基本信息
邱早早  女  硕导  中国科学院上海有机化学研究所
email: qiuzz@sioc.ac.cn
address: 上海市零陵路345号
postalCode:

招生信息

   
招生专业
085600-材料与化工
招生方向
金属有机化学

教育背景

2006-08--2010-07   香港中文大学   博士
2002-09--2005-06   兰州大学   硕士
1998-09--2002-06   兰州大学   学士

工作经历

   
工作简历
2020-08~现在, 中科院上海有机化学研究所, 研究员
2012-07~2020-07,中科院上海有机化学研究所, 副研究员
2010-08~2012-07,香港中文大学, 博士后
2006-08~2010-07,香港中文大学, 博士
2005-10~2006-06,中科院上海有机化学研究所, 研究实习员
2002-09~2005-06,兰州大学, 硕士
1998-09~2002-06,兰州大学, 学士
社会兼职
2020-01-01-今,上海市女科技工作者协会, 理事

专利与奖励

   
奖励信息
(1) 教育部高等学校科学研究优秀成果奖 自然科学二等奖, 二等奖, 部委级, 2019
(2) Thieme Chemistry Journals Award, 其他, 2018
(3) 上海市青年拔尖人才, , 省级, 2016
(4) 中科院卢嘉锡青年人才奖, 院级, 2014
(5) 中科院卓越青年科学家计划, 院级, 2014
(6) 上海市浦江人才, 省级, 2013

出版信息

   
发表论文
(1) Iridium-catalyzed regioselective B(3,6)-dialkenylation or B(4)-alkenylation of o-carboranes via B-H activation and 1,2-carbon migration of alkynes, CHEMICAL COMMUNICATIONS, 2023, 通讯作者
(2) 钯催化硼-碳和硼-杂原子键构建一锅法合成双官能团化邻-碳硼烷, Pd-Catalyzed One-Pot Synthesis of Difunctionalized o-Carboranes via Construction of B—C and B—Heteroatom Bonds, 化学学报, 2022, 第 2 作者
(3) Functionalization of o-carboranes via carboryne intermediates, Chemical Society Reviews, 2022, 第 1 作者
(4) Ir-catalyzed enantioselective B-H alkenylation for asymmetric synthesis of chiral-at-cage o-carboranes, NATURE COMMUNICATIONS, 2021, 通讯作者
(5) Pd-catalyzed selective tetrafunctionalization of diiodo-o-carboranes, CHEMICAL COMMUNICATIONS, 2021, 通讯作者
(6) A Strategy for Selective Catalytic B-H Functionalization of o-Carboranes, ACCOUNTS OF CHEMICAL RESEARCH, 2021, 第 1 作者
(7) Pd-Catalyzed sequential B(3)-I/B(4)-H bond activation for the synthesis of 3,4-benzo-o-carboranes, DALTON TRANSACTIONS, 2021, 通讯作者
(8) Catalytic Cage BH Functionalization of Carboranes via "Cage Walking" Strategy, ACS CATALYSIS, 2021, 第 2 作者
(9) Iridium-Catalyzed Regioselective B(3)-Alkenylation/B(3,6)-Dialkenylation of o-Carboranes by Direct B-H Activation, CHEMISTRY-A EUROPEAN JOURNAL, 2020, 通讯作者
(10) Recent Advances in Transition Metal-Promoted Multicomponent Cascade Reactions for Controlled Synthesis of Complex Carborane Derivatives, CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2020, 通讯作者
(11) 过渡金属促进的多组分串联反应用于合成复杂碳硼烷衍生物的研究进展, Recent Advances in Transition Metal-Promoted Multicomponent Cascade Reactions for Controlled Synthesis of Complex Carborane Derivatives, 有机化学, 2020, 第 2 作者
(12) Palladium-catalyzed intramolecular dehydrogenative coupling of BH and OH: synthesis of carborane-fused benzoxaboroles, DALTON TRANSACTIONS, 2020, 通讯作者
(13) Palladium-Catalyzed Oxidative Annulation of 1-Hydroxy-o-Carborane with Internal Alkynes: Facile Synthesis of Carborane-Fused Oxaboroles, CHINESE JOURNAL OF CHEMISTRY, 2020, 通讯作者
(14) Pd-Catalyzed Selective Bifunctionalization of 3-Iodo-o-Carborane by Pd Migration, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 通讯作者
(15) Jasmonate-mediated wound signalling promotes plant regeneration, NATURE PLANTS, 2019, 第 9 作者
(16) Synthesis of carborane-fused carbo- and heterocycles via zirconacyclopentane intermediates, DALTON TRANSACTIONS, 2018, 通讯作者
(17) Enantioselective Synthesis of Chiral-at-Cage o-Carboranes via Pd-Catalyzed Asymmetric B-H Substitution, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 通讯作者
(18) Reaction of o-Carboryne with Furans: Facile Synthesis of Carborane- Fused Oxanorbornenes and Their Derivatives, Reaction of o-Carboryne with Furans: Facile Synthesis of Carborane- Fused Oxanorbornenes and Their Derivatives, 中国化学:英文版, 2018, 第 3 作者
(19) 钯催化硼基化邻-碳硼烷偶联反应制备3,6-双芳基-邻-碳硼烷, Palladium-Catalyzed Cross-Coupling Reactions of Borylated o-Carborane:Synthesis of 3,6-Diaryl-o-carboranes, 有机化学, 2018, 第 3 作者
(20) Reaction of o-Carboryne with Furans: Facile Synthesis of Carborane- Fused Oxanorbornenes and Their Derivatives, CHINESE JOURNAL OF CHEMISTRY, 2018, 通讯作者
(21) Transition-Metal-Catalyzed Selective Cage B-H Functionalization of o-Carboranes, CHEMISTRYAEUROPEANJOURNAL, 2018, 第 2 作者
(22) Palladium-Catalyzed Cross-Coupling Reactions of Borylated o-Carborane: Synthesis of 3,6-Diaryl-o-carboranes, CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2018, 通讯作者
(23) 钯催化硼基化邻-碳硼烷偶联反应制备3,6-双芳基-邻-碳硼烷, Palladium-Catalyzed Cross-Coupling Reactions of Borylated o-Carborane:Synthesis of 3,6-Diaryl-o-carboranes, 有机化学, 2018, 第 3 作者
(24) Iridium-catalysed regioselective borylation of carboranes via direct B–H activation, NATURE COMMUNICATIONS, 2017, 通讯作者
(25) Reactivity of mixed-sandwich zirconacarborane alkyls with polar unsaturated molecules, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 第 2 作者
(26) Photoarylation of Iodocarboranes with Unactivated (Hetero) Arenes: Facile Synthesis of 1,2-( Hetero)Aryl(n)-o-Carboranes (n=1,2) and o- Carborane-Fused Cyclics, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 第 2 作者
(27) Broad Scope 4+2 Cycloaddition of o-Carboryne with Pentafulvenes Using 1-Li-2-OTf-o-C2B10H10 as Precursor, ORGANOMETALLICS, 2017, 通讯作者
(28) Facile Synthesis of N-Carboranyl Amines through an ortho-Carboryne Intermediate, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 通讯作者
(29) Synthesis, structure, and reactivity of mixed-sandwich zirconacarborane methyl complex (eta(5)-C5Me5)eta(1):eta(5)-(Me2NCH2CH2)C2B9H10ZrMe, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2016, 第 2 作者
(30) Synthesis, structure, and reactivity of mixed-sandwich zirconacarborane methyl complex (η5-C5Me5)η1:η5-(Me2NCH2CH2)C2B9H10ZrMe, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2016, 第 2 作者
(31) Recent advances in transition metal-mediated functionalization of o -carboranes, TETRAHEDRON LETTERS, 2015, 通讯作者
(32) Synthesis, structure, and alkyne insertion of a mixed-sandwich zirconacarborane alkyl, INORGANIC CHEMISTRY FRONTIERS, 2015, 第 2 作者
(33) Synthesis of carborane-fused cyclobutenes and cyclobutanes, SCIENCE CHINA-CHEMISTRY, 2014, 第 3 作者
(34) Generation and reactivity of o-carborynes, DALTON TRANSACTIONS, 2014, 通讯作者
(35) Transition-Metal-Mediated Three-Component Cascade Cyclization: Selective Cage B-C(sp(2)) Coupling of Carborane with Aromatics and Synthesis of Carborane-Fused Tricyclics, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 第 2 作者
(36) Diels-Alder Reaction of o-Carboryne with Fulvenes: Synthesis of Carboranonorbornadienes and Their Transformations, CHEMPLUSCHEM, 2014, 通讯作者
(37) Synthesis of Neutral Group 4 Metal-Carboryne Complexes and Their Reactivity toward Unsaturated Molecules, ORGANOMETALLICS, 2013, 第 2 作者
(38) Reaction of Li2C2B10Me8H2 with NiCl2. Ligand effects on stability ofNi-octamethylcarboryne complexes, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2013, 第 1 作者
(39) Palladium-Catalyzed Selective Fluorination of o-Carboranes, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 第 1 作者
(40) Three-Component 2+2+2 Cycloaddition of Carboryne, Unactivated Alkene, and Alkyne via Zirconacyclopentane Mediated by Nickel: One-Pot Synthesis of Dihydrobenzocarboranes, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 第 2 作者
(41) Synthesis, structural characterization, and reactivity of late transition-metal complexes bearing linked cyclopentadienyl-carboranyl ligands, CANADIAN JOURNAL OF CHEMISTRY, 2012, 第 2 作者
(42) Reaction of Zirconocene-Carboryne with Alkenes: Synthesis and Structure of Zirconacyclopentanes with a Carborane Auxiliary, ORGANOMETALLICS, 2012, 第 2 作者
(43) Synthesis, structure and properties of mixed-sandwich cobalta- and ferra-carboranes with ‘carbon-atoms-adjacent’ C2B9 and C2B10 systems, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2012, 第 1 作者
(44) η^5:σ-Me2c(C5H4)(C2B10H10)Ru(NCCH3)2与中间炔的反应--钌环丁二烯和钌杂环戊三烯配合物的合成与结构, 中国科学:化学, 2011, 第 1 作者
(45) Synthesis and Reaction of Neutral and Cationic Alkyltantalum Complexes with a Linked Cyclopentadienyl-Carboranyl Ligand, ORGANOMETALLICS, 2011, 第 2 作者
(46) Reaction of eta(5):sigma-Me2C(C5H4)(C2B10H10)Ru(NCCH3)(2) with internal alkynes: Synthesis and structural characterization of ruthenium-cyclobutadiene and ruthenacyclopentatriene complexes, SCIENCE CHINA-CHEMISTRY, 2010, 第 1 作者
(47) Synthesis and Structural Characterization of Group 10 Metal-Carboryne Complexes, ORGANOMETALLICS, 2010, 第 1 作者
(48) Reaction of η5: Me_2C(C_5H_4)(C_2B_(10)H_(10))Ru(NCCH3)2 with internal alkynes: Synthesis and structural characterization of ruthenium-cyclobutadiene and ruthenacyclopentatriene complexes, SCIENCE CHINA. CHEMISTRY, 2010, 第 1 作者
(49) 碳硼烷和碳硼炔金属配合物中金属-碳键的化学性质, Unique chemical properties of metal-carbon bonds in metal-carboranyl and metal-carboryne complexes, 中国科学:B辑, 2009, 第 1 作者
(50) Nickel-Mediated Three-Component Cycloaddition Reaction of Carboryne, Alkenes, and Alkynes, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 第 1 作者
(51) 碳硼烷和碳硼炔金属配合物中金属-碳键的化学性质, Unique chemical properties of metal-carbon bonds in metal-carboranyl and metal-carboryne complexes, 中国科学:B辑, 2009, 第 1 作者
(52) Unique chemical properties of metal-carbon bonds in metal-carboranyl and metal-carboryne complexes, SCIENCE IN CHINA SERIES B-CHEMISTRY, 2009, 第 1 作者
(53) Unique chemical properties of metal-carbon bonds in metal-carboranyl and metal-carboryne complexes, SCIENCE IN CHINA SERIES B-CHEMISTRY, 2009, 第 1 作者
(54) Nickel-mediated coupling reactions of carboryne with alkenes: A synthetic route to alkenylcarboranes, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 第 1 作者
(55) 6'-O-取代的薯蓣类衍生物的合成及细胞毒性, 溶血活性研究, Synthesis, cytotoxicity, and hemolytic activity of 6’-O-substituted dioscin derivatives., CARBOHYDR. RES., 2007, 第 2 作者
(56) Synthesis, cytotoxicity, and hemolytic activity of 6′-O-substituted dioscin derivatives, CARBOHYDRATE RESEARCH, 2007, 第 2 作者
(57) 3-杂环基硫取代-1,3,4,5.四氢-2-氧代-苯并氮杂艹卓衍生物的合成, Synthesis of 3-Thioheterocycloyl-1,3,4,5-tetrahdro- 2-oxo- 1 H-benazepine, 有机化学, 2007, 第 1 作者
(58) 3-杂环基硫取代-1,3,4,5-四氢-2-氧代-苯并氮(上艹下卓)杂衍生物的合成, Synthesis of 3-Thioheterocycloyl-1,3,4,5-tetrahdro-2-oxo- 1H-benazepine, CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2007, 通讯作者

科研活动

   
科研项目
( 1 ) 手性碳硼烷的不对称催化合成与应用研究, 负责人, 国家任务, 2021-01--2023-12