基本信息
肖吉昌  男  博导  中国科学院上海有机化学研究所
电子邮件: jchxiao@mail.sioc.ac.cn
通信地址: 上海市零陵路345号
邮政编码: 200032

招生信息

   
招生专业
070303-有机化学
招生方向
氟化学
稀土萃取与稀土化学
氟盐化学

教育背景

2000-08--中科院上海有机所   博士
学历
-- 研究生
学位
-- 博士

工作经历

   
工作简历
2005-08~现在, 中科院上海有机所, 研究员

教授课程

有机氟化学

专利与奖励

   
专利成果
[1] 肖吉昌, 宗国强, 王荣荣, 陆人杰. 一种核纯氟化锂的提纯方法. CN: CN112875730A, 2021-06-01.

[2] 肖吉昌, 杜若冰. 一种制备二烷基次膦酸或其盐的方法. CN: CN112661789A, 2021-04-16.

[3] 肖吉昌, 安华英, 张婷. 一种三氟甲磺酸酐或其类似物的粗品的纯化方法. CN: CN112321464A, 2021-02-05.

[4] 肖吉昌, 向绍基, 安华英. 一种三烷基氧化膦的连续制备装置和制备方法. CN: CN111821932A, 2020-10-27.

[5] 肖吉昌, 杜若冰. 氟烷基碘代物的制备方法. CN: CN110759805A, 2020-02-07.

[6] 肖吉昌, 林锦鸿, 赵艳格. 电解液、电解质、聚合物电解质,其制备方法与应用. CN: CN106785047B, 2019-06-28.

[7] 肖吉昌, 段亚亚, 周斌, 林锦鸿. 含氟三元环化合物、其制备方法及氟烷基锍盐的制备方法. CN: CN105523873B, 2019-03-15.

[8] 肖吉昌, 杜若冰, 崔振华, 安华英, 陆人杰, 张素辉, 张婷, 殷武涛. 从含钴和镍硝酸盐体系中萃取或反萃取钴的方法. 中国: CN106319213B, 2018.09.21.

[9] 肖吉昌, 邓祖勇, 林锦鸿. 二氟甲基鏻盐及其制备方法和应用. 中国: CN106146556B, 2018.09.21.

[10] 欧晓健, 张树峰, 李娟, 张晗, 卢苏君, 朱纪念, 肖吉昌, 杜若冰. 一种含镍和铁的水溶液的处理方法. 中国: CN108315555A, 2018-07-24.

[11] 肖吉昌, 杜若冰, 安华英, 陆人杰, 张婷, 殷武涛, 张素辉. 一种溶剂萃取除铁的方法. 中国: CN105349781B, 2017.12.08.

[12] 肖吉昌, 郑兴, 林锦鸿, 李长峰, 郑曲通, 王冠, 曾贤良, 魏云. 一种齐墩果酸衍生物及其制备方法和用途. 中国: CN105566435B, 2017-12-19.

[13] 肖吉昌, 郑剑, 蔡吉. 新型二氟亚甲基鏻内盐的合成及其应用. 中国: CN103965242B, 2017-12-19.

[14] 肖吉昌, 宗国强. 一种两段式FLiNaK熔盐深度脱氧方法. 中国: CN107274944A, 2017-10-20.

[15] 肖吉昌, 张志兵, 宗国强, 崔振华, 王荣荣, 王正能. 一种气体分布器及包括其的鼓泡反应器. 中国: CN204952849U, 2016-01-13.

[16] 肖吉昌, 杜若冰, 安华英, 陆人杰, 张婷, 殷武涛, 张素辉. 一种萃取剂、萃取体系及应用. 中国: CN105177322A, 2015-12-23.

[17] 肖吉昌, 宗国强, 张志兵, 孙晓刚, 孙加宏, 张龙. 一种用于制备氟化物熔盐的反应罐. 中国: CN204841649U, 2015-12-09.

[18] 陈庆云, 赵刚, 刘超, 郭勇, 肖吉昌, 赵帅, 王文贵, 姜东方. 新型三氟甲基化试剂及其制备和应用. 中国: CN104045585A, 2014-09-17.

[19] 肖吉昌, 杜若冰, 张燕辉, 陆人杰. 一种萃取体系、萃取方法及反萃取方法. 中国: CN103725880A, 2014-04-16.

[20] 肖吉昌, 杜若冰, 王振兴, 张燕辉, 张婷. 一种双烷基次膦酸类化合物或其盐的制备方法及用途. 中国: CN103694273A, 2014-04-02.

[21] 肖吉昌, 宗国强, 孙晓刚, 王荣荣, 孙加宏, 叶新艳. 一种高纯度的氟锂铍熔盐及其制备方法. 中国: CN103606385A, 2014-02-26.

[22] 肖吉昌, 宗国强, 陈伟, 李晓东, 陈博, 张龙, 王正能. 一种高纯度氟铍酸铵的制备方法及其应用. 中国: CN103601222A, 2014-02-26.

[23] 肖吉昌, 宗国强, 孙加宏, 孙晓刚, 李晓东, 叶新艳. 一种用于制备熔盐的熔炼炉. 中国: CN203440069U, 2014-02-19.

[24] 肖吉昌, 宗国强, 王荣荣, 董群安, 陈博, 张龙, 陈伟. 一种高纯度的氟化物熔盐及其制备方法. 中国: CN103219052A, 2013-07-24.

[25] 肖吉昌, 马恒励, 毛婷婷, 张燕辉, 张婷, 殷武涛, 李长峰, 欧阳明. 一种烃基膦酸单烷基酯的合成方法. 中国: CN103073582A, 2013-05-01.

[26] 肖吉昌, 张成潘. 三氟甲基芳基锍盐在金属引发下对杂环化合物的三氟甲基化. 中国: CN101973829A, 2011.02.16.

[27] 肖吉昌, 张成潘, 张 忠, 邵 伟, 严 冲, 强震卫. 一种高密度离子液体及其制备方法. 中国: CN101591296, 2009.12.02.

[28] 肖吉昌, 张成潘, 严 冲, 强震卫. 一种氟烷基磺酰亚胺及其氟烷基磺酰亚胺盐、制备方法和用途. 中国: CN101503382, 2009.08.12.

[29] 肖吉昌, 张 忠, 陈庆云, 田伟生. 一类含氟苯并噻唑磺酰类化合物、制备及应用. 中国: CN101215270, 2008.07.09.

[30] 肖吉昌, 姜明月, 陈超森. 一种具有推拉电子结构的咪唑类离子盐、制备方法及其用途. 中国: CN101143848, 2008-03-19.

[31] 涂嘉浩, 江承忠, 肖吉昌, 蒋龙平. 环氧烷烃聚合催化剂和不同分子量聚环氧烷烃的制备方法. 中国: CN1329423, 2007-08-01.

出版信息

   
发表论文
[1] Zhang, Min, Lin, JinHong, Xiao, JiChang. HCF2Se/HCF2S Installation by Tandem Substitutions from Alkyl Bromides. JOURNAL OF ORGANIC CHEMISTRY[J]. 2021, 86(18): 13153-13159, http://dx.doi.org/10.1021/acs.joc.1c01718.
[2] Shang, XueYun, An, HuaYing, Zhang, Ting, Lin, JinHong, Hao, Fei, Yu, DongHai, Xiao, JiChang, Li, TianDuo. Evaluating and understanding the affinity of metal ions to water and ammonia using density functional theory calculation. CHEMICAL PHYSICS LETTERS[J]. 2021, 768: http://dx.doi.org/10.1016/j.cplett.2021.138398.
[3] Zhang, Min, Lin, JinHong, Jin, ChuanMing, Xiao, JiChang. Difluorocarbene-based cyanodifluoromethylation of alkenes induced by a dual-functional Cu-catalyst. CHEMICAL COMMUNICATIONS[J]. 2021, 57(21): 2649-2652, http://dx.doi.org/10.1039/d1cc00160d.
[4] Hao, Fei, Shang, Xueyun, Liu, Zhenwei, Zhang, He, Lin, JinHong, Xiao, JiChang. Rh-catalyzed tunable defluorinative borylation. CHEMICAL COMMUNICATIONS[J]. 2021, 57(58): 7124-7127, http://dx.doi.org/10.1039/d1cc02079j.
[5] Zhou, Wei, Pan, WenJie, Chen, Jie, Zhang, Min, Lin, JinHong, Cao, Weiguo, Xiao, JiChang. Transition-metal difluorocarbene complexes. CHEMICAL COMMUNICATIONS[J]. 2021, 57(74): 9316-9329, http://dx.doi.org/10.1039/d1cc04029d.
[6] Wu, WenFeng, Lin, JinHong, Xiao, JiChang, Cao, YuCai, Ma, Yanfang. Recent Advances in the Synthesis of CF3- or HCF2-Substituted Cyclopropanes. ASIAN JOURNAL OF ORGANIC CHEMISTRYnull. 2021, 10(3): 485-495, https://www.webofscience.com/wos/woscc/full-record/WOS:000618374800001.
[7] Zhang, Min, Lin, JinHong, Xiao, JiChang. A Readily Available Trifluoromethylation Reagent and Its Difunctionalization of Alkenes. ORGANIC LETTERS[J]. 2021, 23(15): 6079-6083, http://dx.doi.org/10.1021/acs.orglett.1c02146.
[8] 肖吉昌. Contemporary synthetic strategies in organofluorine chemistry. Nature Reviews, Methods Primers. 2021, [9] He, Guowen, Xiao, Xuan, Jin, HanZhou, Lin, JinHong, Zhong, Tongsheng, Zheng, Xing, Xiao, JiChang. Ph2S/selectfluor-promoted deoxydifluorination of aldehydes. TETRAHEDRON[J]. 2021, 83: http://dx.doi.org/10.1016/j.tet.2021.131963.
[10] Zhang, Wei, Lin, JinHong, Wu, Wenfeng, Cao, YuCai, Xiao, JiChang. Dehydroxylative Trifluoromethylthiolation, Trifluoromethylation, and Difluoromethylation of Alcohols. CHINESE JOURNAL OF CHEMISTRY[J]. 2020, 38(2): 169-172, http://lib.cqvip.com/Qikan/Article/Detail?id=7101700402.
[11] Xiang, YaQing, Yao, Xu, Lin, JinHong, Ou, XiaoJian, Li, Rong, Zhou, YuSheng, Yu, DongHai, Xiao, JiChang. Extraction Behavior of Acidic Phosphorus-Containing Compounds to Some Metal Ions: A Combination Research of Experimental and Theoretical Investigations. JOURNAL OF PHYSICAL CHEMISTRY A[J]. 2020, 124(24): 5033-5041, [12] Xiao, Xuan, Zheng, ZiTong, Li, Ting, Zheng, JingLin, Tao, Ting, Chen, LiMei, Gu, JinYing, Yao, Xu, Lin, JinHong, Xiao, JiChang. Recent Advances in Difluoromethylthiolation. SYNTHESIS-STUTTGARTnull. 2020, 52(2): 197-207, https://www.webofscience.com/wos/woscc/full-record/WOS:000502820600003.
[13] Zhang, Wei, Lin, JinHong, Zhang, Pengfei, Xiao, JiChang. A convenient reagent for the conversion of aldoximes into nitriles and isonitriles. CHEMICAL COMMUNICATIONS[J]. 2020, 56(46): 6221-6224, https://www.webofscience.com/wos/woscc/full-record/WOS:000541419600006.
[14] Lin, JinHong, Xiao, JiChang. Fluorinated Ylides/Carbenes and Related Intermediates from Phosphonium/Sulfonium Salts. ACCOUNTS OF CHEMICAL RESEARCHnull. 2020, 53(8): 1498-1510, https://www.webofscience.com/wos/woscc/full-record/WOS:000563017200009.
[15] Zhang, YinXiang, Xiao, Xuan, Fu, ZhiHong, Lin, JinHong, Guo, Yu, Yao, Xu, Cao, YuCai, Du, RuoBing, Zheng, Xing, Xiao, JiChang. Difluorocarbene-Based Cyanation of Aryl Iodides. SYNLETT[J]. 2020, 31(7): 713-717, https://www.webofscience.com/wos/woscc/full-record/WOS:000526694900014.
[16] Zhang, Wei, Gu, YuCheng, Lin, JinHong, Xiao, JiChang. Dehydroxylative Fluorination of Tertiary Alcohols. ORGANIC LETTERS[J]. 2020, 22(16): 6642-6646, http://dx.doi.org/10.1021/acs.orglett.0c02438.
[17] Xiao, Xuan, Yao, Xu, Yu, Jiao, Tang, Ting, Xiao, Can, Gu, Jinying, Lin, JinHong, Zheng, Xing, Xiao, JiChang. A one-step synthesis of gem-difluoroolefins from alcohols. JOURNAL OF FLUORINE CHEMISTRY[J]. 2020, 240: http://dx.doi.org/10.1016/j.jfluchem.2020.109649.
[18] Xu, ZhiWei, Zhang, Wei, Lin, JinHong, Jin, ChuanMing, Xiao, JiChang. Pd-Catalyzed Transfer of Difluorocarbene for Three Component Cross-Coupling. CHINESE JOURNAL OF CHEMISTRY[J]. 2020, 38(12): 1647-1650, http://lib.cqvip.com/Qikan/Article/Detail?id=7103704692.
[19] He, Guowen, Jiang, YanHua, Xiao, Xuan, Lin, JinHong, Zheng, Xing, Du, RuoBing, Cao, YuCai, Xiao, JiChang. Difluorocarbene-based trifluoromethylthiolation of terminal alkynes. JOURNAL OF FLUORINE CHEMISTRY[J]. 2020, 230: http://dx.doi.org/10.1016/j.jfluchem.2019.109437.
[20] Long, Jin, Chen, Jia, Li, Rong, Liu, Zhuo, Xiao, Xuan, Lin, JinHong, Zheng, Xing, Xiao, JiChang. Ph3P/I--Promoted Dichlorination or Dibromination of Epoxides with XCH2CH2X (X = Cl or Br). SYNLETT[J]. 2019, 30(2): 181-184, https://www.webofscience.com/wos/woscc/full-record/WOS:000455224600011.
[21] Min Zhang, Dr. JinHong Lin, Prof. Dr. JiChang Xiao. Photocatalyzed Cyanodifluoromethylation of Alkenes. Angewandte Chemie International Edition. 2019, https://www.webofscience.com/wos/woscc/full-record/WOS:000465413400048.
[22] Jiao Yu, JinHong Lin, Donghai Yu, Ruobing Du, JiChang Xiao. Oxidation of difluorocarbene and subsequent trifluoromethoxylation. Nature Communications[J]. 2019, 10(1): 1-8, https://doaj.org/article/c07c235c8ba24b71b97241c47c4dd27f.
[23] Yu, Jiao, Lin, JinHong, Cao, YuCai, Xiao, JiChang. Visible-light-induced radical hydrodifluoromethylation of alkenes. ORGANIC CHEMISTRY FRONTIERS[J]. 2019, 6(20): 3580-3583, https://www.webofscience.com/wos/woscc/full-record/WOS:000489262600010.
[24] Yu Jiao, Lin Jinhong, Xiao Jichang. ZnO-Promoted Wittig gem-Difluoroolefination of Aldehydes with Ph_3P~+CF_2H·Br~-. Chinese Journal of Organic Chemistry[J]. 2019, 39(1): 265-269, http://lib.cqvip.com/Qikan/Article/Detail?id=6100173768.
[25] Liu, Zhuo, Long, Jin, Xiao, Xuan, Lin, JinHong, Zheng, Xing, Xiao, JiChang, Cao, YuCai. Ph3P+CF2CO2- as an F- and :CF2 source for trifluoromethylthiolation of alkyl halides. CHINESE CHEMICAL LETTERS[J]. 2019, 30(3): 714-716, http://lib.cqvip.com/Qikan/Article/Detail?id=7001849624.
[26] Chen, XinLei, Zhou, ShengHua, Lin, JinHong, Deng, QingHai, Xiao, JiChang. Difluorocarbene-derived trifluoromethylselenolation of benzyl halides. CHEMICAL COMMUNICATIONS[J]. 2019, 55(10): 1410-1413, https://www.webofscience.com/wos/woscc/full-record/WOS:000458546700007.
[27] Zong, Guoqiang, Cui, ZhenHua, Zhang, ZhiBing, Zhang, Long, Xiao, JiChang. Facile preparation of highly pure KF-ZrF4 molten salt. HEAT AND MASS TRANSFER[J]. 2018, 54(10): 2899-2905, https://www.webofscience.com/wos/woscc/full-record/WOS:000444023900001.
[28] Zhang, Wei, Lin, JinHong, Xiao, JiChang. Cu-catalyzed chlorotrifluoromethylation of alkenes with CF3SO2Cl. JOURNAL OF FLUORINE CHEMISTRY[J]. 2018, 215: 25-31, http://dx.doi.org/10.1016/j.jfluchem.2018.09.001.
[29] Chen, Jia, Lin, JinHong, Xiao, JiChang. Dehydroxylation of alcohols for nucleophilic substitution. CHEMICAL COMMUNICATIONS[J]. 2018, 54(51): 7034-7037, https://www.webofscience.com/wos/woscc/full-record/WOS:000436091600017.
[30] Yu, Donghai, Du, Ruobing, Xiao, JiChang, Xu, Shengming, Rong, Chunying, Liu, Shubin. Theoretical Study of pK(a) Values for Trivalent Rare-Earth Metal Cations in Aqueous Solution. JOURNAL OF PHYSICAL CHEMISTRY A[J]. 2018, 122(2): 700-707, https://www.webofscience.com/wos/woscc/full-record/WOS:000423140800024.
[31] Chen, Jia, Lin, JinHong, Xiao, JiChang. Halogenation through Deoxygenation of Alcohols and Aldehydes. ORGANIC LETTERS[J]. 2018, 20(10): 3061-3064, https://www.webofscience.com/wos/woscc/full-record/WOS:000432900200061.
[32] 宗国强, 肖吉昌. 氟化物熔盐的制备及其应用进展. 化工进展[J]. 2018, 37(7): 2455-2472, http://lib.cqvip.com/Qikan/Article/Detail?id=675879897.
[33] Zhang, Wei, Chen, Jia, Lin, JinHong, Xiao, JiChang, Gu, YuCheng. Rapid Dehydroxytrifluoromethoxylation of Alcohols. ISCIENCE[J]. 2018, 5: 110-+, http://dx.doi.org/10.1016/j.isci.2018.07.004.
[34] Pan, XiaoYang, Zhao, Yue, Qu, HongAn, Lin, JinHong, Hang, XiaoChun, Xiao, JiChang. Tri- and di-fluoroethylation of alkenes by visible light photoredox catalysis. ORGANIC CHEMISTRY FRONTIERS[J]. 2018, 5(9): 1452-1456, https://www.webofscience.com/wos/woscc/full-record/WOS:000436110400008.
[35] 肖吉昌. Decarboxylative nucleophilic difluoromethylation of aldehydes and imines. Tetrahedron 2018, 74, 4295-4297. 2018, [36] Zhao, Yue, Lin, JinHong, Hang, XiaoChun, Xiao, JiChang. Ag-Mediated Trifluoromethylthiolation of Inert Csp(3)-H Bond. JOURNAL OF ORGANIC CHEMISTRY[J]. 2018, 83(22): 14120-14125, https://www.webofscience.com/wos/woscc/full-record/WOS:000451101000049.
[37] 肖吉昌. An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of 18F-Labeled α-SCF3 Carbonyl Compounds. Angew. Chem. Int. Ed. 2017, 56, 3196-3200. 2017, [38] Duan, Yaya, Lin, JinHong, Xiao, JiChang, Gu, YuCheng. Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X-H bonds (X = Si, C, P). ORGANIC CHEMISTRY FRONTIERS[J]. 2017, 4(10): 1917-1920, https://www.webofscience.com/wos/woscc/full-record/WOS:000411716700002.
[39] Zeng, XianLiang, Deng, ZuYong, Liu, Can, Zhao, Gang, Lin, JinHong, Zheng, Xing, Xiao, JiChang. Nucleophilic monofluoroalkylation with fluorinated phosphonium salt toward carbonyl and imine compounds. JOURNAL OF FLUORINE CHEMISTRY[J]. 2017, 193: 17-23, http://dx.doi.org/10.1016/j.jfluchem.2016.11.012.
[40] Zong, Guoqiang, Zhang, ZhiBing, Sun, JiaHong, Xiao, JiChang. Preparation of high-purity molten FLiNaK salt by the hydrofluorination process. JOURNAL OF FLUORINE CHEMISTRY[J]. 2017, 197: 134-141, http://dx.doi.org/10.1016/j.jfluchem.2017.03.006.
[41] Huang, Qiuxia, Zheng, Qutong, Duan, Yaya, Lin, JinHong, Xiao, JiChang, Zheng, Xing. Diastereoselective Synthesis of CF3-Containing Vicinal Diamines. JOURNAL OF ORGANIC CHEMISTRY[J]. 2017, 82(15): 8273-8281, https://www.webofscience.com/wos/woscc/full-record/WOS:000407307700059.
[42] Luo, JiaJia, Zhang, Min, Lin, JinHong, Xiao, JiChang. Difluorocarbene for Dehydroxytrifluoromethylthiolation of Alcohols. JOURNAL OF ORGANIC CHEMISTRY[J]. 2017, 82(20): 11206-11211, http://dx.doi.org/10.1021/acs.joc.7b01701.
[43] Duan, Yaya, Lin, JinHong, Xiao, JiChang, Gu, YuCheng. Difluoromethylcarbene for iron-catalyzed cyclopropanation. CHEMICAL COMMUNICATIONS[J]. 2017, 53(27): 3870-3873, http://dx.doi.org/10.1039/c7cc01636k.
[44] Yu, Jiao, Lin, JinHong, Xiao, JiChang. Reaction of Thiocarbonyl Fluoride Generated from Difluorocarbene with Amines. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2017, 56(52): 16669-16673, https://www.webofscience.com/wos/woscc/full-record/WOS:000418359400047.
[45] Zhou, ShengHua, Lin, JinHong, Zhao, Gang, Xiao, JiChang, Cao, WeiGuo. Hydroperfluoroalkylation of electron-deficient olefins with perfluoroalkyl iodides promoted by zinc/viologen. RSC ADVANCES[J]. 2016, 6(65): 60080-60083, http://www.corc.org.cn/handle/1471x/2374652.
[46] Duan, Yaya, Lin, JinHong, Xiao, JiChang, Gu, YuCheng. A Trifluoromethylcarbene Source. ORGANIC LETTERS[J]. 2016, 18(10): 2471-2474, http://dx.doi.org/10.1021/acs.orglett.6b01042.
[47] Deng, Zuyong, Liu, Can, Zeng, XianLiang, Lin, JinHong, Xiao, JiChang. Nucleophilic 1,1-Difluoroethylation with Fluorinated Phosphonium Salt. JOURNAL OF ORGANIC CHEMISTRY[J]. 2016, 81(24): 12084-12090, https://www.webofscience.com/wos/woscc/full-record/WOS:000390180100003.
[48] Deng, Zuyong, Lin, JinHong, Cai, Ji, Xiao, JiChang. Direct Nucleophilic Difluoromethylation of Carbonyl Compounds. ORGANIC LETTERS[J]. 2016, 18(13): 3206-3209, http://www.corc.org.cn/handle/1471x/2374545.
[49] Zheng, QuTong, Wei, Yun, Zheng, Jian, Duan, Yaya, Zhao, Gang, Wang, ZongBao, Lin, JinHong, Zheng, Xing, Xiao, JiChang. Difluoromethylation of N-arylsulfonyl hydrazones with difluorocarbene leading to difluoromethyl aryl sulfones. RSC ADVANCES[J]. 2016, 6(85): 82298-82300, http://www.corc.org.cn/handle/1471x/2376292.
[50] Yue, ChunBo, Lin, JinHong, Cai, Ji, Zhang, ChengPan, Zhao, Gang, Xiao, JiChang, Li, HengFeng. O-Difluoromethylation of 1,3-diones with S-difluoromethyl sulfonium salt. RSC ADVANCES[J]. 2016, 6(42): 35705-35708, https://www.webofscience.com/wos/woscc/full-record/WOS:000374349600066.
[51] Yu, Donghai, Du, Ruobing, Zhang, Suhui, Lu, Renjie, An, Huaying, Xiao, JiChang. Prediction of Solubility Properties from Transfer Energies for Acidic Phosphorus-Containing Rare-Earth Extractants Using Implicit Solvation Model. SOLVENT EXTRACTION AND ION EXCHANGE[J]. 2016, 34(4): 347-354, https://www.webofscience.com/wos/woscc/full-record/WOS:000380062200004.
[52] Zuyong Deng, JinHong Lin, JiChang Xiao. Nucleophilic arylation with tetraarylphosphonium salts. NATURE COMMUNICATIONS[J]. 2016, 7(1): https://doaj.org/article/522ce9be7ee44a2eab0f0182ecda83ba.
[53] Ji, YunLong, Luo, JiaJia, Lin, JinHong, Xiao, JiChang, Gu, YuCheng. Cu-Catalyzed C-H Trifluoromethylation of 3-Arylprop-1-ynes for the Selective Construction of Allenic Csp(2)-CF3 and Propargyl Csp(3)-CF3 Bonds. ORGANIC LETTERS[J]. 2016, 18(5): 1000-1003, https://www.webofscience.com/wos/woscc/full-record/WOS:000371754000029.
[54] Wei, Yun, Yu, Liuying, Lin, Jinhong, Zheng, Xing, Xiao, Jichang. DBU-Promoted Trifluoromethylation of Aryl Iodides with Difluoromethyltriphenylphosphonium Bromide. CHINESE JOURNAL OF CHEMISTRY[J]. 2016, 34(5): 481-484, http://lib.cqvip.com/Qikan/Article/Detail?id=669128215.
[55] Yu, Donghai, Du, Ruobing, Xiao, JiChang. pKa Prediction for Acidic Phosphorus-Containing Compounds Using Multiple Linear Regression with Computational Descriptors. JOURNAL OF COMPUTATIONAL CHEMISTRY[J]. 2016, 37(18): 1668-1671, https://www.webofscience.com/wos/woscc/full-record/WOS:000379163500002.
[56] Liu, Can, Deng, XiaoYun, Zeng, XianLiang, Zhao, Gang, Lin, JinHong, Wang, Hongqing, Xiao, JiChang. Base-free O-difluoromethylation of 1,3-diones with difluorocarbene. JOURNAL OF FLUORINE CHEMISTRY[J]. 2016, 192: 27-30, http://dx.doi.org/10.1016/j.jfluchem.2016.10.011.
[57] Deng, XiaoYun, Lin, JinHong, Xiao, JiChang. Pd-Catalyzed Transfer of Difluorocarbene. ORGANIC LETTERS[J]. 2016, 18(17): 4384-4387, http://www.corc.org.cn/handle/1471x/2376233.
[58] Du, Ruobing, Yu, Donghai, An, Huaying, Zhang, Suhui, Lu, Renjie, Zhao, Gang, Xiao, JiChang. alpha,beta-Substituent effect of dialkylphosphinic acids on lanthanide extraction. RSC ADVANCES[J]. 2016, 6(61): 56004-56008, https://www.webofscience.com/wos/woscc/full-record/WOS:000378275400039.
[59] Zong, Guoqiang, Cui, ZhenHua, Sun, XiaoGang, Xiao, JiChang. One-step synthesis of high-purity Li2BeF4 molten salt. JOURNAL OF FLUORINE CHEMISTRY[J]. 2016, 181: 30-35, http://dx.doi.org/10.1016/j.jfluchem.2015.10.017.
[60] Du, RuoBing, An, Huaying, Zhang, Suhui, Yu, Donghai, Xiao, JiChang. Microwave-assisted synthesis of dialkylphosphinic acids and a structure-reactivity study in rare earth metal extraction. RSC ADVANCES[J]. 2015, 5(126): 104252-104256, https://www.webofscience.com/wos/woscc/full-record/WOS:000366433700060.
[61] Zheng, Jian, Lin, JinHong, Deng, XiaoYun, Xiao, JiChang. 1,8-Diazabicyclo5.4.0undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation. ORGANIC LETTERS[J]. 2015, 17(3): 532-535, https://www.webofscience.com/wos/woscc/full-record/WOS:000349274200036.
[62] Duan, Yaya, Zhou, Bin, Lin, JinHong, Xiao, JiChang. Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenation. CHEMICAL COMMUNICATIONS[J]. 2015, 51(66): 13127-13130, https://www.webofscience.com/wos/woscc/full-record/WOS:000359151100017.
[63] Deng, XiaoYun, Lin, JinHong, Zheng, Jian, Xiao, JiChang. Difluoromethylation and gem-difluorocyclopropenation with difluorocarbene generated by decarboxylation. CHEMICAL COMMUNICATIONS[J]. 2015, 51(42): 8805-8808, https://www.webofscience.com/wos/woscc/full-record/WOS:000354477600018.
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[65] Zheng, Jian, Lin, JinHong, Yu, LiuYing, Wei, Yun, Zheng, Xing, Xiao, JiChang. Cross-Coupling between Difluorocarbene and Carbene-Derived Intermediates Generated from Diazocompounds for the Synthesis of gem-Difluoroolefins. ORGANIC LETTERS[J]. 2015, 17(24): 6150-6153, https://www.webofscience.com/wos/woscc/full-record/WOS:000366878300054.
[66] Wang, ShiMeng, Han, JiaBin, Zhang, ChengPan, Qin, HuaLi, Xiao, JiChang. An overview of reductive trifluoromethylation reactions using electrophilic '+CF3' reagents. TETRAHEDRON[J]. 2015, 71(42): 7949-7976, http://dx.doi.org/10.1016/j.tet.2015.06.056.
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[76] 杜若冰, 张燕辉, 陆人杰, 张婷, 马恒励, 肖吉昌. 盐析剂--氯化钠存在下稀土含量的准确测定. 中国稀土学报[J]. 2014, 32(3): 370-376, http://ir.sioc.ac.cn/handle/331003/38864.
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[79] 肖吉昌. Rh-Catalyzed Allylic C-F Bond Activation: The Stereosynthesis of Trisubstituted Monofluoroalkenes and A Mechanism Study. Org. Biomol. Chem. 2014, 12, 581-588. 2014, [80] 宗国强, 陈博, 张龙, 孙加宏, 董群安, 陈伟, 肖吉昌. FLiNaK 熔盐的制备. 核技术[J]. 2014, 37(5): 050604-1, http://ir.sioc.ac.cn/handle/331003/38865.
[81] 邓晓云, 林锦鸿, 郑剑, 肖吉昌. Cu-Promoted Oxidative Trifluoromethylation of Terminal Alkynes with Difluoromethylene Phosphobetaine. Chin. J. Chem.[J]. 2014, 32(8): 689-693, http://ir.sioc.ac.cn/handle/331003/38869.
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[84] Zhang, ChengPan, Chen, QingYun, Guo, Yong, Xiao, JiChang. Bi-functional fluoroalkylation reagents: an introduction to halo-substituted 3-oxa-perfluoroalkanesulfonyl fluorides. TETRAHEDRON[J]. 2013, 69(51): 10955-10989, http://dx.doi.org/10.1016/j.tet.2013.10.058.
[85] Wang, Xiaoping, Lin, Jinhong, Zhang, Chengpan, Xiao, Jichang, Zheng, Xing. Copper-Mediated Trifluoromethylation of Terminal Alkynes by S-(Trifluoromethyl) diarylsulfonium Salt. CHINESE JOURNAL OF CHEMISTRY[J]. 2013, 31(7): 915-920, http://www.irgrid.ac.cn/handle/1471x/870008.
[86] 张燕辉, 杜若冰, 王振兴, 陆人杰, 毛婷婷, 肖吉昌. 氯乙酸缓冲体系在稀土测定中的应用研究. 中国稀土学报[J]. 2013, 31(5): 636-640, http://www.irgrid.ac.cn/handle/1471x/870010.
[87] Yang, TangPo, Lin, JinHong, Chen, QingYun, Xiao, JiChang. A novel reaction of gem-difluorocyclopropyl ketones with nitriles leading to 2-fluoropyrroles. CHEMICAL COMMUNICATIONS[J]. 2013, 49(84): 9833-9835, http://www.irgrid.ac.cn/handle/1471x/870009.
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[89] Jian Zheng, Dr. JinHong Lin, Dr. Ji Cai, Prof. Dr. JiChang Xiao. Conversion between Difluorocarbene and Difluoromethylene Ylide. Chemistry – A European Journal[J]. 2013, 15261-15266, https://www.webofscience.com/wos/woscc/full-record/WOS:000326290300027.
[90] 吕会朝, 张成潘, 黄晋, 赵巧玲, 马志, 肖吉昌. 聚苯乙烯-co-聚(2,3,4,5,6-五氟苯乙烯)共聚物: 合成及其多孔薄膜的制备. 化学学报[J]. 2012, 70(9): 1125-1130, http://ir.sioc.ac.cn/handle/331003/28403.
[91] Lin Jinhong, Zong Guoqiang, Du Ruobing, Xiao Jichang, Liu Shubin. The asymmetric synthesis of CF3- or -CF2-substituted tetrahydroquinolines by employing a chiral phosphoric acid as catalyst. Chem. Commun.[J]. 2012, 48(62): 7738-7740, http://www.irgrid.ac.cn/handle/1471x/681819.
[92] Zhu Zhiqiang, Jiang Mingyue, Zheng Changge, Xiao Jichang. Efficient synthesis of 1-alkyl-3-methylimidazolium fluorides and possibility of the existence of hydrogen bonding between fluoride anion and C(sp(3))-H. J. Fluor. Chem.[J]. 2012, 133: 160-162, http://dx.doi.org/10.1016/j.jfluchem.2011.08.003.
[93] 郝菲, 蒋华卫, 宗国强, 杜若冰, 陈庆云, 肖吉昌. Electrophilic Fluoroalkylation of Ni(II) N-Confused Porphyrins with Fluoroalkylarylsulfonium Salts. J. Org. Chem.[J]. 2012, 77(7): 3604-3608, http://www.irgrid.ac.cn/handle/1471x/681802.
[94] Zhang, ChengPan, Chen, QingYun, Guo, Yong, Xiao, JiChang, Gu, YuCheng. Progress in fluoroalkylation of organic compounds via sulfinatodehalogenation initiation system. CHEMICAL SOCIETY REVIEWSnull. 2012, 41(12): 4536-4559, http://dx.doi.org/10.1039/c2cs15352a.
[95] Hang, XiaoChun, Gu, WeiPeng, Chen, QingYun, Xiao, JiChang, Xu, WeiGuo, Liu, Shubin. Thermal rearrangement of substituted difluoro(methylene)cyclopropane. JOURNAL OF FLUORINE CHEMISTRY[J]. 2011, 132(1): 63-67, http://dx.doi.org/10.1016/j.jfluchem.2010.11.007.
[96] Zhang, ChengPan, Wang, ZongLing, Chen, QingYun, Zhang, ChunTao, Gu, YuCheng, Xiao, JiChang. Generation of the CF3 radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenes. CHEMICAL COMMUNICATIONS[J]. 2011, 47(23): 6632-6634, http://ir.sioc.ac.cn/handle/331003/13710.
[97] 张成潘, 王宗令, 陈庆云, 张春桃, 顾玉诚, 肖吉昌. Copper-Mediated Trifluoromethylation of Heteroaromatic Compounds by Trifluoromethyl Sulfonium Salts. Angew. Chem.-Int. Edit.[J]. 2011, 50(8): 1896-1900, http://www.irgrid.ac.cn/handle/1471x/581532.
[98] Zhang, He, Zhou, ChangBing, Chen, QingYun, Xiao, JiChang, Hong, Ran. Monofluorovinyl Tosylate: A Useful Building Block for the Synthesis of Terminal Vinyl Monofluorides via Suzuki-Miyaura Coupling. ORGANIC LETTERS[J]. 2011, 13(4): 560-563, http://www.irgrid.ac.cn/handle/1471x/581533.
[99] Zhu, ZhiQiang, Xiao, JiChang. N-Heterocyclic Carbene-Catalyzed Reaction of Alkynyl Aldehydes with 1,3-Keto Esters or 1,3-Diketones. ADVANCED SYNTHESIS & CATALYSIS[J]. 2010, 352(14-15): 2455-2458, http://202.127.28.38/handle/331003/25241.
[100] 肖吉昌. Synthesis and Physicochemical Properties of Bis(fluoroalkanesulfonyl)imide-based Ionic Liquids. Eur. J. Inorg. Chem. 2010, 3419-3422. 2010, [101] Zhang, ChengPan, Cao, HaiPing, Wang, ZongLing, Zhang, ChunTao, Chen, QingYun, Xiao, JiChang. New Electrophilic Bromodifluoromethylation and Pentafluoroethylation Reagents. SYNLETT[J]. 2010, 1089-1092, http://202.127.28.38/handle/331003/13698.
[102] Cheng-Pan Zhang, Zong-Ling Wang, Qing-Yun Chen, Chun-Tao Zhang, Ji-Chang Xiao. One-pot synthesis of arylfluoroalkylsulfoxides and study of their anomalous 19F NMR behavior. Journal of Fluorine Chemistry. 2010, 131(3): 433-438, http://dx.doi.org/10.1016/j.jfluchem.2009.12.019.
[103] 蒋华卫, 郝菲, 陈庆云, 肖吉昌, 刘述斌, 顾玉诚. Electrophilic Reaction of Ag(III) N-Confused Porphyrin with Alcohols. J. Org. Chem.[J]. 2010, 75(10): 3511-3514, http://www.irgrid.ac.cn/handle/1471x/581529.
[104] 张成潘, 王宗令, 陈庆云, 张春桃, 顾玉诚, 肖吉昌. Determination of pK(a) values of fluoroalkanesulfonamides and investigation of their nucleophilicity. J. Fluor. Chem.[J]. 2010, 131(7): 761-766, http://dx.doi.org/10.1016/j.jfluchem.2010.03.013.
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[107] Hang, XiaoChun, Gu, WeiPeng, Chen, QingYun, Xiao, JiChang. Reaction of difluorocarbene with propargyl esters and efficient synthesis of difluorocyclopropyl ketones. TETRAHEDRON[J]. 2009, 65(32): 6320-6324, http://dx.doi.org/10.1016/j.tet.2009.06.019.
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科研活动

   
科研项目
( 1 ) 高张力有机小分子——二氟(亚甲基)环丙烷的合成与反应研究, 主持, 国家级, 2010-01--2012-12
( 2 ) 氟烷基锍盐的制备与反应研究, 主持, 国家级, 2012-01--2015-12
( 3 ) 单氟烯烃的合成与反应, 主持, 国家级, 2015-01--2018-12
( 4 ) 高效稀土萃取剂的分子设计、合成与性能, 主持, 国家级, 2012-01--2016-08
参与会议
(1)Conversion Between Difluorocarbene And Difluoromethylene Ylide   第21届国际氟化学会议   2015-08-23
(2)Synthesis and Reaction of Some Fluorine-containing Phosphonium Salts    第十七届欧洲氟化学会议   2013-07-21

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