吕海燕  女  教授 博导  化学科学学院
电子邮件: haiyanlu@ucas.ac.cn
通信地址: 北京市玉泉路甲19号 中国科学院研究生院
邮政编码: 100049

研究领域

1. 螺烯类分子的合成及其性能研究

2. 热激活延迟荧光分子材料的合成及其OLED器件应用

3. 功能性大环与芳香带分子的合成与性能研究

招生信息

   
招生专业
070303-有机化学
招生方向
有机合成及功能材料

教育背景

   
学历

2003.9- 2006.6 博士, 中国科学院化学研究所
1998.9- 2001.6 硕士, 美国新墨西哥大学化学系(University of New Mexico, USA),
1987.9- 1991.7 学士, 安徽师范大学化学系

教授课程

过渡金属有机化学
有机化学实验(材料专业)
有机化学实验(生物专业)
有机化学实验
有机化学实验(本科)
有机合成方法及应用
高等有机合成
文献阅读
高等有机及高分子化学合成与分离实验

专利与奖励

1.《高等有机及高分子化学合成与分离实验》获得2007-2008学年的校优秀课程
2
. 作为主要完成人之一获得中国科学院教学成果二等奖
     《化学教学实验课程及教学实验室建设》杨镜奎,向军辉,何裕建,曹洁,吕海燕 
3.
《高等有机及高分子化学合成与分离实验》获得2009-2010学年的院系优秀课程 
4.
《过渡金属有机化学》获得2010-2011学年的校优秀课程。 
5.
《过渡金属有机化学》获得2011-2012学年的院系优秀课程。 
6.
《高等有机及高分子化学合成与分离实验》获得2012-2013学年的校优秀课程 

7. 《过渡金属有机化学》获得2019-2020学年的院系优秀课程。

 

出版信息

第一作者或通讯作者

1.   Advances in circularly polarized luminescent materials based on axially chiral compounds, J. Photochem. & Photobio., C: Photochem. Rev. 202250, 100500.

2.   Chiral Thermally Activated Delayed Fluorescence-Active Macrocycles Displaying Efficient Circularly Polarized ElectroluminescenceCCS Chem. 2022178, 10832

3.      Quinoline-based TADF emitters exhibiting aggregation-induced emission for efficient non-doped organic light-emitting diodesMater. Chem. Front.2021, 5, 834

4.      A Green Fluorescent Nitrogen-Doped Aromatic Belt Containing a [6]Cycloparaphenylene SkeletonAngew. Chem. Int. Ed. 2021, 60, 15291 –15295

5.      Axially chiral thermally activated delayed fluorescent emitter with dual emitting core for highly efficient organic light-emitting diodeChem. Commun., 202056, 9380

6.      Sign inversions of circularly polarized luminescence for helical compounds by chemically fine-tuning operations, Chem. Commun. 2020, 56, 1863-1866.

7.      Naphthyridine-based thermally activated delayed fluorescence emitters for highly efficient blue OLEDs, Dyes and Pigments2020178 108324

8.      Advances in helicene derivatives with circularly polarized luminescenceChem. Commun.2019, 55, 13793 - 13803

9.      Novel oxacalix[2]arene[2]triazines with thermally activated delayed fluorescence and aggregationinduced emission propertiesChem. Commun., 2019, 55, 9559 

10.   Naphthyridine-based thermally activated delayed fluorescence emitters for multi-color organic light-emitting diodes with low efficiency roll-offJ.Mater. Chem. C2019, 7, 4673

11.   1,8-Naphthalimide-based circularly polarized TADF enantiomers as the emitters for efficient orange-red OLEDsOrganic Electronics20197071–77

12.   Phthalimide-based ‘‘D–N–A’’ emitters with thermally activated delayed fluorescence and isomer-dependent room-temperature phosphorescence propertiesChem. Commun., 2019, 55, 12172

13.   Helicene-Based Illusory Chiral Supramolecular Expression of the Penrose Stairs: Chiroptical Property and Narcissistic Self-Sorting, Eur. J. Inorg. Chem. 2019, 13, 1847–1853.

14.   Metal-free construction of contiguous quaternary stereocentres with a polycyclic frameworkChem. Commun.2019, 55, 4631

15.   Synthesis, chiroptical properties, and self-assembled nanoparticles of chiral conjugated polymers based on optically stable helical aromatic esters, RSC Adv.2018, 8, 1014–1021

16.   [5]Helicene derivatives containing aromatic imide moiety: synthesis, structure, and photophysical properties, J. Photochem. Photobio. A: Chem. 2018, 355, 408–413

17.   Insights into the effect of donor ability on photophysical properties of dihydroindeno[2,1c]fluorene-based imide derivatives Phys.Chem.Chem.Phys.2018, 20, 7514

18.   Chiral Nanoparticles with Full-Color and White CPL Properties Based on Optically Stable Helical Aromatic Imide Enantiomers, ACS Applied Materials & Interfaces 2018, 10(9), 8225–8230.

19.   Intense blue circularly polarized luminescence from helical aromatic esters, Chem. Commun. 2017, 53(45), 6093-6096.

20.   A new thioimide-based fluorescent ‘turn-on’ and chromogenic chemodosimeter in acetonitrile and its nanoparticles in water for highly selective and sensitive detection of Hg2+, Chin. J. Chem. 2017, 35(4), 435-441.

21.   Synthesis, Structures, and Photophysical Properties of Difuro-Fused Tetrahydro[5]helicene Imide Derivatives, Asian J. Org. Chem. 2016, 5, 1518–1524.

22.   Benzo[5]helicene-based conjugated polymers: synthesis, photophysical properties, and application for the detection of nitroaromatic explosives, Polym. Chem. 20167, 310–318. (back cover paper)

23.   Helical aromatic imide based enantiomers with full-color circularly polarized luminescence, Chem. Commun., 201652, 9921-9924.

24.   Dialkoxybenzo[j]fluoranthenes: synthesis, structures, photophysical properties, and optical waveguide application, RSC Adv. 20155, 18609–18614.

25.   A dinaphtho[8,1,2-cde:2’,1’,8’-uva]pentacene derivative and analogues: synthesis, structures, photophysical and electrochemical properties, Org. Biomol. Chem. 201513, 7628–7632.

26.   Tetrahydro[5]helicene-based dye with remarkable and reversible acid/base stimulated fluorescence switching properties in solution and solid state, Dyes and Pigments2015120, 184-189.

27.   Tetrahydro[5]helicene-based full-color emission dyes in both solution and solid state: synthesis, structures, photophysical properties and optical waveguide application, J. Mater. Chem. C 20142(39), 8373–8380.

28.   Tetrahydro[5]helicene thioimide-based fluorescent and chromogenic chemodosimeter for highly selective and sensitive detection of Hg2+Sensors & Actuators: B. Chem. 2014202, 583–587.

29.   Dihydroindeno[2,1-c]fluorine-Based Imide Dyes: Synthesis, Structures, Photophysical and Electrochemical Properties, J. Org. Chem. 201479(5), 2139−2147.

30.   Tetrahydro[5]helicene-Based Nanoparticles for Structure-Dependent Cell Fluorescent Imaging, Adv. Funct. Mater. 201424(28), 4405–4412 (front cover paper).

31.   Tetrahydro[5]helicene-based imide dyes with intense fluorescence in both solution and solid state, Chem. Commun. 201450(23), 2993−2995 (inside front cover paper).

32.   A Stimulus-Response and Self-Healing Supramolecular Polymer, Macromol. Chem. Phys. 2013, 214, 1596−1601.

33.   Synthesis, Structures and Optical Properties of Aza[4]helicenes, Eur. J. Org. Chem. 201315, 3059–3066.

34.   Simple, efficient and selective colorimetric sensors for naked eye detection of Hg2+, Cu2+ and Fe3+RSC Adv. 20122(10), 4415–4420.

35.   Turn-On Fluorescent Sensor for Selective Detection of Zn2+, Cd2+, and Hg2+ in Water, J. Org. Chem. 201277 (7), 3670–3673.

36.   Sulfonylrhodaminehydrazide: A sensitive and selective chromogenicand fluorescent chemodosimeter for copper ion in aqueous media, Dyes and Pigments201188(3), 257-261.

37.   Highly sensitive and selective turn-on fluorescent chemosensor for Pb2+ and Hg2+ based on a rhodamine–phenylurea conjugate, Chem. Commun. 201046(21), 3765–3767.

38.   Synthesis, Structure and Redox Property of a New Tetrathiafulvalene Based Macrocyclic Compound, Chin. J. Org. Chem. 200929(2), 234-238.

39.   Highly Selective Fluorescence Detection for Mercury (II) Ions in Aqueous Solution Using Water-Soluble Conjugated Polyelectrolytes, Macromol. Rapid Commun. 2008, 29(17), 1467–1471.   

40.   N-(2-Nitrophenylsulfonyl)-N-(4-nitrophenylsulfonyl)methylamine, Acta Cryst2008, E64, 1885.  

41.   Highly Effective Phosphate Electrochemical Sensor Based on Tetrathiafulvalene. Chem. Commun. 2005, 38, 4777–4779. (Highlighted as cover picture 封面文章)   

42.   A Novel Multisignaling Optical-Electrochemical Chemosensor for Anions Based on Tetrathiafulvalene, Org. Lett. 2005, 7(21), 4629–4632.

43.   A Novel Approach to the Synthesis of Amino-Sugars. Routes to Selectively Protected 3-Amino-3-deoxy- aldopentoses Based on Pyridium Salt Photochemistry, J. Org. Chem. 2002, 67(10), 3525–3528.

44.   A Concise Synthesis of the (-)-AllosamizolineAminocyclopentitol Based on Pyridinium Salt PhotochemistryTetrahedron Lett. 2001, 42(29), 4755–4757.

 

科研活动

   
科研项目
( 1 ) 多官能团化螺烯和脱氢螺烯的合成、反应及其性质研究 (项目批准号:21072220), 主持, 国家级, 2011-01--2013-12
( 2 ) 基于四硫富瓦烯化学传感器的合成与性质研究, 主持, 研究所(学校), 2008-11--2011-11
( 3 ) 螺烯及其衍生物的合成与性质研究, 主持, 市地级, 2010-06--2012-11
( 4 ) 基于芳酰亚胺新型有机共轭分子的合成、衍生化及其应用(项目批准号:21272264), 主持, 国家级, 2013-01--2016-12
( 5 ) 基于螺烯荧光纳米染料的合成及其在细胞核成像中应用, 主持, 市地级, 2013-10--2015-09
( 6 ) 基于螺烯手性受体的合成及其在手性分子识别与荧光传感中应用, 主持, 国家级, 2017-01--2020-12
( 7 ) TADF功能化大环与分子笼的合成及其性能研究, 主持, 国家级, 2020-01--2023-12

指导学生

已指导学生

李猛  硕士研究生  070303-有机化学  

刘瑞丽  硕士研究生  070303-有机化学  

郑元辉  硕士研究生  070303-有机化学  

李爽  硕士研究生  085216-化学工程  

李洋洋  硕士研究生  070303-有机化学  

李骁骏  硕士研究生  070303-有机化学  

周丽丽  硕士研究生  070303-有机化学  

何栋强  硕士研究生  070303-有机化学  

牟勇  硕士研究生  070303-有机化学  

张超  硕士研究生  070303-有机化学  

陈诚  硕士研究生  085216-化学工程  

王银凤  硕士研究生  085216-化学工程  

沈伊凡  硕士研究生  070303-有机化学  

赵文龙  硕士研究生  085204-材料工程  

万世鹏  硕士研究生  070303-有机化学  

现指导学生

薛楠  硕士研究生  070303-有机化学  

马计划  硕士研究生  070303-有机化学  

张帆  博士研究生  070303-有机化学  

宋奎柱  硕士研究生  085600-材料与化工  

赵培  博士研究生  085600-材料与化工  

招生方向

有机合成及有机功能材料