基本信息
刘元红  女  博导  中国科学院上海有机化学研究所
电子邮件: yhliu@sioc.ac.cn
通信地址: 上海市零陵路345号
邮政编码: 200032

研究领域

   

招生信息

   
招生专业
070303-有机化学
招生方向
过渡金属催化的有机反应;杂环化合物的合成

教育背景

1997-04--2000-03   北海道大学   博士
1992-09--1995-07   郑州大学   硕士
1988-09--1992-07   郑州大学   学士
学历
   
学位
   

工作经历

   
工作简历
2003-10~现在, 中科院上海有机所, 研究员,百人计划获得者
2000-04~2003-09,北海道大学催化研究中心, JSPS,COE研究员,博士后研究员
1997-04~2000-03,北海道大学, 博士
1992-09~1995-07,郑州大学, 硕士
1988-09~1992-07,郑州大学, 学士
社会兼职
   

教授课程

物理有机化学

专利与奖励

   
奖励信息
(1) Thieme化学杂志奖, , 其他, 2007
(2) 日本化学会杰出报告奖, , 其他, 2007
专利成果
( 1 ) 3-位取代中氮茚(Indolizine)类化合物的高效合成方法, 2006, 第 1 作者, 专利号: ZL200610117996.X
( 2 ) 多环芳烃类化合物、合成方法及其用途, 2007, 第 1 作者, 专利号: 200710046011.3

出版信息

   
发表论文
(1) 1. Gold-Catalyzed Synthesis of Tropone and Its Analogues via Oxidative Ring Expansion of Alkynyl Quinols., Org. Lett., 2015, 第 11 作者
(2) 4. Reactions of Zirconocene−1-Aza-1,3-diene Complexes with Acyl Cyanides: Substrate-Dependent Synthesis of Acyl- or Non-Acyl-Substituted Pyrroles., Organometallics, 2015, 第 11 作者
(3) 2. Cyano-Schmittel Cyclization through Base-Induced Propargyl-Allenyl Isomerization: Highly Modular Synthesis of Pyridine-Fused Aromatic Derivatives., Chem. Eur. J., 2015, 第 11 作者
(4) 5. Cp2TiCl2-catalyzed cis-hydroalumination of propargylic amines with Red-Al: stereoselective synthesis of Z-configured allylic amines, Chem. Commun, 2015, 第 11 作者
(5) 6. Palladium-catalyzed highly efficient synthesis of functionalized indolizines via cross-coupling/cycloisomerization cascade., Chem. Commun., 2015, 第 11 作者
(6) 7. Synthesis of Multiple-Substituted Pyrroles via Gold(I)-Catalyzed Hydroamination/Cyclization Cascade, Org. Lett., 2015, 第 11 作者
(7) 1. Gold-Catalyzed Oxidative Ring Expansion of 2-Alkynyl-1,2-Dihydropyridines or -quinolines: Highly Efficient Synthesis of Functionalized Azepine or Benzazepine Scaffolds, Angew. Chem. Int. Ed., 2015, 第 11 作者
(8) 2. Zirconium-Mediated Multicomponent Reactions of 1,3-Butadiynes with Ylidenemalononitriles to Form Functionalized 1,8-Naphthyridine and Cyclopenta[b]pyridine Derivatives, Chem. Eur. J., 2015, 第 11 作者
(9) 3. Gold(I)-Catalyzed 1,2-Acyloxy Migration/[3+2] Cycloaddition of 1,6-Diynes with an Ynamide Propargyl Ester Moiety: Highly Efficient Synthesis of Functionalized Cyclopenta[b]indoles, Chem. Eur. J. , 2015, 第 11 作者
(10) 4. Gold(I)-Catalyzed 1,4- and/or 1,5-Heteroaryl Migration Reactions through Regiocontrolled Cyclizations, Chem. Eur. J. , 2015, 第 11 作者
(11) 5. Insertion of Nitriles into Zirconocene 1-aza-1,3-diene Complexes: Chemoselective Synthesis of N–H and N-Substituted Pyrroles,  Angew. Chem. Int. Ed., 2014, 第 11 作者
(12) 6. Gold(I)-Catalyzed Furan-yne Cyclizations Involving 1,2-Rearrangement: Efficient Synthesis of Functionalized 1-Naphthols and Its Application to the Synthesis of Wailupemycin G. , Chem. Eur. J., 2014, 第 11 作者
(13) 7. Gold-Catalyzed Cascade Reactions of Furan-ynes with External Nucleophiles Consisting of a 1,2-Rearrangement: Straightforward Synthesis of Multi-Substituted Benzo[b]furans, Chem. Eur. J., 2014, 第 11 作者
(14) 8. Gold-Catalyzed Oxidative Reactions of Propargylic Carbonates Involving 1,2-Carbonate Migration: Stereoselective Synthesis of Functionalized Alkenes., J. Org. Chem., 2014, 第 11 作者
(15) 9. Titanium-mediated cross-coupling reactions of 1,3-butadiynes with α-iminonitriles to 3-aminopyrroles: observation of an imino aza-Nazarov cyclization,  Org. Chem. Front., 2014, 第 11 作者
(16) Gold-Catalyzed Ring Opening Cycloamination of Aziridine-Ynes with Nucleophiles: Regio- and Stereoselective Construction of Highly Functionalized 3-Benzazepine Skeletons.,  Chem. Eur. J. , 2011, 第 11 作者
(17) Gold-Catalyzed Approach to Multisubstituted Fulvenes via Cycloisomerization of Furan/Ynes,  J. Org. Chem., 2011, 第 11 作者
(18) Gold-Catalyzed Cascade Friedel-Crafts/Furan-Yne Cyclization/Heteroenyne Metathesis for the Highly Efficient Construction of Phenanthrene Derivatives. , Adv. Synth. Catal., 2011, 第 11 作者
(19) Highly Efficient Synthesis of Multisubstituted 2-Acyl Furans via PIFA/I2 Mediated Oxidative Cycloisomerization of cis-2-En-4-yn-1-ols., Synlett, 2011, 第 11 作者
(20) 2. One-Pot Synthesis of Indole-Fused Scaffolds via Gold-Catalyzed Tandem Annulation Reactions of 1,2-Bis(alkynyl)-2-en-1-ones with Indoles, J. Org. Chem., 2011, 第 11 作者
(21) 3. Gold-Catalyzed Deacylative Cycloisomerization Reactions of 3-Acylindole/ynes: A New Approach for Carbazole Synthesis, Org. Lett. , 2011, 第 11 作者
(22) 4. Grignard Reagent Acceleration of the Intramolecular Diels-Alder Reaction of Furans with Unactivated Alkynes: Toward Structurally Complex Oxabicyclic Alkenes., Chem. Eur. J. , 2011, 第 11 作者
(23) Highly Stereoselective Synthesis of Trisubstituted cis-[3]Cumulenols from Alkynylated Oxatitanacycles in the Presence of Lewis acids., Organometallics , 2010, 第 11 作者
(24) Gold-Catalyzed Cyclization of Alkynylaziridines as An Efficient Approach Toward Functionalized N-Phth Pyrroles., J Org. Chem., 2010, 第 11 作者
(25) Aldehyde Addition to 1,3-Butadiyne-Derived Zirconacyclocumulenes:Stereoselective Synthesis of cis-[3]Cumulenols.,  Organometallics, 2010, 第 11 作者
(26) Gold-Catalyzed Intramolecular Indole/Alkyne Cyclization Cascades through a Heterolytic Fragmentation: 1,5-Indole Migration and Allenylation., J. Org. Chem. , 2010, 第 11 作者
(27) Gold-Catalyzed Benzannulation of 3-Alkoxy-1,5-enynes: Access to Functionalized Benzenes., J. Org. Chem., 2010, 第 11 作者
(28) Stereoselective synthesis of enynones via base-catalyzed isomerization of 1,5-disubstituted-2,4-pentadiynyl silyl ethers or their alcohol derivatives. , Org. Biomol. Chem., 2010, 第 11 作者
(29) Generation of Allenic/Propargylic Zirconium Complexes and Subsequent Cross-Coupling Reactions: A Facile Synthesis of Multisubstituted Allenes., J Org. Chem,, 2009, 第 11 作者
(30) Diverse Reactivity of Zirconacyclocumulenes Derived from Coupling of Benzynezirconocenes with 1,3-Butadiynes towards Acyl Cyanides: Synthesis of Indeno[2,1-b]pyrroles or [3]Cumulenones., Angew. Chem. Int. Ed., 2009, 第 11 作者
(31) Gold-Catalyzed Cascade Friedel-Crafts/Furan-Alkyne Cycloisomerizations for the Highly Efficient Synthesis of Arylated (Z)-Enones or –Enals., Org. Lett., 2009, 第 11 作者
(32) Stereoselective Synthesis of β-Hydroxyallenes with Multiple Contiguous tereogenic Centers via Aldehyde Addition to alpha-alkenyl-Substituted zirconacyclopentenes. ,  J. Org. Chem. , 2009, 第 11 作者
(33) An Efficient Domino Approach for the Synthesis of Multisubstituted Pyrroles via Gold/Silver-Catalyzed Amination/Cycloisomerization of (Z)-2-En-4-yn-1-ols, Adv.Synth. Catal. , 2009, 第 11 作者
(34) New Synthetic Approach for the Construction of Multi-Substituted 2-Acyl Furans via IBX-Mediated Cascade Oxidation/Cyclization of cis-2-En-4-yn-1-ols. , Chem. Eur. J. , 2008, 第 11 作者
发表著作
   

科研活动

   
科研项目
( 1 ) 国家自然科学基金委杰出青年基金, 主持, 国家级, 2012-01--2015-01
( 2 ) 金催化的若干新型串联反应研究, 主持, 国家级, 2014-01--2017-12
( 3 ) 化学键活化与可控性重组研究, 参与, 国家级, 2015-01--2017-12
( 4 ) 金催化的扩环反应研究, 主持, 国家级, 2016-01--2019-12
参与会议
(1)Versatile Reaction Modes of a-Functionalized Zirconacycles Derived by Coupling Reactions with 1,3-Butadiynes or Enynes   第十六届全国金属有机化学学术讨论会    刘元红   2010-10-22

合作情况

   
项目协作单位
   

指导学生