空穴作用促使的光反应，还原偶联

Chen Xiangyu Group：www.chenxygroup.com/

​中国科学院化学研究所   博士 （导师：叶松研究员）
湘潭大学  学士

070303-有机化学

有机合成，不对称催化，小分子催化，金属有机，自由基化学

​德国亚琛工业大学, 博士后

   

（1） Springer 优秀博士论文, 其他, 2016
（2） 中国科学院优秀博士学位论文, 院级, 2015

   

（1） Visible-Light-Induced Photoreduction of Carborane Phosphonium Salts: Efficient Synthesis of Carborane-Oxindole-Pharmaceutical Hybrids, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 通讯作者
（2） Visible-Light-Induced N-Heterocyclic Carbene-Catalyzed Single Electron Reduction of Mono-Fluoroarenes, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 通讯作者
（3） Alkynyl Sulfonium Salts Can Be Employed as Chalcogen-Bonding Catalysts and Generate Alkynyl Radicals under Blue-Light Irradiation, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 通讯作者
（4） N-heterocyclic carbene-catalyzed radical reactions, N-heterocyclic carbene-catalyzed radical reactions, SCIENCE CHINA-CHEMISTRY, 2021, 通讯作者
（5） Photoinduced alpha-Alkenylation of Katritzky Salts: Synthesis of beta,gamma-Unsaturated Esters, ORGANIC LETTERS, 2021, 通讯作者
（6） A donor-acceptor complex enables the synthesis of E-olefins from alcohols, amines and carboxylic acids, CHEMICALSCIENCE, 2021, 通讯作者
（7） Insight into the Selective Methylene Oxidation Catalyzed by Mn(CF3-PDP)(SbF6)(2)/H2O2/CH2ClCO2H) System: A DFT Mechanistic Study, ORGANIC LETTERS, 2021, 通讯作者
（8） Highly enantioselective 1,6-addition of dienolates to coumarins and chromones through N-heterocyclic carbene catalysis, ORGANIC CHEMISTRY FRONTIERS, 2020, 通讯作者
（9） Visible-Light-Triggered Iodinations Facilitated by Weak Electrostatic Interaction of N-Heterocyclic Carbenes, ORGANIC LETTERS, 2020, 通讯作者
（10） Light-Induced Excited-State Palladium Catalysis for Challenging Couplings, CHEM, 2020, 通讯作者
（11） How does the nickel catalyst control the doubly enantioconvergent coupling of racemic alkyl nucleophiles and electrophiles? The rebound mechanism, ORGANIC CHEMISTRY FRONTIERS, 2020, 通讯作者
（12） Site-Selective Pyridyl Alkyl Ketone Synthesis from N-Alkenoxypyridiniums through Boekelheide-Type Rearrangements, ORGANIC LETTERS, 2020, 通讯作者
（13） Photochemical Decarboxylative C(sp(3))-X Coupling Facilitated by Weak Interaction of N-Heterocyclic Carbene, ORGANIC LETTERS, 2020, 通讯作者
（14） Dual N-heterocyclic carbene/photocatalysis: a new strategy for radical processes, ORGANIC CHEMISTRY FRONTIERS, 2020, 通讯作者
（15） Bifunctional N-Heterocyclic Carbenes Derived from L-Pyroglutamic Acid and Their Applications in Enantioselective Organocatalysis, ACCOUNTS OF CHEMICAL RESEARCH, 2020, 第 1 作者
（16） Intramolecular α-Oxygenation of Amines via N-Heterocyclic Carbene-Catalyzed Domino Reaction of Aryl Aldehyde: Experiment and DFT Calculation, CCS Chem., 2019, 
（17） Radical Umpolung: Efficient Options for the Synthesis of 1,4-Dicarbonyl Compounds, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 通讯作者
（18） Arylatin of Axially Chiral Phosphorothioate Salts by Dinuclear PdI Catalysis, ANGEWCHEMINTED, 2019, 第 1 作者
（19） N-Heterocyclic Carbene-Catalyzed 1,6-Addition of Homoenolate Equivalent Intermediates: Asymmetric Synthesis of Nonspirocyclic Quaternary Oxindoles, CCS Chem., 2019, 第 1 作者
（20） N‐Heterocyclic Carbene Catalysis via Azolium Dienolates: An Efficient Strategy for Remote Enantioselective Functionalizations, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 第 1 作者
（21） Asymmetric Synthesis of Spiro-oxindole-ε-lactones through N-Heterocyclic Carbene Catalysis, Org. Lett., 2018, 通讯作者
（22） N-Heterocyclic Carbene Catalyzed Quadruple Domino Reactions: Asymmetric Synthesis of Cyclopentacchromenones, ANGEWANDTECHEMIEINTERNATIONALEDITION, 2018, 通讯作者
（23） Control of N-Heterocyclic Carbene Catalyzed Reactions of Enals: Asymmetric Synthesis of Oxindole-γ-Amino Acid Derivatives, Angew. Chem. Int. Ed., 2017, 第 1 作者
（24） N-Heterocyclic Carbene Catalyzed 4+2 Annulation of Enals via a Double Vinylogous Michael Addition: Asymmetric Synthesis of 3,5-Diaryl Cyclohexenones, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 第 1 作者
（25） N-Heterocyclic carbene-catalyzed oxidative 3 + 2 annulation of dioxindoles and enals: cross coupling of homoenolate and enolate † †Electronic supplementary information (ESI) available: Experimental procedures and compound characterizations (PDF). CCDC 1041425 ( 3fb ). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039 Click here for additional data file. Click here for additional data file., CHEMICAL SCIENCE, 2016, 第 1 作者
（26） Metal-Free meta-Selective Alkyne Oxyarylation with Pyridine N-Oxides: Rapid Assembly of Metyrapone Analogues, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 第 1 作者

（1） New Strategies for N-Heterocyclic Carbenes Catalyzed Annulations, Springer, 2016-01, 第 1 作者

已指导学生

盛赫  博士研究生  070303-有机化学  

现指导学生

邱炳昇  硕士研究生  085600-材料与化工  

苏小弟  博士研究生  070303-有机化学  

孙娜娜  硕士研究生  085600-材料与化工  

孟春甫  博士研究生  085600-材料与化工  

靳晨龙  硕士研究生  070303-有机化学  

傅贵英  硕士研究生  085600-材料与化工  

孔浩然  硕士研究生  085600-材料与化工  

唐文鑫  博士研究生  070303-有机化学