081705-工业催化

羰基化反应，选择加氢，单原子催化

2008-09--2014-07   中国科学院大连化学物理研究所   博士
2004-09--2008-06   兰州大学   学士

   

2018-07~现在, 中国科学院大连化学物理研究所, 副研究员
2014-07~2018-07,中国科学院大连化学物理研究所, 助理研究员

   

[1] 王爱琴, 虞周楠, 张磊磊, 张盛鑫, 张涛. 一种负载型Rh单原子催化剂在烯烃氢甲酰化反应中的应用. CN: CN114163318A, 2022-03-11.
[2] 王爱琴, 任煜京, 张磊磊, 张涛. 负载型单原子分散贵金属催化剂的制备方法. CN: CN111135840B, 2021-11-23.
[3] 王爱琴, 任煜京, 张磊磊, 张涛. 高分散贵金属负载催化剂在芳香硝基化合物加氢中应用. CN: CN111135822B, 2021-11-09.
[4] 张磊磊, 王爱琴, 张涛. 一种合成α，β不饱和酮的方法. CN: CN113480419A, 2021-10-08.
[5] 王爱琴, 张磊磊, 张涛. 一种负载型催化剂在烯烃羰基化合成酮反应中的应用. CN: CN112979440A, 2021-06-18.
[6] 王爱琴, 张磊磊, 张涛. 一种负载型催化剂在烯烃氢甲酰化反应中的应用. CN: CN112973678A, 2021-06-18.
[7] 王爱琴, 王安, 任煜京, 张磊磊, 张涛. 一种负载型单原子贵金属催化剂在不饱和烃羧甲酯化反应中的应用. CN: CN112830877A, 2021-05-25.
[8] 王爱琴, 任煜京, 张磊磊, 张涛. 负载型单原子分散贵金属催化剂及制备方法. CN: CN111215053A, 2020-06-02.
[9] 王爱琴, 张帆, 张磊磊, 张涛. 一种负载型M 1 -M 2 -载体双功能催化剂及其制备方法和应用. CN: CN109833871A, 2019-06-04.
[10] 张磊磊, 王爱琴, 张涛, 刘文刚. 一种负载型非贵金属催化剂及其制备和应用. CN: CN108114723A, 2018-06-05.
[11] 王爱琴, 刘文刚, 张涛, 张涛. 一种负载型非贵金属催化剂及其制备和应用. CN: CN108114723A, 2018-06-05.
[12] 张磊磊, 王爱琴, 张涛, 刘文刚. 一种负载型Fe基催化剂及其制备和应用. CN: CN108114722A, 2018-06-05.
[13] 刘晓艳, 谭媛, 张磊磊, 刘菲, 王爱琴, 张涛. 一种高效催化不饱和醛酮选择加氢生成不饱和醇的金原子簇催化剂. CN: CN107857692A, 2018-03-30.
[14] 王爱琴, 刘文刚, 张磊磊, 张涛. 一种负载型非贵金属催化剂及其制备和在腈合成上的应用. CN: CN106881131A, 2017-06-23.
[15] 刘晓艳, 裴广贤, 王爱琴, 张涛, 张磊磊. 一种含镍的合金催化剂在炔烃选择加氢反应中的应用. CN: CN106861715A, 2017-06-20.
[16] 刘晓艳, 谭媛, 王爱琴, 张涛, 张磊磊. 一种负载型金原子簇催化剂的应用. CN: CN105985208A, 2016-10-05.
[17] 张磊磊, 王爱琴, 张涛. 一种负载型金钯催化剂及其制备和应用. CN: CN102806105A, 2012-12-05.

   

[1] Leilei Zhang, Aiqin Wang. Site density as an approach to regulating single-atom catalysis. CHEM CATALYSIS. 2023, 3(5): http://dx.doi.org/10.1016/j.checat.2023.100620.
[2] Leilei Zhang, Ji Yang, Xiaofeng Yang, Aiqin Wang, Tao Zhang. Structural evolution of single-atom catalysts. CHEM CATALYSIS. 2023, 3(3): http://dx.doi.org/10.1016/j.checat.2023.100560.
[3] Zhou, Dan, Zhang, Leilei, Liu, Xiaoyan, Qi, Haifeng, Liu, Qinggang, Yang, Ji, Su, Yang, Ma, Jingyuan, Yin, Jianzhong, Wang, Aiqin. Tuning the coordination environment of single-atom catalyst M-N-C towards selective hydrogenation of functionalized nitroarenes. NANO RESEARCH[J]. 2022, 15(1): 519-527, http://apps.webofknowledge.com/CitedFullRecord.do?product=UA&colName=WOS&SID=5CCFccWmJJRAuMzNPjj&search_mode=CitedFullRecord&isickref=WOS:000660374800002.
[4] Shi, Jiajia, Wei, Yao, Zhou, Dan, Zhang, Leilei, Yang, Xiaofeng, Miao, Zhili, Qi, Haifeng, Zhang, Shengxin, Li, Anqi, Liu, Xiaoyan, Yan, Wensheng, Jiang, Zheng, Wang, Aiqin, Zhang, Tao. Introducing Co-O Moiety to Co-N-C Single-Atom Catalyst for Ethylbenzene Dehydrogenation. ACS CATALYSIS. 2022, http://dx.doi.org/10.1021/acscatal.2c01873.
[5] Zhang, Yue, Li, Lin, Liu, Fei, Qi, Haifeng, Zhang, Leilei, Guan, Weixiang, Liu, Yuefeng, Wang, Aiqin, Zhang, Tao. Synergy between Ru and WOxEnables EfficientHydrodeoxygenation of Primary Amides to Amines. ACS CATALYSIS[J]. 2022, 12(11): 6302-6312, [6] Yang, Ji, Qi, Haifeng, Li, Anqi, Liu, Xiaoyan, Yang, Xiaofeng, Zhang, Shengxin, Zhao, Qiao, Jiang, Qike, Su, Yang, Zhang, Leilei, Li, JianFeng, Tian, ZhongQun, Liu, Wei, Wang, Aiqin, Zhang, Tao. Potential-Driven Restructuring of Cu Single Atoms to Nanoparticles for Boosting the Electrochemical Reduction of Nitrate to Ammonia. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2022, 144(27): 12062-12071, [7] Zhou, Dan, Zhang, Leilei, Liu, Wengang, Xu, Gang, Yang, Ji, Jiang, Qike, Wang, Aiqin, Yin, Jianzhong. Reaction kinetics and phase behavior in the chemoselective hydrogenation of 3-nitrostyrene over Co-N-C single-atom catalyst in compressed CO2. CHINESE JOURNAL OF CATALYSIS[J]. 2021, 42(9): 1617-1624, http://dx.doi.org/10.1016/S1872-2067(20)63785-8.
[8] Tan, Yuan, Liu, Xiaoyan, Zhang, Leilei, Liu, Fei, Wang, Aiqin, Zhang, Tao. Producing of cinnamyl alcohol from cinnamaldehyde over supported gold nanocatalyst. CHINESE JOURNAL OF CATALYSIS[J]. 2021, 42(3): 470-481, http://dx.doi.org/10.1016/S1872-2067(20)63678-6.
[9] 谭媛, 刘晓艳, 张磊磊, 刘菲, 王爱琴, 张涛. 纳米金催化肉桂醛选择加氢制肉桂醇（英文）. CHINESE JOURNAL OF CATALYSIS. 2021, 470-481, https://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFDLAST2021&filename=CHUA202103012&v=MzIxOTBoMVQzcVRyV00xRnJDVVI3dWZZZWRuRkNybVZMdktKaVhlYjdHNEhORE1ySTlFWm9SOGVYMUx1eFlTN0Q=.
[10] Qi, Haifeng, Zhang, Leilei, Yang, Jingyi, Su, Yang, Zeng, Guang, Wang, Aiqin, Zhang, Tao. Highly efficient Co single-atom catalyst for epoxidation of plant oils. JOURNAL OF CHEMICAL PHYSICS[J]. 2021, 154(13): https://www.webofscience.com/wos/woscc/full-record/WOS:000636821700003.
[11] Liu, Qiaoyun, Qiao, Botao, Liu, Fei, Zhang, Leilei, Su, Yang, Wang, Aiqin, Zhang, Tao. Catalytic production of 1,4-pentanediol from furfural in a fixed-bed system under mild conditions (vol 22, pg 3532, 2020). GREEN CHEMISTRYnull. 2020, 22(15): 5179-5179, http://dx.doi.org/10.1039/d0gc90075c.
[12] Qi, Haifeng, Liu, Fei, Zhang, Leilei, Li, Lin, Su, Yang, Yang, Jingyi, Hao, Rui, Wang, Aiqin, Zhang, Tao. Modulating trans-imination and hydrogenation towards the highly selective production of primary diamines from dialdehydes. GREEN CHEMISTRY[J]. 2020, 22(20): 6897-6901, https://www.webofscience.com/wos/woscc/full-record/WOS:000579757000018.
[13] Zhang, Leilei, Zhou, Maoxiang, Wang, Aiqin, Zhang, Tao. Selective Hydrogenation over Supported Metal Catalysts: From Nanoparticles to Single Atoms. CHEMICAL REVIEWSnull. 2020, 120(2): 683-733, https://www.webofscience.com/wos/woscc/full-record/WOS:000509426800005.
[14] Yujing Ren, Yan Tang, Leilei Zhang, Xiaoyan Liu, Lin Li, Shu Miao, Dang Sheng Su, Aiqin Wang, Jun Li, Tao Zhang. Unraveling the coordination structure-performance relationship in Pt-1/Fe2O3 single-atom catalyst. NATURE COMMUNICATIONS[J]. 2019, 10(1): https://doaj.org/article/a66b003a03564c0aa00f8da44b8277e5.
[15] Yang, Man, Qi, Haifeng, Liu, Fei, Ren, Yujing, Pan, Xiaoli, Zhang, Leilei, Liu, Xiaoyan, Wang, Hua, Pang, Jifeng, Zheng, Mingyuan, Wang, Aiqin, Zhang, Tao. One-Pot Production of Cellulosic Ethanol via Tandem Catalysis over a Multifunctional Mo/Pt/WOx Catalyst. JOULE[J]. 2019, 3(8): 1937-1948, http://dx.doi.org/10.1016/j.joule.2019.05.020.
[16] Tang, Hailian, Su, Yang, Guo, Yalin, Zhang, Leilei, Li, Tianbo, Zang, Ketao, Liu, Fei, Li, Lin, Luo, Jun, Qiao, Botao, Wang, Junhu. Oxidative strong metal-support interactions (OMSI) of supported platinum-group metal catalysts. CHEMICAL SCIENCE[J]. 2018, 9(32): 6679-6684, https://www.webofscience.com/wos/woscc/full-record/WOS:000442605300011.
[17] Zhang, Leilei, Ren, Yujing, Liu, Wengang, Wang, Aiqin, Zhang, Tao. Single-atom catalyst: a rising star for green synthesis of fine chemicals. NATIONAL SCIENCE REVIEW[J]. 2018, 5(5): 653-672, http://lib.cqvip.com/Qikan/Article/Detail?id=6100230339.
[18] Chen, Fang, Jiang, Xunzhu, Zhang, Leilei, Lang, Rui, Qiao, Botao. Single-atom catalysis: Bridging the homo- and heterogeneous catalysis. CHINESE JOURNAL OF CATALYSIS[J]. 2018, 39(5): 893-898, http://cas-ir.dicp.ac.cn/handle/321008/167140.
[19] Liu, Wengang, Chen, Yinjuan, Qi, Haifeng, Zhang, Leilei, Yan, Wensheng, Liu, Xiaoyan, Yang, Xiaofeng, Miao, Shu, Wang, Wentao, Liu, Chenguang, Wang, Aiqin, Li, Jun, Zhang, Tao. A Durable Nickel Single-Atom Catalyst for Hydrogenation Reactions and Cellulose Valorization under Harsh Conditions. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2018, 57(24): 7071-7075, http://dx.doi.org/10.1002/anie.201802231.
[20] Liu, Wengang, Zhang, Leilei, Liu, Xin, Liu, Xiaoyan, Yang, Xiaofeng, Miao, Shu, Wang, Wentao, Wang, Aiqin, Zhang, Tao. Discriminating Catalytically Active FeNx Species of Atomically Dispersed Fe-N-C Catalyst for Selective Oxidation of the C-H Bond. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2017, 139(31): 10790-10798, http://cas-ir.dicp.ac.cn/handle/321008/149816.
[21] Pei, Guang Xian, Liu, Xiao Yan, Yang, Xiaofeng, Zhang, Leilei, Wang, Aiqin, Li, Lin, Wang, Hua, Wang, Xiaodong, Zhang, Tao. Performance of Cu-Alloyed Pd Single-Atom Catalyst for Semihydrogenation of Acetylene under Simulated Front-End Conditions. ACS CATALYSIS[J]. 2017, 7(2): 1491-1500, http://cas-ir.dicp.ac.cn/handle/321008/169642.
[22] Tan, Yuan, Liu, Xiao Yan, Zhang, Leilei, Wang, Aiqin, Li, Lin, Pan, Xiaoli, Miao, Shu, Haruta, Masatake, Wei, Haisheng, Wang, Hua, Wang, Fangjun, Wang, Xiaodong, Zhang, Tao. ZnAl-Hydrotalcite-Supported Au-25 Nanoclusters as Precatalysts for Chemoselective Hydrogenation of 3-Nitrostyrene. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2017, 56(10): 2709-2713, http://cas-ir.dicp.ac.cn/handle/321008/169614.
[23] Chai, Meng Qian, Tan, Yuan, Pei, Guang Xian, Li, Lin, Zhang, Leilei, Liu, Xiao Yan, Wang, Aiqin, Zhang, Tao. Crystal Plane Effect of ZnO on the Catalytic Activity of Gold Nanoparticles for the Acetylene Hydrogenation Reaction. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2017, 121(36): 19727-19734, http://cas-ir.dicp.ac.cn/handle/321008/150171.
[24] Yang, Jinfan, Li, Shanshan, Zhang, Leilei, Liu, Xiaoyan, Wang, Junhu, Pan, Xiaoli, Li, Ning, Wang, Aiqin, Cong, Yu, Wang, Xiaodong, Zhang, Tao. Hydrodeoxygenation of furans over Pd-FeOx/SiO2 catalyst under atmospheric pressure. APPLIED CATALYSIS B-ENVIRONMENTAL[J]. 2017, 201: 266-277, http://cas-ir.dicp.ac.cn/handle/321008/169936.
[25] Ren, Yujing, Wei, Haisheng, Yin, Guangzhao, Zhang, Leilei, Wang, Aiqin, Zhang, Tao. Oxygen surface groups of activated carbon steer the chemoselective hydrogenation of substituted nitroarenes over nickel nanoparticles. CHEMICAL COMMUNICATIONS[J]. 2017, 53(12): 1969-1972, http://cas-ir.dicp.ac.cn/handle/321008/169512.
[26] Wei, Haisheng, Ren, Yujing, Wang, Aiqin, Liu, Xiaoyan, Liu, Xin, Zhang, Leilei, Miao, Shu, Li, Lin, Liu, Jingyue, Wang, Junhu, Wang, Guofu, Su, Dangsheng, Zhang, Tao. Remarkable effect of alkalis on the chemoselective hydrogenation of functionalized nitroarenes over high-loading Pt/FeOx catalysts. CHEMICAL SCIENCE[J]. 2017, 8(7): 5126-5131, https://www.webofscience.com/wos/woscc/full-record/WOS:000404617300050.
[27] Liu, Wengang, Zhang, Leilei, Yan, Wensheng, Liu, Xiaoyan, Yang, Xiaofeng, Miao, Shu, Wang, Wentao, Wang, Aiqin, Zhang, Tao. Single-atom dispersed Co-N-C catalyst: structure identification and performance for hydrogenative coupling of nitroarenes. CHEMICAL SCIENCE[J]. 2016, 7(9): 5758-5764, http://www.corc.org.cn/handle/1471x/2375170.
[28] 周茂祥, 张磊磊, Jeffrey, T., MILLER, 杨小峰, 刘晓艳, 王爱琴, 张涛. Au6Pd／resin催化伯醇和仲醇氧化偶联一转移加氢反应制备酮类化合物. 催化学报[J]. 2016, 37(10): 1764-1770, http://lib.cqvip.com/Qikan/Article/Detail?id=670385601.
[29] Zhou, Maoxiang, Zhang, Leilei, Miller, Jeffrey T, Yang, Xiaofeng, Liu, Xiaoyan, Wang, Aiqin, Zhang, Tao. Hydrogen auto-transfer under aerobic oxidative conditions: Efficient synthesis of saturated ketones by aerobic C-C cross-coupling of primary and secondary alcohols catalyzed by a Au6Pd/resin catalyst. CHINESE JOURNAL OF CATALYSIS[J]. 2016, 37(10): 1764-1770, http://cas-ir.dicp.ac.cn/handle/321008/169836.
[30] Zhang, Leilei, Wang, Aiqin, Wang, Wentao, Huang, Yanqiang, Liu, Xiaoyan, Miao, Shu, Liu, Jingyue, Zhang, Tao. Co-N-C Catalyst for C-C Coupling Reactions: On the Catalytic Performance and Active Sites. ACS CATALYSIS[J]. 2015, 5(11): 6563-6572, http://cas-ir.dicp.ac.cn/handle/321008/148226.
[31] 刘晓艳, 魏海生, 王爱琴, 张磊磊, 张涛. XAS Characterization of FeOx-Supported Platinum Single-Atom and Pseudo-Single-Atom Catalysts for Chemoselective Hydrogenation of Functionalized Nitroarenes. 16th international conference on x-ray absorption structurenull. 2015, http://cas-ir.dicp.ac.cn/handle/321008/143401.
[32] Wei, Haisheng, Liu, Xiaoyan, Wang, Aiqin, Zhang, Leilei, Qiao, Botao, Yang, Xiaofeng, Huang, Yanqiang, Miao, Shu, Liu, Jingyue, Zhang, Tao. FeOx-supported platinum single-atom and pseudo-single-atom catalysts for chemoselective hydrogenation of functionalized nitroarenes. NATURE COMMUNICATIONS[J]. 2014, 5(1): http://cas-ir.dicp.ac.cn/handle/321008/143945.
[33] Wang, Wentao, Cong, Yu, Zhang, Leilei, Huang, Yanqiang, Wang, Xiaodong, Zhang, Tao. Aerobic oxidative transformation of primary alcohols and amines to amides promoted by a hydroxyapatite-supported gold catalyst in water. TETRAHEDRON LETTERS[J]. 2014, 55(1): 124-127, http://dx.doi.org/10.1016/j.tetlet.2013.10.133.
[34] Zhang, Leilei, Wang, Aiqin, Miller, Jeffrey T, Liu, Xiaoyan, Yang, Xiaofeng, Wang, Wentao, Li, Lin, Huang, Yanqiang, Mou, ChungYuan, Zhang, Tao. Efficient and Durable Au Alloyed Pd Single-Atom Catalyst for the Ullmann Reaction of Aryl Chlorides in Water. ACS CATALYSIS[J]. 2014, 4(5): 1546-1553, http://cas-ir.dicp.ac.cn/handle/321008/145828.
[35] 张磊磊, 王文涛, 王爱琴, 刘晓艳, 杨小峰, 张涛. Green synthesis of amide and imine through aerobic oxidative coupling of alcohol and amine over Au-Pd/resin. the 6th aisa-pacific congress on catalysisnull. 2013, 83-, http://159.226.238.44/handle/321008/120210.
[36] Zhang, Leilei, Wang, Wentao, Wang, Aiqin, Cui, Yitao, Yang, Xiaofeng, Huang, Yanqiang, Liu, Xiaoyan, Liu, Wengang, Son, JinYoung, Oji, Hiroshi, Zhang, Tao. Aerobic oxidative coupling of alcohols and amines over Au-Pd/resin in water: Au/Pd molar ratios switch the reaction pathways to amides or imines. GREEN CHEMISTRY[J]. 2013, 15(10): 2680-2684, http://159.226.238.44/handle/321008/119449.
[37] 张磊磊, 王爱琴, 黄延强, 张涛. A highly efficient ion-exchange resin supported Au-Pd alloy catalyst for Suzuki cross-coupling and Ullmann reactions in water. 15TH INTERNATION CONGRESS ON CATALYSISnull. 2012, 0-, http://159.226.238.44/handle/321008/117184.

   

（ 1 ） 氢甲酰化反应高选择性、抗流失单原子催化剂的研制, 负责人, 国家任务, 2022-01--2025-12
（ 2 ） 乙烯/乙炔羧酯化反应多功能单原子催化剂的构筑, 参与, 国家任务, 2022-01--2026-12
（ 3 ） 用于长链烯烃羰基化反应的单原子催化剂创制, 参与, 国家任务, 2022-01--2026-12