1. 基于核磁共振氟谱的化学传感技术

2. 超分子化学

3. 有机多孔材料

2007-09--2012-05   中国科学院上海有机化学研究所   博士

   

[1] Chen, Yixuan, Gu, Yuefei, Meng Huan, Shao, Qianzhen, Xu, Zhenchuang, Bao, Wenjing, Gu, YuCheng, Xue, Xiaosong, 赵延川. Metal-Free C-H Functionalization via Diaryliodonium Salts with a Chemically Robust Dummy Ligand. Angewandte Chemie[J]. 2022, e202201240-, [2] Xu, Zhenchuang, Gu Siyi, Li, Yipeng, Wu, Jian, 赵延川. Recognition-Enabled Automated Analyte Identification via 19F NMR. Analytical Chemistry[J]. 2022, 94(23): 8285-8292, [3] Li，Huanhuan, Xu, Zhenchuang, Zhang, Siquan, Jia, Yushu, 赵延川. Construction of Lewis Pairs for Optimal Enantioresolution via Recognition-Enabled "Chromatographic" 19F NMR Spectroscopy. Analytical Chemistry[J]. 2022, 94(4): 2023-2031, [4] Wen, Lixian, Meng, Huan, Gu, Siyi, Wu, Jian, Zhao, Yanchuan. Toward Nanomolar Multi-Component Analysis by 19F NMR. Analytical Chemistry[J]. 2022, 94(22): 8024-8032, [5] Xu, Zhenchuang, Fang, Nie, Zhao, Yanchuan. Calix4trap: A Bioinspired Host Equipped with Dual Selection Mechanisms. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2021, 143(8): 3162-3168, https://www.webofscience.com/wos/woscc/full-record/WOS:000626325000019.
[6] Lv, Jinghuang, Chen, Si, Xu, Zhenchuang, Zhang, Siquan, Li, Ya, Zhao, Yanchuan. Synthesis and Characterization of Diastereoisomeric Polyesters Derived from Bisphenols Bearing Vicinal Trifluoromethyl Groups. MACROMOLECULES[J]. 2021, 54(8): 3716-3724, http://dx.doi.org/10.1021/acs.macromol.0c02762.
[7] Dong, Chanjuan, Xu, Zhenchuang, Wen, Lixian, He, Shengyuan, Wu, Jian, Deng, QingHai, Zhao, Yanchuan. Tailoring Sensors and Solvents for Optimal Analysis of Complex Mixtures Via Discriminative F-19 NMR Chemosensing. ANALYTICAL CHEMISTRY[J]. 2021, 93(5): 2968-2973, https://www.webofscience.com/wos/woscc/full-record/WOS:000618858500031.
[8] Cai, Yanyao, Zhu, Wenjie, Zhao, Shujuan, Dong, Chanjuan, Xu, Zhenchuang, Zhao, Yanchuan. Difluorocarbene-Mediated Cascade Cyclization: The Multifunctional Role of Ruppert-Prakash Reagent. ORGANIC LETTERS[J]. 2021, 23(9): 3546-3551, http://dx.doi.org/10.1021/acs.orglett.1c00962.
[9] 陈思, 赵延川. 过渡金属参与及催化的C（sp^3）-C（sp^3）还原自偶联反应. 有机化学[J]. 2020, 40(10): 3078-3093, http://lib.cqvip.com/Qikan/Article/Detail?id=7103355082.
[10] Yipeng Li, Lixian Wen, Huan Meng, Jinghuang Lv, Gen Luo, Yanchuan Zhao. Separation-free Enantiodifferentiation with Chromatogram-like Output. Cell Reports Physical Science[J]. 2020, 1(7): 100100-, http://dx.doi.org/10.1016/j.xcrp.2020.100100.
[11] Chen, Si, Zhao, Yanchuan. C(sp(3))-C(sp(3)) Bond Formation via Transition-Metal Mediated and Catalyzed Reductive Homocouplings. CHINESE JOURNAL OF ORGANIC CHEMISTRYnull. 2020, 40(10): 3078-3093, http://dx.doi.org/10.6023/cjoc202005072.
[12] Chen, Si, Zhao, Yanchuan. Poly(o-xylylene)s via Cobalt-Catalyzed Reductive Polymerization. CHINESE JOURNAL OF CHEMISTRY[J]. 2020, 38(9): 952-958, http://lib.cqvip.com/Qikan/Article/Detail?id=7103390472.
[13] Meng, Huan, Wen, Lixian, Xu, Zhenchuang, Li, Yipeng, Hao, Jian, Zhao, Yanchuan. Nonafluoro-tert-butoxylation of Diaryliodonium Salts. ORGANIC LETTERS[J]. 2019, 21(13): 5206-5210, https://www.webofscience.com/wos/woscc/full-record/WOS:000474795200059.
[14] Xu, Zhenchuang, Liu, Chao, Zhao, Shujuan, Chen, Si, Zhao, Yanchuan. Molecular Sensors for NMR-Based Detection. CHEMICAL REVIEWSnull. 2019, 119(1): 195-230, [15] Benedetti, Francesco Maria, He, Yuan, Lai, Holden, Lin, Sharon, Wu, Albert, Jin, Zexin, Teo, Yew Chin, Ye, Hongzhou, Liu, Chao, Zhao, Yanchuan, Van Voorhis, Troy, De Angelis, M Grazia, Xia, Yan, Swager, Timothy, Smith, Zachary. ROMPs and CANALs: New approaches to design microporous polymers for gas separations. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETYnull. 2019, 258: [16] Zhao, Yanchuan, He, Yuan, Swager, Timothy M. Porous Organic Polymers via Ring Opening Metathesis Polymerization. ACS MACRO LETTERS[J]. 2018, 7(3): 300-304, https://www.webofscience.com/wos/woscc/full-record/WOS:000428220200006.
[17] Zhao, Shujuan, Li, Yipeng, Liu, Chao, Zhao, Yanchuan. Recent advances in mechanochemical C-H functionalization reactions. TETRAHEDRON LETTERS[J]. 2018, 59(4): 317-324, http://dx.doi.org/10.1016/j.tetlet.2017.12.021.
[18] Zhao, Yanchuan, Liu, Qinghe, Jiang, Fanzhou, Hu, Jinbo. Stereoselective carbonyl fluoroolefinations with fluorinated sulfone and sulfoximine reagents. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETYnull. 2017, 253: https://www.webofscience.com/wos/woscc/full-record/WOS:000430569101637.
[19] Zhao, Yanchuan, Rocha, Silvia V, Swager, Timothy M. Mechanochemical Synthesis of Extended Iptycenes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2016, 138(42): 13834-13837, https://www.webofscience.com/wos/woscc/full-record/WOS:000386540500018.
[20] Zhao, Yanchuan, Chen, Lily, Swager, Timothy M. Simultaneous Identification of Neutral and Anionic Species in Complex Mixtures without Separation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2016, 55(3): 917-921, https://www.webofscience.com/wos/woscc/full-record/WOS:000368070000008.
[21] Miao, Wenjun, Ni, Chuanfa, Zhao, Yanchuan, Hu, Jinbo. Nucleophilic Iododifluoromethylation of Carbonyl Compounds Using Difluoromethyl 2-Pyridyl Sulfone. ORGANIC LETTERS[J]. 2016, 18(11): 2766-2769, https://www.webofscience.com/wos/woscc/full-record/WOS:000377319000063.
[22] Chen, Dingben, Ni, Chuanfa, Zhao, Yanchuan, Cai, Xian, Li, Xinjin, Xiao, Pan, Hu, Jinbo. Bis(difluoromethyl)trimethylsilicate Anion: A Key Intermediate in Nucleophilic Difluoromethylation of Enolizable Ketones with Me3SiCF2H. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2016, 55(41): 12632-12636, [23] Gao, Bing, Zhao, Yanchuan, Hu, Jinbo. AgF-Mediated Fluorinative Cross-Coupling of Two Olefins: Facile Access to alpha-CF3 Alkenes and beta-CF3 Ketones. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2015, 54(2): 638-642, https://www.webofscience.com/wos/woscc/full-record/WOS:000347238800046.
[24] Zhao, Yanchuan, Jiang, Fanzhou, Hu, Jinbo. Spontaneous Resolution of Julia-Kocienski Intermediates Facilitates Phase Separation to Produce Z- and E-Monofluoroalkenes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2015, 137(15): 5199-5203, https://www.webofscience.com/wos/woscc/full-record/WOS:000353606700054.
[25] Gao, Bing, Zhao, Yanchuan, Hu, Jinbo. AgF-mediated fluorinative cross-coupling of two olefins. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETYnull. 2015, 249: https://www.webofscience.com/wos/woscc/full-record/WOS:000411186500495.
[26] Zhao, Yanchuan, Swager, Timothy M. Simultaneous Chirality Sensing of Multiple Amines by F-19 NMR. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2015, 137(9): 3221-3224, https://www.webofscience.com/wos/woscc/full-record/WOS:000351187200018.
[27] Gao, Bing, Zhao, Yanchuan, Hu, Jingyu, Hu, Jinbo. Difluoromethyl 2-pyridyl sulfone: a versatile carbonyl gem-difluoroolefination reagent. ORGANIC CHEMISTRY FRONTIERS[J]. 2015, 2(2): 163-168, https://www.webofscience.com/wos/woscc/full-record/WOS:000364443200013.
[28] Gao, Bing, Hu, Jingyu, Zhao, Yanchuan, Hu, Jinbo. Carbonyl olefination of diaryl ketones with heteroaryl sulfoxides. TETRAHEDRON LETTERS[J]. 2015, 56(28): 4180-4183, http://dx.doi.org/10.1016/j.tetlet.2015.05.034.
[29] Jiang, Fanzhou, Zhao, Yanchuan, Hu, Jinbo. Selective monofluorination of active methylene compounds: the important role of ZnCl2 in inhibiting overfluorination. ORGANIC CHEMISTRY FRONTIERS[J]. 2014, 1(6): 625-629, https://www.webofscience.com/wos/woscc/full-record/WOS:000364427300003.
[30] Miao, Wenjun, Ni, Chuanfa, Zhao, Yanchuan, Hu, Jinbo. Radical (2-pyridylsulfonyl)difluoromethylation of terminal alkenes with iododifluoromethyl 2-pyridyl sulfone. JOURNAL OF FLUORINE CHEMISTRY[J]. 2014, 167: 231-236, http://dx.doi.org/10.1016/j.jfluchem.2014.05.012.
[31] Gao, Bing, Zhao, Yanchuan, Hu, Mingyou, Ni, Chuanfa, Hu, Jinbo. gem-Difluoroolefination of Diaryl Ketones and Enolizable Aldehydes with Difluoromethyl 2-Pyridyl Sulfone: New Insights into the Julia-Kocienski Reaction. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2014, 20(25): 7803-7810, https://www.webofscience.com/wos/woscc/full-record/WOS:000337637400035.
[32] 缪文俊, 倪传法, 赵延川, 胡金波. Radical (2-pyridylsulfonyl)difluoromethylation of terminal alkenes with iododifluoromethyl 2-pyridyl sulfone. J. Fluor. Chem.[J]. 2014, 167: 231-236, http://ir.sioc.ac.cn/handle/331003/38827.
[33] Gao, Bing, Zhao, Yanchuan, Ni, Chuanfa, Hu, Jinbo. AgF-Mediated Fluorinative Homocoupling of gem-Difluoroalkenes. ORGANIC LETTERS[J]. 2014, 16(1): 102-105, https://www.webofscience.com/wos/woscc/full-record/WOS:000329472800027.
[34] 姜範洲, 赵延川, 胡金波. Selective mono?uorination of active methylene compounds: the important role of ZnCl2 in inhibiting over?uorination. Org. Chem. Front.[J]. 2014, 1: 625-629, http://ir.sioc.ac.cn/handle/331003/38815.
[35] 高兵, 赵延川, 倪传法, 胡金波. AgF-Mediated Fluorinative Homocoupling of gem-Difluoroalkenes. Org. Lett.[J]. 2014, 16(1): 102-105, http://ir.sioc.ac.cn/handle/331003/38814.
[36] Zeng, Yuwen, Zhang, Laijun, Zhao, Yanchuan, Ni, Chuanfa, Zhao, Jingwei, Hu, Jinbo. Silver-Mediated Trifluoromethylation-Iodination of Arynes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2013, 135(8): 2955-2958, http://www.irgrid.ac.cn/handle/1471x/869982.
[37] Huang, Weizhou, Ni, Chuanfa, Zhao, Yanchuan, Hu, Jinbo. DIAD-mediated metal-free cross dehydrogenative coupling between tertiary amines and alpha-fluorinated sulfones. NEW JOURNAL OF CHEMISTRY[J]. 2013, 37(6): 1684-1687, http://www.irgrid.ac.cn/handle/1471x/869979.
[38] 曾裕文, 张来俊, 赵延川, 倪传法, 赵经纬, 胡金波. Silver-Mediated Trifluoromethylation-Iodination of Arynes. J. Am. Chem. Soc.[J]. 2013, 135(8): 2955-2958, http://www.irgrid.ac.cn/handle/1471x/869982.
[39] Zhao, Yanchuan, Ni, Chuanfa, Jiang, Fanzhou, Gao, Bing, Shen, Xiao, Hu, Jinbo. Copper-Catalyzed Debenzoylative Monofluoromethylation of Aryl Iodides Assisted by the Removable (2-Pyridyl)sulfonyl Group. ACS CATALYSIS[J]. 2013, 3(4): 631-634, https://www.webofscience.com/wos/woscc/full-record/WOS:000317328000023.
[40] 黄维洲, 倪传法, 赵延川, 胡金波. DIAD-mediated metal-free cross dehydrogenative coupling between tertiary amines and alpha-fluorinated sulfones. New J. Chem.[J]. 2013, 37(6): 1684-1687, http://www.irgrid.ac.cn/handle/1471x/869979.
[41] Zhao, Yanchuan, Gao, Bing, Hu, Jinbo. From Olefination to Alkylation: In-Situ Halogenation of Julia-Kocienski Intermediates Leading to Formal Nucleophilic Iodo- and Bromodifluoromethylation of Carbonyl Compounds. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2012, 134(13): 5790-5793, http://www.irgrid.ac.cn/handle/1471x/681803.
[42] Hu, Mingyou, Wang, Fei, Zhao, Yanchuan, He, Zhengbiao, Zhang, Wei, Hu, Jinbo. Difluoro(phenylchalcogen)methylation of aldehydes, ketones, and imines with S-, Se-, and Te-containing reagents PhXCF2H (X = S, Se, Te). JOURNAL OF FLUORINE CHEMISTRY[J]. 2012, 135: 45-58, http://dx.doi.org/10.1016/j.jfluchem.2011.08.007.
[43] Zhao, Yanchuan, Hu, Jinbo. Palladium-Catalyzed 2,2,2-Trifluoroethylation of Organoboronic Acids and Esters. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2012, 51(4): 1033-1036, http://www.irgrid.ac.cn/handle/1471x/681830.
[44] Zhang, Wei, Zhao, Yanchuan, Ni, Chuanfa, Mathew, Thomas, Hu, Jinbo. Palladium-catalyzed allylation of 2,2,2-thfluoroethyl phenyl sulfone, a potential 2,2,2-trifluoroethyl pronucleophile. TETRAHEDRON LETTERS[J]. 2012, 53(48): 6565-6568, http://www.irgrid.ac.cn/handle/1471x/681848.
[45] 赵延川. 新型少氟烷基化试剂的开发和应用. 2012, http://ir.sioc.ac.cn/handle/331003/5967.
[46] Zhao, Yanchuan, Gao, Bing, Ni, Chuanfa, Hu, Jinbo. Copper-Mediated Fluoroalkylation of Aryl Iodides Enables Facile Access to Diverse Fluorinated Compounds: The Important Role of the (2-Pyridyl)sulfonyl Group. ORGANIC LETTERS[J]. 2012, 14(23): 6080-6083, http://www.irgrid.ac.cn/handle/1471x/681855.
[47] Huang, Weizhou, Ni, Chuanfa, Zhao, Yanchuan, Zhang, Wei, Dilman, Alexander D, Hu, Jinbo. Nucleophilic difluoromethylation of C=N bonds in heterocycles with difluoromethyl silane reagents. TETRAHEDRON[J]. 2012, 68(26): 5137-5144, http://www.irgrid.ac.cn/handle/1471x/681789.
[48] Huang, Weizhou, Ni, Chuanfa, Zhao, Yanchuan, Gao, Bing, Hu, Jinbo. Nucleophilic difluoromethylation of N,N-acetals with TMSCF2SO2Ph reagent promoted by trifluoroacetic acid: A facile access to alpha-difluoromethylated tertiary amines. JOURNAL OF FLUORINE CHEMISTRY[J]. 2012, 143: 161-166, http://www.irgrid.ac.cn/handle/1471x/681851.
[49] 赵延川, 张丽君, 许国峰, 郑吉, 胡金波. 以二氟烷基磺酸修饰的聚降冰片烯为基础的聚合物电解质薄膜的制备. 中国科学：化学[J]. 2011, 41(12): 1833-1839, http://lib.cqvip.com/Qikan/Article/Detail?id=40208280.
[50] Zhu, Jieming, Wang, Fei, Huang, Weizhou, Zhao, Yanchuan, Ye, Wenchao, Hu, Jinbo. Copper-Mediated Fluoroalkylation Reactions with (Phenylsulfonyl)-difluoromethyltrimethylsilane: Synthesis of PhSO2CF2-Containing Allenes and Alkynes. SYNLETT[J]. 2011, 899-902, http://ir.sioc.ac.cn/handle/331003/24091.
[51] 赵延川, 张丽君, 许国峰, 郑吉, 胡金波. 以二氟烷基磺酸修饰的聚降冰片烯为基础的聚合物电解质薄膜的制备. 中国科学: 化学[J]. 2011, 41(12): 1833-1839, http://ir.sioc.ac.cn/handle/331003/24081.
[52] Zhao, Yanchuan, Huang, Weizhou, Zheng, Ji, Hu, Jinbo. Efficient and Direct Nucleophilic Difluoromethylation of Carbonyl Compounds and Imines with Me3SiCF2H at Ambient or Low Temperature. ORGANIC LETTERS[J]. 2011, 13(19): 5342-5345, http://ir.sioc.ac.cn/handle/331003/24099.
[53] Shen, Xiao, Zhang, Laijun, Zhao, Yanchuan, Zhu, Lingui, Li, Guangyu, Hu, Jinbo. Nucleophilic Fluoromethylation of Aldehydes with Fluorobis(phenylsulfonyl) methane: The Importance of Strong Li-O Coordination and Fluorine Substitution for C-C Bond Formation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2011, 50(11): 2588-2592, http://www.irgrid.ac.cn/handle/1471x/594219.
[54] Zhu, Jieming, Wang, Fei, Huang, Weizhou, Zhao, Yanchuan, Ye, Wenchao, Hu, Jinbo. Copper-Mediated Fluoroalkylation Reactions with (Phenylsulfonyl)-difluoromethyltrimethylsilane: Synthesis of PhSO2CF2-Containing Allenes and Alkynes. SYNLETT[J]. 2011, 899-902, http://ir.sioc.ac.cn/handle/331003/24091.
[55] Zhu, Lingui, Ni, Chuanfa, Zhao, Yanchuan, Hu, Jinbo. 1-tert-Butyl-1H-tetrazol-5-yl fluoromethyl sulfone (TBTSO2CH2F): a versatile fluoromethylidene synthon and its use in the synthesis of monofluorinated alkenes via Julia-Kocienski olefination. TETRAHEDRON[J]. 2010, 66(27-28): 5089-5100, http://dx.doi.org/10.1016/j.tet.2010.04.113.
[56] Zhao, Yanchuan, Zhu, Jieming, Ni, Chuanfa, Hu, Jinbo. Magnesium Metal-Mediated Reductive Trifluoromethylation of Aldehydes with Phenyl Trifluoromethyl Sulfone. SYNTHESIS-STUTTGART[J]. 2010, 1899-1904, http://www.irgrid.ac.cn/handle/1471x/594213.
[57] Zhu, Lingui, Li, Ya, Zhao, Yanchuan, Hu, Jinbo. Nucleophilic (phenylsulfonyl)difluoromethylation of alkyl halides using PhSO2CF2SiMe3: preparation of gem-difluoroalkenes and trifluoromethyl compounds. TETRAHEDRON LETTERS[J]. 2010, 51(47): 6150-6152, http://dx.doi.org/10.1016/j.tetlet.2010.09.068.
[58] Zhao, Yanchuan, Huang, Weizhou, Zhu, Lingui, Hu, Jinbo. Difluoromethyl 2-Pyridyl Sulfone: A New gem-Difluoroolefination Reagent for Aldehydes and Ketones. ORGANIC LETTERS[J]. 2010, 12(7): 1444-1447, http://www.irgrid.ac.cn/handle/1471x/594214.

现指导学生

温力先  博士研究生  070303-有机化学  

贾琦  硕士研究生  070303-有机化学  

何胜源  硕士研究生  070303-有机化学  

方聂  博士研究生  070303-有机化学  

徐振创  博士研究生  070303-有机化学  

陈怡萱  硕士研究生  085216-化学工程