基本信息
曹直 男 博导 中国科学院山西煤炭化学研究所
电子邮件: caozhi@sxicc.ac.cn
通信地址: 山西省太原市桃园南路27号煤化所908组
邮政编码:
电子邮件: caozhi@sxicc.ac.cn
通信地址: 山西省太原市桃园南路27号煤化所908组
邮政编码:
招生信息
招生专业
070304-物理化学081701-化学工程081705-工业催化
招生方向
不分方向不分方向工业催化
教育背景
2009-08--2014-05 美国普渡大学 研究生博士学位2007-01--2009-07 美国新墨西哥理工大学 研究生硕士学位2000-09--2004-07 西安交通大学 本科学士学位
工作经历
工作简历
2018-12~现在, 中国科学院山西煤炭化学研究所, 研究员2014-05~2018-08,美国加州大学伯克利分校/劳伦斯伯克利国家实验室, 博士后研究员/高级研究科学家2009-08~2014-05,美国普渡大学, 研究生博士学位2007-01~2009-07,美国新墨西哥理工大学, 研究生硕士学位2004-09~2006-12,中科院山西煤炭化学研究所, 研究助理2000-09~2004-07,西安交通大学, 本科学士学位
出版信息
发表论文
(1) Reactive Intermediate Confinement in Beta Zeolites for the Efficient Aerobic Epoxidation of ��-Olefins, Angewandte Chemie International Edition, 2025, 第 9 作者 通讯作者(2) Regioselective hydroformylation of propene catalysed by rhodium-zeolite, Nature, 2024, (3) Regioselective hydroformylation with subnanometer Rh clusters in MFI zeolite, Nature Catalysis, 2024, (4) Regioselective hydroformylation with subnanometre Rh clusters in MFI zeolite, NATURE CATALYSIS, 2024, 第 11 作者 通讯作者(5) Highly stable Carbon-shell encapsulated Ni-Cu bimetallic catalysts for efficient conversion of levulinic acid to ��-valerolactone, CHEMCATCHEM, 2024, 第 8 作者 通讯作者(6) Tuning the electronic properties of supported Cu catalysts for efficient epoxidation of long-chain ��-olefins, FUEL, 2023, 第 10 作者 通讯作者(7) Tuning the electronic properties of supported Cu catalysts for efficient epoxidation of long-chain alpha-olefins, FUEL, 2023, 第 10 作者 通讯作者(8) Insights into the electronic modulation of bimetallic Pt-Sn cluster for the selective hydrogenation of 1,3-butadiene, CATALYSIS SCIENCE & TECHNOLOGY, 2023, 第 12 作者 通讯作者(9) Deconvolution of metal apportionment in bulk metal-organic frameworks, Science Advances, 2022, (10) Boosting the epoxidation of long-chain linear ��-olefins via bimetallic CoIr composite, Fuel, 2022, (11) Boosting the epoxidation of long-chain linear alpha-olefins via bimetallic CoIr composite, FUEL, 2022, 第 13 作者 通讯作者(12) Visualization of on-surface ethylene polymerization through ethylene insertion, SCIENCE, 2022, 第 9 作者(13) Electrocatalytic synthesis of heterocycles from biomass-derived furfuryl alcohols, NATURE COMMUNICATIONS, 2021, 第 5 作者 通讯作者(14) Development of direct conversion of syngas to unsaturated hydrocarbons based on Fischer-Tropsch route, CHEM, 2021, 第 5 作者(15) Photocatalytic Pinacol C-C Coupling and Jet Fuel Precursor Production on ZnIn2S4 Nanosheets, ACS CATALYSIS, 2020, 第 3 作者(16) Theoretical exploration of intrinsic facet-dependent CH4 and C2 formation on Fe5C2 particle, APPLIED CATALYSIS B-ENVIRONMENTAL, 2020, 第 12 作者(17) Hybrid Catalysts for Artificial Photosynthesis: Merging Approaches from Molecular, Materials, and Biological Catalysis, ACCOUNTS OF CHEMICAL RESEARCH, 2020, 第 3 作者 通讯作者(18) Enhanced electrocatalytic hydrogen oxidation on Ni/NiO/C derived from a Ni���based MOF, Angew. Chem., Int. Ed., 2019, 第 1 作者 通讯作者(19) Copper-Catalyzed Decarboxylative Difluoromethylation, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 第 6 作者 通讯作者(20) Csp(3)-Csp(3) Bond-Forming Reductive Elimination from Well-Defined Copper(III) Complexes, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 第 13 作者 通讯作者(21) Interfacial Sites between Cobalt Nitride and Cobalt Act as Bifunctional Catalysts for Hydrogen Electrochemistry, ACS ENERGY LETTERS, 2019, 第 9 作者 通讯作者(22) Copper-Catalyzed, Chloroamide-Directed Benzylic C-H Difluoromethylation, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 第 11 作者 通讯作者(23) Morphology and Reactivity Evolution of HCP and FCC Ru Nanoparticles under CO Atmosphere, ACS CATALYSIS, 2019, 第 2 作者 通讯作者(24) Enhanced Electrocatalytic Hydrogen Oxidation on Ni/NiO/C Derived from a Nickel-Based Metal-Organic Framework, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 第 8 作者 通讯作者(25) Carbon Permeation: The Prerequisite Elementary Step in Iron-Catalyzed Fischer-Tropsch Synthesis, CATALYSIS LETTERS, 2019, 第 3 作者(26) Microwave Synthesis of Ultrathin Nickel Hydroxide Nanosheets with Iron Incorporation for Electrocatalytic Water Oxidation, ACS APPLIED ENERGY MATERIALS, 2019, 第 5 作者 通讯作者(27) Highly Selective Photocatalytic Valorization of Lignin Model Compounds Using Ultrathin Metal/CdS, ACS CATALYSIS, 2019, 第 6 作者 通讯作者(28) Tuning Gold Nanoparticles with Chelating Ligands for Highly Efficient Electrocatalytic CO2 Reduction, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 第 1 作者(29) A Surface Organometallic Chemistry Approach for Electrochemical Carbon Dioxide Reduction, Angew. Chem., Int. Ed., 2018, 第 1 作者(30) A general synthesis approach for supported bimetallic nanoparticles via surface inorganometallic chemistry, SCIENCE, 2018, 第 4 作者(31) Copper-Mediated Trifluoromethylation of Benzylic Csp(3)-H Bonds, CHEMISTRY-A EUROPEAN JOURNAL, 2018, 第 5 作者(32) Supramolecular Porphyrin Cages Assembled at Molecular-Materials Interfaces for Electrocatalytic CO Reduction, ACS CENTRAL SCIENCE, 2017, 第 2 作者(33) A Molecular Surface Functionalization Approach to Tuning Nanoparticle Electrocatalysts for Carbon Dioxide Reduction, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 第 1 作者(34) Diruthenium-Polyyn-diyl-Diruthenium Wires: Electronic Coupling in the Long Distance Regime, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 第 1 作者(35) Adsorption of NO, NO 2, pyridine and pyrrole on ��-Mo 2C(0 0 0 1): A DFT study, SURFACE SCIENCE, 2007, 第 5 作者(36) Thiophene Adsorption and Activation on MoP(001), ��-Mo2N(100), and Ni2P(001): Density Functional Theory Studies, JOURNAL PHYSICAL CHEMISTRY B, 2006, 第 4 作者(37) Density functional theory study into the adsorption of CO 2, H and CH x ( x = 0���3) as well as C 2H 4 on ��-Mo 2C(0 0 0 1), SURFACE SCIENCE, 2006, 第 4 作者(38) Structure and Energy of Mo27SxCy Clusters: A Density Functional Theory Study, JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 第 2 作者
科研活动
科研项目
( 1 ) 多相催化中的金属-分子筛界面, 负责人, 国家任务, 2025-01--2028-12( 2 ) α-烯烃氢甲酰化新型多相催化剂的研发, 负责人, 中国科学院计划, 2025-01--2026-12( 3 ) 煤基中长链α-烯烃氢甲酰化的催化基础研究, 负责人, 地方任务, 2025-01--2027-12( 4 ) 煤制化学品关键反应和催化基础研究, 负责人, 国家任务, 2023-12--2027-11( 5 ) 顺酐一步加氢生产四氢呋喃的研究, 负责人, 地方任务, 2022-05--2025-05( 6 ) 长链α-烯烃氢甲酰化的催化基础研究, 负责人, 国家任务, 2022-01--2025-12( 7 ) 煤制油产品中 α-烯烃的氢甲酰化应用研究, 负责人, 地方任务, 2021-06--2023-06( 8 ) 国家人才计划青年项目, 负责人, 国家任务, 2021-01--2024-12( 9 ) α-烯烃的环氧化催化技术研究, 负责人, 研究所自主部署, 2021-01--2022-12( 10 ) 中高碳链α-烯烃的氢甲酰化基础研究, 负责人, 研究所自主部署, 2020-07--2022-06( 11 ) 煤制油产品中高碳烯烃环氧化高值转化的催化基础研究, 负责人, 国家任务, 2020-01--2023-12( 12 ) 煤制油产品中α-烯烃的环氧化基础研究, 负责人, 研究所自主部署, 2020-01--2021-12( 13 ) 中科院****-“青年俊才”项目(****C类), 负责人, 中国科学院计划, 2019-01--2025-12( 14 ) 碳基能源体系高效清洁转化利用的探索, 负责人, 研究所自主部署, 2019-01--2023-12( 15 ) 山西省****青年项目, 负责人, 地方任务, 2018-01--2023-12
参与会议
(1)Valorization of long-chain linear α-olefins in Fischer-Tropsch synthesis downstream processes 2024-04-21(2)Regioselective hydroformylation of propene with single site Rh catalyst 2023-08-13(3)Conversion of syngas to value-added chemicals: a systematic theoretical and experimental study 2019-08-25(4)Electrocatalytic carbon fixation on molecular-material hybrids 2017-10-29(5)Molecular-materials approaches to tuning nanoparticle electrocatalysts for CO2 reduction 2016-10-26