基本信息

陈祥雨  男  博导  化学科学学院

www.chenxygroup.com/

电子邮件: chenxiangyu20@ucas.ac.cn
通信地址: 北京怀柔区怀北镇怀北庄中国科学院雁栖湖校区
邮政编码: 101408

研究领域

空穴作用促使的光反应,还原偶联

Chen Xiangyu Groupwww.chenxygroup.com/

教育背景

​中国科学院化学研究所   博士 (导师:叶松研究员)
湘潭大学  学士


招生专业
070303-有机化学
招生方向
有机合成,不对称催化,小分子催化,金属有机,自由基化学

主要工作经历

​德国亚琛工业大学, 博士后


奖励

   
奖励信息
(1) Springer 优秀博士论文, 其他, 2016
(2) 中国科学院优秀博士学位论文, 院级, 2015

出版信息

   
近5年代表性论文
[1] 陈祥雨. Visible-Light-Induced Photoreduction of Carborane Phosphonium Salts: Efficient Synthesis of Carborane-Oxindole-Pharmaceutical Hybrids. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2023, e202305088-, [2] Sheng, He, Liu, Qiang, Zhang, BeiBei, Wang, ZhiXiang, Chen, XiangYu. Visible-Light-Induced N-Heterocyclic Carbene-Catalyzed Single Electron Reduction of Mono-Fluoroarenes. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 2023, 62(12): [3] Lu, Yu, Liu, Qiang, Wang, ZhiXiang, Chen, XiangYu. Alkynyl Sulfonium Salts Can Be Employed as Chalcogen-Bonding Catalysts and Generate Alkynyl Radicals under Blue-Light Irradiation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2022, 61(16): http://dx.doi.org/10.1002/anie.202116071.
[4] Chen, KunQuan, Sheng, He, Liu, Qiang, Shao, PanLin, Chen, XiangYu. N-heterocyclic carbene-catalyzed radical reactions. SCIENCE CHINA-CHEMISTRY[J]. 2021, 64(1): 7-16, http://lib.cqvip.com/Qikan/Article/Detail?id=7103812428.
[5] Zhang, ChaoShen, Bao, Lei, Chen, KunQuan, Wang, ZhiXiang, Chen, XiangYu. Photoinduced alpha-Alkenylation of Katritzky Salts: Synthesis of beta,gamma-Unsaturated Esters. ORGANIC LETTERS[J]. 2021, 23(5): 1577-1581, http://dx.doi.org/10.1021/acs.orglett.0c04287.
[6] Chen, KunQuan, Shen, Jie, Wang, ZhiXiang, Chen, XiangYu. A donor-acceptor complex enables the synthesis of E-olefins from alcohols, amines and carboxylic acids. CHEMICALSCIENCE[J]. 2021, 12(19): 6684-6690, https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8132930/.
[7] Zhao, Ruihua, Chen, XiangYu, Wang, ZhiXiang. Insight into the Selective Methylene Oxidation Catalyzed by Mn(CF3-PDP)(SbF6)(2)/H2O2/CH2ClCO2H) System: A DFT Mechanistic Study. ORGANIC LETTERS[J]. 2021, 23(5): 1535-1540, http://dx.doi.org/10.1021/acs.orglett.0c04102.
[8] Liu, Qiang, Wang, ZhiXiang, Chen, XiangYu. Highly enantioselective 1,6-addition of dienolates to coumarins and chromones through N-heterocyclic carbene catalysis. ORGANIC CHEMISTRY FRONTIERS[J]. 2020, 7(22): 3692-3697, https://www.webofscience.com/wos/woscc/full-record/WOS:000588191600012.
[9] Sheng, He, Liu, Qiang, Su, XiaoDi, Lu, Yu, Wang, ZhiXiang, Chen, XiangYu. Visible-Light-Triggered Iodinations Facilitated by Weak Electrostatic Interaction of N-Heterocyclic Carbenes. ORGANIC LETTERS[J]. 2020, 22(18): 7187-7192, http://dx.doi.org/10.1021/acs.orglett.0c02523.
[10] Liu, Zhixiong, Chen, XiangYu. Light-Induced Excited-State Palladium Catalysis for Challenging Couplings. CHEM. 2020, 6(6): 1219-1221, http://dx.doi.org/10.1016/j.chempr.2020.05.015.
[11] Zhang, Chaoshen, Lu, Yu, Zhao, Ruihua, Chen, XiangYu, Wang, ZhiXiang. How does the nickel catalyst control the doubly enantioconvergent coupling of racemic alkyl nucleophiles and electrophiles? The rebound mechanism. ORGANIC CHEMISTRY FRONTIERS[J]. 2020, 7(21): 3411-3419, https://www.webofscience.com/wos/woscc/full-record/WOS:000582936400007.
[12] Liu, Qiang, Zhang, ChaoShen, Sheng, He, Enders, Dieter, Wang, ZhiXiang, Chen, XiangYu. Site-Selective Pyridyl Alkyl Ketone Synthesis from N-Alkenoxypyridiniums through Boekelheide-Type Rearrangements. ORGANIC LETTERS[J]. 2020, 22(14): 5617-5621, http://dx.doi.org/10.1021/acs.orglett.0c01984.
[13] Chen, KunQuan, Wang, ZhiXiang, Chen, XiangYu. Photochemical Decarboxylative C(sp(3))-X Coupling Facilitated by Weak Interaction of N-Heterocyclic Carbene. ORGANIC LETTERS[J]. 2020, 22(20): 8059-8064, http://dx.doi.org/10.1021/acs.orglett.0c03006.
[14] Chen, XiangYu, Gao, ZhongHua, Ye, Song. Bifunctional N-Heterocyclic Carbenes Derived from L-Pyroglutamic Acid and Their Applications in Enantioselective Organocatalysis. ACCOUNTS OF CHEMICAL RESEARCHnull. 2020, 53(3): 690-702, https://www.webofscience.com/wos/woscc/full-record/WOS:000526398000014.
[15] Liu, Qiang, Chen, XiangYu. Dual N-heterocyclic carbene/photocatalysis: a new strategy for radical processes. ORGANIC CHEMISTRY FRONTIERSnull. 2020, 7(15): 2082-2087, http://dx.doi.org/10.1039/d0qo00494d.
[16] Gao Zhonghua. Intramolecular α-Oxygenation of Amines via N-Heterocyclic Carbene-Catalyzed Domino Reaction of Aryl Aldehyde: Experiment and DFT Calculation. CCS Chem.. 2019, [17] Chen, XiangYu, Enders, Dieter. Radical Umpolung: Efficient Options for the Synthesis of 1,4-Dicarbonyl Compounds. ANGEWANDTE CHEMIE-INTERNATIONAL EDITIONnull. 2019, 58(20): 6488-6490, [18] Chen Xiangyu. Arylatin of Axially Chiral Phosphorothioate Salts by Dinuclear PdI Catalysis. ANGEWCHEMINTED. 2019, [19] Chen Xiangyu. N-Heterocyclic Carbene-Catalyzed 1,6-Addition of Homoenolate Equivalent Intermediates: Asymmetric Synthesis of Nonspirocyclic Quaternary Oxindoles. CCS Chem.. 2019, [20] Chen, XiangYu, Liu, Qiang, Chauhan, Pankaj, Enders, Dieter. N-Heterocyclic Carbene Catalysis via Azolium Dienolates: An Efficient Strategy for Remote Enantioselective Functionalizations. ANGEWANDTE CHEMIE-INTERNATIONAL EDITIONnull. 2018, 57(15): 3862-3873, https://www.webofscience.com/wos/woscc/full-record/WOS:000428350200004.
[21] Chen Xiangyu. Asymmetric Synthesis of Spiro-oxindole-ε-lactones through N-Heterocyclic Carbene Catalysis. Org. Lett.. 2018, [22] Liu, Qiang, Chen, XiangYu, Puttreddy, Rakesh, Rissanen, Kari, Enders, Dieter. N-Heterocyclic Carbene Catalyzed Quadruple Domino Reactions: Asymmetric Synthesis of Cyclopentacchromenones. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2018, 57(52): 17100-17103, https://www.doi.org/10.1002/anie.201810402.
[23] Chen Xiangyu. Control of N-Heterocyclic Carbene Catalyzed Reactions of Enals: Asymmetric Synthesis of Oxindole-γ-Amino Acid Derivatives. Angew. Chem. Int. Ed.. 2017, [24] Chen, XiangYu, Liu, Qiang, Chauhan, Pankaj, Li, Sun, Peuronen, Anssi, Rissanen, Kari, Jafari, Ehsan, Enders, Dieter. N-Heterocyclic Carbene Catalyzed 4+2 Annulation of Enals via a Double Vinylogous Michael Addition: Asymmetric Synthesis of 3,5-Diaryl Cyclohexenones. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2017, 56(22): 6241-6245, https://www.doi.org/10.1002/anie.201702881.
[25] XiangYu Chen, KunQuan Chen, DeQun Sun, Song Ye. N-Heterocyclic carbene-catalyzed oxidative 3 + 2 annulation of dioxindoles and enals: cross coupling of homoenolate and enolate † †Electronic supplementary information (ESI) available: Experimental procedures and compound characterizations (PDF). CCDC 1041425 ( 3fb ). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039 Click here for additional data file. Click here for additional data file.. CHEMICAL SCIENCE. 2016, 8(3): 1936-1941, https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5384455/.
[26] Chen, Xiangyu, Ruider, Stefan A, Hartmann, Rolf W, Gonzalez, Leticia, Maulide, Nuno. Metal-Free meta-Selective Alkyne Oxyarylation with Pyridine N-Oxides: Rapid Assembly of Metyrapone Analogues. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2016, 55(49): 15424-15428, https://www.doi.org/10.1002/anie.201607988.
发表著作
(1) New Strategies for N-Heterocyclic Carbenes Catalyzed Annulations, Springer, 2016-01, 第 1 作者

指导学生

已指导学生

盛赫  博士研究生  070303-有机化学  

现指导学生

邱炳昇  硕士研究生  085600-材料与化工  

苏小弟  博士研究生  070303-有机化学  

孙娜娜  硕士研究生  085600-材料与化工  

孟春甫  博士研究生  085600-材料与化工  

靳晨龙  硕士研究生  070303-有机化学  

傅贵英  硕士研究生  085600-材料与化工  

孔浩然  硕士研究生  085600-材料与化工  

唐文鑫  博士研究生  070303-有机化学