新型金属氢化物储氢及其功能化研究

080501-材料物理与化学

储氢材料，储氢系统，催化，电化学

2011-09--2014-09   大连理工大学-大连化学物理研究所联培   博士
2008-09--2011-06   湘潭大学   硕士
2004-09--2008-06   湘潭大学   学士

   

2018-12~现在, 中国科学院大连化学物理研究所, 副研究员
2014-12~2018-11,德国Helmholtz-Zentrum Geesthacht, 博士后

2020-12-01-2025-09-29,全国氢能标准化技术委员会委员, 委员

   

[1] 曹湖军, 陈萍. 一种聚合物包覆储氢材料及其制备方法和应用. CN: CN112390224A, 2021-02-23.

[2] 陈萍, 曹湖军. 一种廉价大规模制备氮基金属化合物储氢材料的方法. CN: CN105776132B, 2019-04-23.

[3] 陈萍, 曹湖军. 金属氮基化合物储氢材料热力学性能的改善方法. 中国: CN104649223A, 2015-05-27.

   

[1] Zou, Ren, Zhang, Weijin, Dai, Min, Lei, Gangtie, Jiang, Qike, Cao, Hujun, Chen, Ping. One-Step Synthesis of Light Metal Nanoparticle from Metastable Complex. SMALL[J]. 2023, 19(8): http://dx.doi.org/10.1002/smll.202206518.
[2] 张炜进, 崔继荣, 王上上, 曹湖军, 吴安安, 夏元华, 蒋齐可, 郭建平, 何腾, 陈萍. Deforming lanthanum trihydride for superionic conduction. Nature[J]. 2023, 616(7955): 73-76, https://doi.org/10.1038/s41586-023-05815-0.
[3] Zou, Ren, Li, Jialing, Cui, Jirong, Zhang, Weijin, Lei, Gangtie, Cao, Hujun, Chen, Ping. Catalyst-free synthesis of lithium hydride at room temperature. CHEMICAL COMMUNICATIONS[J]. 2023, 59(18): 2660-2663, http://dx.doi.org/10.1039/d2cc06849d.
[4] Feng, Sheng, Gao, Wenbo, Guo, Jianping, Cao, Hujun, Chen, Ping. Electrodriven Chemical Looping Ammonia Synthesis Mediated by Lithium Imide. ACS ENERGY LETTERS. 2023, 1567-1574, http://dx.doi.org/10.1021/acsenergylett.2c02730.
[5] Han Wu, Liang Yang, Jiaqi Wen, Yongfeng Xu, Yongli Cai, 高文波, 王倩茹, 关业勤, Sheng Feng, Hujun Cao, 何腾, Lin Liu, 张绍骞, 郭建平, Ping Chen. Plasma-Driven Nitrogen Fixation on Sodium Hydride. Advanced Energy Materials[J]. 2023, [6] Cao, Hujun, Pistidda, Claudio, Richter, Theresia M M, Capurso, Giovanni, Milanese, Chiara, Tseng, JoChi, Shang, Yuanyuan, Niewa, Rainer, Chen, Ping, Klassen, Thomas, Dornheim, Martin. De-hydrogenation/Rehydrogenation Properties and Reaction Mechanism of A(m)Zn(NH2)(n)-2nLiH Systems (A = Li, K, Na, and Rb). SUSTAINABILITY[J]. 2022, 14(3): http://dx.doi.org/10.3390/su14031672.
[7] 王江, 雷刚铁, 何腾, 曹湖军, 陈萍. Defect-rich potassium amide: A new solid-state potassium ion electrolyte. Journal of Energy Chemistry[J]. 2022, 69: 555-560, [8] Min Dai, Joshua Adedeji Bolarin, Gangtie Lei, Zhi Li, Teng He, Hujun Cao, Ping Chen. Potassium hydride reduced black TiO2−x for boosting the hydrogenation of magnesium at room temperature. JOURNAL OF ALLOYS AND COMPOUNDS[J]. 2022, 897: [9] Zou, Ren, Bolarin, Joshua Adedeji, Lei, Gangtie, Gao, Wenbo, Li, Zhi, Cao, Hujun, Chen, Ping. Microwave-assisted reduction of Ti species in MgH2-TiO2 composite and its effect on hydrogen storage. CHEMICAL ENGINEERING JOURNAL[J]. 2022, 450: [10] Yuan, Zirui, Li, Shaohan, Wang, Kaiwen, Xu, Nuo, Sun, Weiwei, Sun, Litao, Cao, Hujun, Lin, Huaijun, Zhu, Yunfeng, Zhang, Yao. in-situ formed Pt nano-clusters serving as destabilization-catalysis bi-functional additive for MgH2. CHEMICAL ENGINEERING JOURNAL[J]. 2022, 435: http://dx.doi.org/10.1016/j.cej.2022.135050.
[11] Dai Min, Lei Gangtie, Zhang Zhao, Li Zhi, Cao Hujun, Chen Ping. Room Temperature Hydrogen Absorption of V2O5 Catalyzed MgH2/Mg. ACTA CHIMICA SINICA[J]. 2022, 80(3): 303-309, http://dx.doi.org/10.6023/A21120561.
[12] Bolarin, Joshua Adedeji, Zou, Ren, Li, Zhi, Zhang, Zhao, Cao, Hujun. MXenes for magnesium-based hydrides: A review. APPLIED MATERIALS TODAYnull. 2022, 29: http://dx.doi.org/10.1016/j.apmt.2022.101570.
[13] Pei, Qijun, He, Teng, Yu, Yang, Jing, Zijun, Wang, Jintao, Tan, Khai Chen, Guo, Jianping, Liu, Lin, Cao, Hujun, Chen, Ping. Fabrication of oxygen vacancies through assembling an amorphous titanate overlayer on titanium oxide for a catalytic water-gas shift reaction. JOURNAL OF MATERIALS CHEMISTRY A[J]. 2021, 9(5): 2784-2791, http://dx.doi.org/10.1039/d0ta11641f.
[14] Wang, Qianru, Pan, Jaysree, Guo, Jianping, Hansen, Heine Anton, Xie, Hua, Jiang, Ling, Hua, Lei, Li, Haiyang, Guan, Yeqin, Wang, Peikun, Gao, Wenbo, Liu, Lin, Cao, Hujun, Xiong, Zhitao, Vegge, Tejs, Chen, Ping. Ternary ruthenium complex hydrides for ammonia synthesis via the associative mechanism. NATURE CATALYSIS[J]. 2021, 4(11): 959-+, http://dx.doi.org/10.1038/s41929-021-00698-8.
[15] Bolarin, Joshua Adedeji, Zhang, Zhao, Cao, Hujun, Li, Zhi, He, Teng, Chen, Ping. Room Temperature Hydrogen Absorption of Mg/MgH2 Catalyzed by BaTiO3. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2021, 125(36): 19631-19641, http://dx.doi.org/10.1021/acs.jpcc.1c05560.
[16] He, Teng, Cao, Hujun, Chen, Ping. The Roles of Alkali/Alkaline Earth Metals in the Materials Design and Development for Hydrogen Storage. ACCOUNTS OF MATERIALS RESEARCH[J]. 2021, 2(9): 726-738, [17] 高文波, Sheng Feng, 严寒雪, qianru wang, hua xie, Ling Jiang, Weijin Zhang, 关业勤, Han Wu, Hujun Cao, 郭建平, Ping Chen. In-situ formed Co from Co-Mg-O solid solution synergizing with LiH for efficient ammonia synthesis. Chemical Communications[J]. 2021, 57: 8576-8579, [18] Wang, Jiang, Lei, Gangtie, Pistidda, Claudio, He, Teng, Cao, Hujun, Dornheim, Martin, Chen, Ping. Hydrogen storage properties and reaction mechanisms of K2Mn(NH2)(4)-8LiH system. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY[J]. 2021, 46(80): 40196-40202, http://dx.doi.org/10.1016/j.ijhydene.2021.09.216.
[19] Feng, Sheng, Gao, Wenbo, Wang, Qianru, Guan, Yeqin, Yan, Hanxue, Wu, Han, Cao, Hujun, Guo, Jianping, Chen, Ping. A multi-functional composite nitrogen carrier for ammonia production via a chemical looping route. JOURNAL OF MATERIALS CHEMISTRY A[J]. 2021, 9(2): 1039-1047, https://www.webofscience.com/wos/woscc/full-record/WOS:000609149500027.
[20] Zhang, Zhao, Cao, Hujun, Xiong, Zhitao, Bolarin, Joshua Adedeji, Zhang, Weijin, Chen, Ping. Can nitrogen-based complex hydrides be a hydrogen isotope separation material?. CHEMICAL COMMUNICATIONS[J]. 2021, 57(78): 10063-10066, http://dx.doi.org/10.1039/d1cc03825g.
[21] Yan, Hanxue, Gao, Wenbo, Wang, Qianru, Guan, Yeqin, Feng, Sheng, Wu, Han, Guo, Qing, Cao, Hujun, Guo, Jianping, Chen, Ping. Lithium Palladium Hydride Promotes Chemical Looping Ammonia Synthesis Mediated by Lithium Imide and Hydride. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2021, 125(12): 6716-6722, http://dx.doi.org/10.1021/acs.jpcc.1c01230.
[22] Joshua AdedejiBolarin, 张钊, 曹湖军, 李智, 何腾, 陈萍. NaH doped TiO2 as a high-performance catalyst for Mg/MgH2 cycling stability and room temperature absorption. Journal of Magnesium and Alloys[J]. 2021, [23] Cao, Hujun, Pistidda, Claudio, Castro Riglos, Maria Victoria, Chaudhary, AnnaLisa, Capurso, Giovanni, Tseng, JoChi, Puszkiel, Julian, Wharmby, Michael T, Gemming, Thomas, Chen, Ping, Klassen, Thomas, Dornheim, Martin. Conversion of magnesium waste into a complex magnesium hydride system: Mg(NH2)(2)-LiH. SUSTAINABLE ENERGY & FUELS[J]. 2020, 4(4): 1915-1923, https://www.webofscience.com/wos/woscc/full-record/WOS:000526855200035.
[24] Zhang, Zhao, Cao, Hujun, Zhang, Weijin, Cui, Jirong, Xiong, Zhitao, Chen, Ping. Thermochemical transformation and reversible performance of Mg(NH2)(2)-NaMgH3 system. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY[J]. 2020, 45(43): 23069-23075, http://dx.doi.org/10.1016/j.ijhydene.2020.06.094.
[25] Cui, Jirong, Zhang, Weijin, Cao, Hujun, Chen, Ping. Mild-condition synthesis of A(2)ZnH(4) (A = K, Rb, Cs) and their effects on the hydrogen storage properties of 2LiH-Mg(NH2)(2). JOURNAL OF ENERGY CHEMISTRY[J]. 2020, 50(11): 358-364, http://lib.cqvip.com/Qikan/Article/Detail?id=7103120599.
[26] 冯圣, 高文波, 曹湖军, 郭建平, 陈萍. 化学链合成氨研究进展. 化学学报[J]. 2020, 78(9): 916-927, http://lib.cqvip.com/Qikan/Article/Detail?id=7103158775.
[27] Feng Sheng, Gao Wenbo, Cao Hujun, Guo Jianping, Chen Ping. Advances in the Chemical Looping Ammonia Synthesis. ACTA CHIMICA SINICA[J]. 2020, 78(9): 916-927, https://www.webofscience.com/wos/woscc/full-record/WOS:000589508000008.
[28] Gizer, Goekhan, Cao, Hujun, Puszkiel, Julian, Pistidda, Claudio, Santoru, Antonio, Zhang, Weijin, He, Teng, Chen, Ping, Klassen, Thomas, Dornheim, Martin. Enhancement Effect of Bimetallic Amide K2Mn(NH2)(4) and In-Situ Formed KH and Mn4N on the Dehydrogenation/Hydrogenation Properties of Li-Mg-N-H System. ENERGIES[J]. 2019, 12(14): https://doaj.org/article/d1dcdce0e11e467c99334958edf22134.
[29] He, Teng, Cao, Hujun, Chen, Ping. Complex Hydrides for Energy Storage, Conversion, and Utilization. ADVANCED MATERIALS[J]. 2019, 31(50): http://dx.doi.org/10.1002/adma.201902757.
[30] Wang, Han, Cao, Hujun, Zhang, Weijin, Chen, Jian, Wu, Hui, Pistidda, Claudio, Ju, Xiaohua, Zhou, Wei, Wu, Guotao, Etter, Martin, Klassen, Thomas, Dornheim, Martin, Chen, Ping. Li2NH-LiBH4: a Complex Hydride with Near Ambient Hydrogen Adsorption and Fast Lithium Ion Conduction. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2018, 24(6): 1342-1347, http://cas-ir.dicp.ac.cn/handle/321008/168492.
[31] Cao, Hujun, Georgopanos, Prokopios, Capurso, Giovanni, Pistidda, Claudio, Weigelt, Fynn, Chaudhary, AnnaLisa, Filiz, Volkan, Tseng, JoChi, Wharmby, Michael T, Dornheim, Martin, Abetz, Volker, Klassen, Thomas. Air-stable metal hydride-polymer composites of Mg(NH2)(2)-LiH and TPX (TM). MATERIALS TODAY ENERGY[J]. 2018, 10: 98-107, https://www.webofscience.com/wos/woscc/full-record/WOS:000480515400012.
[32] Cao, Hujun, Pistidda, Claudio, Richter, Theresia M M, Santoru, Antonio, Milanese, Chiara, Garroni, Sebastiano, Bednarcik, Jozef, Chaudhary, AnnaLisa, Gizer, Goekhan, Liermann, HannsPeter, Niewa, Rainer, Ping, Chen, Klassen, Thomas, Dornheim, Martin. In Situ X-ray Diffraction Studies on the De/rehydrogenation Processes of the K-2Zn(NH2)(4)-8LiH System. JOURNALOFPHYSICALCHEMISTRYC[J]. 2017, 121(3): 1546-1551, http://cas-ir.dicp.ac.cn/handle/321008/169638.
[33] Cao, Hujun, Guo, Jianping, Chang, Fei, Pistidda, Claudio, Zhou, Wei, Zhang, Xilun, Santoru, Antonio, Wu, Hui, Schell, Norbert, Niewa, Rainer, Chen, Ping, Klassen, Thomas, Dornheim, Martin. Transition and Alkali Metal Complex Ternary Amides for Ammonia Synthesis and Decomposition. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2017, 23(41): 9766-9771, http://cas-ir.dicp.ac.cn/handle/321008/151909.
[34] Cao, Hujun, Santoru, Antonio, Pistidda, Claudio, Richter, Theresia M M, Chaudhary, AnnaLisa, Gizer, Goekhan, Niewa, Rainer, Chen, Ping, Klassen, Thomas, Dornheim, Martin. New synthesis route for ternary transition metal amides as well as ultrafast amide-hydride hydrogen storage materials. CHEMICAL COMMUNICATIONS[J]. 2016, 52(29): 5100-5103, http://cas-ir.dicp.ac.cn/handle/321008/170722.
[35] Wang, Han, Cao, Hujun, Wu, Guotao, He, Teng, Chen, Ping. The improved Hydrogen Storage Performances of the Multi-Component Composite: 2Mg(NH2)(2)-3LiH-LiBH4. ENERGIES[J]. 2015, 8(7): 6898-6909, http://cas-ir.dicp.ac.cn/handle/321008/146478.
[36] Cao, Hujun, Richter, Theresia M M, Pistidda, Claudio, Chaudhary, AnnaLisa, Santoru, Antonio, Gizer, Goekhan, Niewa, Rainer, Chen, Ping, Klassen, Thomas, Dornheim, Martin. Ternary Amides Containing Transition Metals for Hydrogen Storage: A Case Study with Alkali Metal Amidozincates. CHEMSUSCHEM[J]. 2015, 8(22): 3777-3782, http://cas-ir.dicp.ac.cn/handle/321008/171580.
[37] Hujun Cao, Theresia M M Richter, Claudio Pistidda, AnnaLisa Chaudhary, Antonio Santoru, Gouml, khan Gizer, Rainer Niewa, 陈萍, Thomas Klassen and Martin Dornheim. Ternary Amides Containing Transition Metals for Hydrogen Storge: A Case Study with Alkali Metal Amidozincates. CHEMSUSCHEM[J]. 2015, 8: 3777-, http://cas-ir.dicp.ac.cn/handle/321008/148228.
[38] 陈萍, 郭建平, 曹湖军, 陈君儿, 熊智涛, 吴国涛. Amides, amines and ammonia as hydrogen carriers. 3rd international symposium on chemistry for energy conversion and storagenull. 2015, http://cas-ir.dicp.ac.cn/handle/321008/143494.
[39] Cao, Hujun, Wang, Han, He, Teng, Wu, Guotao, Xiong, Zhitao, Qiu, Jieshan, Chen, Ping. Improved kinetics of the Mg(NH2)(2)-2LiH system by addition of lithium halides. RSC ADVANCES[J]. 2014, 4(61): 32555-32561, http://cas-ir.dicp.ac.cn/handle/321008/144283.
[40] 曹湖军, 王建辉, 熊智涛, 吴国涛, 陈萍. Improved Dehydrogenation Properties of the Mg(NH2)2-2LiH System. 6th forum on new materials of \null. 2014, 60-, http://159.226.238.44/handle/321008/119960.
[41] Yu, Pei, Chua, Yong Shen, Cao, Hujun, Xiong, Zhitao, Wu, Guotao, Chen, Ping. Hydrogen storage over alkali metal hydride and alkali metal hydroxide composites. JOURNAL OF ENERGY CHEMISTRY[J]. 2014, 23(4): 414-419, http://lib.cqvip.com/Qikan/Article/Detail?id=662119181.
[42] 陈萍, 陈君儿, 曹湖军, 吴国涛, 熊智涛. Amides and Amines for Hydrogen Storage. the energy future 2014 conferencenull. 2014, http://cas-ir.dicp.ac.cn/handle/321008/143657.
[43] Zhang, Yao, Xiong, Zhitao, Cao, Hujun, Wu, Guotao, Chen, Ping. The enhanced hydrogen storage performance of (Mg-B-N-H)-doped Mg(NH2)-2LiH system. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY[J]. 2014, 39(4): 1710-1718, http://dx.doi.org/10.1016/j.ijhydene.2013.11.008.
[44] Cao, Hujun, Wu, Guotao, Zhang, Yao, Xiong, Zhitao, Qiu, Jieshan, Chen, Ping. Effective thermodynamic alteration to Mg(NH2)(2)-LiH system: achieving near ambient-temperature hydrogen storage. JOURNAL OF MATERIALS CHEMISTRY A[J]. 2014, 2(38): 15816-15822, http://cas-ir.dicp.ac.cn/handle/321008/145579.
[45] 曹湖军, Yao Zhang, 王涵, 何腾, 熊智涛, 吴国涛, 陈萍. Modified Hydrogen Storage Performance of Mg(NH2)2/LiH Composite. europea hydrogen energy conference 2014null. 2014, 23-, http://159.226.238.44/handle/321008/120004.
[46] 陈萍, 陈君儿, 曹湖军, 吴国涛, 熊智涛. Nitrogen based materials for hydrogen storage. 14th international symposium on metal-hydrogen systemsnull. 2014, 169-, http://159.226.238.44/handle/321008/119945.
[47] Cao, Hujun, Wang, Jianhui, Chua, Yongshen, Wang, Han, Wu, Guotao, Xiong, Zhitao, Qiu, Jieshan, Chen, Ping. NH3 Mediated or Ion Migration Reaction: The Case Study on Halide-Amide System. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2014, 118(5): 2344-2349, http://cas-ir.dicp.ac.cn/handle/321008/144448.
[48] Cao, Hujun, Chua, Yongshen, Zhang, Yao, Xiong, Zhitao, Wu, Guotao, Qiu, Jieshan, Chen, Ping. Releasing 9.6 wt% of H-2 from Mg(NH2)(2)-3LiH-NH3BH3 through mechanochemical reaction. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY[J]. 2013, 38(25): 10446-10452, http://dx.doi.org/10.1016/j.ijhydene.2013.06.036.
[49] Cao, Hujun, Zhang, Yao, Wang, Jianhui, Xiong, Zhitao, Wu, Guotao, Qiu, Jieshan, Chen, Ping. Effects of Al-based additives on the hydrogen storage performance of the Mg(NH2)(2)-2LiH system. DALTON TRANSACTIONS[J]. 2013, 42(15): 5524-5531, http://159.226.238.44/handle/321008/119380.
[50] Cao, Hujun, Zhang, Yao, Wang, Jianhui, Xiong, Zhitao, Wu, Guotao, Chen, Ping. Materials design and modification on amide-based composites for hydrogen storage. PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL[J]. 2012, 22(6): 550-560, http://lib.cqvip.com/Qikan/Article/Detail?id=690757489201206006.
[51] Yang Yu, Weijin Zhang, Hujun Cao, Teng He, Ping Chen. Ion migration in hydride materials. TRENDS IN CHEMISTRY. http://dx.doi.org/10.1016/j.trechm.2022.07.006.
[52] Joshua Adedeji Bolarin, Ren Zou, Zhi Li, Alexis Munyentwali, Zhao Zhang, Hujun Cao. Recent path to ultrafine Mg/MgH2 synthesis for sustainable hydrogen storage. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY. http://dx.doi.org/10.1016/j.ijhydene.2023.04.234.

（1） 氢化物：载氢载能体, 科学出版社, 2021-06, 第 4 作者

   

（ 1 ） 钾(铷)基三元过渡金属氢化物对氨基镁-氢化锂体系储氢性能的影响及其作用机理的研究, 主持, 国家级, 2019-01--2021-12
（ 2 ） 高密度储氢体系的开发、规模化制备及系统集成 技术, 主持, 省级, 2021-01--2023-12
（ 3 ） 高密度储氢材料及其可逆吸/放氢技术, 主持, 国家级, 2021-12--2025-11
（ 4 ） 中国科学院青年创新促进会, 主持, 部委级, 2019-01--2022-12

Martin Dornheim教授, Helmholtz-Zentrum Geesthacht, Germany

Hui Wu教授, NIST, USA

Chiara Milanese教授, University of Pavia, Italy

Rainer Niewa教授, University of Stuttgart, Germany

现指导学生

程咨博  硕士研究生  085600-材料与化工