基本信息
胡金波 男 博导 中国科学院上海有机化学研究所
电子邮件: jinbohu@mail.sioc.ac.cn
通信地址: 上海市徐汇区零陵路345号
邮政编码: 200032
电子邮件: jinbohu@mail.sioc.ac.cn
通信地址: 上海市徐汇区零陵路345号
邮政编码: 200032
研究领域
有机氟化学研究,包括:(1)有机氟化学新试剂、新反应;(2)含氟分子制备和相互转化过程中的科学本质研究;(3)含氟功能材料的合成。
招生信息
每年招收硕博连读研究生2名,或招收硕士考博士研究生1名。
招生专业
070303-有机化学
招生方向
有机氟化学
教育背景
学历
-- 研究生
学位
-- 博士
出版信息
发表论文
[1] Artem G. Savchenko, Mikhail O. Zubkov, Vladimir A. Kokorekin, jinbo hu, Dilman Alexander. Sulfones Bearing Perfluorinated Pyridine Group: Synthesis and Photocatalytic Reaction with α-(Trifluoromethyl)styrenes. ChemCatChem[J]. 2023, 第 4 作者15: e202300505, [2] Huanhuan Song, Weihao Li, Xiaoying Wang, Kaiteng Wang, Jingwen Li, Shuai Liu, Pin Gao, Xin-Hua Duan, 胡金波, 胡明友. Pentacoordinate Phosphoranes as Versatile Reagents in Fluoroalkylation Reactions. CCS Chemistry[J]. 2023, 第 9 作者[3] Xiu Wang, 胡金波. Sulfur-based organofluorine reagents for selective fluorination, fluoroalkylation, and fluoroolefination reactions Xiu Wang &Jinbo HuORCID Icon. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS[J]. 2023, 第 2 作者 通讯作者 [4] 陈定奔, 高翔, 宋绍睿, 寇敏, 倪传法, 胡金波. (二氟甲基)三甲基硅烷试剂参与的二氟甲基化反应. 中国科学:化学[J]. 2023, 第 6 作者 通讯作者 53(3): 375-387, http://lib.cqvip.com/Qikan/Article/Detail?id=7109220327.[5] Liu, An, Sun, Shuo, Xie, Qiqiang, Huang, Rumin, Kong, Taige, Ni, Chuanfa, Hu, Jinbo. From intramolecular cyclization to intermolecular hydrolysis: TMSCF 2 Br-enabled carbonylation of aldehydes/ketones and amines to α-hydroxyamides. ORGANIC CHEMISTRY FRONTIERS[J]. 2023, 第 7 作者 通讯作者 10(21): 5343-5351, http://dx.doi.org/10.1039/d3qo00665d.[6] Wei Du, 罗沁钰, Zhiqiang Wei, Xiu Wang, chuanfa ni, 胡金波. Switching from 2-Pyridination to Difluoromethylation: Ligand-Enabled Nickel-Catalyzed Reductive Difluoromethylation of Aryl Iodides with Difluoromethyl 2-Pyridyl Sulfone. 中国科学:化学(英文版)[J]. 2023, 第 6 作者 通讯作者 66(10): 2785-2790, [7] Zhengzhao Lou, hu jingyu, chuanfa ni, Xiu Wang, 胡金波. Unusual single electron transfer reactions between alkenes and iodine electrophiles. Chinese Journal of Chemistry[J]. 2023, 第 5 作者 通讯作者 42: 471-477, [8] Liu, An, Ni, Chuanfa, Xie, Qiqiang, Hu, Jinbo. Transition-Metal-Free Controllable Single and Double Difluoromethylene Formal Insertions into C-H Bonds of Aldehydes with TMSCF2Br. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2023, 第 4 作者 通讯作者 [9] Wei, Zhiqiang, Zheng, Weiqin, Wan, Xiaolong, Hu, Jinbo. Copper-Catalyzed Enantioselective Difluoromethylation-Alkynylation of Olefins by Solving the Dilemma between Acidities and Reduction Potentials of Difluoromethylating Agents. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2023, 第 4 作者 通讯作者 62(37): http://dx.doi.org/10.1002/anie.202308816.[10] 倪传法, 胡金波. 消旋炔丙基磺酸酯的对映选择性三氟甲氧基化反应. 有机化学[J]. 2023, 第 2 作者 通讯作者 43: 2582-2583, [11] Guo, Junkai, Wang, Xiu, Ni, Chuanfa, Wan, Xiaolong, Hu, Jinbo. SulfoxFluor-enabled deoxyazidation of alcohols with NaN3. NATURE COMMUNICATIONS[J]. 2022, 第 5 作者 通讯作者 13(1): http://dx.doi.org/10.1038/s41467-022-30132-x.[12] Wang, Xiu, Pan, Shitao, Luo, Qinyu, Wang, Qian, Ni, Chuanfa, Hu, Jinbo. Controllable Single and Double Difluoromethylene Insertions into C-Cu Bonds: Copper-Mediated Tetrafluoroethylation and Hexafluoropropylation of Aryl Iodides with TMSCF2H and TMSCF2Br. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2022, 第 6 作者 通讯作者 144(27): 12202-12211, http://dx.doi.org/10.1021/jacs.2c0310412202J.[13] Wei, Zhiqiang, Lou, Zhengzhao, Ni, Chuanfa, Zhang, Wei, Hu, Jinbo. Visible-light-promoted S-trifluoromethylation of thiophenols with trifluoromethyl phenyl sulfone. CHEMICAL COMMUNICATIONS[J]. 2022, 第 5 作者 通讯作者 58(72): 10024-10027, http://dx.doi.org/10.1039/d2cc03921d.[14] Kuang, Cuiwen, Ni, Chuanfa, Gu, Yucheng, Hu, Jinbo. Photoredox-Catalyzed Ring-Opening Addition Reaction between Benzyl Bromides and Cyclic Ethers. SYNTHESIS-STUTTGART[J]. 2022, 第 4 作者 通讯作者 54(5): 1272-1286, http://dx.doi.org/10.1055/a-1671-6856.[15] 胡金波. Dynamic Kinetic Resolution-Enabled Highly Stereoselective Nucleophilic Fluoroalkylation to Access Chiral β-Fluoro Amines. Org. Lett.[J]. 2022, 第 1 作者24(32): 5982-5987, [16] Qinghe Liu, Taige Kong, Chuanfa Ni, Jinbo Hu. Reagent-Controlled Highly Stereoselective Difluoromethylation: Efficient Access to Chiral α-Difluoromethylamines from Ketimines. MOLECULES[J]. 2022, 第 4 作者27: https://doaj.org/article/59e3f1ead10e470497c423dfaaa27dce.[17] Pan, Shitao, Xie, Qiqiang, Wang, Xiu, Wang, Qian, Ni, Chuanfa, Hu, Jinbo. Copper-mediated pentafluoroethylation of organoboronates and terminal alkynes with TMSCF3. CHEMICAL COMMUNICATIONS[J]. 2022, 第 6 作者 通讯作者 58(33): 5156-5159, http://dx.doi.org/10.1039/d2cc00975g.[18] Liu, Renxiang, Zhou, XiaoCong, He, XinYi, Li, YuanQiang, Zheng, Weiqin, Wang, Xiu, Guo, Junkai, Ni, Chuanfa, Hu, Jinbo. Modified and Scalable Synthesis of N-Tosyl-4-Chlorobenzenesulfonimidoyl Fluoride (SulfoxFluor): Direct Imidation of Sulfinyl Chlorides with Chloramine-T Trihydrate. ORGANIC PROCESS RESEARCH & DEVELOPMENT[J]. 2022, 第 9 作者 通讯作者 26(2): 380-386, http://dx.doi.org/10.1021/acs.oprd.1c00431.[19] Luo, Qinyu, Wang, Xiu, Hu, Jinbo. Synthesis of fluoroalkenes via Julia and Julia-Kocienski olefination reactions. TETRAHEDRON[J]. 2022, 第 3 作者 通讯作者 113: http://dx.doi.org/10.1016/j.tet.2022.132694.[20] 胡金波. Palladium-Catalyzed Defluorinative Coupling of Difluoroalkenes and Aryl Boronic Acids for Ketone Synthesis. Angew. Chem.Int. Ed.[J]. 2022, 第 1 作者e202213646: [21] 胡金波. Difluoromethyl 2-Pyridyl Sulfoximine: A Stereoselective Nucleophilic Reagent for Difluoro(aminosulfinyl)methylation and Difluoro(aminosulfonyl)methylation. CCS Chem.[J]. 2022, 第 1 作者 通讯作者 4: 3648-3659, [22] 胡金波. Synthesis of Aryl Perfluorocyclopropyl Ethers via [2 + 1] Cyclopropanation Using TMSCF2Br Reagent. Org. Lett.[J]. 2022, 第 1 作者24: 3589-3593, [23] Meng, Depei, Lyu, Yichong, Ni, Chuanfa, Zhou, Min, Li, Yang, Hu, Jinbo. S-(Trifluoromethyl)Benzothioate (TFBT): A KF-Based Reagent for Nucleophilic Trifluoromethylthiolation. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2022, 第 6 作者 通讯作者 28(13): http://dx.doi.org/10.1002/chem.202104395.[24] Ji Meishan, Zhu Chen. Iron-Catalyzed Fluoroalkylation of Arylborates with Sulfone Reagents: Beyond the Limitation of Reduction Potential. CHINESE JOURNAL OF ORGANIC CHEMISTRY[J]. 2021, 41(7): 2914-2915, http://dx.doi.org/10.6023/cjoc202100049.[25] Wang, Xiu, Ye, Wenchao, Kong, Taige, Wang, Chenlu, Ni, Chuanfa, Hu, Jinbo. Divergent S- and C-Difluoromethylation of 2-Substituted Benzothiazoles. ORGANIC LETTERS[J]. 2021, 第 6 作者 通讯作者 23(21): 8554-8558, http://dx.doi.org/10.1021/acs.orglett.1c03267.[26] 胡金波. Photoredox Catalyzed Ring-Opening Addition Reaction Between Benzyl Bromides and Cyclic Ethers. Synthesis. 2021, 第 1 作者 通讯作者 [27] 胡金波. Nucleophilic Trifluoromethylation of Azinium Salts with Zn(CF3)2•bpy. Tetrahedron. 2021, 第 1 作者 通讯作者 [28] Jia, Rulong, Wang, Xiu, Hu, Jinbo. Recent advance in synthetic applications of difluoromethyl phenyl sulfone and its derivatives. TETRAHEDRON LETTERS. 2021, 第 3 作者 通讯作者 75: http://dx.doi.org/10.1016/j.tetlet.2021.153182.[29] Wang, Xiu, Zhou, Min, Liu, Qinghe, Ni, Chuanfa, Fei, Zhongbo, Li, Wei, Hu, Jinbo. Deoxyfluorination of alcohols with aryl fluorosulfonates. CHEMICALCOMMUNICATIONS[J]. 2021, 第 7 作者 通讯作者 57(66): 8170-8173, http://dx.doi.org/10.1039/d1cc02617h.[30] Rong, Jian, Ni, Chuanfa, Gu, Yucheng, Hu, Jinbo. Synthesis of Enantiopure Benzo Fused Cyclic Sulfoximines Through Stereoselective 3+2 Cycloaddition between N-tert-Butanesulfinyl (2-Pyridyl)sulfonyl-difluoromethyl Ketimines and Arynes. HELVETICA CHIMICA ACTA[J]. 2021, 第 4 作者 通讯作者 104(4): http://dx.doi.org/10.1002/hlca.202100019.[31] Zhang, Rongyi, Li, Qigang, Xie, Qiqiang, Ni, Chuanfa, Hu, Jinbo. Difluorocarbene-Induced Ring-Opening Difluoromethylation-Halogenation of Cyclic (Thio)Ethers with TMSCF2X (X=Br, Cl)**. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2021, 第 5 作者 通讯作者 27(71): 17773-17779, http://dx.doi.org/10.1002/chem.202103428.[32] Chen, Dingben, Fan, Zili, Huang, Ling, Gao, Kaili, Xiao, Pan, Ni, Chuanfa, Hu, Jinbo. TMSCFX2 (X = Cl, Br) as halofluorocarbene sources for the synthesis of halofluorocyclopropanes. CHEMICAL COMMUNICATIONS[J]. 2021, 第 7 作者 通讯作者 57(3): 319-322, https://www.webofscience.com/wos/woscc/full-record/WOS:000607739000025.[33] 胡金波. A Radical Chlorodifluoromethylation Protocol for Late Stage Difluoromethylation and Its Application to An Oncology Candidate. Cell Reports Physical Science. 2021, 第 1 作者 通讯作者 [34] Wang, Qian, Liu, An, Wang, Yan, Ni, Chuanfa, Hu, Jinbo. Copper-Mediated Cross-Coupling of Diazo Compounds with Sulfinates. ORGANIC LETTERS[J]. 2021, 第 5 作者 通讯作者 23(17): 6919-6924, http://dx.doi.org/10.1021/acs.orglett.1c02481.[35] Zhou, Xin, Ni, Chuanfa, Deng, Ling, Hu, Jinbo. Electrochemical reduction of fluoroalkyl sulfones for radical fluoroalkylation of alkenes. CHEMICAL COMMUNICATIONS[J]. 2021, 第 4 作者 通讯作者 57(70): 8750-8753, http://dx.doi.org/10.1039/d1cc03258e.[36] Supranovich, Vyacheslav, I, Volodin, Alexander D, Korlyukov, Alexander A, Hu, Jinbo, Dilman, Alexander D. Reaction of (bromodifluoromethyl)trimethylsilane with HMPA: Structural studies. JOURNAL OF FLUORINE CHEMISTRY[J]. 2021, 第 4 作者250: http://dx.doi.org/10.1016/j.jfluchem.2021.109881.[37] Miao, Wenjun, Ni, Chuanfa, Xiao, Pan, Jia, Rulong, Zhang, Wei, Hu, Jinbo. Nickel-Catalyzed Reductive 2-Pyridination of Aryl Iodides with Difluoromethyl 2-Pyridyl Sulfone. ORGANIC LETTERS[J]. 2021, 第 6 作者 通讯作者 23(3): 711-715, http://dx.doi.org/10.1021/acs.orglett.0c03939.[38] 肖吉昌. Contemporary synthetic strategies in organofluorine chemistry. Nature Reviews, Methods Primers. 2021, [39] Wang, Xiu, Wang, Fei, Huang, Fengfeng, Ni, Chuanfa, Hu, Jinbo. Deoxyfluorination of Carboxylic Acids with CpFluor: Access to Acyl Fluorides and Amides. ORGANIC LETTERS[J]. 2021, 第 5 作者 通讯作者 23(5): 1764-1768, http://dx.doi.org/10.1021/acs.orglett.1c00190.[40] Wang, Qian, Tao, Quan, Dong, Hui, Ni, Chuanfa, Xie, Xiaoming, Hu, Jinbo. Fluorination Triggers Fluoroalkylation: Nucleophilic Perfluoro-tert-butylation with 1,1-Dibromo-2,2-bis(trifluoromethyl)ethylene (DBBF) and CsF. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2021, 第 6 作者 通讯作者 60(52): 27318-27323, http://dx.doi.org/10.1002/anie.202113727.[41] 倪传法, 胡金波. 涉及碳-氟键断裂与重组的氟化重排反应:由炔丙基氟制备官能团化偕二氟烯丙基化合物. 有机化学[J]. 2020, 第 2 作者40(9): 2997-2998, https://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFDAUTO&filename=YJHU202009042&v=MDgyNTBoMVQzcVRyV00xRnJDVVI3cWVadWR1Rnl2blVyelBQQ2ZEZTdHNEhOSE1wbzlCWm9SOGVYMUx1eFlTN0Q=.[42] Liang, Huamin, Liu, Ran, Zhou, Min, Fu, Yue, Ni, Chuanfa, Hu, Jinbo. Difluorocarbene-Triggered Cyclization: Synthesis of (Hetero)arene-Fused 2,2-Difluoro-2,3-dihydrothiophenes. ORGANIC LETTERS[J]. 2020, 第 6 作者 通讯作者 22(17): 7047-7051, https://www.webofscience.com/wos/woscc/full-record/WOS:000569377600068.[43] Zhang, Rongyi, Ni, Chuanfa, Xie, Qiqiang, Hu, Jinbo. Difluoromethylation of alcohols with TMSCF2Br in water: A new insight into the generation and reactions of difluorocarbene in a two-phase system. TETRAHEDRON[J]. 2020, 第 4 作者 通讯作者 76(50): http://dx.doi.org/10.1016/j.tet.2020.131676.[44] 胡金波. From C1 to C3 : Copper-Catalyzed gem-Bis(trifluoromethyl)olefination of a-Diazo Esters with TMSCF3. Angew. Chem. Int. Ed. 2020, 59, 8507 –8511. 2020, 第 1 作者 通讯作者 [45] Wei, Jun, Bao, Kun, Wang, Yuan, Sheng, Rong, Hu, Jinbo. Novel usage of 2-BTSO2CF2H for metal-free electrophilic difluoroalkanethiolation of indoles. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2020, 第 5 作者 通讯作者 18(24): 4556-4559, https://www.webofscience.com/wos/woscc/full-record/WOS:000544927100006.[46] 胡金波. Highly diastereoselective and thermodynamically controlled nucleophilic addition of a-fluoro-a-phenylthio-aphenylsulfonylmethane (FTSM) to aldehydes. Tetrahedron 76 (2020) 130877. 2020, 第 1 作者 通讯作者 [47] Qiqiang Xie, Jinbo Hu. Chen's Reagent: A Versatile Reagent for Trifluoromethylation,Difluoromethylenation, and Difluoroalkylation in Organic Synthesis. 中国化学:英文版[J]. 2020, 第 2 作者38(2): 202-212, http://lib.cqvip.com/Qikan/Article/Detail?id=7101700406.[48] Wenchao Ye, Chuanfa Ni, Jinbo Hu. Stereoselective nucleophilic monofluoromethylation of tert-butanesulfinimines: Dynamic thermodynamic Resolution of racemic α-fluoro carbanions. JOURNAL OF FLUORINE CHEMISTRY. 2020, 第 3 作者231: http://dx.doi.org/10.1016/j.jfluchem.2020.109451.[49] Tang, Yong, Hu, Jinbo. In deep memory of Professor Rolf Huisgen, a great chemist, who passed away on March 26, 2020. CHINESE JOURNAL OF CHEMISTRY. 2020, 第 2 作者 通讯作者 38(5): 529-529, http://lib.cqvip.com/Qikan/Article/Detail?id=7102221656.[50] Zubkov, Mikhail O, Kosobokov, Mikhail D, Levin, Vitalij V, Kokorekin, Vladimir A, Korlyukov, Alexander A, Hu, Jinbo, Dilman, Alexander D. A novel photoredox-active group for the generation of fluorinated radicals from difluorostyrenes. CHEMICAL SCIENCE[J]. 2020, 第 6 作者11(3): 737-741, http://dx.doi.org/10.1039/c9sc04643g.[51] Ni, Chuanfa, Hu, Jinbo. Fluorinative Rearrangement Involving Cleavage and Recombination of Carbon-Fluorine Bond: Synthesis of Functionalized Allylic gem-Difluorides from Propargylic Fluorides. CHINESE JOURNAL OF ORGANIC CHEMISTRY. 2020, 第 2 作者 通讯作者 40(9): 2997-2998, http://dx.doi.org/10.6023/cjoc202000056.[52] Kuang, Cuiwen, Zhou, Xin, Xie, Qiqiang, Ni, Chuanfa, Gu, Yucheng, Hu, Jinbo. Generation of Carbocations under Photoredox Catalysis: Electrophilic Aromatic Substitution with 1-Fluoroalkylbenzyl Bromides. ORGANIC LETTERS[J]. 2020, 第 6 作者 通讯作者 22(21): 8670-8675, http://dx.doi.org/10.1021/acs.orglett.0c03258.[53] Xiao Pan, Ni Chuanfa, Miao Wenjun, Zhou Min, Hu Jingyu, Chen Dingben, Hu Jinbo. Fluoroalkylation of Various Nucleophiles with Fluoroalkyl Sulfones through a Single Electron Transfer Process.. THE JOURNAL OF ORGANIC CHEMISTRY. 2019, 第 7 作者[54] Wei, Jun, Bao, Kun, Qi, Chengcheng, Liu, Yao, Ni, Chuanfa, Sheng, Rong, Hu, Jinbo. Transition-Metal-Free Electrophilic Fluoroalkanesulfinylation of Electron-Rich (Het)Arenes with Fluoroalkyl Heteroaryl Sulfones via C(Het)-S and S=O Bond Cleavage. ADVANCED SYNTHESIS & CATALYSIS[J]. 2019, 第 7 作者 通讯作者 361(24): 5528-5533, https://www.webofscience.com/wos/woscc/full-record/WOS:000494414200001.[55] Guo, Junkai, Kuang, Cuiwen, Rong, Jian, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo. Rapid Deoxyfluorination of Alcohols with N-Tosyl-4-chlorobenzenesulfonimidoyl Fluoride (SulfoxFluor) at Room Temperature. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2019, 第 6 作者 通讯作者 25(30): 7259-7264, https://www.webofscience.com/wos/woscc/full-record/WOS:000469274700003.[56] Xing, Bo, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo. Pentafluoroethylation of Arenediazonium Tetrafluoroborates Using On-Site Generated Tetrafluoroethylene. CHINESE JOURNAL OF CHEMISTRY[J]. 2019, 第 4 作者 通讯作者 37(11): 1131-1136, http://lib.cqvip.com/Qikan/Article/Detail?id=7101064977.[57] 胡金波. Controllable double CF2-insertion into sp2 C–Cu bond using TMSCF3: a facile access to tetrafluoroethylene-bridged structures†. chem. Sci.. 2019, 第 1 作者 通讯作者 [58] Tsui, Gavin Chit, Hu, Jinbo. Organofluorine Chemistry. ASIAN JOURNAL OF ORGANIC CHEMISTRY. 2019, 第 2 作者 通讯作者 8(5): 566-567, https://www.webofscience.com/wos/woscc/full-record/WOS:000472711500001.[59] Wei, Jun, Liang, Huamin, Ni, Chuanfa, Sheng, Rong, Hu, Jinbo. Transition-Metal-Free Desulfinative Cross-Coupling of Heteroaryl Sulfinates with Grignard Reagents. ORGANIC LETTERS[J]. 2019, 第 5 作者 通讯作者 21(4): 937-940, [60] Hu, Jinbo. From C1 to C2: Pentafluoroethylation with Ruppert-Prakash reagent. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2019, 第 1 作者257: [61] 刘俊, 胡金波. 神奇的氟元素. 化学教育(中英文)[J]. 2019, 第 2 作者40(21): 1-3, http://lib.cqvip.com/Qikan/Article/Detail?id=7100347291.[62] Xie, Qiqiang, Zhu, Ziyue, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo. A General Protocol for C-H Difluoromethylation of Carbon Acids with TMSCF2Br. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2019, 第 5 作者 通讯作者 58(19): 6405-6410, [63] Xie, Qiqiang, Zhu, Ziyue, Ni, Chuanfa, Hu, Jinbo. Nucleophilic (Phenylsulfonyl/arylthio)difluoromethylation of Aldehydes with TMSCF2Br: A Three-Component Strategy. ORGANIC LETTERS[J]. 2019, 第 4 作者 通讯作者 21(22): 9138-9141, https://www.webofscience.com/wos/woscc/full-record/WOS:000497259500058.[64] Miao, Wenjun, Zhao, Yanchuan, Ni, Chuanfa, Gao, Bing, Zhang, Wei, Hu, Jinbo. Iron-Catalyzed Difluoromethylation of Arylzincs with Difluoromethyl 2-Pyridyl Sulfone. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2018, 第 6 作者 通讯作者 140(3): 880-883, https://www.webofscience.com/wos/woscc/full-record/WOS:000423496700007.[65] 胡金波, 丁奎岭. 有机氟化学:独特和有用的化学研究前沿. 化学学报[J]. 2018, 第 1 作者76(12): 905-906, http://lib.cqvip.com/Qikan/Article/Detail?id=6100115484.[66] Hu Jinbo, Ding Kuiling. Organofluorine Chemistry: A Unique and Useful Research Frontier of Chemistry. ACTA CHIMICA SINICA. 2018, 第 1 作者 通讯作者 76(12): 905-906, https://www.webofscience.com/wos/woscc/full-record/WOS:000456161700001.[67] 胡金波. Access to 2,2-diaryl-1,1-difluoroethenes via palladium-Catalyzed dehydrosulfonylative cross-coupling of α-[difluoro(phenylsulfonyl)methyl]benzyl tosylates: PhSO2CF2H as a difluoromethylidene equivalent for connecting aromatic aldehydes. Tetrahedron. 2018, 第 1 作者 通讯作者 [68] 胡金波. Trifluoromethyl Benzoate (TFBz): A Versatile Trifluoromethoxylation Reagent. Journal of American Chemical Society. 2018, 第 1 作者 通讯作者 [69] Jingyu Hu, Yide Yang, Zhengzhao Lou, Chuanfa Ni, Jinbo Hu. Fluoro-Hydroxylation of gem-Difluoroalkenes:Synthesis of 18O-labeled α-CF3 Alcohols. 中国化学:英文版[J]. 2018, 第 5 作者36(12): 1202-1208, http://lib.cqvip.com/Qikan/Article/Detail?id=6100154729.[70] Jingyu Hu, Yide Yang, Zhengzhao Lou, Chuanfa Ni, Jinbo Hu. Fluoro-Hydroxylation of gem-Difluoroalkenes:Synthesis of 18O-labeled α-CF3 Alcohols. 中国化学:英文版[J]. 2018, 第 5 作者36(12): 1202-1208, http://lib.cqvip.com/Qikan/Article/Detail?id=6100154729.[71] Xing, Bo, Ni, Chuanfa, Hu, Jinbo. Copper-Mediated Di- and Monofluoromethanesulfonylation of Arenediazonium Tetrafluoroborates: Probing the Fluorine Effect. CHINESE JOURNAL OF CHEMISTRY[J]. 2018, 第 3 作者 通讯作者 36(3): 206-212, http://lib.cqvip.com/Qikan/Article/Detail?id=675013613.[72] Wei, Jun, Gu, Dongyan, Wang, Shengdan, Hu, Jinbo, Dong, Xiaowu, Sheng, Rong. Visible-light-mediated radical arylthiodifluoromethylation of isocyanides with fluorinated 2-pyridyl sulfones. ORGANIC CHEMISTRY FRONTIERS[J]. 2018, 第 4 作者5(17): 2568-2572, https://www.webofscience.com/wos/woscc/full-record/WOS:000443281400008.[73] Xie, Qiqiang, Li, Lingchun, Zhu, Ziyue, Zhang, Rongyi, Ni, Chuanfa, Hu, Jinbo. From C-1 to C-2: TMSCF3 as a Precursor for Pentafluoroethylation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2018, 第 6 作者 通讯作者 57(40): 13211-13215, https://www.webofscience.com/wos/woscc/full-record/WOS:000445445700038.[74] Supranovich, Vyacheslav, I, Levin, Vitalij V, Struchkova, Marina, I, Hu, Jinbo, Dilman, Alexander D. Visible light-mediated difluoroalkylation of electron-deficient alkenes. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY[J]. 2018, 第 4 作者14(1): 1637-1641, https://doaj.org/article/7f006b9e176d4935a47a7736255f8230.[75] Xing, Bo, Ni, Chuanfa, Hu, Jinbo. Hypervalent Iodine(III)-Catalyzed Balz-Schiemann Fluorination under Mild Conditions. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2018, 第 3 作者 通讯作者 57(31): 9896-9900, http://dx.doi.org/10.1002/anie.201802466.[76] Rui Zhang, Chuanfa Ni, Zhengbiao He, Jinbo Hu. Organocatalyzed Decarboxylative Trifluoromethylation of β -Ketoacids. TOPICS IN CATALYSIS,. 2018, 第 4 作者61: [77] Wang, Lingfei, Wei, Jun, Wu, Ranran, Cheng, Gang, Li, Xinjin, Hu, Jinbo, Hu, Yongzhou, Sheng, Rong. The stability and reactivity of tri-, di-, and monofluoromethyl/methoxy/methylthio groups on arenes under acidic and basic conditions. ORGANIC CHEMISTRY FRONTIERS[J]. 2017, 第 6 作者4(2): 214-223, [78] Rong, Jian, Ni, Chuanfa, Hu, Jinbo. Metal-Catalyzed Direct Difluoromethylation Reactions. ASIAN JOURNAL OF ORGANIC CHEMISTRY. 2017, 第 3 作者 通讯作者 6(2): 139-152, http://dx.doi.org/10.1002/ajoc.201600509.[79] Qinghe Liu, Chuanfa Ni, Jinbo Hu. China's flourishing synthetic organofluorine chemistry:innovations in the new millennium. 国家科学评论:英文版[J]. 2017, 第 3 作者4(3): 303-325, http://lib.cqvip.com/Qikan/Article/Detail?id=673005844.[80] Zhao, Yanchuan, Liu, Qinghe, Jiang, Fanzhou, Hu, Jinbo. Stereoselective carbonyl fluoroolefinations with fluorinated sulfone and sulfoximine reagents. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2017, 第 4 作者253: https://www.webofscience.com/wos/woscc/full-record/WOS:000430569101637.[81] 荣健, 倪传法, 王云泽, 匡翠文, 顾玉诚, 胡金波. 可见光促进下氟烷基砜对芳基烯烃的自由基氟烷基化反应. 化学学报[J]. 2017, 第 6 作者105-109, [82] Jiang, Fanzhou, Ni, Chuanfa, Hu, Jinbo. Efficient nucleophilic difluoromethylation of aldehydes with (phenylsulfonyl)difluoromethylzinc and (phenylsulfonyl) difluoromethylcadmium reagents. JOURNALOFFLUORINECHEMISTRY[J]. 2017, 第 3 作者 通讯作者 198: 67-75, http://dx.doi.org/10.1016/j.jfluchem.2016.12.005.[83] Rong Jian, Ni Chuanfa, Wang Yunze, Kuang Cuiwen, Gu Yucheng, Hu Jinbo. Radical Fluoroalkylation of Aryl Alkenes with Fluorinated Sulfones by Visible- Light Photoredox Catalysis. ACTA CHIMICA SINICA[J]. 2017, 第 6 作者 通讯作者 75(1): 105-109, https://www.webofscience.com/wos/woscc/full-record/WOS:000395965800015.[84] Xie, Qiqiang, Ni, Chuanfa, Zhang, Rongyi, Li, Lingchun, Rong, Jian, Hu, Jinbo. Efficient Difluoromethylation of Alcohols Using TMSCF2Br as a Unique and Practical Difluorocarbene Reagent under Mild Conditions. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2017, 第 6 作者 通讯作者 56(12): 3206-3210, https://www.webofscience.com/wos/woscc/full-record/WOS:000397329300012.[85] 胡金波. Stereoselective Carbonyl Olefination with Sulfoximine: Facile Access to Z- and E-Terminal Monofluoroalkenes. Angew. Chem. Int. Ed.. 2017, 第 1 作者 通讯作者 [86] Li, Lingchun, Ni, Chuanfa, Xie, Qiqiang, Hu, Mingyou, Wang, Fei, Hu, Jinbo. TMSCF3 as a Convenient Source of CF2=CF2 for Pentafluoroethylation, (Aryloxy)tetrafluoroethylation, and Tetrafluoroethylation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2017, 第 6 作者 通讯作者 56(33): 9971-9975, https://www.webofscience.com/wos/woscc/full-record/WOS:000406798700062.[87] Rui Zhang, Chuanfa Ni, Zhengbiao He, Jinbo Hu. Decarboxylative fluorination of β-Ketoacids with N-fluorobenzenesulfonimide (NFSI) for the synthesis of α-fluoroketones: Substrate scope and mechanistic investigation. JOURNAL OF FLUORINE CHEMISTRY. 2017, 第 4 作者203: 166-172, http://dx.doi.org/10.1016/j.jfluchem.2017.08.010.[88] Liu, Qinghe, Ni, Chuanfa, Hu, Jinbo. China's flourishing synthetic organofluorine chemistry: innovations in the new millennium. NATIONAL SCIENCE REVIEW[J]. 2017, 第 3 作者 通讯作者 4(3): 303-325, http://lib.cqvip.com/Qikan/Article/Detail?id=673005844.[89] Li Xinjin, Zhao Jingwei, Hu Mingyou, Chen Dingben, Ni Chuanfa, Wang Limin, Hu Jinbo. Copper-mediated aerobic (phenylsulfonyl)difluoromethylation of arylboronic acids with difluoromethyl phenyl sulfone.. CHEMICAL COMMUNICATIONS (CAMBRIDGE, ENGLAND). 2016, 第 7 作者http://kns.cnki.net/KCMS/detail/detail.aspx?QueryID=0&CurRec=1&recid=&FileName=SJPD13D33F5270A9342A807BE2B22F49690D&DbName=SJPD_05&DbCode=SJPD&yx=&pr=&URLID=&bsm=.[90] Zhou Min, Ni Chuanfa, He Zhengbiao, Hu Jinbo. O-Trifluoromethylation of Phenols: Access to Aryl Trifluoromethyl Ethers by O-Carboxydifluoromethylation and Decarboxylative Fluorination.. ORGANIC LETTERS. 2016, 第 4 作者https://www.webofscience.com/wos/woscc/full-record/WOS:000381236300062.[91] He, Zhengbiao, Tan, Ping, Hu, Jinbo. Copper-Catalyzed Trifluoromethylation of Polysubstituted Alkenes Assisted by Decarboxylation. ORGANIC LETTERS[J]. 2016, 第 3 作者 通讯作者 18(1): 72-75, https://www.webofscience.com/wos/woscc/full-record/WOS:000367702400019.[92] Xie Qiqiang, Li Xinjin, Ni Chuanfa, Hu Jinbo, Hu Mingyou. Copper-Mediated Deuterotrifluoromethylation of α-Diazo Esters. 中国化学:英文版[J]. 2016, 第 4 作者469-472, http://lib.cqvip.com/Qikan/Article/Detail?id=669128212.[93] Zeng, Yuwen, Hu, Jinbo. Bridging Fluorine and Aryne Chemistry: Vicinal Difunctionalization of Arynes Involving Nucleophilic Fluorination, Trifluoromethylation, or Trifluoromethylthiolation. SYNTHESIS-STUTTGART. 2016, 第 2 作者 通讯作者 48(14): 2137-2150, https://www.webofscience.com/wos/woscc/full-record/WOS:000380251800004.[94] 胡金波. The Unique Fluorine Effects in Organic Chemistry: Recent Facts and Insights into Fluoroalkylations. Chem. Soc. Rev.. 2016, 第 1 作者 通讯作者 [95] Dr. Dingben Chen, Dr. Chuanfa Ni, Dr. Yanchuan Zhao, Xian Cai, Xinjin Li, Pan Xiao, Prof. Dr. Jinbo Hu. Bis(difluoromethyl)trimethylsilicate Anion: A Key Intermediate in Nucleophilic Difluoromethylation of Enolizable Ketones with Me3SiCF2H. ANGEWANDTE CHEMIE. 2016, [96] Jian Rong, Ling Deng, Ping Tan, Dr. Chuanfa Ni, Dr. Yucheng Gu, Prof. Dr. Jinbo Hu. Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible‐Light Photoredox Catalysis. ANGEWANDTE CHEMIE. 2016, [97] 胡金波. Copper-Catalyzed Trifluoromethylation of Polysubstituted Alkenes Assisted by Decarboxylation. Org. Lett.. 2016, 第 1 作者 通讯作者 [98] Yuwen Zeng, Jinbo Hu. Bridging Fluorine and Aryne Chemistry: Vicinal Difunctionalization of Arynes Involving Nucleophilic Fluorination, Trifluoromethylation, or Trifluoromethylthiolation. SYNTHESIS (STUTTG). 2016, 第 2 作者48(14): http://kns.cnki.net/KCMS/detail/detail.aspx?QueryID=0&CurRec=2&recid=&FileName=SJGT672759A12A2AE1D079B2802E31A2227D&DbName=WWMERGEJ03&DbCode=WWME&yx=&pr=&URLID=&bsm=.[99] Lingchun Li, Chuanfa Ni, Fei Wang, Jinbo Hu. Deoxyfluorination of alcohols with 3,3-difluoro-1,2-diarylcyclopropenes. NATURE COMMUNICATIONS[J]. 2016, 第 4 作者 通讯作者 7: https://doaj.org/article/a543bfff6b39429489f2280db98b4d64.[100] Rong, Jian, Deng, Ling, Tan, Ping, Ni, Chuanfa, Gu, Yucheng, Hu, Jinbo. Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible-Light Photoredox Catalysis. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2016, 第 6 作者 通讯作者 55(8): 2743-2747, https://www.webofscience.com/wos/woscc/full-record/WOS:000370655700018.[101] Miao, Wenjun, Ni, Chuanfa, Zhao, Yanchuan, Hu, Jinbo. Nucleophilic Iododifluoromethylation of Carbonyl Compounds Using Difluoromethyl 2-Pyridyl Sulfone. ORGANIC LETTERS[J]. 2016, 第 4 作者 通讯作者 18(11): 2766-2769, https://www.webofscience.com/wos/woscc/full-record/WOS:000377319000063.[102] Mingyou Hu, Qiqiang Xie, Xinjin Li, Chuanfa Ni, Jinbo Hu. Copper-Mediated Deuterotrifluoromethylation of α-Diazo Esters. 中国化学:英文版[J]. 2016, 第 5 作者469-472, http://lib.cqvip.com/Qikan/Article/Detail?id=669128212.[103] Chen, Dingben, Ni, Chuanfa, Zhao, Yanchuan, Cai, Xian, Li, Xinjin, Xiao, Pan, Hu, Jinbo. Bis(difluoromethyl)trimethylsilicate Anion: A Key Intermediate in Nucleophilic Difluoromethylation of Enolizable Ketones with Me3SiCF2H. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2016, 第 7 作者 通讯作者 55(41): 12632-12636, [104] Ni, Chuanfa, Hu, Jinbo. The unique fluorine effects in organic reactions: recent facts and insights into fluoroalkylations. CHEMICAL SOCIETY REVIEWS. 2016, 第 2 作者 通讯作者 45(20): 5441-5454, https://www.webofscience.com/wos/woscc/full-record/WOS:000385181300001.[105] 胡金波. Silver-Mediated Trifluoromethylthiolation−Iodination of Arynes. Org. Lett.. 2016, 第 1 作者 通讯作者 [106] Hu, Mingyou, Xie, Qiqiang, Li, Xinjin, Ni, Chuanfa, Hu, Jinbo. Copper-Mediated Deuterotrifluoromethylation of alpha-Diazo Esters. CHINESE JOURNAL OF CHEMISTRY[J]. 2016, 第 5 作者 通讯作者 34(5): 469-472, https://www.webofscience.com/wos/woscc/full-record/WOS:000379678600006.[107] Zeng, Yuwen, Hu, Jinbo. Bridging Fluorine and Aryne Chemistry: Vicinal Difunctionalization of Arynes Involving Nucleophilic Fluorination, Trifluoromethylation, or Trifluoromethylthiolation. SYNTHESIS-STUTTGART. 2016, 第 2 作者 通讯作者 48(14): 2137-2150, https://www.webofscience.com/wos/woscc/full-record/WOS:000380251800004.[108] Li, Xinjin, Zhao, Jingwei, Wang, Yunze, Rong, Jian, Hu, Mingyou, Chen, Dingben, Xiao, Pan, Ni, Chuanfa, Wang, Limin, Hu, Jinbo. Copper-Mediated Aromatic 1,1-Difluoroethylation with (1,1-Difluoroethyl)trimethylsilane (TMSCF2CH3). CHEMISTRY-AN ASIAN JOURNAL[J]. 2016, 第 10 作者 通讯作者 11(12): 1789-1792, https://www.webofscience.com/wos/woscc/full-record/WOS:000379519400007.[109] Shen, Xiao, Liu, Qinghe, Zhang, Wei, Hu, Jinbo. Stereoselective Synthesis of (Sulfonimidoyl)cyclopropanes with (R)-PhSO(NTs)CH2Cl and ,-Unsaturated Weinreb Amides: Tuning the of Selectivity between C-Cl and C-S Bond Cleavage. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY[J]. 2016, 第 4 作者 通讯作者 2016(5): 906-909, http://dx.doi.org/10.1002/ejoc.201501611.[110] Zeng, Yuwen, Ni, Chuanfa, Hu, Jinbo. Recent Advances in the One-Step Synthesis of Distally Fluorinated Ketones. CHEMISTRY-A EUROPEAN JOURNAL. 2016, 第 3 作者 通讯作者 22(10): 3210-3223, https://www.webofscience.com/wos/woscc/full-record/WOS:000371419200004.[111] Zeng Yuwen Ni Chuanfa Hu Jinbo. Recent Advances in the One-Step Synthesis of Distally Fluorinated Ketones. 2016, 22(10): 3210-3223, [112] Li, Xinjin, Zhao, Jingwei, Hu, Mingyou, Chen, Dingben, Ni, Chuanfa, Wang, Limin, Hu, Jinbo. Copper-mediated aerobic (phenylsulfonyl)difluoromethylation of arylboronic acids with difluoromethyl phenyl sulfone. CHEMICAL COMMUNICATIONS[J]. 2016, 第 7 作者 通讯作者 52(18): 3657-3660, https://www.webofscience.com/wos/woscc/full-record/WOS:000371008500014.[113] Zhou, Min, Ni, Chuanfa, He, Zhengbiao, Hu, Jinbo. O-Trifluoromethylation of Phenols: Access to Aryl Trifluoromethyl Ethers by O-Carboxydifluoromethylation and Decarboxylative Fluorination. ORGANIC LETTERS[J]. 2016, 第 4 作者 通讯作者 18(15): 3754-3757, https://www.webofscience.com/wos/woscc/full-record/WOS:000381236300062.[114] Zeng, Yuwen, Hu, Jinbo. Silver-Mediated Trifluoromethylthiolation-Iodination of Arynes. ORGANIC LETTERS[J]. 2016, 第 2 作者 通讯作者 18(4): 856-859, https://www.webofscience.com/wos/woscc/full-record/WOS:000370768200058.[115] Xiao, Pan, Rong, Jian, Ni, Chuanfa, Guo, Junkai, Li, Xinjin, Chen, Dingben, Hu, Jinbo. Radical (Phenylsulfonyl)difluoromethylation of Isocyanides with PhSO2CF2H under Transition-Metal-Free Conditions. ORGANICLETTERS[J]. 2016, 第 7 作者 通讯作者 18(22): 5912-5915, https://www.webofscience.com/wos/woscc/full-record/WOS:000388428600036.[116] Lingchun Li, Chuanfa Ni, Fei Wang, Junkai Guo, Jinbo Hu. Deoxyfluorination of alcohols with 3,3-difluoro-1,2-diarylcyclopropenes(CpFluors). 2016, 第 5 作者http://kns.cnki.net/KCMS/detail/detail.aspx?QueryID=0&CurRec=6&recid=&FileName=ZGHY201611003122&DbName=CPFDLAST2018&DbCode=CPFD&yx=&pr=&URLID=&bsm=.[117] Gao, Bing, Zhao, Yanchuan, Hu, Jinbo. AgF-Mediated Fluorinative Cross-Coupling of Two Olefins: Facile Access to alpha-CF3 Alkenes and beta-CF3 Ketones. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2015, 第 3 作者 通讯作者 54(2): 638-642, https://www.webofscience.com/wos/woscc/full-record/WOS:000347238800046.[118] He, Zhengbiao, Tan, Ping, Ni, Chuanfa, Hu, Jinbo. Fluoroalkylative Aryl Migration of Conjugated N-Arylsulfonylated Amides Using Easily Accessible Sodium Di- and Monofluoroalkanesulfinates. ORGANIC LETTERS[J]. 2015, 第 4 作者 通讯作者 17(8): 1838-1841, https://www.webofscience.com/wos/woscc/full-record/WOS:000353314800006.[119] Zeng, Yuwen, Li, Guangyu, Hu, Jinbo. Diphenyliodonium-Catalyzed Fluorination of Arynes: Synthesis of ortho-Fluoroiodoarenes. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2015, 第 3 作者 通讯作者 54(37): 10773-10777, [120] Ni, Chuanfa, Jiang, Fanzhou, Zeng, Yuwen, Hu, Jinbo. Chemically oxidative fluorination with fluoride ions. JOURNAL OF FLUORINE CHEMISTRY. 2015, 第 4 作者 通讯作者 179: 3-13, http://dx.doi.org/10.1016/j.jfluchem.2015.06.026.[121] 胡金波. 过渡金属促进的二氟烷基化和一氟烷基化反应研究进展. Acta Chim. Sinica. 2015, 第 1 作者 通讯作者 [122] 胡金波. Recent advances in green fluorine chemistry. Reports in Organic Chemistry. 2015, 第 1 作者 通讯作者 [123] Ni Chuanfa, Zhu Lingui, Hu Jinbo. Advances in Transition-Metal-Mediated Di- and Monofluoroalkylations. ACTA CHIMICA SINICA[J]. 2015, 第 3 作者73(2): 90-115, https://www.webofscience.com/wos/woscc/full-record/WOS:000351421800002.[124] Luo, Tao, Zhang, Rui, Shen, Xiao, Zhang, Wei, Ni, Chuanfa, Hu, Jinbo. Bronsted acid-catalyzed 1,2-fluorine migration with fluoroepoxides. DALTON TRANSACTIONS[J]. 2015, 第 6 作者 通讯作者 44(45): 19636-19641, https://www.webofscience.com/wos/woscc/full-record/WOS:000364912100027.[125] Zhao, Yanchuan, Jiang, Fanzhou, Hu, Jinbo. Spontaneous Resolution of Julia-Kocienski Intermediates Facilitates Phase Separation to Produce Z- and E-Monofluoroalkenes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2015, 第 3 作者 通讯作者 137(15): 5199-5203, https://www.webofscience.com/wos/woscc/full-record/WOS:000353606700054.[126] Gao, Bing, Zhao, Yanchuan, Hu, Jinbo. AgF-mediated fluorinative cross-coupling of two olefins. ABSTRACTSOFPAPERSOFTHEAMERICANCHEMICALSOCIETY. 2015, 第 3 作者249: https://www.webofscience.com/wos/woscc/full-record/WOS:000411186500495.[127] 胡金波. Spontaneous Resolution of Julia-Kocienski Intermediates Facilitates Phase Separation to Produce Z- and E‑Monofluoroalkenes. J. Am. Chem. Soc.. 2015, 第 1 作者 通讯作者 [128] Ni Chuanfa, Zhu Lingui, Hu Jinbo. Advances in Transition-Metal-Mediated Di- and Monofluoroalkylations. ACTA CHIMICA SINICA[J]. 2015, 第 3 作者73(2): 90-115, https://www.webofscience.com/wos/woscc/full-record/WOS:000351421800002.[129] Zhu, Jieming, Ni, Chuanfa, Gao, Bing, Hu, Jinbo. Copper(0)-mediated fluoroalkylation of iodobenzene with 2-bromo-1,1,2,2-tetrafluoroethyl compounds: Investigation on the influence of R substituent on the reactivity of RCF2Cu species. JOURNAL OF FLUORINE CHEMISTRY[J]. 2015, 第 4 作者 通讯作者 171: 139-147, http://dx.doi.org/10.1016/j.jfluchem.2014.08.011.[130] Ni, Chuanfa, Hu, Mingyou, Hu, Jinbo. Good Partnership between Sulfur and Fluorine: Sulfur-Based Fluorination and Fluoroalkylation Reagents for Organic Synthesis. CHEMICAL REVIEWS. 2015, 第 3 作者 通讯作者 115(2): 765-825, https://www.webofscience.com/wos/woscc/full-record/WOS:000348689400008.[131] 胡金波. AgF-Mediated Fluorinative Cross-Coupling of Two Olefins: FacileAccess to a-CF3 Alkenes and b-CF3 Ketones**. Angew. Chem. Int. Ed. 2015, 第 1 作者 通讯作者 [132] Gao, Bing, Zhao, Yanchuan, Hu, Jingyu, Hu, Jinbo. Difluoromethyl 2-pyridyl sulfone: a versatile carbonyl gem-difluoroolefination reagent. ORGANIC CHEMISTRY FRONTIERS[J]. 2015, 第 4 作者2(2): 163-168, https://www.webofscience.com/wos/woscc/full-record/WOS:000364443200013.[133] Li, Xinjin, Zhao, Jingwei, Zhang, Liang, Hu, Mingyou, Wang, Limin, Hu, Jinbo. Copper-Mediated Trifluoromethylation Using Phenyl Trifluoromethyl Sulfoxide. ORGANIC LETTERS[J]. 2015, 第 6 作者17(2): 298-301, https://www.webofscience.com/wos/woscc/full-record/WOS:000348331800033.[134] 胡金波. Chemically oxidative fluorination with fluoride ions. Journal of Fluorine Chemistry. 2015, 第 1 作者 通讯作者 [135] Hu, Mingyou, Ni, Chuanfa, Li, Lingchun, Han, Yongxin, Hu, Jinbo. gem-Difluoroolefination of Diazo Compounds with TMSCF3 or TMSCF2Br: Transition-Metal-Free Cross-Coupling of Two Carbene Precursors. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2015, 第 5 作者 通讯作者 137(45): 14496-14501, https://www.webofscience.com/wos/woscc/full-record/WOS:000365148500037.[136] Li, Shan, Peng, Peng, Wei, Jun, Hu, Yongzhou, Hu, Jinbo, Sheng, Rong. Nucleophilic Difluoroalkylation of Isocyanates with Difluoromethyl 2-Pyridyl Sulfone. ADVANCED SYNTHESIS & CATALYSIS[J]. 2015, 第 5 作者357(16-17): 3429-3434, https://www.webofscience.com/wos/woscc/full-record/WOS:000368342400004.[137] Hu, Jingyu, Gao, Bing, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo. Palladium-Catalyzed Monofluoromethylation of Arylboronic Esters with Fluoromethyl Iodide. 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Stereoselective Nucleophilic Fluoromethylation of Aryl Ketones: Dynamic Kinetic Resolution of Chiral alpha-Fluoro Carbanions. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2014, 第 4 作者 通讯作者 53(3): 775-779, http://dx.doi.org/10.1002/anie.201308484.[150] 沈晓, 刘庆贺, 倪传法, 胡金波. Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF2H: Facile Entry into gem-Difluoroalkenes. CHIN. J. CHEM.[J]. 2014, 第 4 作者32(8): 703-708, http://ir.sioc.ac.cn/handle/331003/38826.[151] Zeng, Yuwen, Hu, Jinbo. Silver-Catalyzed Formal Insertion of Arynes into RfI Bonds. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2014, 第 2 作者 通讯作者 20(23): 6866-6870, https://www.webofscience.com/wos/woscc/full-record/WOS:000337574800007.[152] Luo, Tao, Zhang, Rui, Zhang, Wei, Shen, Xiao, Umemoto, Teruo, Hu, Jinbo. Divergent Rearrangements of Cyclopropyl-Substituted Fluoroepoxides Involving C-F Bond Cleavage and Formation. ORGANIC LETTERS[J]. 2014, 第 6 作者 通讯作者 16(3): 888-891, https://www.webofscience.com/wos/woscc/full-record/WOS:000331163900063.[153] 高兵, 赵延川, 胡明友, 倪传法, 胡金波. Gem-Difluoroolefination of Diaryl Ketones and Enolizable Aldehydes with Difluoromethyl 2-Pyridyl Sulfone: New Insights into the Julia-Kocienski Reaction. CHEM.-EUR. J.[J]. 2014, 第 5 作者20(25): 7803-7810, http://ir.sioc.ac.cn/handle/331003/38821.[154] Hu, Mingyou, Rong, Jian, Miao, Wenjun, Ni, Chuanfa, Han, Yongxin, Hu, Jinbo. Copper-Mediated Trifluoromethylthiolation of alpha-Diazoesters. ORGANIC LETTERS[J]. 2014, 第 6 作者 通讯作者 16(7): 2030-2033, https://www.webofscience.com/wos/woscc/full-record/WOS:000334016600051.[155] 叶文超, 张来俊, 倪传法, 荣健, 胡金波. Stereoselective 3+2 cycloaddition of N-tert-butanesulfinyl imines to arynes facilitated by a removable PhSO2CF2 group: synthesis and transformation of cyclic sulfoximines. CHEM. 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Deoxygenative gem-difluoroolefination of carbonyl compounds with (chlorodifluoromethyl)trimethylsilane and triphenylphosphine. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY[J]. 2014, 第 4 作者 通讯作者 10(1): 344-351, https://doaj.org/article/6634ba7affb24527a054ed8e3049772d.[167] 沈晓, 刘庆贺, 罗涛, 胡金波. Nucleophilic Difluoromethylation of Epoxides with PhSO(NTBS)CF2H by a Preorganization Strategy. CHEM.-EUR. J.[J]. 2014, 第 4 作者20(22): 6795-6800, http://ir.sioc.ac.cn/handle/331003/38819.[168] 胡明友, 荣健, 缪文俊, 倪传法, 韩永新, 胡金波. Copper-Mediated Trifluoromethylthiolation of alpha-Diazoesters. ORGLETT[J]. 2014, 第 6 作者16(7): 2030-2033, http://ir.sioc.ac.cn/handle/331003/38818.[169] Shen, Xiao, Liu, Qinghe, Ni, Chuanfa, Hu, Jinbo. Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF2H: Facile Entry into gem-Difluoroalkenes. 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DIAD-mediated metal-free cross dehydrogenative coupling between tertiary amines and alpha-fluorinated sulfones. NEWJCHEM[J]. 2013, 第 4 作者37(6): 1684-1687, http://www.irgrid.ac.cn/handle/1471x/869979.[182] Zeng, Yuwen, Zhang, Laijun, Zhao, Yanchuan, Ni, Chuanfa, Zhao, Jingwei, Hu, Jinbo. Silver-Mediated Trifluoromethylation-Iodination of Arynes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2013, 第 6 作者 通讯作者 135(8): 2955-2958, http://www.irgrid.ac.cn/handle/1471x/869982.[183] Hu, Mingyou, He, Zhengbiao, Gao, Bing, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo. Copper-Catalyzed gem-Difluoroolefination of Diazo Compounds with TMSCF3 via C-F Bond Cleavage. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2013, 第 6 作者 通讯作者 135(46): 17302-17305, http://www.irgrid.ac.cn/handle/1471x/869978.[184] 何正标, 张锐, 胡明友, 李铃春, 倪传法, 胡金波. Copper-mediated trifluoromethylation of propiolic acids: facile synthesis of alpha-trifluoromethyl ketones. CHEM. 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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2012, 第 3 作者 通讯作者 134(13): 5790-5793, http://www.irgrid.ac.cn/handle/1471x/681803.[196] Shen, Xiao, Zhang, Wei, Ni, Chuanfa, Gu, Yucheng, Hu, Jinbo. Tuning the Reactivity of Difluoromethyl Sulfoximines from Electrophilic to Nucleophilic: Stereoselective Nucleophilic Difluoromethylation of Aryl Ketones. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2012, 第 5 作者 通讯作者 134(41): 16999-17002, http://www.irgrid.ac.cn/handle/1471x/681841.[197] Hu, Mingyou, Wang, Fei, Zhao, Yanchuan, He, Zhengbiao, Zhang, Wei, Hu, Jinbo. Difluoro(phenylchalcogen)methylation of aldehydes, ketones, and imines with S-, Se-, and Te-containing reagents PhXCF2H (X = S, Se, Te). JOURNAL OF FLUORINE CHEMISTRY[J]. 2012, 第 6 作者 通讯作者 135: 45-58, http://dx.doi.org/10.1016/j.jfluchem.2011.08.007.[198] Zhao, Yanchuan, Hu, Jinbo. Palladium-Catalyzed 2,2,2-Trifluoroethylation of Organoboronic Acids and Esters. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2012, 第 2 作者 通讯作者 51(4): 1033-1036, http://www.irgrid.ac.cn/handle/1471x/681830.[199] Zhang, Wei, Zhao, Yanchuan, Ni, Chuanfa, Mathew, Thomas, Hu, Jinbo. Palladium-catalyzed allylation of 2,2,2-thfluoroethyl phenyl sulfone, a potential 2,2,2-trifluoroethyl pronucleophile. TETRAHEDRON LETTERS[J]. 2012, 第 5 作者53(48): 6565-6568, http://www.irgrid.ac.cn/handle/1471x/681848.[200] Zhang, Wei, Ni, Chuanfa, Hu, Jinbo, Horvath, IT. Selective Fluoroalkylation of Organic Compounds by Tackling the "Negative Fluorine Effect". FLUOROUS CHEMISTRY. 2012, 第 11 作者308: 25-44, https://www.webofscience.com/wos/woscc/full-record/WOS:000300911800003.[201] Zhao, Yanchuan, Gao, Bing, Ni, Chuanfa, Hu, Jinbo. Copper-Mediated Fluoroalkylation of Aryl Iodides Enables Facile Access to Diverse Fluorinated Compounds: The Important Role of the (2-Pyridyl)sulfonyl Group. ORGANIC LETTERS[J]. 2012, 第 4 作者 通讯作者 14(23): 6080-6083, http://www.irgrid.ac.cn/handle/1471x/681855.[202] Huang, Weizhou, Ni, Chuanfa, Zhao, Yanchuan, Zhang, Wei, Dilman, Alexander D, Hu, Jinbo. Nucleophilic difluoromethylation of C=N bonds in heterocycles with difluoromethyl silane reagents. TETRAHEDRON[J]. 2012, 第 6 作者 通讯作者 68(26): 5137-5144, http://www.irgrid.ac.cn/handle/1471x/681789.[203] He, Zhengbiao, Luo, Tao, Hu, Mingyou, Cao, Yanjing, Hu, Jinbo. Copper-Catalyzed Di- and Trifluoromethylation of alpha,beta-Unsaturated Carboxylic Acids: A Protocol for Vinylic Fluoroalkylations. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2012, 第 5 作者 通讯作者 51(16): 3944-3947, http://www.irgrid.ac.cn/handle/1471x/681821.[204] Huang, Weizhou, Ni, Chuanfa, Zhao, Yanchuan, Gao, Bing, Hu, Jinbo. Nucleophilic difluoromethylation of N,N-acetals with TMSCF2SO2Ph reagent promoted by trifluoroacetic acid: A facile access to alpha-difluoromethylated tertiary amines. JOURNAL OF FLUORINE CHEMISTRY[J]. 2012, 第 5 作者 通讯作者 143: 161-166, http://www.irgrid.ac.cn/handle/1471x/681851.[205] Kosobokov, Mikhail D, Dilman, Alexander D, Struchkova, Marina I, Belyakov, Pavel A, Hu, Jinbo. Reactions of Sulfur- and Phosphorus-Substituted Fluoroalkylating Silicon Reagents with Imines and Enamines under Acidic Conditions. JOURNAL OF ORGANIC CHEMISTRY[J]. 2012, 第 5 作者77(4): 2080-2086, http://dx.doi.org/10.1021/jo202669w.[206] He, Zhengbiao, Hu, Mingyou, Luo, Tao, Li, Lingchun, Hu, Jinbo. Copper-Catalyzed Difluoromethylation of ss,?-Unsaturated Carboxylic Acids: An Efficient Allylic Difluoromethylation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2012, 第 5 作者 通讯作者 51(46): 11545-11547, https://www.webofscience.com/wos/woscc/full-record/WOS:000310875700024.[207] Shen, Xiao, Zhang, Wei, Zhang, Lei, Luo, Tao, Wan, Xiaolong, Gu, Yucheng, Hu, Jinbo. Enantioselective Synthesis of Cyclopropanes That Contain Fluorinated Tertiary Stereogenic Carbon Centers: A Chiral a-Fluoro Carbanion Strategy. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2012, 第 7 作者 通讯作者 51(28): 6966-6970, http://dx.doi.org/10.1002/anie.201202451.[208] Hu, Mingyou, Ni, Chuanfa, Hu, Jinbo. Copper-Mediated Trifluoromethylation of alpha-Diazo Esters with TMSCF3: The Important Role of Water as a Promoter. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2012, 第 3 作者 通讯作者 134(37): 15257-15260, http://www.irgrid.ac.cn/handle/1471x/681839.[209] Shen, Xiao, Ni, Chuanfa, Hu, Jinbo. Nucleophilic Fluoroalkylation of alpha,beta-Unsaturated Carbonyl Compounds with alpha-Fluorinated Sulfones: Investigation of the Reversibility of 1,2-Additions and the Formation of 1,4-Adducts. HELVETICA CHIMICA ACTA[J]. 2012, 第 3 作者 通讯作者 95(10): 2043-2051, http://dx.doi.org/10.1002/hlca.201200445.[210] 赵延川, 黄维洲, 郑吉, 胡金波. Efficient and Direct Nucleophilic Difluoromethylation of Carbonyl Compounds and Imines with Me(3)SiCF(2)H at Ambient or Low Temperature. ORG. LETT.[J]. 2011, 第 4 作者13(19): 5342-5345, http://ir.sioc.ac.cn/handle/331003/24099.[211] 王飞, 黄维洲, 胡金波. Difluoromethylation of O-, S-, N-, C-Nucleophiles Using Difluoromethyltri(n-butyl)ammonium Chloride as a New Difluorocarbene Source. 中国化学:英文版[J]. 2011, 第 3 作者29(12): 2717-2721, http://lib.cqvip.com/Qikan/Article/Detail?id=40185183.[212] 赵延川, 张丽君, 许国峰, 郑吉, 胡金波. 以二氟烷基磺酸修饰的聚降冰片烯为基础的聚合物电解质薄膜的制备. 中国科学:化学[J]. 2011, 第 5 作者41(12): 1833-1839, http://lib.cqvip.com/Qikan/Article/Detail?id=40208280.[213] Zhu JieMing, Wang Fei, Hu JinBo. Free radical fluoroalkylation of terminal alkenes and alkynes with iododifluoromethanesulfonamides. SCIENCE CHINA-CHEMISTRY[J]. 2011, 第 3 作者 通讯作者 54(1): 95-102, http://www.irgrid.ac.cn/handle/1471x/594221.[214] Zhu, Jieming, Wang, Fei, Huang, Weizhou, Zhao, Yanchuan, Ye, Wenchao, Hu, Jinbo. Copper-Mediated Fluoroalkylation Reactions with (Phenylsulfonyl)-difluoromethyltrimethylsilane: Synthesis of PhSO2CF2-Containing Allenes and Alkynes. SYNLETT[J]. 2011, 第 6 作者 通讯作者 899-902, http://ir.sioc.ac.cn/handle/331003/24091.[215] Wang, Fei, Zhang, Laijun, Zheng, Ji, Hu, Jinbo. Chlorodifluoromethyl aryl ketones and sulfones as difluorocarbene reagents: The substituent effect. JOURNAL OF FLUORINE CHEMISTRY[J]. 2011, 第 4 作者 通讯作者 132(8): 521-528, http://dx.doi.org/10.1016/j.jfluchem.2011.05.009.[216] Wang, Fei, Zhang, Wei, Zhu, Jieming, Li, Huaifeng, Huang, KuoWei, Hu, Jinbo. Chloride ion-catalyzed generation of difluorocarbene for efficient preparation of gem-difluorinated cyclopropenes and cyclopropanes. CHEMICAL COMMUNICATIONS[J]. 2011, 第 6 作者47(8): 2411-2413, http://www.irgrid.ac.cn/handle/1471x/594220.[217] 赵延川, 张丽君, 许国峰, 郑吉, 胡金波. 以二氟烷基磺酸修饰的聚降冰片烯为基础的聚合物电解质薄膜的制备. 中国科学: 化学[J]. 2011, 第 5 作者41(12): 1833-1839, http://ir.sioc.ac.cn/handle/331003/24081.[218] Wang Fei, Huang Weizhou, Hu Jinbo. Difluoromethylation of O-, S-, N-, C-Nucleophiles Using Difluoromethyltri(n-butyl)ammonium Chloride as a New Difluorocarbene Source. CHINESE JOURNAL OF CHEMISTRY[J]. 2011, 第 3 作者 通讯作者 29(12): 2717-2721, http://lib.cqvip.com/Qikan/Article/Detail?id=40185183.[219] Zhao, Yanchuan, Huang, Weizhou, Zheng, Ji, Hu, Jinbo. Efficient and Direct Nucleophilic Difluoromethylation of Carbonyl Compounds and Imines with Me3SiCF2H at Ambient or Low Temperature. ORGANIC LETTERS[J]. 2011, 第 4 作者 通讯作者 13(19): 5342-5345, http://ir.sioc.ac.cn/handle/331003/24099.[220] Ni, Chuanfa, Hu, Jinbo. Selective Nucleophilic Fluoroalkylations Facilitated by Removable Activation Groups. SYNLETT[J]. 2011, 第 2 作者 通讯作者 770-782, http://www.irgrid.ac.cn/handle/1471x/594223.[221] Shen, Xiao, Zhang, Laijun, Zhao, Yanchuan, Zhu, Lingui, Li, Guangyu, Hu, Jinbo. Nucleophilic Fluoromethylation of Aldehydes with Fluorobis(phenylsulfonyl) methane: The Importance of Strong Li-O Coordination and Fluorine Substitution for C-C Bond Formation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2011, 第 6 作者 通讯作者 50(11): 2588-2592, http://www.irgrid.ac.cn/handle/1471x/594219.[222] Hu, Jinbo. Development of new fluoroalkylation and fluoroolefination methods. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2011, 第 1 作者242: https://www.webofscience.com/wos/woscc/full-record/WOS:000299378302868.[223] Zhu, Jieming, Wang, Fei, Huang, Weizhou, Zhao, Yanchuan, Ye, Wenchao, Hu, Jinbo. Copper-Mediated Fluoroalkylation Reactions with (Phenylsulfonyl)-difluoromethyltrimethylsilane: Synthesis of PhSO2CF2-Containing Allenes and Alkynes. SYNLETT[J]. 2011, 第 6 作者 通讯作者 899-902, http://ir.sioc.ac.cn/handle/331003/24091.[224] Prakash, G K Surya, Ni, Chuanfa, Wang, Fang, Hu, Jinbo, Olah, George A. From Difluoromethyl 2-Pyridyl Sulfone to Difluorinated Sulfonates: A Protocol for Nucleophilic Difluoro(sulfonato)methylation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2011, 第 4 作者50(11): 2559-2563, http://dx.doi.org/10.1002/anie.201007594.[225] Wang, Fei, Luo, Tao, Hu, Jinbo, Wang, Ying, Krishnan, Hema S, Jog, Parag V, Ganesh, Somesh K, Prakash, G K Surya, Olah, George A. Synthesis of gem-Difluorinated Cyclopropanes and Cyclopropenes: Trifluoromethyltrimethylsilane as a Difluorocarbene Source. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2011, 第 3 作者 通讯作者 50(31): 7153-7157, http://www.irgrid.ac.cn/handle/1471x/594225.[226] Zhu, Jieming, Zhang, Wei, Zhang, Laijun, Liu, Jun, Zheng, Ji, Hu, Jinbo. Copper-Mediated Fluoroalkylation Reactions with Iododifluoroacetamides: Controlling the Selectivity among Cross-Coupling, Intramolecular Cyclization, and Homocoupling Reactions. JOURNAL OF ORGANIC CHEMISTRY[J]. 2010, 第 6 作者 通讯作者 75(16): 5505-5512, http://www.irgrid.ac.cn/handle/1471x/594211.[227] Zhu, Lingui, Ni, Chuanfa, Zhao, Yanchuan, Hu, Jinbo. 1-tert-Butyl-1H-tetrazol-5-yl fluoromethyl sulfone (TBTSO2CH2F): a versatile fluoromethylidene synthon and its use in the synthesis of monofluorinated alkenes via Julia-Kocienski olefination. TETRAHEDRON[J]. 2010, 第 4 作者 通讯作者 66(27-28): 5089-5100, http://dx.doi.org/10.1016/j.tet.2010.04.113.[228] Liu, Jun, Hu, Jinbo. Highly Diastereoselective Synthesis of alpha-Difluoromethyl Amines from N-tert-Butylsulfinyl Ketimines and Difluoromethyl Phenyl Sulfone. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2010, 第 2 作者 通讯作者 16(37): 11443-11454, http://www.irgrid.ac.cn/handle/1471x/594210.[229] Zhao, Yanchuan, Zhu, Jieming, Ni, Chuanfa, Hu, Jinbo. Magnesium Metal-Mediated Reductive Trifluoromethylation of Aldehydes with Phenyl Trifluoromethyl Sulfone. SYNTHESIS-STUTTGART[J]. 2010, 第 4 作者 通讯作者 1899-1904, http://www.irgrid.ac.cn/handle/1471x/594213.[230] Zemtsov, Artem A, Levin, Vitalij V, Dilman, Alexander D, Struchkova, Marina I, Belyakov, Pavel A, Tartakovsky, Vladimir A, Hu, Jinbo. Reaction of Baylis-Hillman Adducts with Fluorinated Silanes. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY[J]. 2010, 第 7 作者2010(35): 6779-6785, https://www.doi.org/10.1002/ejoc.201001051.[231] Zhang, Wei, Hu, Jinbo. Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from alpha-Fluorosulfoximines. ADVANCEDSYNTHESISCATALYSIS[J]. 2010, 第 2 作者 通讯作者 352(16): 2799-2804, http://www.irgrid.ac.cn/handle/1471x/594209.[232] Zhu, Lingui, Li, Ya, Zhao, Yanchuan, Hu, Jinbo. Nucleophilic (phenylsulfonyl)difluoromethylation of alkyl halides using PhSO2CF2SiMe3: preparation of gem-difluoroalkenes and trifluoromethyl compounds. TETRAHEDRON LETTERS[J]. 2010, 第 4 作者 通讯作者 51(47): 6150-6152, http://dx.doi.org/10.1016/j.tetlet.2010.09.068.[233] Zhao, Yanchuan, Huang, Weizhou, Zhu, Lingui, Hu, Jinbo. Difluoromethyl 2-Pyridyl Sulfone: A New gem-Difluoroolefination Reagent for Aldehydes and Ketones. ORGANIC LETTERS[J]. 2010, 第 4 作者 通讯作者 12(7): 1444-1447, http://www.irgrid.ac.cn/handle/1471x/594214.[234] Ni, Chuanfa, Zhang, Laijun, Hu, Jinbo. Synthesis of Fluorinated beta-Ketosulfones and gem-Disulfones by Nucleophilic Fluoroalkylation of Esters and Sulfinates with Di- and Monofluoromethyl Sulfones. JOURNAL OF ORGANIC CHEMISTRY[J]. 2009, 第 3 作者 通讯作者 74(10): 3767-3771, http://www.irgrid.ac.cn/handle/1471x/594200.[235] Hu, Jinbo, Zhang, Wei, Wang, Fei. Selective difluoromethylation and monofluoromethylation reactions. CHEMICAL COMMUNICATIONS[J]. 2009, 第 1 作者 通讯作者 Unassigned(48): 7465-7478, http://www.irgrid.ac.cn/handle/1471x/594205.[236] Zhang, Wei, Huang, Weizhou, Hu, Jinbo. Highly Stereoselective Synthesis of Monofluoroalkenes from alpha-Fluorosulfoximines and Nitrones. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2009, 第 3 作者 通讯作者 48(52): 9858-9861, https://www.webofscience.com/wos/woscc/full-record/WOS:000273452200015.[237] Li, Ya, Li, Huaifeng, Hu, Jinbo. Free radical (phenylsulfonyl)difluoromethylation of alkynes with PhSO2CF2I reagent: stereoselective preparation of PhSO2CF2- and CF2H-substituted alkenes. TETRAHEDRON[J]. 2009, 第 3 作者 通讯作者 65(2): 478-483, http://dx.doi.org/10.1016/j.tet.2008.11.011.[238] Wang Fei, Hu Jinbo. Bronsted Acid Mediated (sp(3))Carbon-Fluorine Bond Activation: Inter- and Intramolecular Arylation of Trifluoromethylated Arenes. CHINESE JOURNAL OF CHEMISTRY[J]. 2009, 第 2 作者 通讯作者 27(1): 93-98, http://www.irgrid.ac.cn/handle/1471x/594202.[239] Zhang, Wei, Wang, Fei, Hu, Jinbo. N-Tosyl-S-difluoromethyl-S-phenylsulfoximine: A New Difluoromethylation Reagent for S-, N-, and C-Nucleophiles. ORGANIC LETTERS[J]. 2009, 第 3 作者 通讯作者 11(10): 2109-2112, http://www.irgrid.ac.cn/handle/1471x/594199.[240] Hu, Jinbo. Nucleophilic, radical, and electrophilic (phenylsulfonyl)difluoromethylations. JOURNAL OF FLUORINE CHEMISTRY[J]. 2009, 第 1 作者 通讯作者 130(12): 1130-1139, http://dx.doi.org/10.1016/j.jfluchem.2009.05.016.[241] Liu, Jun, Hu, Jinbo. Synthesis of fluorinated chiral amines using N-tert-butylsulfinyl imines. FUTURE MEDICINAL CHEMISTRY[J]. 2009, 第 2 作者 通讯作者 1(5): 875-888, http://www.irgrid.ac.cn/handle/1471x/594206.[242] Zhang, Laijun, Zhang, Wei, Liu, Jun, Hu, Jinbo. C-F Bond Cleavage by Intramolecular S(N)2 Reaction of Alkyl Fluorides with O- and N-Nucleophiles. JOURNAL OF ORGANIC CHEMISTRY[J]. 2009, 第 4 作者 通讯作者 74(7): 2850-2853, http://www.irgrid.ac.cn/handle/1471x/594201.[243] Ni, Chuanfa, Hu, Jinbo. Palladium/acetic acid-catalyzed fluoroalkylation of alkynes with monofluorinated sulfones as pronucleophiles. TETRAHEDRON LETTERS[J]. 2009, 第 2 作者 通讯作者 50(52): 7252-7255, http://dx.doi.org/10.1016/j.tetlet.2009.09.126.[244] 张伟, 黄维洲, 胡金波. Highly Stereoselective Synthesis of Monofluoroalkenes from α-Fluorosulfoximines and Nitrones. ANGEW. CHEM.-INT. EDIT.[J]. 2009, 第 3 作者48(52): 9858-9861, http://ir.sioc.ac.cn/handle/331003/24063.[245] Liu, Jun, Ni, Chuanfa, Wang, Fang, Hu, Jinbo. Stereoselective synthesis of alpha-difluoromethyl-beta-amino alcohols via nucleophilic difluoromethylation with Me3SiCF2SO2Ph. TETRAHEDRON LETTERS[J]. 2008, 第 4 作者 通讯作者 49(10): 1605-1608, http://ir.sioc.ac.cn/handle/331003/24041.[246] 刘俊, 倪传法, 王方, 胡金波. Stereoselective synthesis of alpha-difluoromethyl-beta-amino alcohols via nucleophilic difluoromethylation with Me3SiCF2SO2Ph. TETRAHEDRON LETT.[J]. 2008, 第 4 作者49(10): 1605-1608, http://ir.sioc.ac.cn/handle/331003/24041.[247] Li, Ya, Hu, Jinbo. Fluoride ion-mediated nucleophilic fluoroalkylation of alkyl halides with Me(3)SiCF(2)SPh: Synthesis of PhSCF(2)- and CF(2)H-containing compounds. JOURNAL OF FLUORINE CHEMISTRY[J]. 2008, 第 2 作者 通讯作者 129(5): 382-385, http://dx.doi.org/10.1016/j.jfluchem.2008.01.010.[248] Hu, Jinbo. FLUO 30-Stereoselective synthesis of partially fluorinated amines with fluorinated organosulfur reagents. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2008, 第 1 作者236: https://www.webofscience.com/wos/woscc/full-record/WOS:000270256304579.[249] Zhang, Wei, Zhu, Jieming, Hu, Jinbo. Electrophilic (phenylsulfonyl)difluoromethylation of thiols with a hypervalent iodine(III)-CF2SO2Ph reagent. TETRAHEDRON LETTERS[J]. 2008, 第 3 作者 通讯作者 49(34): 5006-5008, http://dx.doi.org/10.1016/j.tetlet.2008.06.064.[250] Ni, Chuanfa, Zhang, Laijun, Hu, Jinbo. Nucleophilic fluoroalkylation of alpha,beta-enones, arynes, and activated alkynes with fluorinated sulfones: Probing the hard/soft nature of fluorinated carbanions. JOURNAL OF ORGANIC CHEMISTRY[J]. 2008, 第 3 作者 通讯作者 73(15): 5699-5713, http://www.irgrid.ac.cn/handle/1471x/594194.[251] 李亚, 胡金波. Fluoride ion-mediated nucleophilic fluoroalkylation of alkyl halides with Me3SiCF2SPh: Synthesis of PhSCF2- and CF2H-containing compounds. J. FLUOR. CHEM.[J]. 2008, 第 2 作者129(5): 382-385, http://dx.doi.org/10.1016/j.jfluchem.2008.01.010.[252] Liu, Jun, Zhang, Laijun, Hu, Jinbo. Stereoselective Monofluoromethylation of N-tert-Butylsulfinyl Ketimines Using Pregenerated Fluoro(phenylsulfonyl)methyl Anion. ORGANIC LETTERS[J]. 2008, 第 3 作者 通讯作者 10(23): 5377-5380, http://www.irgrid.ac.cn/handle/1471x/594198.[253] Ni, Chuanfa, Wang, Fang, Hu, Jinbo. Enantioselective nucleophilic difluoromethylation of aromatic aldehydes with Me3SiCF2SO2Ph and PhSO2CF2H reagents catalyzed by chiral quaternary ammonium salts. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY[J]. 2008, 第 3 作者 通讯作者 4(1): http://www.irgrid.ac.cn/handle/1471x/594195.[254] Mogi, Ryo, Morisaki, Kazuo, Hu, Jinbo, Prakash, G K Surya, Olah, George A. Synthesis of 1,1-difluoroethylsilanes and their application for the introduction of the 1,1-difluoroethyl group. JOURNAL OF FLUORINE CHEMISTRY[J]. 2007, 第 3 作者128(10): 1098-1103, http://dx.doi.org/10.1016/j.jfluchem.2007.03.013.[255] Li, Ya, Liu, Jun, Zhang, Laijun, Zhu, Lingui, Hu, Jinbo. Radical (phenylsulfonyl)difluoromethylation with iododifluoromethyl phenyl sulfone. JOURNAL OF ORGANIC CHEMISTRY[J]. 2007, 第 5 作者 通讯作者 72(15): 5824-5827, http://www.irgrid.ac.cn/handle/1471x/594185.[256] Li, Ya, Hu, Jinbo. Stereoselective difluoromethylenation using Me3SiCF2SPh: Synthesis of chiral 2,4-disubstituted 3,3-difluoropyrrolidines. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2007, 第 2 作者 通讯作者 46(14): 2489-2492, http://www.irgrid.ac.cn/handle/1471x/594187.[257] Zhang, Wei, Zhu, Lingui, Hu, Jinbo. Electrophilic monofluoromethylation of O-nucleophiles, S-nucleophiles, and N-nucleophiles with chlorofluoromethane. TETRAHEDRON[J]. 2007, 第 3 作者 通讯作者 63(43): 10569-10575, https://www.webofscience.com/wos/woscc/full-record/WOS:000252092400001.[258] Ni, Chuanfa, Liu, Jun, Zhang, Laijun, Hu, Jinbo. A remarkably efficient fluoroalkylation of cyclic sulfates and sulfamidates with PhSO2CF2H: Facile entry into beta-difluoromethylated or beta-difluoromethylenated alcohols and amines. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2007, 第 4 作者 通讯作者 46(5): 786-789, http://www.irgrid.ac.cn/handle/1471x/594188.[259] Zhang, Laijun, Li, Ya, Hu, Jinbo. Preparation of 1-aryl-2,2-difluoro enol esters via dehydrosulfonylation of alpha-(phenylsulfonyl)difluoromethylated benzoates. JOURNAL OF FLUORINE CHEMISTRY[J]. 2007, 第 3 作者 通讯作者 128(7): 755-761, http://www.irgrid.ac.cn/handle/1471x/594184.[260] 张伟, 朱林桂, 胡金波. Electrophilic Monofluoromethylation of O-, S-, N-Nucleophiles with Chlorofluoromethane. TETRAHEDRON[J]. 2007, 第 3 作者63(43): 10569-10575, http://ir.sioc.ac.cn/handle/331003/24027.[261] Zhu, Lingui, Li, Ya, Ni, Chuanfa, Hu, Jinbo, Beier, Petr, Wang, Ying, Prakash, G K Surya, Olah, George A. Nucleophilic (phenylsulfinyl)difluoromethylation of carbonyl compounds with difluoromethyl phenyl sulfoxide. JOURNAL OF FLUORINE CHEMISTRY[J]. 2007, 第 4 作者 通讯作者 128(10): 1241-1247, http://dx.doi.org/10.1016/j.jfluchem.2007.05.003.[262] 郑吉, 李亚, 张来俊, 胡金波, Meuzalaar, Federsel. Chlorodifluoromethyl Phenyl Sulfone: A Novel Non-ODS-Based Difluorocarbene Reagent for O- and N-Difluoromethylations. CHEM. COMMUN.[J]. 2007, 第 4 作者5149-5151, http://ir.sioc.ac.cn/handle/331003/24025.[263] Liu, Jun, Li, Ya, Hu, Jinbo. Stereoselective synthesis of di- and monofluoromethylated vicinal ethylenediamines with di- and monofluoromethyl sulfones. 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指导学生
已指导学生
李亚 博士研究生 070303-有机化学
倪传法 博士研究生 070303-有机化学
朱林桂 博士研究生 070303-有机化学
张来俊 博士研究生 070303-有机化学
刘俊 博士研究生 070303-有机化学
朱杰明 博士研究生 070303-有机化学
张伟 博士研究生 070303-有机化学
王飞 博士研究生 070303-有机化学
现指导学生
黄维洲 博士研究生 070303-有机化学
高兵 硕士研究生 070303-有机化学
罗涛 硕士研究生 070303-有机化学
赵延川 博士研究生 070303-有机化学
何正标 博士研究生 070303-有机化学
叶文超 博士研究生 070303-有机化学
胡明友 博士研究生 070303-有机化学
沈晓 博士研究生 070303-有机化学