手性聚合物的选择性聚合

   

070305-高分子化学与物理

手性材料合成

2012-09--2017-07   中科院上海有机化学研究所   博士学位
2008-09--2012-07   山东大学   学士学位

   

2020-01~现在, 中科院青岛生物能源与过程研究所, 副研究员
2019-09~2019-12,中科院青岛生物能源与过程研究所, 助理研究员
2017-08~2019-08,中科院青岛生物能源与过程研究所, 博士后

   

[1] 王庆刚, 徐广强, 杨茹琳, 周丽. 一种锌催化剂催化环酯开环聚合的方法. CN: CN112079999B, 2021-11-16.
[2] 王庆刚, 徐广强, 苏家丰. 一种从聚ε-己内酯废弃物回收己内酯的方法. 202111337624.9, 2021-11-10.
[3] 王庆刚, 徐广强, 杨茹琳, 周先悦. 一种从聚乳酸废弃物回收丙交酯的方法. 202111199225.0, 2021-10-14.
[4] 王庆刚, 徐广强, 刘涛. 一种锌催化剂催化芳香族聚碳酸酯氨解的方法. 202111136228.X, 2021-09-27.
[5] 王庆刚, 徐广强, 王子悦. 一种温和条件下锌催化剂催化聚碳酸酯胺醇解的方法. 202111135201.9, 2021-09-27.
[6] 王庆刚, 徐广强, 周先悦. 一种利用胺醇体系解聚聚碳酸酯材料的方法. 202111136205.9, 2021-09-27.
[7] 王庆刚, 徐广强, 杨茹琳. 一种锌催化剂催化聚碳酸酯醇解的方法. 202111136229.4, 2021-09-27.
[8] 王庆刚, 徐广强, 周先悦. 一种镁催化体系催化解聚聚乳酸及其类似物的方法. 202111052518.6, 2021-09-08.
[9] 王庆刚, 徐广强, 周先悦. 一种镁催化体系催化丙交酯及其类似物开环聚合的方法. 202111051347.5, 2021-09-08.
[10] 王庆刚, 徐广强, 杨茹琳. 一种锌催化剂催化降解废弃聚酯材料的方法. CN: CN113173856A, 2021-07-27.
[11] 王庆刚, 徐广强, 杨茹琳. 一种锌催化剂催化聚乳酸材料回收再利用的方法. CN: CN113150375A, 2021-07-23.
[12] 王庆刚, 徐广强, 杨茹琳, 周丽. 一种应用聚酯材料可控解聚的锌催化剂及其催化方法. CN: CN112076790B, 2021-07-23.
[13] 王庆刚, 徐广强, 杨茹琳. 一种锌催化剂催化废弃聚酯材料降解的方法. 202110332669.0, 2021-03-30.
[14] 王庆刚, 徐广强, 吕承东, 杨茹琳. 一种渐变式聚酯的合成方法. 202110104799.9, 2021-01-26.
[15] 王庆刚, 徐广强, 杨茹琳, 周丽. 一种应用于催化环酯开环聚合和聚酯材料可控解聚的锌催化剂及其催化方法. PCT/CN2020/114663, 2020-09-11.
[16] 王庆刚, 徐广强, 郭泫华. 一种由甲基酮出发直接合成氧化呋咱的方法. CN: CN110615771A, 2019-12-27.
[17] 王庆刚, 周丽, 徐广强, 咸漠, 吕承东, 孙西同. 一种有机协同催化内酯开环聚合的无金属催化体系. CN: CN109851765A, 2019-06-07.
[18] 王庆刚, 周丽, 徐广强, 咸漠, 吕承东, 孙西同. 一种有机协同催化三元杂环开环聚合的无金属催化体系. CN: CN109734904A, 2019-05-10.
[19] 王庆刚, 徐广强, 咸漠, 吕承东. 一种新型手性硝基联萘酚及其衍生物的合成方法. CN: CN108658774A, 2018-10-16.
[20] 王庆刚, 徐广强, 咸漠, 周丽. 一种富电子芳烃的直接硝化方法. CN: CN108530242A, 2018-09-14.

   

[1] Yang,Rulin, Xu,Guangqiang, Dong,Bingzhe, Hou,Hongbin, Wang,Qinggang. A "Polymer to Polymer" Chemical Recycling of PLA Plastics by the "DE–RE Polymerization" Strategy. Macromolecules[J]. 2022, 55(5): 1726-1735, https://www.x-mol.com/paper/1486869313964990464?adv.
[2] Xu,Guangqiang, Wang,Qinggang. Chemically recyclable polymer materials: polymerization and depolymerization cycles. Green Chemistry[J]. 2022, https://www.x-mol.com/paper/1498103348327112704?adv.
[3] Wang,Ziyue, Yang,Rulin, Xu,Guangqiang, Liu,Tao, Wang,Qinggang. Chemical Upcycling of Poly(bisphenol A carbonate) Plastic Catalyzed by ZnX2 via an Amino-Alcoholysis Strategy. ACS SUSTAINABLE CHEMISTRY & ENGINEERING[J]. 2022, 10(14): 4529-4537, https://www.x-mol.com/paper/1509664903492853760?adv.
[4] Zhou, Li, Wang, Zhenyu, Xu, Guangqiang, Lv, Chengdong, Wang, Qinggang. Structure and activity relationship studies of N-heterocyclic olefin and thiourea/urea catalytic systems: application in ring-opening polymerization of lactones. POLYMER CHEMISTRY[J]. 2021, 12(12): 1806-1815, http://dx.doi.org/10.1039/d0py01747g.
[5] Wang, ZhenYu, Xu, GuangQiang, Zhou, Li, Lv, ChengDong, Yang, RuLin, Dong, BingZhe, Wang, QingGang. Isoselective Ring-opening Polymerization of Racemic Lactide Catalyzed by N-heterocyclic Olefin/(Thio)urea Organocatalysts. CHINESE JOURNAL OF POLYMER SCIENCE[J]. 2021, 39(6): 709-715, http://dx.doi.org/10.1007/s10118-021-2535-x.
[6] Guo, Xuanhua, Xu, Guangqiang, Zhou, Li, Yan, Huating, Hao, XinQi, Wang, Qinggang. Synthesis and application of alpha-carbonyl nitrile oxides. ORGANIC CHEMISTRY FRONTIERS[J]. 2020, 7(17): 2467-2473, http://dx.doi.org/10.1039/d0qo00780c.
[7] Mahmood, Qaiser, Xu, Guangqiang, Zhou, Li, Guo, Xuanhua, Wang, Qinggang. Chiral 1,5,7-triazabicyclo4.4.0dec-5-ene (TBD)-Catalyzed Stereoselective Ring-Opening Polymerization of rac-Lactide: High Reactivity for Isotactic Enriched Polylactides (PLAs). POLYMERS[J]. 2020, 12(10): https://www.webofscience.com/wos/woscc/full-record/WOS:000587424400001.
[8] Lv, Chengdong, Zhou, Li, Yuan, Ruiting, Mahmood, Qaiser, Xu, Guangqiang, Wang, Qinggang. Isoselective ring-opening polymerization and asymmetric kinetic resolution polymerization of rac-lactide catalyzed by bifunctional iminophosphorane-thiourea/urea catalysts. NEW JOURNAL OF CHEMISTRY[J]. 2020, 44(4): 1648-1655, [9] Xu Guangqiang. Chiral phosphoric acid catalyzed asymmetric kinetic resolution polymerization of 6-aryl-ε-caprolactones. Polym. Chem.. 2020, [10] Yan, Huating, Xu, Guangqiang, Yang, Rulin, Lv, Chengdong, Zhou, Li, Hao, XinQi, Wang, Qinggang. Organocatalytic Ring-Opening Polymerization Strategies for Synthesis of Poly(phosphothioesters) with a Pendent Phenyl Group. SYNLETT[J]. 2020, 31(12): 1167-1171, [11] Xu, Guangqiang, Mahmood, Qaiser, Lv, Chengdong, Yang, Rulin, Zhou, Li, Wang, Qinggang. Asymmetric kinetic resolution polymerization. COORDINATION CHEMISTRY REVIEWSnull. 2020, 414: http://dx.doi.org/10.1016/j.ccr.2020.213296.
[12] Lv, Chengdong, Yang, Rulin, Xu, Guangqiang, Zhou, Li, Wang, Qinggang. Phosphoric acids catalyzed asymmetric kinetic resolution polymerization of benzyl substituted epsilon-caprolactones: Efficient protocol for stereogradient polycaprolactones. EUROPEAN POLYMER JOURNAL[J]. 2020, 133: https://www.webofscience.com/wos/woscc/full-record/WOS:000549179400031.
[13] Xu Guangqiang. N-heterocyclic olefns catalyzed ring-opening polymerization of N-tosyl aziridines. Eur. Polym. J.. 2020, [14] Chengdong Lv, Rulin Yang, Guangqiang Xu, Li Zhou, Qinggang Wang. Phosphoric acids catalyzed asymmetric kinetic resolution polymerization of benzyl substituted ε-caprolactones: Efficient protocol for stereogradient polycaprolactones. EUROPEAN POLYMER JOURNAL. 2020, 133: http://dx.doi.org/10.1016/j.eurpolymj.2020.109792.
[15] Zhou, Li, Wang, Zhenyu, Xu, Guangqiang, Yang, Rulin, Yan, Huating, Hao, XinQi, Wang, Qinggang. N-heterocyclic olefins catalyzed ring-opening polymerization of N-tosyl aziridines. EUROPEAN POLYMER JOURNAL[J]. 2020, 140: http://dx.doi.org/10.1016/j.eurpolymj.2020.110046.
[16] Yuan, Ruiting, Xu, Guangqiang, Lv, Chengdong, Zhou, Li, Yang, Rulin, Wang, Qinggang. Bifunctional phosphazene-thiourea/urea catalyzed ring -opening polymerization of cyclic esters. MATERIALS TODAY COMMUNICATIONS[J]. 2020, 22: http://dx.doi.org/10.1016/j.mtcomm.2019.100747.
[17] Yang, Rulin, Xu, Guangqiang, Lv, Chengdong, Dong, Bingzhe, Zhou, Li, Wang, Qinggang. Zn(HMDS)(2) as a Versatile Transesterification Catalyst for Polyesters Synthesis and Degradation toward a Circular Materials Economy Approach. ACS SUSTAINABLE CHEMISTRY & ENGINEERING[J]. 2020, 8(50): 18347-18353, https://www.webofscience.com/wos/woscc/full-record/WOS:000602569600001.
[18] Lv, Chengdong, Xu, Guangqiang, Yang, Rulin, Zhou, Li, Wang, Qinggang. Chiral phosphoric acid catalyzed asymmetric kinetic resolution polymerization of 6-aryl-epsilon-caprolactones. POLYMER CHEMISTRY[J]. 2020, 11(26): 4203-4207, https://www.webofscience.com/wos/woscc/full-record/WOS:000545817400001.
[19] Xu Guangqiang. Phosphoric acids catalyzed asymmetric kinetic resolution polymerization of benzyl substituted ε-caprolactones: Effcient protocol for stereogradient polycaprolactones. Eur. Polym. J.. 2020, [20] 周丽, 徐广强, Mahmood, Qaiser, 吕承东, 王晓武, 孙西同, 郭凯, 王庆刚. N-Heterocyclic olefins and thioureas as an efficient cooperative catalyst system for ringopening polymerization of δ-valerolactone. Polymer Chemistry[J]. 2019, 10: 1832-1838, https://www.x-mol.com/paperRedirect/5583318.
[21] Yuan, Ruiting, Shou, Qinghui, Mahmood, Qaiser, Xu, Guangqiang, Sun, Xitong, Wan, Jiaqi, Wang, Qinggang. Kinetic Studies on Guanidine-Superbase-Promoted Ring-Opening Polymerization of epsilon-Caprolactone. SYNLETT[J]. 2019, 30(8): 928-931, https://www.webofscience.com/wos/woscc/full-record/WOS:000467271100009.
[22] Guo, Xuanhua, Lv, Chengdong, Mahmood, Qaiser, Zhou, Li, Xu, Guangqiang, Wang, Qinggang. Solvent-controlled chemoselective N-dealkylation-N-nitrosation or C-nitration of N-alkyl anilines with tert-butyl nitrite. ORGANIC CHEMISTRY FRONTIERS[J]. 2019, 6(19): 3401-3407, https://www.webofscience.com/wos/woscc/full-record/WOS:000487508600013.
[23] Xu, Guangqiang, Zhou, Li, Lv, Chengdong, Xian, Mo, Wang, Qinggang. Metal- and acid-free, TBN-mediated direct C-H nitration of arenes. JOURNAL OF SAUDI CHEMICAL SOCIETY[J]. 2019, 23(7): 896-902, [24] Zhou, Li, Xu, Guangqiang, Mahmood, Qaiser, Lv, Chengdong, Wang, Xiaowu, Sun, Xitong, Guo, Kai, Wang, Qinggang. N-Heterocyclic olefins and thioureas as an efficient cooperative catalyst system for ring-opening polymerization of delta-valerolactone. POLYMER CHEMISTRY[J]. 2019, 10(14): 1832-1838, [25] Xu Qiang, Guo Dong, Zhang Peidong, Zhang Xiumei, Li Wentao, Wu Zhongxin. Seasonal variation in species composition and abundance of demersal fish and invertebrates in a Seagrass Natural Reserve on the eastern coast of the Shandong Peninsula, China. CHINESE JOURNAL OF OCEANOLOGY AND LIMNOLOGY[J]. 2016, 34(2): 330-341, https://www.webofscience.com/wos/woscc/full-record/WOS:000371607000008.

   

（ 1 ） 氧羧基环内酸酐(OCAs)的不对称拆分聚合反应研究, 主持, 国家级, 2020-01--2022-12
（ 2 ） 聚烯烃生物材料合成技术开发, 主持, 院级, 2019-04--2020-04