基本信息
张纯喜  男  博导  中国科学院化学研究所
电子邮件: chunxizhang@iccas.ac.cn
通信地址: 北京中关村北一街2号
邮政编码: 100190

招生信息

   
招生专业
070304-物理化学
070301-无机化学
招生方向
生物和人工光合成作用;金属酶催化中心结构、机理及其模拟
金属酶催化中心的结构、机理及其模拟

专利与奖励

   
专利成果
( 1 ) 含稀土离子的仿生水裂解催化剂及其制备方法和应用, 2023, 第 1 作者, 专利号: CN115710292A

( 2 ) 含有Mn 3 SrO 4 和Mn 4 SrO 4 核心结构的簇合物及其制备方法和应用, 2019, 第 1 作者, 专利号: CN109748939A

( 3 ) 一种含有Mn 4 CaO 4 核心结构的水裂解催化剂,其制备方法及其应用, 2015, 第 1 作者, 专利号: CN104761591A

( 4 ) 一种含有Mn 4 CaO 4 核心结构的水裂解催化剂,其制备方法及其应用, 2015, 第 1 作者, 专利号: CN104761591A

( 5 ) 一种多苯并咪唑铁配合物,其制备方法及其应用, 2013, 第 1 作者, 专利号: CN103204882A

出版信息

   
发表论文
(1) Mimicking the Oxygen-Evolving Center in Photosynthesis, FRONTIERS IN PLANT SCIENCE, 2022, 第 5 作者  通讯作者
(2) Redox-Induced Structural Change in Artificial Heterometallic-Oxide Cluster Mimicking the Photosynthetic Oxygen-Evolving Center, CHEMISTRY-A EUROPEAN JOURNAL, 2022, 第 5 作者  通讯作者
(3) Synthesizing Mechanism of the Mn4Ca Cluster Mimicking the Oxygen-Evolving Center in Photosynthesis, CHEMSUSCHEM, 2022, 第 5 作者  通讯作者
(4) A Novel Attitude Measurement While Drilling System Based on Single-Axis Fiber Optic Gyroscope, IEEETRANSACTIONSONINSTRUMENTATIONANDMEASUREMENT, 2022, 第 2 作者
(5) Structural Reorganization of a Synthetic Mimic of the Oxygen-Evolving Center in Multiple Redox Transitions Revealed by Electrochemical FTIR Spectra, JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2021, 第 4 作者
(6) 光合作用放氧反应, Photosynthetic oxygen-evolving reaction, 自然杂志, 2021, 第 1 作者
(7) Rare-Earth Elements Can Structurally and Energetically Replace the Calcium in a Synthetic Mn4CaO4-Cluster Mimicking the OxygenEvolving Center in Photosynthesis, JOURNALOFTHEAMERICANCHEMICALSOCIETY, 2021, 第 6 作者  通讯作者
(8) Mimicking the Catalytic Center for the Water-Splitting Reaction in Photosystem II, CATALYSTS, 2020, 第 6 作者  通讯作者
(9) alpha-Lys(424) Participates in Insertion of FeMoco to MoFe Protein and Maintains Nitrogenase Activity in Klebsiella oxytoca M5al, FRONTIERS IN MICROBIOLOGY, 2019, 第 5 作者
(10) Proton-free electron-trapping feature of titanium dioxide nanoparticles without the characteristic blue color, COMMUNICATIONSCHEMISTRY, 2019, 第 5 作者
(11) Syntheses, Crystal Structures and Catalytic Activities of Two Novel Mn_2Dy_2O_2 Complexes, CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 第 4 作者  通讯作者
(12) Artificial Mn4Ca Clusters with Exchangeable Solvent Molecules Mimicking the Oxygen-Evolving Center in Photosynthesis, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 第 5 作者  通讯作者
(13) A new milestone for photosynthesis, NATIONAL SCIENCE REVIEW, 2018, 第 1 作者  通讯作者
(14) Artificial Mn-4-oxido complexes mimic the oxygen-evolving center in photosynthesis, SCIENCE BULLETIN, 2017, 第 4 作者  通讯作者
(15) Natural and Artificial Mn4Ca Cluster for the Water Splitting Reaction, CHEMSUSCHEM, 2017, 第 5 作者  通讯作者
(16) 人工模拟光合作用水裂解催化中心Mn_4Ca-簇的研究进展, Mimicking the catalytic center of Mn_4Ca-cluster for the water-splitting reaction in photosynthesis, 中国科学. 化学, 2016, 第 4 作者
(17) 自然和人工光合作用水裂解催化剂, Catalysts for Water-Splitting Reaction in Natural and Artificial Photosynthesis, 化学通报, 2016, 第 1 作者
(18) 从自然光合作用到人工光合作用, From natural photosynthesis to artificial photosynthesis, 中国科学. 化学, 2016, 第 1 作者
(19) Synthesis, characterization, and reactivity of a side-on manganese(III)-peroxo complex bearing a pentadentate aminopyridine ligand, DALTON TRANSACTIONS, 2016, 第 3 作者  通讯作者
(20) The first artificial Mn4Ca-cluster mimicking the oxygen-evolving center in photosystem II, SCIENCE CHINA-LIFE SCIENCES, 2015, 第 1 作者  通讯作者
(21) Artificial synthetic (MnCa)-Ca-IV-oxido complexes mimic the oxygen-evolving complex in photosystem II, DALTON TRANSACTIONS, 2015, 第 2 作者  通讯作者
(22) A synthetic Mn4Ca-cluster mimicking the oxygen-evolving center of photosynthesis, SCIENCE, 2015, 第 1 作者  通讯作者
(23) Synthesis, Structure and Catalytic Activity of a Manganese(III) Complex Based on 2-(2-Hydroxyphenyl)-5,6-dichlorobenzimidazole Ligands, CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 第 2 作者  通讯作者
(24) A synthetic model for the oxygen-evolving complex in Sr2+-containing photosystem II, CHEMICAL COMMUNICATIONS, 2014, 第 2 作者  通讯作者
(25) Location and function of the high-affinity chloride in the oxygen-evolving complex - Implications from comparing studies on Cl-/Br-/I--substituted photosystem II prepared using two different methods, JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY, 2014, 第 2 作者  通讯作者
(26) Assignment of the ��_4-O5 atom in catalytic center for water oxidation in photosystem ���, CHINESE SCIENCE BULLETIN, 2013, 第 2 作者
(27) 光系统Ⅱ水氧化中心Mn_4Ca簇中μ_4-O5原子的指认, 科学通报, 2013, 第 2 作者
(28) Assignment of the mu(4)-O5 atom in catalytic center for water oxidation in photosystem II, CHINESE SCIENCE BULLETIN, 2013, 第 2 作者  通讯作者
(29) Sll1466, a glycosyl transferase homolog involved in global cellular regulation and high-light tolerance of Synechocystis PCC6803, BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS, 2011, 第 3 作者
(30) Methanol as a probe to investigate the relationship between the secondary electron donor Tyr(Z) and the substrate water molecules in active photosystem II, CHINESE SCIENCE BULLETIN, 2010, 第 2 作者  通讯作者
(31) 甲醇为探针研究活性光系统Ⅱ次级电子给体TyrZ与底物水分子作用机制, 科学通报, 2010, 第 2 作者
(32) Low-temperature electron transfer suggests two types of Q(A) in intact photosystem II, BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS, 2010, 第 2 作者  通讯作者
(33) Substitution of chloride by bromide modifies the low-temperature tyrosine Z oxidation in active photosystem II, BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS, 2010, 第 2 作者  通讯作者
(34) Probing tyrosine Z oxidation in photosystem II core complex isolated from spinach by EPR at liquid helium temperatures, PHOTOSYNTHESIS RESEARCH, 2009, 第 2 作者  通讯作者
(35) Zinc compounds with or without Zn-Zn bond: Alkali metal reduction of LZnCl2 (L = alpha-diimine ligands), DALTON TRANSACTIONS, 2009, 第 5 作者
(36) Acceptor side effects on the electron transfer at cryogenic temperatures in intact photosystem II, BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS, 2008, 第 2 作者  通讯作者
(37) Aggregation of tetranuclear Mn building blocks with alkali ion. Syntheses, crystal structures and chemical behaviors of monomer, dimer and polymer containing Mn4(mu(3)-O)(2)(8+) units, DALTON TRANSACTIONS, 2007, 第 7 作者
(38) Isotopic oxygen exchange and EPR studies of superoxide species on the SrF2/La2O3 catalyst, CATALYSISLETTERS, 2007, 第 4 作者
(39) Intramolecular electron transfer within the substituted tetrathiafulvalene-quinone dyads: facilitated by metal ion and photomodulation in the presence of spiropyran, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 第 5 作者
(40) Three-stage refolding/unfolding of the dual-color beta-subunit in R-phycocyanin from Polysiphonia urceolata, BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS, 2007, 第 3 作者
(41) Recognition of various biomolecules by the environment-sensitive spectral responses of hypocrellin B, PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2007, 第 3 作者
(42) Low-barrier hydrogen bond plays key role in active photosystem II - A new model for photosynthetic water oxidation, BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS, 2007, 第 1 作者  通讯作者
(43) Cr介质中生长的棕色固氮菌突变株UW3的固氮酶CrFe蛋白的特性, 科学通报, 2006, 第 3 作者
(44) Interaction between tyrosine(Z) and substrate water in active photosystem II, BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS, 2006, 第 1 作者  通讯作者
(45) 缺失nifZ棕色固氮菌突变株(DJ194)钼铁蛋白的金属原子簇的组成与分布, 科学通报, 2005, 第 2 作者
(46) 棕色固氮菌nifE缺失突变株(DJ35)钼铁蛋白的特性, 科学通报, 2005, 第 3 作者
(47) Characterization of a FeMo cofactor-deficient MoFe protein from a nifE-deleted strain (DJ35) of Azotobacter vinelandii, Characterization of a FeMo cofactor-deficient MoFe protein from a nifE-deleted strain (DJ35) of Azotobacter vinelandii, 中国科学通报:英文版, 2005, 第 3 作者

科研活动

   
科研项目
( 1 ) 光合作用蛋白质机器中电子转移和水裂解催化反应的人工模拟研究, 负责人, 国家任务, 2017-07--2022-06