基本信息
徐宝华  女  博导  中国科学院过程工程研究所
电子邮件: bhxu@home.ipe.ac.cn
通信地址: 北京海淀区北二条街1号
邮政编码: 100190

招生信息

   
招生专业
081705-工业催化
081704-应用化学
招生方向
有机金属催化
离子液体催化

教育背景

2005-09--2008-06   南京大学   博士
2002-09--2005-06   东华大学   硕士
1998-09--2002-06   安徽工程大学   学士

工作经历

   
工作简历
2012-11~现在, 中科院过程工程所, 研究员
2008-09~2012-09,Muenster大学(GER), 博士后研究员

教授课程

Chemical Reaction Engineering

专利与奖励

   
专利成果
( 1 ) 制备硫代-1,2-二碳代-闭式-十二碳硼烷(12)有机衍生物的方法及其产物, 发明, 2012, 第 2 作者, 专利号: 200810024505.6
( 2 ) 免焙烘无甲醛涂料染色纳米粘合剂水性胶乳, 发明, 2006, 第 1 作者, 专利号: ZL200410089507.5
( 3 ) 一种β-大马烯酮香料的制备方法, 发明, 2014, 第 3 作者, 专利号: 201410256241.2
( 4 ) 一种酸性离子液体催化剂在催化多元糖醇制备相应的脱水化合物中的用途, 发明, 2016, 第 1 作者, 专利号: 201610312860.8
( 5 ) 一种己二腈的制备方法, 发明, 2019, 第 3 作者, 专利号: 201910501004.0
( 6 ) 一种多孔碱性负载离子液体催 化剂及其制备方法和用途, 发明, 2019, 第 2 作者, 专利号: CN108126749A
( 7 ) 一种自由基信号增强、在线分 离及实时在线分析系统, 发明, 2018, 第 2 作者, 专利号: 201811172638.8
( 8 ) 酸性离子液体@COF杂化材料的 制备及在多元糖醇脱水反应中 的应用, 发明, 2019, 第 1 作者, 专利号: 201910476715.7

出版信息

   
发表论文
(1) Cobalt-Catalyzed Chemoselective Transfer Hydrogenation of C=C and C=O Bonds with Alkanols., ChemCatChem, 2019, 通讯作者
(2) N-Hydroxyphthalimide/Benzoquinone-Catalyzed Chlorination of Hydrocarbon C−H Bond with N-Chlorosuccinimide., Org. Biomol. Chem., 2019, 通讯作者
(3) Tris(pyrazolyl)borate Cobalt-Catalyzed Hydrogenation of C=O, C=C, and C=N Bonds: An Assistant Role of a Lewis Base., Org. Lett., 2019, 通讯作者
(4) Cobalt-Catalyzed Direct Transformation of Aldehydes to Esters: A Crucial Role of the Enone as Mediator, Org. Chem. Front., 2019, 通讯作者
(5) Cobalt-Catalyzed Intermolecular Hydroacylation of Aldehydes: Initiation of Hydride Transfer Enables Turnover, Org. Chem. Front., 2018, 通讯作者
(6) Cobalt/N-Hydroxyphthalimide(NHPI)-Catalyzed Aerobic Oxidation of Hydrocarbons with Ionic Liquid Additive, Mol. Catal., 2018, 通讯作者
(7) The Chitin/Keggin-type Heteropolyacid Hybrid Microspheres as Catalyst for Oxidation of Methacrolein to Methacrylic Acid., Chem Eng. J., 2018, 第 3 作者
(8) SiCl4-catalyzed/PR3-mediated b-C(sp3)-H functionalization of nitrones to a,b-unsaturated imines and aromatic heterocycles., Tetrahedron, 2018, 通讯作者
(9) A metal-free direct C(sp3)–H cyanation reaction with cyanobenziodoxolones, Org. Biomol. Chem., 2018, 第 3 作者
(10) Cobalt/N, N', N''‐Trihydroxyisocyanuric Acid (THICA)‐Catalyzed Aerobic Oxidative Esterification and Amidation of Aldehydes., Asian J. Org. Chem., 2018, 通讯作者
(11) A Modified Heteropoly Acid Catalyst with Cetyltrimethylammonium Bromide for Methacrolein to Methacrylic Acid, J. Ind. Eng. Chem., 2018, 第 4 作者
(12) Ionic Liquids as Bifunctional Cosolvents Enhanced CO2 Conversion Catalysed by NADH-dependent Formate Dehydrogenase, Catalysts, 2018, 第 2 作者
(13) Efficient Ionic Liquid–based platform for Multi-Enzymatic Conversion of Carbon Dioxide to Methanol., Green Chem., 2018, 第 8 作者
(14) Brnsted Acidic Ionic Liquids-Catalyzed Dehydrative Formation of Isosorbide from Sorbitol: Introduce a Continuous Process, Catal. Sci. Technol., 2017, 第 2 作者
(15) Oxidation of Aromatic Aldehydes to Esters: A Sulfate Radical Redox System, J. Org. Chem., 2017, 通讯作者
(16) Cs(NH4)xH3–xPMo11VO40 Catalyzed Selective Oxidation of Methacrolein to Methacrylic Acid: Effects of NH4+ on the Structure and Catalytic Activity, Ind. Eng. Chem. Res., 2017, 第 5 作者
(17) Cobalt(II)/TFA-Catalyzed Oxidative Esterification of Aldehydes/Alcohols: Dual Role of the Acid Co-Catalyst, Asian J. Org. Chem., 2017, 通讯作者
(18) Cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp3)–H bonds, Tetrahedron, 2017, 通讯作者
(19) Cobalt(Ⅱ)-Catalyzed Oxidative Esterification of Aldehydes: A Cooperative Effect between Cobalt and Iodide Ion., Org. Chem. Front., 2016, 通讯作者
(20) Cobalt-Catalyzed Dehydrogenative Coupling of Alcohols/Aldehydes and Amines: an Important Role of Hydration of Imines., Asian J. Org. Chem., 2016, 通讯作者
(21) Solvent Effect on the Debromination/Dehydrobromination of Bromo-damascone, Flavour Frag. J., 2016, 通讯作者
(22) Fixation of CO2 into cyclic cabonates catalyzed by ionic liquids: a multi-scale approach., Green Chemistry, 2015, 第 1 作者
(23) Reaction of 6-Dimethylaminopentafulvene with the Mes2P-CH2CH2-B(C6F5)2 Frustrated Lewis Pair, Chem. Eur. J., 2012, 第 1 作者
(24) Reaction of Frustrated Lewis Pairs with Ketones and Esters, Chem. Asian. J., 2012, 第 1 作者
(25) Alkenylborane-derived frustrated Lewis pairs: metal-free catalytic hydrogenation reactions of electron-deficient alkenes, Organometallics , 2012, 第 2 作者
(26) Reaction of Frustrated Lewis Pairs with Conjugated Ynones?Selective Metal-Free Catalytic Hydrogenation of the Carbon-Carbon Triple Bond, Angew. Chem., Int. Ed., 2011, 第 1 作者
(27) Reaction of Aminodihydropentalenes with HB(C6F5)2 ? The Crucial Role of Dihydrogen Elimination, J. Am. Chem. Soc., 2011, 第 1 作者
(28) 6-Dimethylaminopentafulvene as Lewis Base Component in Frustrated Lewis Pairs: Carbon-Carbon Coupling in FLP Chemistry, Organometallics , 2011, 第 1 作者
(29) Disulfuration and hydrosulfuration of an alkyne at a 1,2-dicarba-closo-dodecaborane-thiolate ligand, Dalton Trans., 2011, 第 2 作者
(30) Selective Carbon-Carbon Bond Activation by Strongly Electrophilic Boranes, Chem. Eur. J., 2010, 第 1 作者
(31) Zirconocene Complexes Bearing Novel 3-Dimethylamino-1,2-dihydropentalene Derived Ligand Systems, Dalton Trans., 2010, 第 1 作者
(32) Ferrocene-Substituted Dithio-o-Carborane Isomers: Influence on the Native Conformation of Myoglobin Protein, Chem. Eur. J., 2010, 第 2 作者
(33) Reactions of 16e CpCo Half-Sandwich Complexes Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dichalcogenolate Ligand with Ethynylferrocene and Dimethyl Acetylenedicarboxylate, Chem. Eur. J., 2008, 第 1 作者
(34) Cobalt(III)-Mediated Competitive Disulfuration and Hydrosulfuration of Terminal Alkynes, Inorg. Chem. , 2008, 第 1 作者
(35) Metal-Induced B-H Activation: Addition of Methyl Acetylene Monocarboxylate to CpCo Half-Sandwich Complexes Containing a Chelating 1,2-Dicarba-closo-dodecarbarane-1,2-dichalcogenolate Ligand, Organometallics, 2008, 第 1 作者
(36) Reactivity of CpCo 16e Half-Sandwich Complexes Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dichalcogenolate Ligand toward Phenylacetylene, Organometallics , 2007, 第 1 作者
(37) Dinuclear Ruthenium(I)/Ruthenium(III) Half-Sandwich Complexes Containing Bridging E-E (E = S, Se) ligand and Two Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligands and Their Reactivity with Alkynes, Organometallics, 2007, 第 2 作者

科研活动

   
科研项目
( 1 ) 面上基金, 主持, 国家级, 2015-01--2018-12
( 2 ) 反应过程电子传递原位分析仪, 主持, 部委级, 2016-03--2018-03
( 3 ) 烯烃与CO2羰基酯化反应的非贵金属催化剂及过程调控研究, 主持, 国家级, 2017-01--2019-12
( 4 ) 新型离子液体杂化材料的微纳结构、性能调控及分离新过程, 主持, 国家级, 2018-01--2021-12

指导学生

已指导学生

曹云丽  博士研究生  081702-化学工艺  

刘博  博士研究生  081701-化学工程  

朱德萍  硕士研究生  085216-化学工程  

李婷  硕士研究生  085216-化学工程  

现指导学生

杜一然  博士研究生  081701-化学工程  

马爽爽  博士研究生  081704-应用化学  

丁光荣  博士研究生  081701-化学工程  

李晓强  硕士研究生  081704-应用化学  

孙瑞  博士研究生  081704-应用化学  

栾力焜  硕士研究生  081701-化学工程