbene Complexes by Domino [4+2]/[2+2] Cycloaddition of 2-Isopropenyl-2-oxazoline to 1-Alkynyl Fischer Carbene Complexes of Chromium and Tungsten. 

Organometallics 2005, 24, 302-308.

40. Gu, K. C.; Chen, J. Z.; Zheng, Z. Y.; Wu, S. Z.; Wu, X. W.; Han, X. W. Yu, Z. K.;* Synthesis and Structural Characterization of (Pyrazolyl)alkenyl Fischer Carbene Complexes of Chromium and Tungsten. 

Polyhedron 2005, 24, 173-180.

39. Yu, Z. K.; Knox, J. E.; Korolev, A. V.; Heeg, M. J.; Schlegel, H. B.; Winter, C. H.* Synthesis, Characterization, and Hydrolysis Products of (h2-tBu2pz)AlH-(h:h1,h1-tBu2pz)2AlH2. Structural Characterization of a Complex Containing h1-, h2-, and m:h1,h1-Pyrazolato Ligands and a Complex Containing a Terminal Hydroxo Ligand. 

Eur. J. Inorg. Chem. 2005, 2, 330-337. 

38. Chen, J. Z.; Ling, G.; Yu, Z. K.;* Lu, S.* N-Aryl Amides from Selenium-Catalyzed Reactions of Nitroaromatics and Amides in the Presence of Carbon Monoxide and Organic Base. 

Adv. Synth. Catal. 2004, 346, 1267-1270.

37. Tian, F. S.; Yu, Z. K.;* Lu, S. W.* Efficient Reductive Selenation of Aromatic Aldehydes to Symmetrical Diselenides with Se/CO/H2O under Atmospheric Pressure. 

J. Org. Chem. 2004, 69, 4520-4523.

36. Wang, X. F.; Lu, S. W.;* Yu, Z. K.* Selenium-Catalyzed Carbonylation of Nitroaromatics to Symmetric Diarylureas under Atmospheric Pressure. 

Adv. Synth. Catal. 2004, 346, 929-932.

35. Yu, Z. K.; Verkade, J. G.* Catalytic Dimerization of Allyl Phenyl Sulfone in the Presence of a Proazaphosphatrane Catalyst. 

Adv. Synth. Catal. 2004, 346, 539-541.

34. Yu, Z. K.; Korolev, A. V.; Heeg, M. J.; Winter, C. H.* Synthesis and Structural Characterization of Gallium Complexes Derived from Treatment of Gallium Trichloride with 3,5-Diphenylpyrazole. 

Polyhedron 2002, 21, 1117.

33. Yu, Z. K.; Wittbrodt, J. M.; Xia, A. B.; Heeg, M. J.; Schlegel, H. B.; Winter, C. H.* Hydrogen and Dihydrogen Bonding as Important Features of the Reactivity of the Bridging Hydride in Pyrazolate-Bridged Dialuminum Complexes. 

Organometallics 2001, 20, 4301-4303.

32. Yu, Z. K.; Heeg, M. J.; Winter, C. H.* A Bridging Ethyl Complex of Aluminum. 

Chem. Commun. 2001, 353-354.

31. Yu, Z. K.; Wittbrodt, J. M.; Heeg, M. J.; Schlegel, H. B.; Winter, C. H.* Unusually Stable Pyrazolate-Bridged Dialuminum Complexes Containing Bridged Methyl Groups. 

J. Am. Chem. Soc. 2000, 122, 9338-9339.

30. Yu, Z. K.; Verkade, J. G.* P(MeNCH2CH2)3N: An Efficient Catalyst for the Desilylation of tert-Butyldimethylsilyl Ethers. 

J. Org. Chem. 2000, 65, 2065-2068.

29. Yu, Z. K.; Verkade, J. G.* Desulfurization of Organosulfur Compounds with Lithium and Sodium. 

Energy & Fuels 1999, 13, 23-28.

28. Liu, X. D.; Yu, Z. K.; Verkade, J. G.* Free and Polymer-Based Azaphosphatrane-Catalyzed Dehydrobromination with NaH.

J. Org. Chem. 1999, 64, 8058-8058; 4840-4843.

27. Yu, Z. K.; Verkade, J. G.* P(MeNCH2CH2)3N: An Efficent Desulfurizing Reagent. 

Heteroatom Chem. 1999, 10, 544-547.

26. Kisanga, P.; McLeod, D.; Liu, X. D.; Yu, Z. K.; Ilankumaran, P.; Wang, Z. G.; McLaughlin, P. A.; Verkade, J. G.* New Chemistry of ZP(RNCH2CH2)3N Systems. 

Phosphorous, Sulfur and Silicon 1999, 146, 106-114.

25. Yu, Z. K.; Verkade, J. G.* Mild and Efficient Desulfurization of Alkyl Sulfides with Sodium. 

Tetrahedron Lett. 1998, 39, 2671-2674.

24. Yu, Z. K.; Verkade, J. G.* Reductive Desulfurization of Organosulfur Compounds with Sodium in Liquid Ammonia. 

Phosphorous, Sulfur and Silicon 1998, 133, 79-82.

23. Yu, Z. K.; Mohan, T.; Erdmann, K.; Verkade, J. G.* 31P NMR Analysis of and Sulfur Removal from Coal Materials. 

American Chemical Society, Division of Fuel Chemistry, Preprints, 1998, 43, 905-908.

22. Aumann, R.;* Yu, Z. K.; Frolich, R. Cyclopentadienes by Novel Annulation of Alkoxyl-Substituted Lactims to (1-Alkynyl)carbene Complexes of Chromium and Tungsten via Binuclear Carbene Complexes. 

Organometallics 1998, 17, 2897-2905.

21. Aumann, R.;* Yu, Z. K.; Frolich, R.; Zippel, F. Mesoionic Pyrrolium Complexes and Dihydropyrroles by Cycloaddition of (Non-enolizable) Imines to [(1-Alkynyl)carbene]tungsten Complex. 

Eur. J. Inorg. Chem. 1998, 11, 1623-1629.

20. Aumann, R.;* Yu, Z. K.; Frolich, R. Dihydropyridinyl Carbene Complexes by [4+2] Annulation of Alkenyl- or Aryl Imines to (1-Alkynyl)carbene Complexes of Chromium and Tungsten. 

J. Organomet. Chem. 1997, 549, 311-318.

19. Yu, Z. K.; Aumann, R.;* Frolich, R.; Roths, K.; Hecht, J. 1-Metalla-1,3,5,7-octatetraenes from (1-Alkynyl)carbene Complexes of Chromium and Tungsten via [6-(1-Alkenyl)]pyranylidene Complexes. 

J. Organomet. Chem. 1997, 541, 187-198.

18. Yu, Z. K.; Liao, S. J.;* Xu, Y.; Yang, B.; Yu, D. R. Hydrogenation of Nitroaromatics by Polymer-Anchored Bimetallic Palladium-Ruthenium and Palladium-Platinum Catalysts under Mild Conditions. 

J. Mol. Catal., A: Chem. 1997, 120, 247-255.

17. Yang, B.; Yu, Z. K.; Xu, Y.;* Liao, S. J. Hydrogenation of Nitrobenzene with Dually Supported Bimetallic Catalysts. 

Chin. Petrochem. Eng. 1997, 26, 740-744.

16. Yu, Z. K.; Xu, Y.; Liao, S. J.;* Jiang, H.; Yang, B.; et al. Highly Active Polymer-Anchored Bimetallic Palladium-Based Catalysts for the Carbonylation of Allyl Halides under Atmospheric Pressure. 

React. Funct. Polym. 1996, 31, 201-205.

15. Yu, Z. K.; Liao, S. J.;* Xu, Y.; Yu, D. R. Facile Hydrodebromination of Organic Bromides with Dihydrogen and Polymer-Anchored Palladium Catalyst under Mild Conditions. 

React. Funct. Polym. 1996, 29, 151-157.

14. Yu, Z. K.; Xu, Y.; Liao, S. J.;* Liu, R. Catalytic Behaviors and Gas Permeation Properties of Palladium-Containing Phenophthalein Poly(ether sulfone). 

J. Appl. Polym. Sci. 1996, 61, 599-605.

13. Yu, Z. K.;* Wang, S. H.; Yan, S. G. Structures and Relationship Between the 119Sn NMR Chemical Shifts and pKa of Their Parent Acids in Organotin(IV) Carboxylates. 

Heteroatom Chem. 1996, 7, 3-8.

12. Yang, B.; Yu, Z. K.; Xu, Y.;* Liao, S. J. Synergic Effect of Polymer-Supported Pd-Pt Bimetallic Catalysts on the Hydrogenation of Nitroaromatics. 

Chin. Chem. Lett. 1996, 7, 663-666.

11. Yu, Z. K.; Xu, Y.; Liao, S. J.;* Yu, D. R. Catalytic Properties of Polymer-Supported Palladium Catalysts in the Hydrogenation and Carbonylation. 

Chin. J. Chem. (Acta Chim. Sinica) 1996, 54, 253-260.

10. Yu, Z. K.; Liao, S. J.;* Xu, Y.; Yang, B.; Yu, D. R. A Remarkable Synergic Effect of Polymer-Anchored Bimetallic Palladium-Ruthenium Catalysts in the Selective Hydrogenation of p-Chloronitrobenzene. 

Chem. Commun. 1995, 1155-1156.

9. Yu, Z. K.;* Yan, S. G.; Zen, P. J.; Chen, J. The Reaction of Diphenyltin(IV) or Triphenyltin(IV) Chloride with 3,4,5-Trimethoxybenzoyl Salicylahydrazone. The Crystal Structure of Ph2[(MeO)3C6H2C(O)N2CHC6H4O]Sn. 

Heteroatom Chem. 1995, 6, 513-517.

8. Yu, Z. K.; Xu, Y.; Liao, S. J.;* Yu, D. R. Synergic Effect of Polymer-Anchored Bimetallic Catalysts in the Carbonylation of Allyl Chloride. 

Chin. J. Catal. 1995, 16, 7-8.

7. Yu, Z. K.; Xu, Y.; Liao, S. J.;* Yu, D. R. Synthesis of Butenoic Acid with Soluble Polymer-Anchored Palladium Catalysts. 

Chin. J. Catal. 1995, 16, 124-130.

6. Yu, Z. K.; Wang, S. H.;* Yang, Z. Y.; Han, X. W. Spectral Characterization of di-n-Butyltin(IV) Carboxylates. 

Chin. J. Magn. Reson. 1994, 11, 35-42.

5. Yu, Z. K.;* Wang, S. H.; Yang, Z. Y.; Liu, X. M.; Hu, N. H. Synthesis and Molecular Structure of nBu2[(MeO)3C6H2C(O)N2CHC6H4O]Sn Formed in the Reaction of di-n-Butyltin(IV) Oxide with 3,4,5-Trimethoxybenzoyl Salicylahydrazone. 

J. Organomet. Chem. 1993, 447, 189-195.

4. Yu, Z. K.; Wang, S. H.* Carbon-Carbon Bond Formation from Palladium-Catalyzed Reactions of Organotin(IV) and Electrophiles.  

Chin. J. Org. Chem. 1993, 13, 579-589.

3. Hu, X. Q.; Wang, S. H.;* Yan, S. G.; Yu, Z. K. Spectral Characterization of Heterocyclic Organotin(IV) Compounds. 

Chin. J. Magn. Reson. 1993, 10, 17-24.

2. Yu, Z. K.; Wang, S. H.* Improved Preparation of Organotin(IV) Reagents R3SnLi. 

Chin. Chem. Reag. 1993, 15, 108-110. 

    1. Yu, Z. K.;* Wang, S. H. Chemically Plating Nickel on Ceramic Semiconductor Material. 

    Chin. Chem. World 1992, 6, 283-284.


发表论文
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[27] Zhengkun Yu. Transition-Metal-Catalyzed Direct C-H Cyanoalkylation and Cyanoalkoxylation of Internal Alkenes via Radical C-C Bond Cleavage of Cycloketone Oxime Esters. Adv. Synth. Catal.. 2019, [28] Wang, Qingfu, Chai, Huining, Yu, Zhengkun. Acceptorless Dehydrogenation of N-Heterocycles and Secondary Alcohols by Ru(II)-NNC Complexes Bearing a Pyrazoyl-indolyl-pyridine Ligand. ORGANOMETALLICS[J]. 2018, 37(4): 584-591, http://cas-ir.dicp.ac.cn/handle/321008/168870.
[29] Liu, Tingting, Wang, Liandi, Wu, Kaikai, Yu, Zhengkun. Manganese-Catalyzed beta-Alkylation of Secondary Alcohols with Primary Alcohols under Phosphine-Free Conditions. ACS CATALYSIS[J]. 2018, 8(8): 7201-7207, https://www.webofscience.com/wos/woscc/full-record/WOS:000441112400040.
[30] Liu, Zhuqing, Wu, Ping, He, Yuan, Yang, Ting, Yu, Zhengkun. 4+1 Cycloaddition of Enaminothiones and Aldehyde N-Tosylhydrazones Toward 3-Aminothiophenes. ADVANCEDSYNTHESISCATALYSIS[J]. 2018, 360(22): 4381-4392, http://www.corc.org.cn/handle/1471x/2373108.
[31] Guo, Tenglong, Huang, Fei, Jiang, Quanbin, Yu, Zhengkun. PIDA-Mediated Formal Olefinic C=C Bond Cleavage of alpha-Oxo-Ketene N,N-Acetals toward Substituted Oxazolines. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2018, 24(54): 14368-14372, http://cas-ir.dicp.ac.cn/handle/321008/166942.
[32] Liu, Zhuqing, Huang, Fei, Wui, Ping, Wang, Quannan, Yu, Zhengkun. Amide Bond Formation Assisted by Vicinal Alkylthio Migration in Enaminones: Metal- and CO-Free Synthesis of alpha,beta-Unsaturated Amides. JOURNAL OF ORGANIC CHEMISTRY[J]. 2018, 83(10): 5731-5750, https://www.webofscience.com/wos/woscc/full-record/WOS:000432900800039.
[33] Zhengkun Yu. A Simple Aliphatic Diamine Auxiliary for Palladium-Catalyzed Arylation of Unactivated β-C(sp3)-H Bonds. Adv. Synth. Catal.. 2018, [34] Jiang, Quanbin, Guo, Tenglong, Gao, Runli, Wang, Quannan, Lou, Jiang, Yu, Zhengkun. alpha,beta-Unsaturated N-Acylindoles: An Alternative Class of Michael Acceptors and Their Application in Asymmetric Borylation. JOURNAL OF ORGANIC CHEMISTRY[J]. 2018, 83(15): 7981-7993, https://www.webofscience.com/wos/woscc/full-record/WOS:000441112900039.
[35] Wang, Quannan, Liu, Zhuqing, Lou, Jiang, Yu, Zhengkun. Palladium-Catalyzed C-S Bond Cleavage with Allenoates: Synthesis of Tetrasubstituted 2-Alkenylfuran Derivatives. ORGANIC LETTERS[J]. 2018, 20(19): 6007-6011, http://cas-ir.dicp.ac.cn/handle/321008/166902.
[36] Zhengkun Yu. Metal-Free Selective Csp-Csp and Csp-Csp3 Bond Cleavages of N,S-Enynes toward Thiophene-Fused N-Heterocycles. Adv. Synth. Catal.. 2018, [37] Liu, Tingting, Chai, Huining, Wang, Liandi, Yu, Zhengkun. Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones. ORGANOMETALLICS[J]. 2017, 36(15): 2914-2921, http://cas-ir.dicp.ac.cn/handle/321008/149811.
[38] Wang, Quannan, Lou, Jiang, Wu, Ping, Wu, Kaikai, Yu, Zhengkun. Iron-Mediated Oxidative C-H Alkylation of S,S-Functionalized Internal Olefins via C(sp(2))-H/C(sp(3))-H Cross-Coupling. ADVANCED SYNTHESIS & CATALYSIS[J]. 2017, 359(17): 2981-2998, http://cas-ir.dicp.ac.cn/handle/321008/149868.
[39] Chai, Huining, Liu, Tingting, Zheng, Daoyuan, Yu, Zhengkun. Cooperative N-H and CH2 Skeleton Effects on the Catalytic Activities of Bimetallic Ru(II)-NNN Complexes: Experimental and Theoretical Study. ORGANOMETALLICS[J]. 2017, 36(21): 4268-4277, http://cas-ir.dicp.ac.cn/handle/321008/149744.
[40] Wang, Qingfu, Chai, Huining, Yu, Zhengkun. Dimeric Ruthenium(II)-NNN Complex Catalysts Bearing a Pyrazolyl-Pyridylamino-Pyridine Ligand for Transfer Hydrogenation of Ketones and Acceptorless Dehydrogenation of Alcohols. ORGANOMETALLICS[J]. 2017, 36(18): 3638-3644, http://dx.doi.org/10.1021/acs.organomet.7b00587.
[41] Lou, Jiang, Wang, Quannan, Wu, Kaikai, Wu, Ping, Yu, Zhengkun. Iron-Catalyzed Oxidative C-H Functionalization of Internal Olefins for the Synthesis of Tetrasubstituted Furans. ORGANIC LETTERS[J]. 2017, 19(12): 3287-3290, https://www.webofscience.com/wos/woscc/full-record/WOS:000403854300063.
[42] Wang, Quannan, Yang, Xiaoge, Wu, Ping, Yu, Zhengkun. Photoredox-Catalyzed C-H Arylation of Internal Alkenes to Tetrasubstituted Alkenes: Synthesis of Tamoxifen. ORGANIC LETTERS[J]. 2017, 19(22): 6248-6251, http://cas-ir.dicp.ac.cn/handle/321008/168344.
[43] Chai, Huining, Liu, Tingting, Yu, Zhengkun. NHTs Effect on the Enantioselectivity of Ru(II) Complex Catalysts Bearing a Chiral Bis(NHTs)-Substituted Imidazolyl-Oxazolinyl-Pyridine Ligand for Asymmetric Transfer Hydrogenation of Ketones. ORGANOMETALLICS[J]. 2017, 36(21): 4136-4144, http://cas-ir.dicp.ac.cn/handle/321008/149684.
[44] Zhengkun Yu. A Versatile Ru(II)-NNP Complex Catalyst for the Synthesis of Multisubstituted Pyrroles and Pyridines. Organometallics. 2017, [45] Liu, Zhuqing, Huang, Fei, Lou, Jiang, Wang, Quannan, Yu, Zhengkun. Copper-promoted direct C-H alkoxylation of S,S-functionalized internal olefins with alcohols. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2017, 15(26): 5535-5540, https://www.webofscience.com/wos/woscc/full-record/WOS:000405003900012.
[46] Huang, Fei, Liu, Zhuqing, Wang, Quannan, Lou, Jiang, Yu, Zhengkun. Copper-Catalyzed Formal Carbene Migratory Insertion into Internal Olefinic C=C Bonds with N-Tosylhydrazones To Access Iminofuran and 2(3H)-Furanone Derivatives. ORGANIC LETTERS[J]. 2017, 19(13): 3660-3663, https://www.webofscience.com/wos/woscc/full-record/WOS:000405358300083.
[47] Jiang, Quanbin, Guo, Tenglong, Yu, Zhengkun. Copper-Catalyzed Asymmetric Borylation: Construction of a Stereogenic Carbon Center Bearing Both CF3 and Organoboron Functional Groups. JOURNAL OF ORGANIC CHEMISTRY[J]. 2017, 82(4): 1951-1960, http://cas-ir.dicp.ac.cn/handle/321008/169482.
[48] Wu, Ping, Wu, Kaikai, Wang, Liandi, Yu, Zhengkun. Iron-Promoted Difunctionalization of Alkenes by Phenylselenylation/1,2-Aryl Migration. ORGANIC LETTERS[J]. 2017, 19(19): 5450-5453, https://www.webofscience.com/wos/woscc/full-record/WOS:000412789600113.
[49] Chai Huining, Wang Qingfu, Liu Tingting, Yu Zhengkun, Liu Tingting. Diruthenium(II)-NNN pincer complex catalysts for transfer hydrogenation of ketones. DALTON TRANSACTIONS[J]. 2016, 45(44): 17843-17849, http://cas-ir.dicp.ac.cn/handle/321008/169778.
[50] Gao, Yuan, Zhang, Haijun, Zou, Lili, Wu, Ping, Yu, Zhengkun, Lu, Xianbo, Chen, Jiping. Quantification of Short-Chain Chlorinated Paraffins by Deuterodechlorination Combined with Gas Chromatography-Mass Spectrometry. ENVIRONMENTAL SCIENCE & TECHNOLOGY[J]. 2016, 50(7): 3746-3753, http://cas-ir.dicp.ac.cn/handle/321008/170700.
[51] Guo, Tenglong, Jiang, Quanbin, Yu, Zhengkun. Copper-Catalyzed Ring-Expansion/Thiolactonization via Azidation of Internal Olefinic C-H Bond under Mild Conditions. ADVANCED SYNTHESIS & CATALYSIS[J]. 2016, 358(21): 3450-3457, http://cas-ir.dicp.ac.cn/handle/321008/150506.
[52] Zhengkun Yu. C-Alkylation of Ketones and Related Compounds by Alcohols via Transition Metal-Catalyzed Dehydrogenatin. Angew. Chem. Int. Ed.. 2016, [53] Wang, Qingfu, Wu, Kaikai, Yu, Zhengkun. Ruthenium(III)-Catalyzed beta-Alkylation of Secondary Alcohols with Primary Alcohols. ORGANOMETALLICS[J]. 2016, 35(9): 1251-1256, http://cas-ir.dicp.ac.cn/handle/321008/170934.
[54] Zhengkun Yu. Rhodium(III)-Catalyzed sp2 C-H Addition to CF3-Substituted Unsaturated Ketones. Chem. Commun.. 2016, [55] Yang Qin Wang Qingfu Yu Zhengkun. Substitution of alcohols by N-nucleophiles via transition metal-catalyzed dehydrogenation. 2015, 44(8): 2305-2329, [56] Yang Xiaoge, Liu Zhuqing, Sun Chenglin, Chen Jiping, Yu Zhengkun. Palladium-Catalyzed Oxidative Cross-Coupling of α-Cyanoketene Dithioacetals with Olefins. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2015, 21: 14085-, http://cas-ir.dicp.ac.cn/handle/321008/148039.
[57] Wu, Kaikai, Wu, Ping, Chen, Jiping, Sun, Chenglin, Yu, Zhengkun. Bronsted Acid-Promoted Cascade Alkylation/Cyclization of Pyrroles with N,N-Dimethylaminomethyleneglutaconic Acid Dinitrile: A Concise Route to Cyclopentabpyrroles. ADVANCED SYNTHESIS & CATALYSIS[J]. 2015, 357(14-15): 3353-3358, http://cas-ir.dicp.ac.cn/handle/321008/148040.
[58] Chai Huining, Liu Tingting, Wang Qingfu, Yu Zhengkun. Substituent Effect on the Catalytic Activity of Ru(II) Complexes Bearing a Pyridyl-Supported Pyrazolyl-Imidazolyl Ligand for Transfer Hydrogenation of Ketones. ORGANOMETALLICS[J]. 2015, 34: 5278-, http://cas-ir.dicp.ac.cn/handle/321008/148042.
[59] Wu, Ping, Wang, Liandi, Wu, Kaikai, Yu, Zhengkun. Bronsted Acid Catalyzed PhSe Transfer versus Radical Aryl Transfer: Linear Codimerization of Styrenes and Internal Olefins. ORGANIC LETTERS[J]. 2015, 17(4): 868-871, http://cas-ir.dicp.ac.cn/handle/321008/148034.
[60] Jiang Quanbin, Guo Tenglong, Yu Zhengkun. Copper-Catalyzed Tandem (Asymmetric) Borylation of β-Chloroalkly Aryl Ketones and Related Compounds. CHEMCATCHEM[J]. 2015, 7: 660-, http://cas-ir.dicp.ac.cn/handle/321008/148032.
[61] Geng, Ningbo, Zhang, Haijun, Zhang, Baoqin, Wu, Ping, Wang, Feidi, Yu, Zhengkun, Chen, Jiping. Effects of Short-Chain Chlorinated Paraffins Exposure on the Viability and Metabolism of Human Hepatoma HepG2 Cells. ENVIRONMENTAL SCIENCE & TECHNOLOGY[J]. 2015, 49(5): 3076-3083, http://cas-ir.dicp.ac.cn/handle/321008/146080.
[62] Yang Xiaoge, Wu Kaikai, Wu Ping, Chen Jiping, Sun Chenglin, Yu Zhengkun. Bronsted Acid-Mediated Annulation of α-Oxo Ketene Dithio-acetals to Pyrroles: Efficient Synthesis of Structurally Diverse Cyclopentabpyrroles. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2015, 21: 9323-, http://cas-ir.dicp.ac.cn/handle/321008/148037.
[63] 郭腾龙, 姜权彬, 余正坤. Palladium-Catalyzed Oxidative Annulation of in-situ Generated Enones to Pyrroles: A Concise Route to Functionalized Indoles. ORGANIC CHEMISTRY FRONTIERS有机化学前沿[J]. 2015, 2: 1361-, http://cas-ir.dicp.ac.cn/handle/321008/148041.
[64] Huang, Fei, Wu, Ping, Wang, Liandi, Chen, Jiping, Sun, Chenglin, Yu, Zhengkun. Copper-Mediated Intramolecular Oxidative C-H/C-H Cross-Coupling of alpha-Oxo Ketene N,S-Acetals for Indole Synthesis. JOURNAL OF ORGANIC CHEMISTRY[J]. 2014, 79(21): 10553-10560, http://cas-ir.dicp.ac.cn/handle/321008/145747.
[65] Guo, Tenglong, Jiang, Quanbin, Huang, Fei, Chen, Jiping, Yu, Zhengkun. Palladium-catalyzed, copper-mediated construction of benzene rings from the reactions of indoles with in situ generated enones. ORGANIC CHEMISTRY FRONTIERS[J]. 2014, 1(6): 707-711, https://www.webofscience.com/wos/woscc/full-record/WOS:000364427300018.
[66] Yang, Qin, Xu, Tongyu, Yu, Zhengkun. Iron-Mediated Carboarylation/Cyclization of Propargylanilines with Acetals: A Concise Route to Indeno2,1-cquinolines. ORGANIC LETTERS[J]. 2014, 16(24): 6310-6313, http://cas-ir.dicp.ac.cn/handle/321008/145758.
[67] Du, Wangming, Wang, Qingfu, Wang, Liandi, Yu, Zhengkun. Ruthenium Complex Catalysts Supported by a Bis(trifluoromethyl)pyrazolyl-Pyridyl-Based NNN Ligand for Transfer Hydrogenation of Ketones. ORGANOMETALLICS[J]. 2014, 33(4): 974-982, http://cas-ir.dicp.ac.cn/handle/321008/144202.
[68] Yang, Qin, Wu, Ping, Chen, Jiping, Yu, Zhengkun. Iron-catalyzed alkylation of alpha-oxo ketene dithioacetals. CHEMICAL COMMUNICATIONS[J]. 2014, 50(48): 6337-6339, http://cas-ir.dicp.ac.cn/handle/321008/145807.
[69] Jin, Weiwei, Yang, Qin, Wu, Ping, Chen, Jiping, Yu, Zhengkun. Palladium-Catalyzed Oxidative Heck-Type Allylation of beta,beta-Disubstituted Enones with Allyl Carbonates. ADVANCED SYNTHESIS & CATALYSIS[J]. 2014, 356(9): 2097-2102, http://cas-ir.dicp.ac.cn/handle/321008/145763.
[70] Huang, Fei, Wu, Ping, Wang, Liandi, Chen, Jiping, Sun, Chenglin, Yu, Zhengkun. Copper-mediated intramolecular oxidative C-H/N-H cross-coupling of alpha-alkenoyl ketene N,S-acetals to synthesize pyrrolone derivatives. CHEMICAL COMMUNICATIONS[J]. 2014, 50(83): 12479-12481, http://cas-ir.dicp.ac.cn/handle/321008/145737.
[71] Mao, Zhifeng, Huang, Fei, Yu, Haifeng, Chen, Jiping, Yu, Zhengkun, Xu, Zhaoqing. Copper-Catalyzed Trifluoromethylation of Internal Olefinic C-H Bonds: Efficient Routes to Trifluoromethylated Tetrasubstituted Olefins and N-Heterocycles. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2014, 20(12): 3439-3445, http://cas-ir.dicp.ac.cn/handle/321008/144092.
[72] Du, Wangming, Wu, Ping, Wang, Qingfu, Yu, Zhengkun. Ruthenium(II) Complex Catalysts Bearing a Pyridyl-Based Benzimidazolyl-Benzotriazolyl Ligand for Transfer Hydrogenation of Ketones. ORGANOMETALLICS[J]. 2013, 32(10): 3083-3090, http://www.irgrid.ac.cn/handle/1471x/858738.
[73] Jiang, Quanbin, Guo, Tenglong, Wang, Qingfu, Wu, Ping, Yu, Zhengkun. Rhodium(I)-Catalyzed Arylation of beta-Chloro Ketones and Related Derivatives through Domino Dehydrochlorination/Conjugate Addition. ADVANCED SYNTHESIS & CATALYSIS[J]. 2013, 355(9): 1874-1880, http://159.226.238.44/handle/321008/137484.
[74] Wang, Liandi, He, Wei, Yu, Zhengkun. Transition-metal mediated carbon-sulfur bond activation and transformations. CHEMICAL SOCIETY REVIEWS[J]. 2013, 42(2): 599-621, http://159.226.238.44/handle/321008/137790.
[75] Jin, Weiwei, Wang, Liandi, Yu, Zhengkun. A Highly Active Ruthenium(II) Pyrazolyl-Pyridyl-Pyrazole Complex Catalyst for Transfer Hydrogenation of Ketones. ORGANOMETALLICS[J]. 2012, 31(15): 5664-5667, http://159.226.238.44/handle/321008/143126.
[76] Zhengkun Yu. Bronsted Acid Activation Strategy in Transition Metal-Catalyzed Asymmetric Hydrogenation of Unprotected N-H Imines, Enamines and N-Heteroaromatics. Angew. Chem. Int. Ed.. 2012, [77] Zhengkun Yu. FeCl3.6H2O-Catalyzed Alkenylation of Indoles with Aldehydes. J. Org. Chem.. 2012, [78] Dai, Chao, Xu, Zhaoqing, Huang, Fei, Yu, Zhengkun, Gao, YanFeng. Lewis Acid-Catalyzed, Copper(II)-Mediated Synthesis of Heteroaryl Thioethers under Base-Free Conditions. JOURNAL OF ORGANIC CHEMISTRY[J]. 2012, 77(9): 4414-4419, http://www.irgrid.ac.cn/handle/1471x/721836.
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[82] Luo, Ning, Zheng, Zhaoyan, Yu, Zhengkun. Highly Regioselective 3+2 Annulation of Azomethine Imines with 1-Alkynyl Fischer Carbene Complexes to Functionalized N,N-Bicyclic Pyrazolidin-3-ones. ORGANIC LETTERS[J]. 2011, 13(13): 3384-3387, http://www.irgrid.ac.cn/handle/1471x/456930.
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[86] Wu, Xiaowei, Yu, Zhengkun. Metal and phosgene-free synthesis of 1H-quinazoline-2,4-diones by selenium-catalyzed carbonylation of o-nitrobenzamides. TETRAHEDRON LETTERS[J]. 2010, 51(11): 1500-1503, http://dx.doi.org/10.1016/j.tetlet.2010.01.040.
[87] Zhengkun Yu. RuCl3.xH2O-Catalyzed Direct Arylation of Arenes with Aryl Chlorides in the Presence of Triphenylphosphine.. 2010, [88] Zhengkun Yu. Palladium-Catalyzed Direct Cross-Coupling of Internal Alkenes with Terminal Alkenes to Functionalized 1,3-Butadienes via C-H Bond Activation: Efficient Synthesis of Bicyclic Pyridones.. 2010, [89] Xu, Tongyu, Yang, Qin, Li, Dongpo, Dong, Jinhua, Yu, Zhengkun, Li, Yuxue. Iron(III)-Catalyzed Cyclization of Alkynyl Aldehyde Acetals: Experimental and Computational Studies. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2010, 16(30): 9264-9272, http://159.226.238.44/handle/321008/142134.
[90] Ye, Wenjing, Luo, Ning, Yu, Zhengkun. Rhodium-Catalyzed Direct Alkenylation and Arylation of Arene C-H Bonds via Decarbonylation of Cinnamoyl Chlorides, Cinnamic Anhydrides, and Poly(aroyl) Chlorides. ORGANOMETALLICS[J]. 2010, 29(4): 1049-1052, http://159.226.238.44/handle/321008/142253.
[91] Luo, Ning, Yu, Zhengkun. Multiple reactivities of dithranol towards 1-alkynyl Fischer carbene complexes (CO)(5)M=C(OEt)C CPh (M = Cr, W) - Efficient chemical synthesis of aromatic polyketides. JOURNAL OF ORGANOMETALLIC CHEMISTRY[J]. 2009, 694(19): 3058-3067, http://159.226.238.44/handle/321008/102295.
[92] Zhengkun Yu. Direct Alkenylation of Indoles through Acid-mediated Substitution Reactions with alpha-Oxo Ketene Dithioacetals: Efficient Synthesis of Indole Alkaloids Meridianin Derivatives.. 2009, [93] Zhao, Miao, Yu, Zhengkun, Yan, Shenggang, Li, Yang. Ruthenium(II) complex catalysts bearing a pyridyl-supported pyrazolyl-imine ligand for transfer hydrogenation of ketones. JOURNAL OF ORGANOMETALLIC CHEMISTRY[J]. 2009, 694(19): 3068-3075, http://dx.doi.org/10.1016/j.jorganchem.2009.05.028.
[94] Li, Yu, Yu, Zhengkun. Palladium-Catalyzed Carbonylative Cycloisomerization of gamma-Propynyl-1,3-diketones: A Concise Route to Polysubstituted Furans. JOURNAL OF ORGANIC CHEMISTRY[J]. 2009, 74(22): 8904-8907, http://159.226.238.44/handle/321008/141339.
[95] Zhao, Miao, Yu, Zhengkun, Yan, Shenggang, Li, Yang. Room-temperature Ru(II)-catalyzed transfer hydrogenation of ketones and aldehydes in air. TETRAHEDRON LETTERS[J]. 2009, 50(32): 4624-4628, http://dx.doi.org/10.1016/j.tetlet.2009.05.100.
[96] Tan, Weiqiang, Yu, Zhengkun, Liu, Bing, Wu, Kaikai, Liu, Zishuang, Chen, Jinzhu. Synthesis and structural characterization of (CH2)(n)-bridged indenyl-pyrazoles and their cyclopentadienyl nickel(II) complexes. JOURNAL OF ORGANOMETALLIC CHEMISTRY[J]. 2009, 694(2): 199-206, http://dx.doi.org/10.1016/j.jorganchem.2008.10.021.
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[98] Jin, Weiwei, Yu, Zhengkun, He, Wei, Ye, Wenjing, Xiao, WenJing. Efficient Rh(I)-Catalyzed Direct Arylation and Alkenylation of Arene C-H Bonds via Decarbonylation of Benzoic and Cinnamic Anhydrides. ORGANIC LETTERS[J]. 2009, 11(6): 1317-1320, http://159.226.238.44/handle/321008/102291.
[99] Zeng, Fanlong, Yu, Zhengkun. Construction of Highly Active Ruthenium(II) NNN Complex Catalysts Bearing a Pyridyl-Supported Pyrazolyl-Imidazolyl Ligand for Transfer Hydrogenation of Ketones. ORGANOMETALLICS[J]. 2009, 28(6): 1855-1862, http://159.226.238.44/handle/321008/102305.
[100] Ceng Fanlong, Yu Zhengkun. Ruthenium(II) Complexes Bearing a Pyridyl-Supported Pyrazolyl-N-Heterocyclic Carbene (NNC) Ligand and Their Catalytic Activity in Transfer Hydrogenation of Ketones. ORGANOMETALLICS[J]. 2008, 27(22): 6025-6028, http://159.226.238.44/handle/321008/100941.
[101] Tan, Weiqiang, Yu, Zhengkun, He, Wei, Wang, Liandi, Sun, Jie, Chen, Jinzhu. A toluene guest in a poly(heteronuclear) complex host of ferrocenyl-(CH2)(2)-bridged bis(pyrazole). ORGANOMETALLICS[J]. 2008, 27(19): 4833-4836, http://159.226.238.44/handle/321008/100943.
[102] Zhao, Xiaodan, Yu, Zhengkun. Rhodium-catalyzed regioselective C-H functionalization via decarbonylation of acid chlorides and C-H bond activation under phosphine-free conditions. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2008, 130(26): 8136-+, http://159.226.238.44/handle/321008/140813.
[103] Zeng, Fanlong, Yu, Zhengkun. Exceptionally efficient unsymmetrical ruthenium(II) NNN complex catalysts bearing a pyridyl-based pyrazolyl-imidazolyl ligand for transfer hydrogenation of ketones. ORGANOMETALLICS[J]. 2008, 27(13): 2898-2901, http://159.226.238.44/handle/321008/101161.
[104] Li, Yu, Yu, Zhengkun, Wu, Sizhong. Efficient copper(II)-catalyzed addition of activated methylene compounds to alkenes. JOURNAL OF ORGANIC CHEMISTRY[J]. 2008, 73(14): 5647-5650, http://159.226.238.44/handle/321008/100937.

科研活动

科技部973项目 （参与）

科技部863重点项目 （主持）

国家自然科学基金 （主持）

科技部重大专项 （参与）
 
中国科学院领域前沿项目 （主持）
 
国内企业合作项目 （主持） 

辽宁省自然科学基金 （主持）
 
国家重点实验室开放课题基金 （主持）

科研项目
（ 1 ） 惰性碳-杂原子键的激活与重组（973项目）, 参与, 国家级, 2009-01--2013-08
（ 2 ） 低短链氯化石蜡含量的中长链氯化石蜡工业生产技术（863重点项目）, 主持, 国家级, 2010-07--2012-12
（ 3 ） 惰性化学键的活化与转化, 主持, 部委级, 2010-01--2011-11
（ 4 ） 短链氯化石蜡(SCCPs)标样制备（国家科技重大专项）, 主持, 国家级, 2009-08--2011-12
（ 5 ） 过渡金属配合物催化剂（国家自然科学基金）, 主持, 国家级, 2010-01--2012-12
（ 6 ） 有机仲胺和叔胺绿色合成方法研究, 主持, 研究所（学校）, 2010-12--2011-11
（ 7 ） 基于alpha-羰基二硫缩烯酮的抗癌药物合成研究(省自然科学基金), 主持, 省级, 2011-01--2012-12
（ 8 ） 过渡金属催化的经由非活化氯代烷烃sp3 C-Cl键断裂的Domino反应研究, 主持, 国家级, 2013-01--2016-12
（ 9 ） 过渡金属催化的经由内烯烃烯基碳-氢键活化的多取代氮杂环化合物合成, 主持, 国家级, 2015-01--2018-12
（ 10 ） 过渡金属双金属配合物催化剂研究, 主持, 国家级, 2017-01--2020-12
（ 11 ） 以煤制油副产重蜡为原料的氯化石蜡生产技术, 主持, 院级, 2016-09--2018-12
（ 12 ） 含烯（炔）惰性体系的高效转化, 主持, 国家级, 2015-01--2019-07
（ 13 ） ACISS化合物平台研制, 参与, 研究所（学校）, 2015-05--2017-12
（ 14 ） N,S-官能化烯烃的多反应性研究, 主持, 国家级, 2019-01--2022-12

指导学生


已指导学生 

孙小娇 硕士研究生 070303-有机化学（2005年毕业）
 
邓海霞 硕士研究生 070303-有机化学（2005年毕业） 

郑兆艳 博士研究生 070303-有机化学（2006年毕业）

赵晓丹 博士研究生 070303-有机化学（2007年毕业）

谭伟强 博士研究生 070303-有机化学（2008年毕业） 

曾凡龙 博士研究生 070303-有机化学（2008年毕业）
 
李雨 博士研究生 070303-有机化学（2009年毕业）

赵 秒博士研究生 070303-有机化学（2009年毕业）

徐同玉 博士研究生 070303-有机化学（2010年毕业）

罗 宁 博士研究生 070303-有机化学（2010年毕业）

吴小伟 博士后 070303-有机化学（2005年出站） 

王红梅 高级访问学者 070303-有机化学（2006年） 

于海峰 博士后 070303-有机化学（2010年出站） 


现指导学生

叶文静 博士研究生 070303-有机化学

金伟伟 博士研究生 070303-有机化学

杜旺明 博士研究生 070303-有机化学

杨琴 博士研究生 070303-有机化学

姜权彬 博士研究生 070303-有机化学
 
赫 巍 硕士研究生 070303-有机化学（在职研究生）
 
王连弟 硕士研究生 070303-有机化学（在职研究生）