基本信息
康麒凯 男 硕导 杭州高等研究院
电子邮件： kangqikai@ucas.ac.cn
通信地址： 杭州市西湖区转塘街道象山支弄1号
邮政编码：
电子邮件： kangqikai@ucas.ac.cn
通信地址： 杭州市西湖区转塘街道象山支弄1号
邮政编码：
招生信息
招生专业
070303-有机化学
085600-材料与化工
070305-高分子化学与物理
085600-材料与化工
070305-高分子化学与物理
招生方向
金属有机化学，不对称催化，有机方法学
有机高分子材料
有机高分子材料
教育背景
2011-09--2016-07 中国科学院大学上海有机所 博士
2007-09--2011-06 南京理工大学化工学院 学士学位
2007-09--2011-06 南京理工大学化工学院 学士学位
工作经历
工作简历
2021-08~2022-04,西湖大学, 副研究员
2019-08~2021-07,西湖大学, 博士后
2019-03~2019-07,西湖大学, 助理研究员
2016-10~2018-12,日本京都大学, 博士后
2019-08~2021-07,西湖大学, 博士后
2019-03~2019-07,西湖大学, 助理研究员
2016-10~2018-12,日本京都大学, 博士后
专利与奖励
专利成果
（ 1 ） 一种酚和胺直接偶联合成芳胺化合物的方法, 发明专利, 2021, 第 3 作者, 专利号: CN113845492A
（ 2 ） 一种芳环苄位碳氢键选择性氘代的方法, 发明专利, 2021, 第 2 作者, 专利号: CN113563147A
（ 3 ） 具有光学活性的环己基噁唑啉配体的合成方法及其用途, 发明专利, 2018, 第 4 作者, 专利号: CN104926747B
（ 2 ） 一种芳环苄位碳氢键选择性氘代的方法, 发明专利, 2021, 第 2 作者, 专利号: CN113563147A
（ 3 ） 具有光学活性的环己基噁唑啉配体的合成方法及其用途, 发明专利, 2018, 第 4 作者, 专利号: CN104926747B
出版信息
发表论文
[1] Kang, QiKai, Li, Yuntong, Chen, Kai, Zhu, Hui, Wu, WenQiang, Lin, Yunzhi, Shi, Hang. Rhodium-Catalyzed Stereoselective Deuteration of Benzylic C-H Bonds via Reversible eta(6)-Coordination. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2022, 第 1 作者61(11): http://dx.doi.org/10.1002/anie.202117381.
[2] Chen, Kai, Kang, QiKai, Li, Yuntong, Wu, WenQiang, Zhu, Hui, Shi, Hang. Catalytic Amination of Phenols with Amines. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2022, 第 2 作者144(3): 1144-1151, http://dx.doi.org/10.1021/jacs.1c12622.
[3] Kang, QiKai, Shi, Hang. Catalytic Hydrogen Isotope Exchange Reactions in Late-Stage Functionalization. SYNLETT[J]. 2022, 第 1 作者33(4): 329-338, http://dx.doi.org/10.1055/a-1354-0367.
[4] Kang, QiKai, Lin, Yunzhi, Li, Yuntong, Xu, Lun, Li, Ke, Shi, Hang. Catalytic SNAr Hydroxylation and Alkoxylation of Aryl Fluorides. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2021, 第 1 作者60(37): 20391-20399, http://dx.doi.org/10.1002/anie.202106440.
[5] Kang, QiKai, Lin, Yunzhi, Li, Yuntong, Shi, Hang. Transition-Metal-Catalyzed Amination of Aryl Fluorides. SYNLETT[J]. 2020, 第 1 作者31(12): 1135-1139,
[6] Kang, QiKai, Lin, Yunzhi, Li, Yuntong, Shi, Hang. Ru(II)-Catalyzed Amination of Aryl Fluorides via eta(6)-Coordination. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2020, 第 1 作者142(8): 3706-3711, https://www.webofscience.com/wos/woscc/full-record/WOS:000517360400007.
[7] 康麒凯. Asymmetric Synthesis of α-Amino Acids by Organocatalytic Biomimetic Transamination. Org. Lett.[J]. 2019, 第 1 作者
[8] Kang, QiKai, Selvakumar, Sermadurai, Arumugam, Natarajan, Almansour, Abdulrahman I, Kumar, Raju Suresh, Maruoka, Keiji. Enantioselective Alkylation of N-Arylhydrazones Derived from -Keto Esters and Isatin Derivatives through Asymmetric Phase-Transfer Catalysis. CHEMISTRY-AN ASIAN JOURNAL[J]. 2018, 第 1 作者13(14): 1780-1783, https://www.webofscience.com/wos/woscc/full-record/WOS:000439497300003.
[9] Selvakumar, Sermadurai, Kang, QiKai, Arumugam, Natarajan, Almansour, Abdulrahman I, Kumar, Raju Suresh, Maruoka, Keiji. Hypervalent iodine(III) catalyzed radical hydroacylation of chiral alkylidenemalonates with aliphatic aldehydes under photolysis. TETRAHEDRON[J]. 2017, 第 2 作者73(40): 5841-5846, http://dx.doi.org/10.1016/j.tet.2017.08.018.
[10] Liu, QiongJie, Wang, Lijia, Kang, QiKai, Zhang, X Peter, Tang, Yong. Cy-SaBOX/Copper(II)-Catalyzed Highly Diastereo- and Enantioselective Synthesis of Bicyclic N,O Acetals. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2016, 第 3 作者55(32): 9220-9223, https://www.webofscience.com/wos/woscc/full-record/WOS:000383371800015.
[11] Kang, QiKai, Wang, Lijia, Liu, QiongJie, Li, JunFang, Tang, Yong. Asymmetric H2O-Nucleophilic Ring Opening of D-A Cyclopropanes: Catalyst Serves as a Source of Water. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2015, 第 1 作者137(46): 14594-14597, https://www.webofscience.com/wos/woscc/full-record/WOS:000366004700011.
[12] 康麒凯, 王丽佳, 郑中博, 李军方, 唐勇. Sidearm as a Control in the Asymmetric Ring Opening Reaction of Donor-Acceptor Cyclopropane. CHIN. J. CHEM.[J]. 2014, 第 1 作者32(8): 669-672, http://ir.sioc.ac.cn/handle/331003/39105.
[13] Li, Feng, Chen, Lin, Kang, Qikai, Cai, Jianguang, Zhu, Guangjun. Regioselective N-alkylation with alcohols for the preparation of 2-(N-alkylamino)quinazolines and 2-(N-alkylamino)pyrimidines. NEW JOURNAL OF CHEMISTRY[J]. 2013, 第 3 作者37(3): 624-631, https://www.webofscience.com/wos/woscc/full-record/WOS:000314973000013.
[14] Li, Feng, Shan, Haixia, Chen, Lin, Kang, Qikai, Zou, Po. Direct N-alkylation of amino-azoles with alcohols catalyzed by an iridium complex/base system. CHEMICAL COMMUNICATIONS[J]. 2012, 第 4 作者48(4): 603-605, https://www.webofscience.com/wos/woscc/full-record/WOS:000299019200037.
[15] Li, Feng, Kang, Qikai, Shan, Haixia, Chen, Lin, Xie, Jianjiang. Regioselective N-Alkylation of 2-Aminoimidazoles with Alcohols to 2-(N-Alkylamino)imidazoles Catalyzed by the Cp*IrCl22/K2CO3 System. EUROPEANJOURNALOFORGANICCHEMISTRY[J]. 2012, 第 2 作者2012(26): 5085-5092, https://www.webofscience.com/wos/woscc/full-record/WOS:000308294700027.
[16] Li, Feng, Shan, Haixia, Kang, Qikai, Chen, Lin. Regioselective N-alkylation of 2-aminobenzothiazoles with benzylic alcohols. CHEMICAL COMMUNICATIONS[J]. 2011, 第 3 作者47(17): 5058-5060, https://www.webofscience.com/wos/woscc/full-record/WOS:000289523000062.
[2] Chen, Kai, Kang, QiKai, Li, Yuntong, Wu, WenQiang, Zhu, Hui, Shi, Hang. Catalytic Amination of Phenols with Amines. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2022, 第 2 作者144(3): 1144-1151, http://dx.doi.org/10.1021/jacs.1c12622.
[3] Kang, QiKai, Shi, Hang. Catalytic Hydrogen Isotope Exchange Reactions in Late-Stage Functionalization. SYNLETT[J]. 2022, 第 1 作者33(4): 329-338, http://dx.doi.org/10.1055/a-1354-0367.
[4] Kang, QiKai, Lin, Yunzhi, Li, Yuntong, Xu, Lun, Li, Ke, Shi, Hang. Catalytic SNAr Hydroxylation and Alkoxylation of Aryl Fluorides. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2021, 第 1 作者60(37): 20391-20399, http://dx.doi.org/10.1002/anie.202106440.
[5] Kang, QiKai, Lin, Yunzhi, Li, Yuntong, Shi, Hang. Transition-Metal-Catalyzed Amination of Aryl Fluorides. SYNLETT[J]. 2020, 第 1 作者31(12): 1135-1139,
[6] Kang, QiKai, Lin, Yunzhi, Li, Yuntong, Shi, Hang. Ru(II)-Catalyzed Amination of Aryl Fluorides via eta(6)-Coordination. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2020, 第 1 作者142(8): 3706-3711, https://www.webofscience.com/wos/woscc/full-record/WOS:000517360400007.
[7] 康麒凯. Asymmetric Synthesis of α-Amino Acids by Organocatalytic Biomimetic Transamination. Org. Lett.[J]. 2019, 第 1 作者
[8] Kang, QiKai, Selvakumar, Sermadurai, Arumugam, Natarajan, Almansour, Abdulrahman I, Kumar, Raju Suresh, Maruoka, Keiji. Enantioselective Alkylation of N-Arylhydrazones Derived from -Keto Esters and Isatin Derivatives through Asymmetric Phase-Transfer Catalysis. CHEMISTRY-AN ASIAN JOURNAL[J]. 2018, 第 1 作者13(14): 1780-1783, https://www.webofscience.com/wos/woscc/full-record/WOS:000439497300003.
[9] Selvakumar, Sermadurai, Kang, QiKai, Arumugam, Natarajan, Almansour, Abdulrahman I, Kumar, Raju Suresh, Maruoka, Keiji. Hypervalent iodine(III) catalyzed radical hydroacylation of chiral alkylidenemalonates with aliphatic aldehydes under photolysis. TETRAHEDRON[J]. 2017, 第 2 作者73(40): 5841-5846, http://dx.doi.org/10.1016/j.tet.2017.08.018.
[10] Liu, QiongJie, Wang, Lijia, Kang, QiKai, Zhang, X Peter, Tang, Yong. Cy-SaBOX/Copper(II)-Catalyzed Highly Diastereo- and Enantioselective Synthesis of Bicyclic N,O Acetals. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2016, 第 3 作者55(32): 9220-9223, https://www.webofscience.com/wos/woscc/full-record/WOS:000383371800015.
[11] Kang, QiKai, Wang, Lijia, Liu, QiongJie, Li, JunFang, Tang, Yong. Asymmetric H2O-Nucleophilic Ring Opening of D-A Cyclopropanes: Catalyst Serves as a Source of Water. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2015, 第 1 作者137(46): 14594-14597, https://www.webofscience.com/wos/woscc/full-record/WOS:000366004700011.
[12] 康麒凯, 王丽佳, 郑中博, 李军方, 唐勇. Sidearm as a Control in the Asymmetric Ring Opening Reaction of Donor-Acceptor Cyclopropane. CHIN. J. CHEM.[J]. 2014, 第 1 作者32(8): 669-672, http://ir.sioc.ac.cn/handle/331003/39105.
[13] Li, Feng, Chen, Lin, Kang, Qikai, Cai, Jianguang, Zhu, Guangjun. Regioselective N-alkylation with alcohols for the preparation of 2-(N-alkylamino)quinazolines and 2-(N-alkylamino)pyrimidines. NEW JOURNAL OF CHEMISTRY[J]. 2013, 第 3 作者37(3): 624-631, https://www.webofscience.com/wos/woscc/full-record/WOS:000314973000013.
[14] Li, Feng, Shan, Haixia, Chen, Lin, Kang, Qikai, Zou, Po. Direct N-alkylation of amino-azoles with alcohols catalyzed by an iridium complex/base system. CHEMICAL COMMUNICATIONS[J]. 2012, 第 4 作者48(4): 603-605, https://www.webofscience.com/wos/woscc/full-record/WOS:000299019200037.
[15] Li, Feng, Kang, Qikai, Shan, Haixia, Chen, Lin, Xie, Jianjiang. Regioselective N-Alkylation of 2-Aminoimidazoles with Alcohols to 2-(N-Alkylamino)imidazoles Catalyzed by the Cp*IrCl22/K2CO3 System. EUROPEANJOURNALOFORGANICCHEMISTRY[J]. 2012, 第 2 作者2012(26): 5085-5092, https://www.webofscience.com/wos/woscc/full-record/WOS:000308294700027.
[16] Li, Feng, Shan, Haixia, Kang, Qikai, Chen, Lin. Regioselective N-alkylation of 2-aminobenzothiazoles with benzylic alcohols. CHEMICAL COMMUNICATIONS[J]. 2011, 第 3 作者47(17): 5058-5060, https://www.webofscience.com/wos/woscc/full-record/WOS:000289523000062.